Aits 2223 PT III Jeea Paper 1 Sol

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2023
PART TEST – III
PAPER –1
TEST DATE: 25-12-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. A, B, C
Sol. Rays passing through optical centres passes unreflected. Two images are formed at I1 and I2
For a convex lens,
1 1 1
 
v u f
u = 0.4m f = 0.2m
1 1 1 1 1 1
=     
v u f v 0.4 0.2
1 1 1
  
v 0.2 0.4
1 1
 
v 0.4
(A) v = 0.4 meter.
(B) Number of images formed = 2
 0.4 
(C) Separation between images is 2  3  3  = 12 mm
 0.4 
2. A, B, C, D
2G 2Gdz y
Sol. Gravitational field due to a long wire, dE = =
r r dE
a
P

2 d  r
2Gdz d  dz 

EP  dE.cos  =  r r
 2Gd   2
a

d  z2 

2 z dz z
 a 
EP  4G tan1  
 2d 
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AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 2
3. A, B, C, D
Sol. Q = K
and use basic concept
4. A, B, C
Sol.  = 1m
x
/4 = x
So, x = 25 cm
Max = 125  25 max
Max = 100 cm
y = 3/4 = 75 cm
MIN = 125  75 = 50 cm
y
/2 = distance between nodes = 50 cm
min
5. A, C, D
Sol. (A) O
B
A
(C) O
i
A B i
I
(D) Image is inverted  It should be real
6. A, B, C
Sol. Due to a convex mirror of focal length 2.5 cm and due to a concave mirror having its pole at (2cm,
0) real virtual pair
7. D
Sol. Use basic formulae for the given physical quantities to derive the dimensions.
8. D
Sol. F  20 c m
u  30 c m
uF ( 30)(20) 600
v    60 c m
uF 30  20 10
v 60
m    2
u 30
Real, inverted and magnified
F  40 c m
u  30 c m
3 AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
( 30)( 40)
v  120 c m
30  40
v   120 
m        4
u
   30 
virtual, erect and magnified
u2 u1 u2  u 1
(R)  
v u R
1 3 / 2 1 3 / 2
 
v 20 10
1 3 1
 
v 40 20
1 1 3 23 1
     v  40
v 20 40 40 40
ui v 3 / 2  40 
m      3
ur u 1  20 
Virtual, erect, magnified
uF ( 40)( 40) 1600
(S)v     20
uF 40  40 80
v 20 1
m   
u 40 2
Virtual, erect, diminished.
9. C
Sol. Use momentum conservation during collision. In case of a plane mirror image and object will be
equidistant from the mirror
10. D
Sol. Q   B  E Pr oduct   B  E Re ac tan t Q
Section – B
11. 0.24
N
Sol. Thrust of the ejected water on the tank T  au2 where u is the speed T
of the ejected water from tank 
2gh f
u= 2
1 a A 
Now for the tank to slide, Tsin     mg  T cos  
mg
mg
T
sin    cos 
Ahg 2 a A  
 au2   2

sin    cos  1 a A  sin    cos 
2x a 
 2
 m where x = and m =
1 x A sin    cos 
1  m2  1
 x for   37 and   0.5
m
1  0.25  1
m = 0.5 and x 
0.5
Hence xmin = 0.236
12. 0.12
air
Sol. PC  PD  2gh2  P0  2 gh2
PA  PB  1gh1 B D
and PB  PC (neglecting the density of air as
h2 = 20cm
compared to water or mercury) h1=
 PA  P0  2 gh2  1gh1 Q 10cm
= 105  10 13.8  0.1  1 0.2   103 A

C
5 4 5 2
= 10  10 1.38  0.2  =1.16 10 N / m
Water
Mercury
13. 6.00
Sol. Area of element = wdy
y
dF = wgydy a
wgD2 P0+gh P0
Net force = . . .(1)
2 s
d = wgydy(D  y)
wgD3
= . . .(2)
6
Putting the value of F and  in equation (1) and (2)
D = 10 m and W = 6 m
14. 3.75
Sol. Let V be the total volume of the piece of wood and V be its volume inside the liquid. Since the
wood piece is in equilibrium
Weight of the wood piece = buoyant force
 Vg = V 0 g
 AL  g = AL 0 g
 Now if the wood piece is pressed by distance x below the fluid.
Buoyant force = A(L+x) 0g
Net force = A(L+x)0g – AL g
= AL0g + Ax 0g – A L  g
= A x 0 g in the vertically upward direction (Since A L 0g = AL  g)
 Therefore the pressing force = Ax 0g in the vertically downward direction.
The work done by the pressing force for a small displacement dx
dW = Fdx = Ax 0 g dx
Total work done by the pressing force
L/2
 W =  dW = A 0 g 
0
x dx
2 2
A 0 g L 10  1200  10  (0.5)2
= = = 3.75 J
8 8
15. 13.33
Sol. R = V/I = 12/2 = 6 
R  V I 
Error,  100      100
R  V I 
 0.4 0.2 
   100
 12 2 
= 13.33%
 Resistance = (613.33%)
16. 1.53
Sol. Pitch of the Screw gauge = 5/10 mm = 0.5 mm
Pitch 0.5
Least count =   0.005mm
100 100
Pitch scale reading = PitchN = 0.53 = 1.5 mm
Difference of the cap reading = F~I = 6
Circular scale reading = Difference  L.C = 0.03 mm
Diameter = P.S.R. + C.S.R. = (1.5+0.03)mm = 1.53 mm
17. 0.20
Sol. The focal length of the lens is given by
1 1 1
 
f |v| |u|
substituting the values, we get,
f = 19.9 cm, 20.1 cm, 19.9 cm, 20.2
The average focal length  20.0 cm
The error in a typical measurement:
f u v
 
f 2 u2 v 2
f  0.4 0.4 
 2 
  20  0.01
f  40 (40.5)2 
f = 0.01  20 = 0.2 cm
18. 8.00
GM
Sol. Initial orbital speed v1  …(i)
2R 4RE
GM
Final orbital speed v 2  …(ii) 2RE
4R
vp 
For elliptical orbit va
From COAM E a
v1  2R  v 2  4R c
v Transfer
 v 2  …(iii)
2 Orbit
1 GMm 1 GMm
From COE mv12  = mv22 
2 2R 2 4R
2GM
 v1 
3R
1  2GM GM  1  GM 1 2GM  GMm
So, energy required = m    m  
2  3R 2R  2  4R 4 3R  8R
Chemistry PART – II
Section – A
19. A, C
Sol. Suppose meq. of NaOH and Na2CO3 in the mixture are x and y respectively.
When phenolphthalein is used as indicator
y
x   40  0.1  4 … (i)
2
When methyl orange is used as indicator
x  y  60  0.1  6 … (ii)
Solving Eq. (i) and Eq. (ii), we get
x  2 meq. and y  4 meq.

 Weight of NaOH in the mixture  2  103  40  5  0.4 g . 

Weight of Na2 CO3 in mixture  4  103  53  5  1.06 g 
0.4
Weight % of NaOH in the mixture   100  27.4%
0.4  1.06
20. A, B, D
Sol. 3H2 O
XeO3  6HF
2H2 O
XeF6 XeO2 F2  4HF
H2 O
XeOF4  2HF
21. B, C, D
Sol. Physisorption is multilayer
log (x/m) vs. log (P) log (x/m)

Slope is +ve.
log (P)
Physisorption favour at low temperature and high pressure.
Hphysisorption  Hchemisorption
22. A, B, D
Sol. Mond’s process is used for the purification of Ni.
23. B, C
1  16  2  4
Sol. Mmix  8
1 2
rx Mmix

rmix Mx
8
2  Mx  2
Mx
 Gas is H2 gas.
rH2 4
  2  rx  2 rHe
rHe 2
 (B) and (C) are correct statement.
24. A, C, D
Sol. From given data
1 2
XA  XB 
3 3
Where, XA and XB are mole fraction of A and B in liquid phase.
If the YA and YB are mole fraction of And B in vapour phase.
1
100 
YA PAo X A / Ptotal PAo X A 3 5
 o  o  
YB PB XB / Ptotal PB XB 2 8
80 
3
YA nA W A / MA WA
    A and B are isomer 
YB nB WB / MB WB
5
 Mass ratio of A and B  .
8
1 2
PTotal  PAo X A  PBo XB  100   80 
3 3
260
 torr
3
25. D
Sol. Ziglar Natta  TiCl4  Al  C2 H5 3
Ostwald process  Pt
Contact process  V2 O5
Haber process  Fe
26. B
Sol. Conceptual
27. B
Sol. Application of Boyle’s Law.
28. D
3
Sol. Cr H2 O  
 6
 d2 sp3  Cr 3  d3  t 32g eog
3
Co  CN 
 6
 d2 sp3  Co3  d6  t 62g eog
CuF6 4   sp3 d2  Cu2  d9  t 62g e3g
MnF6 3  sp3 d2  Mn3  d4  t 32g e1g
Section – B
29. 8.00
K SP K SP
Sol.  Ag 
  Anode      1  0.75 M
Br 
 Ag 
  Cathode  0.1  0.8  0.08 M
 Ag 
  Cathode
Ecell  0.0591log
 Ag 
  Anode
 0.08 
0.591  0.0591log  
 K SP / 0.75 
0.75  0.08
10  log
K SP
0.75  0.08
 10 10 
K SP
0.08  0.75
 K SP   6  1012
1010
K SP 6  1012
Solubility   mol / lit.
Br   0.75
 
x  10 12  8  1012
x  8
30. 15.58
RT 0.082  500
Sol. VA    20.5 lit
PA 2
A  B is isothermal path
P V 21.5  2
 VB  A A   10.25 litre
PB 4
B  C is adiabatic path

PB  VC  5
   CP  R
PC  VB  2
5
4  VC  3 3
   CV  R
2  VB  2
5 V 5
log 2  log C 
3 VB 3
V
 log C  log 23/5
VB
VC
 23/5  1.52
VB
 VC  1.52  10.25
= 15.58 litre
31. 729.00
40 3
  NA  a3 6.022
 6.022  1023  6  108  
Sol. MAgX  
4 4
 216 g / mole
 MX  216  108  108 g / mole
If all atoms along one body diagonal have been removed, the formula of unit cell
 Ag4 1 X 1  Ag3 X15
4
4 4
15
 Mass of 1 mole of these unit cell  108  3  108  = 729.00
4
32. 4.35
Sol. Number of equivalent of HCl used = Number equivalent of CaCl2 obtained = Number of
600  0.1
equivalent of plaster of paris can form   0.06
1000
 1  Mol.wt. 145
Equivalent weight of plaster of paris  CaSO 4 . H2 O   
 2  2 2
1 145
 Maximum weight of CaSO4 . H2 O that can be obtained  0.06   4.35 g .
2 2
33. 6.25
1  1 1 1
Sol.      S cm 1
R A 50 1 50
1
 1000
m  50  100 S cm2 mol1
0.2
 100 100 1
 m   
 om  o    o 
H
50  350
CH3 COO
4
Van’t Hoff factor i  1    1.25
  i.C.R.T.
1
  1.25  0.2  300   6.25 atm .
12
34. 78.50
Sol. a  6r
r
a
1 1
Effective number of atom in one unit cell  4   8  4  9
4 2
9  r 2
 %P.E.   100
a2
9  3.14  r 2
  100
 6r 2
9  314r 2 314
 2

36r 4
= 78.5%
35. 0.70
Sol. Amount of thermal energy required  w  CS  T
Amount of thermal energy in beaker A  200  CS   90  40   10000 CS
Amount of thermal energy in beaker B  100  CS   90  20   7000 CS
Amount of thermal energy in beaker C  150  CS   90  50   6000 CS
Amount of thermal energy in beaker D  300  CS   90  30   18000 CS
 w  6000 CS , x  7000 CS , y  10000 CS , z  18000 CS
x 7000 CS
   0.7
y 10000 CS
36. 9.00
45
Sol. Weight of oxalic acid in 50 ml solution before adsorption   50  4.5 gm
500
50
Weight of oxalic acid in 50 ml solution after adsorption  0.6   90  2.7 gm
1000
 Weight of oxalic acid adsorbed by 0.2 gm of charcoal = 4.5 – 2.7 = 1.8 g
1
 Weight adsorbed per gram  1.8   9 gm .
0.2
Mathematics PART – III
Section – A
37. A, B, C
4
C 2  60  12  96
Sol. P4  42 , P5 = 0, P6   6
4 46 4
38. A, D
         
Sol. P1  3 , P2  1 and P1  P2  0  P3  P1  P2  P3 P1 P2
39. C, D
m 101  m  1 n  1
Sol.  , N
n 51 2
40. A, C, D
 z3  z2   z  z4  2 3 4
Sol.   R   z  z   zz  1  0 for given order z, z , z , z
 z  z2   z3  z 4 
 2   4  
 arg z   0,    , 2 
 3   3 
41. A, C, D
Sol. det(M1) = det(M2) = 0  det(aM1 + bM2) = 0  a, b  R
42. A, B
Sol. z1, z2, z3 are the roots of the equation z3  2z 2  2 2 z   3  0
43. B
Sol. n(A) > n(B)  Total number of cases 211
n(A) = n(B)  Total number of 32 cases
44. D
Sol. (a + b + c) ((a – b)2 + (b – c)2 + (c – a)2) = 2
If a, b, c  Z  (1, 0, 0), (0, 1, 0), (0, 0, 1) are solutions
1
If t    a = c, 2a + b = 2 , a – b = t  infinite possibility
t
45. D
Sol. |((z – 2)8 – 38| = |(z – z1) (z – z2)(z – z3) ..... (z – z8)|
46. C
Sol. (I) There are 4 distinct path
1
(II) There are  10 C5  distinct path
3
(III) Count rectangle of all possible dimension = 73
(IV) There are 218 distinct path
Section – B
47. 95.00
Sol. Let i be the event that i is the upper left corner of required square
95 417
 P  i  2  3  4    P  1c  2c  3c  c4  
512 512
48. 81.00
Sol. Suppose there are Tn ways to cover n steps
Tn = Tn – 1 + Tn – 2 + Tn – 3, T1 = 1, T2 = 2
49. 220.00
Sol. Let p = 9 – a, q = 9 – a3  p + a2 + q + a4 = 9  12C3 = 220
50. 4.00
Sol. |A2 + |A|A + Tr(A)·I2| = 4(2(|A| – 1)2 + 1)
51. 23.00
Sol. P(x) = x3 + 2x2 + 3x + 3
52. 3.00
    
p q r  p r  2 2 2
Sol.    q  0  p  q  3 r
 3   3 
53. 2.78
1 2
Sol. Let  = u,  = u + v,  = u + 2v,  = u + 3v  p  q    u  1 u2  2u  9 
9
54. 834.00
Sol. Let im = n  9 34 cases
im5 = n2  8  33 cases
im9 = n3  8  33 cases

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

(D) Image is inverted  It should be real

= 105  10 13.8  0.1  1 0.2   103 A

log (x/m) vs. log (P) log (x/m)

CuF6 4   sp3 d2  Cu2  d9  t 62g e3g

MnF6 3  sp3 d2  Mn3  d4  t 32g e1g

Mathematics PART – III

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