Beaconhouse School System

(Cantt Campus, Lahore)

Name: ……………………………………. Class Test: Molar calculations/ Stoichiometric Calculations Class/Section:……..………..

1 Two different hydrocarbons each contain the same percentage by mass of hydrogen.5070/11/M/J/10/Q#10

It follows that they have the same

A empirical formula.
B number of isomers.
C relative molecular mass.
D structural formula.

2 What is the mass of one mole of carbon-12? 5070/12/M/J/10/Q#10

A 0.012 g B 0.024 g C 1g D 12 g

3
3 What is the concentration of iodine molecules, I2, in a solution containing 2.54 g of iodine in 250 cm of solution?
5070/11/O/N/10/Q#11

3 3 3 3
A 0.01 mol / dm B 0.02 mol / dm C 0.04 mol / dm D 0.08 mol / dm

4 What is the mass of oxygen contained in 72 g of pure water? 5070/11/M/J/11/Q#4

[Relative atomic masses: H = 1; O = 16]

A 16 g B 32 g C 64 g D 70 g

5 The empirical formula of a liquid compound is C2H4O. 5070/11/M/J/11/Q#10

To find the empirical formula, it is necessary to know the

A density of the compound.

B percentage composition of the compound.
C relative molecular mass of the compound.
D volume occupied by 1 mole of the compound.

6 The equation for the reaction between calcium carbonate and hydrochloric acid is shown. 5070/11/M/J/11/Q#9

CaCO3(s) + 2HCl (aq) → CaCl 2(aq) + H2O(l) + CO2(g)

3
How many moles of calcium carbonate will give 24 cm of carbon dioxide when reacted with an excess of
the acid?
3
(Assume one mole of carbon dioxide occupies 24 dm .)

A 1 mol B 0.1 mol C 0.01 mol D 0.001 mol

7 What is the ratio of the number of molecules in 71 g of gaseous chlorine to the number of molecules in 2 g of
gaseous hydrogen? [Relative atomic masses Ar (atomic weights): H, 1: Cl, 35.5] 5070/11/O/N/11/Q#11

A 1:1 B 1:2 C 2:1 D 71 : 2

 CHEMISTRY BSS- CC

8 What is the relative molecular mass Mr of CuSO4.5H2O? 5070/11/O/N/11/Q#12

A 160 B 178 C 186 D 250

3 3 3
9 15.0 cm of 1.0 mol / dm potassium hydroxide just neutralise 20.0cm of a solution of nitric acid.

What is the concentration of the acid? 5070/11/O/N/12/Q#9

3
A 0.75 mol / dm B
3
1.0 mol / dm C 1.5
3
mol / dm D 7.5 mol
3
/ dm
10 The equation for the burning of hydrogen in oxygen is shown. 5070/11/O/N/12/Q#11

2H2(g) + O2(g) → 2H2O(g)

What does this equation indicate?

A 2 atoms of hydrogen combine with 2 atoms of oxygen.

B 2 g of hydrogen combine with 1g of oxygen.
C 2 moles of steam can be obtained from 0.5 mole of oxygen.
D 2 moles of steam can be obtained from 1 mole of oxygen

11 What has the same mass as 0.25 mol of copper atoms? 5070/12/M/J/12/Q#13

A 0.5 mol of oxygen molecules

B 1 mol of sulfur dioxide molecules
C 1.5 mol of water molecules
D 2 mol of oxygen atoms

12 The equation for the burning of hydrogen in oxygen is shown. 5070/11/O/N/12/Q#11

2H2(g) + O2(g) → 2H2O(g)

What does this equation indicate?

A 2 atoms of hydrogen combine with 2 atoms of oxygen.

B 2 g of hydrogen combine with 1g of oxygen.
C 2 moles of steam can be obtained from 0.5 mole of oxygen.
D 2 moles of steam can be obtained from 1 mole of oxygen

13 The equation for the burning of hydrogen in oxygen is shown. 5070/11/O/N/12/Q#11

2H2(g) + O2(g) → 2H2O(g)

What does this equation indicate?

 CHEMISTRY BSS- CC

D 2 atoms of hydrogen combine with 2 atoms of oxygen.

E 2 g of hydrogen combine with 1g of oxygen.
F 2 moles of steam can be obtained from 0.5 mole of oxygen.
D 2 moles of steam can be obtained from 1 mole of oxygen

14 What has the same mass as 0.25 mol of copper atoms? 5070/12/M/J/12/Q#13

A 0.5 mol of oxygen molecules

B 1 mol of sulfur dioxide molecules

C 1.5 mol of water molecules

D 2 mol of oxygen atoms

3 3 3
15. 15.0 cm of 1.0 mol / dm potassium hydroxide just neutralise 20.0cm of a solution of nitric acid.

```What is the concentration of the acid? 5070/11/O/N/12/Q#9

3
A 0.75 mol / dm
3
B 1.0 mol / dm
3
C 1.5 mol / dm
3
D 7.5 mol / dm

16 At the start of a reaction, a 1.00 dm3 solution contains 0.300 mol of ethanol. 5070/11/M/J/17/Q#20
After 100 seconds the concentration of the ethanol has decreased to 0.296 mol / dm3.
What is the rate of reaction over the first 100 seconds?

A 2.96 10–3mol / dm3/ s

B 3.00 10–5mol / dm3/ s
C 4.00 10–5mol / dm3/ s
D 8.00 10–5mol / dm3/ s

1. 23 g of ethanol, C2H5OH, under acidic

conditions.
How many moles of ethanol can be completely oxidised by one mole of
potassium manganate(VII) under these conditions?

A 0.37 B 0.80 C 1.00 D 1.25

17 The formula for hydrated copper(II) nitrate is Cu(NO3)2.xH2O. It contains 36.5% water of
crystallisation by mass.

What is the value of x?

[Ar: H, 1; N, 14; O, 16; Cu, 64]

A 4 B 5 C 6 D 7
CHEMISTRY BSS- CC

18 25.0 g of hydrated copper(II) sulfate crystals are heated to produce anhydrous copper(II) sulfate
and water vapour.

CuSO4.5H2O(s) → CuSO4(s) + 5H2O(g)

What is the mass of anhydrous copper(II) sulfate formed?

[Mr: CuSO4, 160; H2O, 18]

A 9.0 g B 16.0 g C 22.5 g D 25.0 g

3 3
19 In an experiment, 1 cm of a gaseous hydrocarbon, Z, requires 4 cm of oxygen for complete
3
combustion to give 3 cm of carbon dioxide. All gas volumes are measured at r.t.p.
Which formula represents Z?

A C2H2 B C2H4 C C3H4 D C3H8

20 3 3 3 3
50.0 cm of 0.10 mol / dm silver nitrate, AgNO3, is added to 150.0 cm of 0.05 mol / dm sodium
chloride, NaCl, in a beaker as well as solid silver chloride, what is present in the beaker after
reaction?

A aqueous silver nitrate and aqueous sodium nitrate

B aqueous sodium chloride and aqueous sodium nitrate
C aqueous sodium chloride only
D aqueous sodium nitrate only

21 Nitrogen monoxide and oxygen react to form nitrogen dioxide.

2NO(g) + O2(g) → 2NO2(g)

3
What is the maximum volume of nitrogen dioxide that could be obtained when 1 dm
3
of nitrogen monoxide reacts with 2 dm of oxygen?
3 3 3
A 1 dm B 2 dm C 3 dm D 4 dm3

5070_12_M/J/13_Q#11
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22 One volume of a gaseous element X2 combines with an equal volume of gaseous hydrogen to
form two volumes of a gaseous hydride.

What is the formula for the hydride of X?

A H2X B HX C HX2 D H 2 X2

23 Ammonia is manufactured from nitrogen and hydrogen by the Haber process.

CHEMISTRY BSS- CC

N2(g) + 3H2(g) 2NH3(g)

What is the percentage yield when 60 kg of ammonia is produced from 60kg of hydrogen?

A 5.9% B 17.6% C 35.3% D 50.0%

24 What is the relative molecular mass, Mr, of CuSO4.5H2O?

A 127 B 160 C 178 D 250

25 18 g of water contains the same number of molecules as 5070/12/O/N/13/Q#10

A 18 g of ammonia gas.
B 2 g of hydrogen gas.
C 14 g of nitrogen gas.
D 16 g of oxygen gas.

3 3
26 The complete combustion of 20 cm of a gaseous alkane, X, requires 130 cm of oxygen.
Both volumes were measured at r.t.p. 5070/12/O/N/13/Q#11

What could be the identity of X?

A butane
B ethane
C methane
D propane

27 Sodium hydrogencarbonate decomposes on heating. 5070/12/O/N/13/Q#15

2NaHCO3 → Na2CO3 + H2O + CO2

In an experiment, a 5.0 mol sample of sodium hydrogencarbonate is heated.

Which volume of carbon dioxide, measured at room temperature and pressure, is evolved?
3 3 3 3
A 24 dm B 36 dm C 48 dm D 60 dm

27 One volume of a gaseous element X2 combines with an equal volume of gaseous hydrogen to form
two volumes of a gaseous hydride. 5070/12/M/J/13/Q#11

What is the formula for the hydride of X?

A H2X B HX C HX2 D H 2 X2

28 An element, E, forms a hydride, E H4, which contains 90.0% by mass of E. 5070/11/M/J/14/Q#9

If the relative atomic mass of hydrogen is 1, what is the relative atomic mass of E?
CHEMISTRY BSS- CC

A 9 B 36 C 86 D 90

29 A piece of chalk has a mass of 23.0 g. Chalk is impure calcium carbonate. When analysed, the
chalk is found to contain 0.226 moles of pure calcium carbonate. [Mr : CaCO3 , 100] 5070/11/M/J/14/Q#10

What is the percentage purity of the piece of chalk?

A 0.983% B 1.02% C 77.0% D 98.3%

30 5070_12_M/J/13_Q#33
_______________________________________________________________________________________

The proportion of nitrogen by mass in CO(NH2)2 is ……1…… that in 5070/12/M/J/13/Q#33

NH4NO3. The proportion of nitrogen by mole in CO(NH2)2 is ……2…… that in

NH4NO3. Which words correctly complete gaps 1 and 2?

1 2

A equal to equal to
B higher than equal to
C higher than higher than
D lower than lower than

31 The compounds CO(NH2)2 and NH4NO3 are used as fertilisers.

The proportion of nitrogen by mass in CO(NH2)2 is ……1…… that in NH4NO3.

The proportion of nitrogen by mole in CO(NH2)2 is ……2…… that in NH4NO3.

Which words correctly complete gaps 1 and 2?

1 2

A equal to equal to
B higher than equal to
C higher than higher than
D lower than lower than

32 Sulfuric acid and potassium hydroxide can react together to form potassium hydrogensulfate,
KHSO4, and water only.
5070/11/M/J/14/Q#11

Which amounts of the reactants are required?

A equal masses of sulfuric acid and potassium hydroxide

B equal numbers of moles of sulfuric acid and potassium hydroxide
C 1 mol of sulfuric acid to 2 mol of potassium hydroxide
CHEMISTRY BSS- CC

D 2 mol of sulfuric acid to 1 mol of potassium hydroxide

33 Two different hydrocarbons each contain the same percentage by mass of hydrogen. 5070/11/M/J/10/Q#10

It follows that they have the same

A empirical formula.
B number of isomers.
C relative molecular mass.
D structural formula.

3 3 3
34 0.5 mol / dm hydrochloric acid is added gradually to a flask containing 20cm of 2 mol / dm
sodium hydroxide solution.
3
What is the total volume, in cm , of the mixture in the flask when the solution is just neutral?

A 30 B 40 C 60 D 100

5070_12_O/N/12_Q#14
_______________________________________________________________________________________

35 Two of the reactions used in the manufacture of nitric acid, HNO3, are shown.

2NO + O2 → 2NO2

4NO2 + 2H2O + O2 → 4HNO3

What is the maximum number of moles of nitric acid which could be formed from one mole of
nitrogen monoxide, NO?

A 0.5 B 1.0 C 2.0 D 4.0

35 37
36 Two isotopes of chlorine are Cl and Cl .

Using these isotopes, how many different relative molecular masses are possible for the
compound with molecular formula C2H3Cl 3?

A 2 B 3 C 4 D 5

37 Sodium hydrogencarbonate decomposes on heating. 5070/11/O/N/13/Q#11

2NaHCO3 → Na2CO3 + H2O + CO2

In an experiment, a 5.0 mol sample of sodium hydrogencarbonate is heated.

Which volume of carbon dioxide, measured at room temperature and pressure, is evolved?
CHEMISTRY BSS- CC

3 3 3 3
A 24 dm B 36 dm C 48 dm D 60 dm

38 Which statement about the four gases carbon dioxide, CO2, hydrogen, H2, oxygen, O2
and ozone, O3 is correct? 5070/11/O/N/13/Q#13

A One mole of each gas occupies the same volume at a given temperature and pressure.
B Ozone has the fastest rate of diffusion at a given temperature and pressure.
C They are all denser than air.
D They are all elements.

3
39 1.00 dm of ammonia gas is passed over heated copper(II) oxide.

3CuO(s) + 2NH3(g) → 3Cu(s) + N2(g) + 3H2O(l)

What is the volume of nitrogen formed when measured at the same temperature and pressure as
the ammonia?
3 3 3 3
A 0.25 dm B 0.50dm C 1.00dm D 2.00dm
40 A volume of ethane, C2H6, at r.t.p. has a mass of 20 g. 5070/11/O/N/14/Q#10

What is the mass of an equal volume of propene, C3H6, at r.t.p.?

A 20 g B 21 g C 28 g D 42 g

41 Analysis of a sample of an oxide of nitrogen gave the following data. 5070/11/O/N/14/Q#13

● percentage by mass of nitrogen 47%

● percentage by mass of oxygen 53%

What is the empirical formula of this oxide?

[Ar: N, 14; O, 16]

A NO B NO2 C N2O D N2O3

1 It has been suggested that the cars of the future could be powered by fuel cells. One
type of fuel cell uses the chemical reaction between oxygen and hydrogen to produce
electricity.
[2]
IIron reacts with dilute hydrochloric acid to form iron(II) chloride. 5070/21/O/N/13/Q#6 [c] (i) (ii),(iii)

Fe(s) + 2HCl (aq) FeCl2(aq) + H2(g)

3 3
A student added 2.1 g of iron to 50 cm of 0.10 mol / dm hydrochloric acid.

(i) Calculate the amount, in moles, of iron present.

........................................... mol [1]

(ii) Calculate the amount, in moles, of hydrochloric acid present.

........................................... mol [1]

(iii) Calculate the volume of hydrogen formed in this reaction, measured at room
temperature and pressure.

3
...........................................cm [2]

(a) A compound of carbon, hydrogen and chlorine contains 0.48 g of carbon, 0.08 g of
hydrogen and 1.42 g of chlorine.
5070/21/O/N/13/Q#7 [a](i) (ii)
 (i) Deduce the empirical formula of this compound.

(ii) The relative molecular mass of this compound is 99.

Deduce the molecular formula of this compound.

[1]
(e) Sodium hydroxide is an alkali. 5070/21/O/N/13/Q#9 [e], [f] (i) ,(ii), (iii)

Give the formula of the ion present in sodium hydroxide which causes it to be alkaline.

...................................................................................................................................... [1]
3
(f) A student titrated a metal hydroxide with 0.200 mol/dm hydrochloric acid.
3 3 3
It required 12.5 cm of hydrochloric acid to neutralise 25.0 cm of 0.0500 mol / dm
metal hydroxide solution.

(i) Calculate the amount, in moles, of hydrochloric acid used.

........................................... mol [1]

(ii) Calculate the amount, in moles, of metal hydroxide present.

........................................... mol [1]

 2 Dilute hydrofluoric acid reacts with aqueous calcium hydroxide.

2HF(aq) + Ca(OH)2(aq) CaF2(aq) + 2H2O(l)

3 3
What is the minimum volume, in cm , of 0.150 mol / dm Ca(OH)2 required to
react completely with a solution containing 0.200 g of HF?

3
volume of Ca(OH)2(aq) = ................................................... cm [3]

3 Aqueous sodium sulfate can be used to prepare barium sulfate. 5070/21/M/J/17 Q#3 ((c)

2+ 2–
Ba (aq) + SO4 (aq) BaSO4(s)

3 3
In an experiment, 20.0 cm of 0.550 mol / dm of barium nitrate was added to excess
aqueous sodium sulfate.
(i) Calculate the maximum mass of barium sulfate that could be

made. [The relative formula mass of BaSO4 is 233.]

Analysis of a compound Z obtained from the planet Mars showed Z has the following
composition.

element percentage by mass

potassium 39.4
iron 28.3
oxygen 32.3

(a) Show that the empirical formula of Z is K2FeO4.

(b) K
2
 FeO4 can be prepared in the laboratory by the reaction between iron(III) oxide, Fe2O3,
chlorine, Cl2, and potassium hydroxide, KOH.

Fe2O3 + 3Cl2 + 10 KOH 2K2FeO4 + 6KCl + 5H2O

3 –3
A 2.00 g sample of Fe2O3 is added to 20.0 cm of 4.00 mol dm KOH.

(i) Calculate the amount, in moles, of Fe2O3 used.

..................................................................................................................................

............................................................................................................................ [2]

(ii) Calculate the amount, in moles, of KOH used.

..................................................................................................................................

............................................................................................................................ [1]

(iii) Which reagent, Fe2O3 or KOH, is in excess in this reaction?

..................................................................................................................................

Explain your answer.

..................................................................................................................................

............................................................................................................................ [1]

Nitrogen monoxide reacts with carbon monoxide as shown in the equation.5070/21/M/J/10/Q#6 ((e)

2NO + 2CO N2 + 2CO2

23
(f) Using the information that one mole contains 6.02 × 10 particles, calculate the
number of electrons in one mole of NO molecules.

..........................................................................................................................................

.................................................................................................................................... [1]

(b) A factory uses 100 tonnes of ammonia each day to produce 160 tonnes of nitrogen
monoxide, NO. 5070/21/M/J/10/Q#8 (b)
Calculate the percentage yield of nitrogen monoxide.

[3]

percentage yield = .................................[3]

 (ii) A mass of 1.92 g of dry barium sulfate was obtained. Calculate the percentage yield of
barium sulfate.

percentage yield of barium sulfate = ........................ % [1]

(c) Potassium sulfate can be prepared by reacting aqueous potassium hydroxide with dilute sulfuric
acid.

2KOH + H2SO4 K2SO4 + 2H2O

3 3
In an experiment, 20.0 cm of 0.650 mol / dm sulfuric acid is just neutralised by aqueous
potassium hydroxide.
(ii) Calculate the maximum mass of potassium sulfate, K2SO4, that could be prepared.

[The relative formula mass of K2SO4 is 174.]

maximum mass of potassium sulfate = .......................... g [2]

(iii) After crystallisation, 1.72 g of dry potassium sulfate was obtained. Calculate the percentage
yield of potassium sulfate.

percentage yield of potassium sulfate = .......................... % [1]

A3 Barium chloride can be prepared by reacting barium carbonate with dilute hydrochloric acid.

BaCO3 + 2HCl BaCl2 + H2O + CO2

3 3
Excess barium carbonate is reacted with 40.0 cm of 1.50 mol / dm hydrochloric

acid. After purification the percentage yield of barium chloride was 75.0 %.
Calculate the mass of barium chloride prepared.

Give your answer to three significant figures.

[Mr : BaCl2 , 208]

mass of barium chloride .............................................. g [3]

(c) Calculate the volume of oxygen, measured at room temperature and pressure, needed to
completely combust 1.00 tonne of hydrazine.

6
[One tonne is 10 grams. One mole of any gas at room temperature and pressure
3
occupies a volume of 24 dm .] 5070/22/M/J/10/Q#8

3
volume of oxygen = .............................. dm [3]