Lemon

1.4. ****
Lemonrubyjane Lae Mon Winn
 878

CH3 CH3
345 5
a ⑧ 7 ↓ | I
-
D
21 Y 3 2 7

5-ethyl-3-methyloctane CH3
2-methyl-5-(1,2-dimethyl-propyl)
- nonance

1 2 1

3 1
5
2 1
S

1 -

ethyl -
2,4-dimethyl cyclooctane 6-ethyl-1-methyl-1-cyclohexene

5 ⑥

8765432/ u I

2
3

5-methyl-J-octene-1-yns
acid
4-methyl-benzoic

2 I

34567

3-methyl-3-heptene
iTyyi

eton
an- I
2(2H))3 - X-
1/
-/
NO2
= CH
-

21CH3

By P ↑
IT
↑X
11
+

in product
13 duct- Br
Br

oH OH

↓ 'A
para

eatho r-Y
+

1x
CHICAO_CACHS CACHOO +

is
plas you

⑧
(a, i
e
y

c
=
 ITIcoo
↑
11
-

a
2n +
2520".
p-π conjugation

g.M.
FG. electronegativity

<s4-
Ex

mov: (ii
Fisher rules

① ↑ ⑩:amwel.br:2)gpu
s butandis horizontal 9.87 news:B:sp
③ B
&P48 nog erygi"

unfi

&
⑦ fige converse

18
~10ofm
&
⑬
R nawonagos. "

&
①G ①

S anticlockwise
=

cla S ↑

Note:Room. Itmay.S
 samesatdifferent

same side => configuration differentside -> E configuration

alcohol acid
carboxylic

ether
alkyne

amine amide

arene

Ketone

#
* #
*
#
*

# * *

1 2 3 M

1> 4(2)3
1 2 3 4

3>1>4)2
1 2 4
3

21-334
 X Fc
-

iy,y1
↓
-
CH3
H

methyl groups are in equativial position.

1)I -<Hs gcA3,5 X_,Dv;D,

 1H, 292300:5:97

(132942)
CHCHz
CH3
A H

H
A A
1 HH
CHz

most stable conformer leaststable conformer

CHICH = C CHCH3
=

sp3 sp2 Sp Sp2 sp3

It is chiral

2c 2
+
-
N -
H -
X
D. S =

6 2 30
2x20
+ -

6
=

#x Br
+ + B -

yy

itschiral.
has chiralcenters &
 acid base base acid

p-π conjugation #π conjugation pπ conjugation

compoundA
CH - CH
C =

compoundto
-XCH cicis
KMnOn
CH3(2100H
EXCH-CHzH, (
+

-> = 0
=

NaNHz

I IX cNa c+bE
+

CH
= > CH c=
CH
-

=
-
c =

↳cH,cl
CCH3
#CH
- C =

compound
 1, . I

2
1

1-chloro-4-bromo butane

2 oxacyclopentanone

12 43 21

1
2-butenaL

2,4-dimethylphenol

1234567

2-methyl cyclohexanone 2-chloro-4,5-dimethyldeptane

benzoic anhydride 3-nitzaniline

[ -32/

4.oxa pentanoic acid methanoate

phenyl
 2
3
-
↓

2 2
7
3

5-chloro-2-cyclopentenol
acid
3-ethylbeneric

3
1

4-ethyl-2-methyl-1.A-pyrvole N-methylcyclohexanamine

2
9

chloride
2naphthyl ethanoyl

THe CHO C001

CHz
= CH

! CsHgOH CHzCHzI
+

CHzcHcHz

CH CH2CHs

(*Fc00H
-N -

CHzCH CHCHON0z
=
 NCCHsY2
↓ w=0

HFT
oNa

7- (20

CHzCH [HCH0
=

CH3 COOH CO2

+

CHzCHzCHCHCOH
0H

(H,b -

CH3
kN

NH2

Bry|Br
*
CATCHzCHCH
CA3 H
& -

c C =

+3 +3

CH3CONHCH3

NTENCl

#=
 CHIC
<H3

CHICH CHCH3
NTCCHzOH

CHzCH CHCH3
=

=
-

Br

11Ason, proveto ·*NonpreBINHaw wawoNENsaTO Re

beBy

(a))(d) > (c))(b)

·NH2

Te
NH2 NH2
=
*** #IXwoz
sing ·magoza
(

M
-

(c))(d)>(b))(a)ot
1811 t potin 1x
x))(d))(a))(b)

3
primary neice:1) i)
-

() > (b) (a)

(a))(c))(b)

sucrose

(b))(a))(c)

(a)
 (b) (d) (a)

Lysine migrates electrophoresis pH

at 7.0.
cathode
to on
paper

functional isomers

epimers

anomers