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Chemistry

Flame Tests
 Clean a platinum or nichrome (a nickel-chromium alloy) wire by dipping it into concentrated hydrochloric acid and
then holding it in a hot Bunsen flame. Repeat this until the wire produces no color in the flame.
 When the wire is clean, moisten it again in the acid and then dip it into a small amount of the solid to be tested
so that some sticks to the wire. Place the wire back in the flame.
 If the flame color is weak, it is often helpful to dip the wire back in the acid and put it back into the flame as if
cleaning it. This should produce a very short but intense flash of color.

 Lithium-Red
 Sodium-Yellow
 Potassium-Lilac
 Calcium-Orange-Red
 Copper-Blue-Green
 Lead-Gray white

Chemical tests
Carbonate ion test
The carbonate ion will react with dilute acids to produce carbon dioxide gas.  The presence of carbon dioxide can then
be confirmed by using limewater.
Halide ion test
 The halides (group VII ions) can be identified using silver nitrate solution.  The sample is first treated with dilute nitric
acid solution to remove hydroxide and carbonate ions which would give a false positive result.  Dilute silver nitrate
solution is then added and the colour of the precipitate formed will indicate which halide is present.
 chloride ions give a white precipitate of silver chloride
 bromide ions give a cream precipitate of silver bromide
 iodide ions give a yellow precipitate of silver iodide
Sulphate ion test
To test for the sulphate ion the sample is first treated with dilute hydrochloric acid to remove carbonate ions which
would give a false positive result.  The sample is then treated with barium chloride solution.  A white precipitate of
barium sulphate is formed if sulphate ions are present.
Rust Prevention
1. Use an Alloy: The use of alloys, like stainless steel, is one of the most common ways to prevent rust, or slow it down.
Stainless steel isn’t suitable or economical for all applications, but it will work for many.
2. Apply Oil: A coating of oil will help to prevent rust or slow it down, since it inhibits moisture from reaching the iron in the metal.
However, an oily surface might be problematic for some tools or machines and poses environmental and human health
concerns.
3. Apply a Dry Coating: Special rust preventative products dry with no residue and form a protective barrier over metal parts and
equipment. These are effective for products in use, in shipping, storage and more.
4. Paint the Metal: A good quality paint will slow down rusting by preventing moisture from reaching the metal.
5. Store Properly: Store metal parts or products in a low-moisture area, or inside a temperature and humidity-controlled
environment to significantly slow down rust. Use of desiccant drying agents in this storage are also helpful.
6. Galvanize: Galvanizing coats iron or steel in zinc to protect from rust. Zinc corrodes at a much slower rate than iron or steel,
so it’s highly effective for slowing rust.
7. Blueing: This process creates a layer of magnetite over the metal to prevent rust. The metal must be regularly oiled to
maintain rust resistance, and it will turn blue or black in the process.
8. Powder Coating: A layer of acrylic, vinyl, epoxy or other substances will prevent moisture from reaching the metal, thereby
preventing rust.
9. VCI Packaging: Vapor Corrosion Inhibitors (VCI) are a type of chemical compound that when infused into various packaging
materials, protect metals by emitting rust eradicating vapors into an enclosed air space to prevent corrosion on a metal
surface.

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