(2022PJM08062022) Major Test - 220Paper-I Test Pattern

r�
, 1 PROTON
---•EDUCATION
�� CENTRE OF EXCELLENCE
CLASSROOM CONTACT PROGRAMME MT-220 JEE(Main)
FULL SYLLABUS
(Academic Session : 2022- 2023) 08-06-2022
JEE(Main) : TARGET COURSE (SCORE - VII)
SOLUTIONS
Physics PART – I

SECTION – A
1. C
Sol. lgG = (l - lg)S
10 × G = (50 - 10)12
G = 48 
2. A
2
hc   z1  1 
Sol.  a 2 (z  1)2   4
 1  z1  1 
2
  z2  1  1
And     z1  2z  1
2  z  1  4
z 1
 z2 
2
3. C
Sol.

Fcos   Mgsin 
mg tan 
B
i
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4. A
IE I 1
Sol.  1.25    C 
IC IE 1.25

5. A
 qin
Sol.  E.ds   0

qin
E.4r12 
0
qin
E
4 0r12
r r
1 1
 r
Where qin   dV   0  1  4r 2dr
0 0
 R
 r3 r4 
 40  1  1 
 3 4R 
0r1  3r1 
 From (i) E  1  
30  4R 

6. B
2GM
Sol. ve   11.2 km/s
R
2GM 2GM
ve  2  2  11.2  22.4 km/s.
R/4 R

7. D
Sol. Image distance is 30 cm
1 1 1
 
F f f
1 2

30 f
As optical axis shifts down by (y – x) for second lens
y  x 1
m
yx
y  4.5 cm

8. A
 uf 
Sol. u1  u,v1    
uf 
u2  ,v 2   f
uf uf  uf  f 2 f2
v 2  v1  f  
uf uf uf
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9. C
Sol. Time taken for current to grow upto 50% is
L
t 50%  1
R
L
t 50%  2
R
 t 2  t1 (because L 2  L1 )
Hence correct graph is 3

10. B
Sol. Ferromagnetic and not diamagnetic or paramagnetic

11. C
2D
Sol. y is linear position from centre.
d

12. B
Bx 22 Bx12
Sol. 
2 2
B 2
 x 2  x12 
2
B(x 2  x1 )(x 2  x1 )
2
B
 x 2  x1 
2
B  2 B  
    2x1 
6 2

   2x1
3
 2
2x1    
3 3

x1 
3

13. C
Sol. The equivalent circuit of above fig between A and D can be drawn as

10 10 Balanced wheatstone
10
A bridge A Series

10 10  10

D D
10 10
10

So     
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14. B
Sol. The direction of current in the solenoid is anti- v
clockwise as seen by observer. On displacing it
towards the loop a current in the loop will be N N S
induced in a direction so as to oppose the
approach of solenoid. Therefore the direction of Observer
induced current as observed by the observer will
be clockwise.

15. A
Sol. i  2t
 i will increase with time
 B 
 
 Induced current will be ACW to produce magnetic field  to oppose
increasing flux (Lenz’s law)

16. B
Sol. If balance length is not obtained then it means that potential difference across external resistance
is more than potential difference across potentiometer wire.

17. A
Sol.

F  FC
kq1q2 mv 2

r2 r
q1q2
v
40rm
2r 40m
T  2r
v q1q2
163m  0r 3
T
q1q2

18. B
Sol. If the sheet is heated then both d1 and d2 will increase since the thermal expansion of isotropic
solid is similar to true photographic enlargement.

19. C
Sol. Heat lost by A = Heat gained by B
        Since  and Temperature of the mixture (T) =
28°C
       
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20. B
Sol. From figure it is clear that separation between lenses
  

d 5 cm
20 cm

SECTION – B
21. 00009.00
Sol. The final surface energy must be less than the original surface energy
2/3
 3r 2  TL
4    2rLT
 4  1/3
9
r
2
22. 00005.00
Sol. I  mgx sin 
1 2 d2 
 mr  mgx sin 
2 dt 2
d2  2g  4r  4r xG
 2   3 m2R
dt 2
r  3  G 
8g
  f
3r mg
= 0.46 Hz
23. 00000.15
Sol. Energy of incident photons in eV is given as
12431
E eV
1800
As work function of metal is 2eV, the maximum kinetic energy of ejected electrons is
KEmax  E  
 KEmax  6.9  2eV
 KEmax  4.9eV
If max be the speed of fastest electrons then we have
1
m max
2
 4.9  1.6  1019 joule
2
2  4.9  1.6  10 19
  max 
9.1 10 31
  max  1.31 10 6 m/s
When an electron with this speed enters a uniform magnetic field normally it follows a circular
path whose radius can be given by
mv mv 2
r [As qvB  ]
qB r
9.1 10 31  1.31 106
 r
1.6  10 19  5  105
 r  0.149 m
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24. 00002.39
C1C3 CC
Sol. E  C1C 2 cos 0t  cos(0  )t  1 3 cos(0  )t
2 2
Of the three components, the highest frequency component will liberate the electrons with
maximum kinetic energy
h
( K .E ) max    (0  )   = 2.39 eV.
2
25. 00001.66
Sol. If central maxima is formed at point P on the screen, then P Screen
Path difference = S2P + (g–1)t – S1P – wd sin 30° = 0 x
water
xd w = 4/3 S1
 S 2 P  S1 P    w d sin 30  ( g  1)  t d t =30°
D
 x  1.66 cm g
s
S2
D

26. 00007.60
Sol. Concept of vertical circular motion.

27. 00033.60
Sol. From the concept of charging of capacitor.

28. 00000.90
Sol. From the concept of work done by gas.

29. 00000.80
Sol. For water column in one arm of U tube, h1 = 10.0 cm; 1 (density = 1 gcm–3)
For spirit column in other arm of U tube, h2 = 12.5 cm; 2 = ?
As the mercury columns in the two arms of U tube are in level, therefore pressure exerted by
each is equal.
h11 10  1
Hence h11 g  h2  2 g or  2    0.8 g cm–3
h2 12.5
Therefore, relative density of spirit = 2 /1 = 0.8 / 1 = 0.8

30. 00007.00
mA  MA 
Sol. ( ACM ) x  A M
mM m A
M  0  mR mR
( ACM ) y  
mM mM A
f  ( M  m) A … (i)
( M  m) g  N  ( M  m)( ACM ) y … (ii)
mgR  I A  … (iii)
A  R … (iv)
 N = 70 N
 n=7
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Chemistry PART – II

SECTION – A

31. A
hc
Sol.  corresponds to the wave length of the visible light and  

The order of ability to produce d-orbital splitting of various ligands:
CO  CN  NO2  en  NH3  H2O  OH  F  cl  Br   I
strong field weak field
ligands ligands
(larger ) (smaller )

32. C
1000K b w1
Sol. b 
m1w1
m1(A 2B)  90  2A  B
2A  B  90
we get A = 40; B=10

33. C
Sol. pH changes from 0 to 7.
Accordingly Ered. decreases by 0.059 log10–7 i.e. 0.059 × (–7) = – 0.41 volt.

34. C
Sol. Factual.

35. C
Sol. Factual.

36. C
Sol. SO2  Br2  2H2O  2HBr  H2SO4

37. A
Sol. Eq. KMnO4 = Eq. FeC2O4
5 × moles of KMnO4 = 1 × 3

38. C
Sol. O

P
HO OH
H

2  20  0.1  40  M

0.1 MKOH

39. B
0.693 0.693
Sol. K   4  10 2
t 50% 34.65
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40. D
3 a
Sol. Diamond has ZnS structure. In it r + r = (Nearest distance is between corner C atom and
4
C atom in tetrahedral void).

41. C
Sol. Factual

42. D
Sol. 4KI  HgCl2  K 2HgI4  2KCl
Remained KI = 5 – 4 = 1 mol
1 mol K2HgI4 and 2 mol KCl is formed.
(K 2HgI4  2K   HgI24 )
( Tf )o  K f (i1m1  i2m2  i3m3 )
(Tf )0  4.78o C

43. D
Sol. Because Pex = 0, -PexΔV = 0, so that no work is performed in this case.

44. C
Sol. All- cis –[10] annulene obeys (4n+2) π rule, but it is not aromatic because it is too strained when
planar.

45. A
Sol. Small concentration of phenol (0.2%) acts as antiseptic while 1% solution of phenol acts as
disinfectant.

46. A
Sol. acetaldehyde K f  1.06  acetone(K f  0.001) Chloral(K f  2000)
Formaldehyde(K f  2280) Hexafluoro acetone(K f  1.2  10 6 )

47. C
Sol.
O3

NaBH4
 OH  OH

48. D
Sol. Factual

49. D
Sol. Factual

50. D
Sol. D-Fructose gives two products on reduction as a new chiral atom is formed at C–2 carbon.
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SECTION – B

51. 00009.00
Sol. Basic Buffer
 Salt 
pOH  pK b  log10  
 weak base 
pOH  5  log10 3  log10 (3)
pH  14  pOH
pH  14  5  log10 3  log10 3
pH  9

52. 00003.00
Sol. 1. Phenyl alanine - –CH2–C6H5
2. Tryptophan -

3. Histidine -

53. 00113.60
Sol. First order type reaction follow, time= 4  t 1  4  28.4 =113.60
2

54. 00009.20
7.8
Sol.   2  102
390
K a  c 2  16  10 6
or pK a  4.8

55. 00018.00
Sol.

Molecular formula of Y = C9H8O4

Molecular mass of (Y) = 108 + 8 + 64 = 180

56. 00000.25
[B]
Sol. K eq. 
[A]
10 100
K1000  10 and K 2000   100
1 1
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o
G1000 ( RT lnk eq )1000 1000  ln10 58. 00006.15
Now,   Sol. 2Al  3H2SO 4  Al2 (SO 4 )3  3H2
Go2000 ( RT lnK eq )2000 2000  ln100
 0.25 5.4
Moles of Al takes   0.2
27
57. 00013.32 50  50
Moles of H2SO4 taken   0.25
Sol. Eocell  1.23  0.00  1.23V 1000
Gocell  nFEocell  2  96500  1.23J 0.2 0.25
As  , H2 SO 4 is limiting reagent
2 3
 Work derived from this fuel cell
3

70
100
 
 Gocell  10 3  xJ Now, moles of H2 formed   0.25  0.25
3
Since insulated vessel, hence q = 0 nRT
 Volume of H2 gas formed 
From equation, for monoatomic gas, P
 3R  0.25  0.082  300
w  U  x  nCV,m  C V,m     6.15L
 2  1
70 3
Or,   2  96500  1.23   10 3  1  8.314  
100 2
   
59. 00001.20
68  106
Sol. Initial moles of U238  x
238
7
Moles of U238 decayed in three half-lives  x
8
In decay from U238 to Pb206 , each U238 atom decays and produces 8 -particles and hence,
total number of -particles emitted out
7 
  x   8  NA
8 
68  106
 7  6.022  1023
238
 1.204  1018
60. 00018.00
Sol.
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Mathematics PART – III

SECTION – A

61. C
b
Sol. The asymptotes are y =  x
a
b b

2ab 1
 tan30° = a a2  2 2

b a b 3
1 2
a
 a2 – b2 =  23 ab.
Also a2 + b2 = a2e2
 e4 – 16e2 + 16 = 0
 e2 = 8  43
 e = 6  2.

62. B
Sol. The pair of lines x2 – 3y2 + 3xy + 3x (lx + my) = 0 are perpendicular to each other.
 1 – 3 + 3l = 0  l = 2
3
3 
Hence the chords are 2x – 3 + 3my = 0, which pass through the fixed point  , 0  .
2 

63. C
Sol. Major axis of hyperbola bisects the asymptote
 equation of other asymptote x = 2y
equation of hyperbola (y – 2x)(x – 2y) + k = 0 it passes through (3, 4)
 required equation 2x2 + 2y2 – 5xy + 10 = 0.

64. A
3
Sol. Putting x  in 2 x 2  2 y 2  15 x  6 y  1  0
y
We get
2
3 3
2    2y 2  5    6 y  1  0
y
  y
18 15
2
 2y   6y  1  0
y y
18  2y 4  15 y  6 y 3  y 2  0
2y 4  6 y 3  y 2  15 y  18  0
 yi  3  yi  9

65. B
Sol. The equation of tangent is y = mx  25m2  16, it passes through (–2, 5)
5  2m  25m2  16
 (2m  5)2  25m 2  16
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 4m2  20m  25  25m2  16

 21m2  20m  41  0
 (m  1)(21m  41)  0
 [m1 ]  1, [m2 ]  1
 equation of tangents are y = – x + 3 and y = x + 3 they intersect at (0, 3).

66. A
Sol. If x1x 2 x3  30 then number of solution 33
If x1x 2 x 3  15 then number of solution 32
Similarly for x1x 2 x 3 equal to 10 & 6 solution are 32 & 32 and x1x 2 x 3 equal to
5, 3 & 2 solution are 3 each i.e. 3  3 and for x1x 2 x 3 = 1 there is just one solution
Total  33  3  32  3  2  1 = 64

67. B
Sol. f "  x   3f '  x   3
d 3x d 3x

dx
 
e f  x   3e 3 x 
dx

e f '  x   e 3x  0 
 e 3x  f '  x   1 is increasing function
e 3x  f '  x   1  f '  0   1x  0
 f  x   x is increasing function

68. C
 x 2  2x  1   x  12 
Sol. f '  x   cos    cos  
 5   5 
1  x  1
2
9
Since 0  x  2,  
5 5 5
 x  1  x  1
2 2

cos  0 only when 
5 5 2
5
x   1 is a point of local maximum
2

69. B
1
x2  t2
Sol. f x  0 2  t dt
1
 x2 4 
  t2  dt
0  2 1 2t
1

 x 2  4 in2   2
2

5
 y  x 2In2  4In2 
2
Which is a parabola
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70. C
2 2
 8 x2 
Sol.   y 2  y1  dx    x 2  4 
2 2  4
 dx

 8
2
x  2
 2  2  
0 x  4 4 
2 2
16  1 x  1  x3 
 tan   
4  2  0 2  3  0
8 8
 
4 6
 2
 2   
 3

71. C
y2
Sol.  3xy  2y  x 2  x  c
2
y 2  6xy  4y  2x 2  2x  c
y 2  2x 2  6xy  4y  2x  c

72. B
Sol.  x  40  200  50  40  7990
7990
Corrected x   39.95
200
Incorrect  x 2  n  2  x 2   200 15 2  402   365000
Correct  x 2  36410  502  402  364100
364100
  39.95   14.98
2
Correct  
200

73. B

Sol.
dy
 
2
 2

x 2  4x  3  2x  4  x  7x  10   2x  7  x  4x  3  
dx x 2  7x  10  
2
x 2  7x  10
 2x  14x  20x  4x  28x  40
3 2 2

2x 3  8x 2  6x  7x 2  28x  21 19x 2  14x  19

 0
 x 2  7x  10   x 2  7x  10 
2 2

74. A
    
Sol.  a  c  .a  b.a  a.a
1

3
    
Taking cross product  a  c   a  b  a  0
   
2     
 b  a   a.c  a
 a c   a.c  a  b  a  c

2
a
 2
   ba
 
a  b .c   2  
a
8
3
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75. A
 3
Sol. tan 
2 4
24
 sin  
25
 Area of ORQ is
1 24
 OR  OQ   34
2 25
OR  OQ  25

76. A
yx yx
Sol. Let x, y
2 2
x2 y2
 1
8 4
a2  8,b 2  4
12 3
e 
8 2
x  ae, y  0
yx 3 yx
 8 , 0
2 2 2

77. D
C7 6 C2
10
10  9  8  6  5 10 5
Sol.   
9  9  8  7  6  5  4 3! x  2! x  9  9  8  7  6  5  4 6  2  9  7  4 1512

78. D
Sol. x = 2R cos A, y = 2R cos B, z = 2R cos C
xy 4R2 cos A cosB
  cot A cotB
ab ab
xy yz zx
    cot A cotB  cot B cot C  cot Ccot A  1
ab bc ac

79. A
Sol. Let  is angle made by OP with x-axis and let  be angle made by tangent at P with x-axis giving

   2  
2
dy y
tan   and tan  
dx x

80. B
Sol. Make truth table.
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SECTION – B
81. 00005.00
Sol. B+C=–A
tan (B + C) = – tan A
 1 1
h  
 17 3    22   20h    22
 
h2 7  51  h2  7
1
51

1
Area of triangle ABC     20  11  110
2

82. 00003.00
Sol. Area of square 2(a2 + b2) = 10
 a 2  b 2  5,  a  b   1
 ab  2 and a  b  3
3
 a  2, b  1, e   4e2  3
4

83. 00005.00
Sol. At least one books can be selected in (m + 1) n – 1

84. 00002.00
tan1   tan1   tan1     
Sol.  tan1  
3  3  6


 2
tan   tan1   tan1 
1

85. 00001.00

Sol. Let tan  x
2
1 1  x2 1  x 2 1 4.x 2
 2    
x 1  x 2 1  x2 x2 1 x2
 1  x  4x  5x  1
4 4 4


 5 tan4  1
2
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16 llT-JEE I NEET I OLYMPIADS

86. 00005.76
Sol. Point is (a sec, b tan)
asymptotes are bx  ay-=0 and bx + ay = 0
ab secθ - ab tanθ absecθ + abtanθ
Now ×
a2 + b2 a2 + b2
a2b2 144
= 2 2
= .
a +b 25

87. 00001.66
Sol. b + c = 4a
sinB + sinC = 4sinA
BC BC
cos  4 cos
2 2
B C B C  B C B C
cos cos  sin sin  4 cos cos  sin sin 
2 2 2 2  2 2 2 2
B C B C
3 cos cos  5 sin sin
2 2 2 2
B C 5
cot cot  .
2 2 3
88. 03456.00
Sol. y = ax2 + bx + c, vertex is (4, 2)
b 4ac - b2 b2
 4=− , b = – 8a, =2  c=2+ = 2 +16a
2a 4a 4a
Now  = abc = – 8a2(2 + 16a) = –16(a2 + 8a3)
dΔ
 = –16(2a +24a2) < 0  a  [1, 3].
da
 |max = –144, |min = −3600
 Difference = 3456.

89. 00000.50
Sol. Since square of sides are given. cosine rule will be applicable
b2 + c2 - a2
cos A =  b4 + c4 + a4 + 2b2c2 –2a2b2 –2a2c2 = 4b2c2cos2A
2bc
 a4 + b4 + c4 = 2a2c2 + 2a2b2 + b2c2(-2 + 4 cos2 A)
compare with given values gives - 2 + 4cos2 A = 1
3 1 1
 cos2 A =  sin2 A =  sin A =
4 4 2

90. 00000.50
Sol. The two curves are y  x  2  2 & y  3  x  2 y=4–x Y
The area bounded (2, 3)

=shaded area
2
=2  1  x  4  x  dx
3/2
y=1+x (2, 2)

2 1 (2, 0) X
 2  x 2  3x   .
3/2 2 (3/2, 5/2)