Final PCM 21-2-24 Sol

Sri Chaitanya IIT Academy WRT-3 21-2-24 JEE MAINS 11th NM
ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
Q.NO ANS. Q.NO ANS. Q.NO ANS.
1 B 1 C 1 C
2 D 2 C 2 C
3 D 3 C 3 A
4 B 4 D 4 A
5 D 5 B 5 D
6 D 6 B 6 B
7 A 7 B 7 C
8 C 8 C 8 C
9 A 9 C 9 A
10 C 10 A 10 C
11 A 11 B 11 C
12 C 12 A 12 D
13 C 13 D 13 B
14 A 14 A 14 C
15 C 15 D 15 D
16 C 16 A 16 D
17 C 17 C 17 B
18 B 18 D 18 B
19 B 19 D 19 A
20 C 20 A 20 D
1 5 1 2 1 12
2 2 2 0.0108 2 2
3 1.96 3 108 3 2
4 760.00 4 3 4 32
5 4 5 12 5 10
6 100.00 6 4 6 7
7 3 7 2 7 604
8 1 8 125 8 60
9 10.00 9 9000 9 11
10 15.88 10 186 10 500
PHYSICS SOLUTIONS
Sol:1 A collision which is not elastic changes only the Sol:4 Nothing is mentioned about coefficient of restitu-
normal component of velocity. tion. Hence the only true statement is their final
Here the normal component is – b. Hence it be- velocities may be zero.
come (+eb) after collision keeping the x-compo- Sol:5 Thrust = pressure at the centre × area
nent (tangential) as before collision. = g(1/2)h × A = (1/2)ghA

 v f  a î  eb ĵ = (1/2) × 1000×10 × 0.5×0.5Nm-2 = 1250Nm-2
y ^ ^ Sol:6 Just after release velocity of package and satellite
v = ai^ - bj^

ai + ebj are exactly same and both are moving under earth’s
gravity in circular motion. Hence, package will also
move in same circular orbit.
x
Floor m2
Sol:7 u = v1 + m v 2 ....(1)
1
Hence (B).
Sol:2 At the condition of equilibrium v2 – v1 = u ....(2)
k f1  k i1  v1 
2
4m1m 2
Glycerin
Oil h k i1 = 1   = (m  m )2
10cm  u  1 2
10-h
A B 12  10
Sol:8 = h × 103 × 10
800  10  4
Mercury  h = 15cm
Pressure at point A = Pressure at point B  GMm

Sol:9 T.M.E. =
PA = PB  10×1.3×g r1  r2
= h ×0.8×g + (10-h)×13.6×g Using conservation of energy
By solving we get h = 9.7cm
 GMm  GMm 1
  mVmax
2
Sol:3 r1  r2 r1 2
1m
2m
 GMm 1
4m   mVmin
2
8m
r2 2
v = v1 + v2 + v3 + v4 + ...... 2GMr2
Solve for Vmax 
GM GM GM GM GM GM (r1  r2 )r1
=       
1 2 4 8 16 32 Sol:10 Pi = mv1 + mv2
.......... Pf = (m + M) v
 1 1 1  mv1  Mv 2
= – GM 1  2  4  8  .......   G.P. of infi- Pi = Pf  v = (m  M)
 
By energy conservation
 1 
nite series = – GM  1 – 1/ 2  1 1 1 1
mv12 + Mv22 = (M + m) v2 + kx2
2 2 2 2
v = – GM (2) = – 2GM Ans.
1

(mv 1  Mv 2 )2 In horizontal direction Fext = 0, so centre of mass
mv12
2
+ Mv22 = (M + m)  kx
(M  m)2 move with constant velocity in horizontal plane.
(M + m)v0 = m(v0 + u cos a)
mM
solving x = (v1 –v2) (M  m)k m u cos 
V0 =
M
Sol:11 Gravitational field is a conservative force field. In
2GM 2GMe  10 2GMe
a conservative force field work done is path Sol:18 V = = Re = 10
R Re
independent. 10
 WI = WII = WIII = 110 k m/s
Sol:12 From momentum conservation M 38.25
Sol:19 Volume of gold, V    1.982cm 3
u  19.3
mu = 2mv  v= 2 Apparent loss in wt. = 38.25 - 33.865 = 4.385g
from energy conservation
Volume of displaced water  4.385  4.385cm 3
2 1
1 u u2
× 2m ×   = 2 mgh  h= Volume of hollow = 4.385 - 1.982 = 2.403 cm3
2 2 8g
Sol:20 Given change is internal change on fish + water
3/2 system. Hence external force will remain same.
T1 r  T
Sol:13 T =  r1  or = (4)3/2 or T = 40 hr.
2  2 5
Numerical Based Questions :
   
Sol:1 1 kg î – 2 ˆj + 2kg 4 î – 5ˆj = 3 v 
  
90 -
0
v1  v = 3 î – 4 ˆj , | v | = 5 m/s
v2 = v1
Sol.2 The buoyant force is 20g and buoyant force = Vg
Sol:14 90 -
0
Vg = 40g

 40
Vg = 20g   =2
   20
I  p  2m 2gh cos   r to surface.
GM m GM e
Sol:3 We know that g m  2
and g e 
  d  2h  Rm R e2
Sol:15 g 1 – R  = g 1 – R  or d = 2h
   
2
gm  Mm   R e 
  . 
Sol:16 For the floatation V0d0g = Vind g  Vin = V0
d0 g e  M e   R m 
d
M e 80 D e R 4
d0  d  d0  But,  ,  e 
 Vout = V0-Vin = V0- V0 = V0  Mm 1 Dm R m 1

d  d 
and ge = 9.8ms-2
Vout d  d 0 1  4  16 1
2
  . gm
    
V0 d 
9.8 80  1  80 5
Sol:17  gm = (9.8/5) = 1.96ms-2
Sol:4 Weight of block
= Weight of displaced oil + Weight of displaced
water
 mg = V10g + V2wg
 m = (10×10×6)×0.6+(10×10×4)×1
u - velocity of shell with respect to gun. = 760gm
2
Sol:5 Sol:7 Collision is perfectly elastic collision, particle 2 is
at rest (u2 = 0)
V1 = – V2 (given)
(m1 – m 2 ) u1 –2m1 u1
(m1  m 2 ) = (m1  m 2 )
m1 – m2 = – 2m1 = 3m1 = m2
m1 1
from momentum conservation :
m2 = 3
9m = (2m)V1 – (m)V2
Sol:8 Buoyant force,
 9 = 2V1 – V2 ..... (1)
FB = BVg = 1000 × 10 × V = 104V N
V1  V2
e= 1 ......(2) Gravitational force, FG = bvg = 0.5 × 104VN
9
from eqn. (1) and eqn. (2) V1 = 6 m/sec.  Net upward force = 0.5 × 104V N
For second collision between second block and  Net work done on the ball in bringing to
third block : surface = 0.5 × 104VJ
(2m) 6 + m(0) = (2m + m) VC say ball rises to a height h, then
 VC = 4 m/sec.  0.5 × 104V = mgh = V × 500 × 10 × h
Sol:6 Using conservation of energy 0.5 10 4
 h= = 1m
5000
3GM 2 1  3G (M / 8) 2 1M 2
 MV02  ×8+ V ×8
5R 2 5(R / 2) 2 8 Sol:9 Force = gV = 1000×10×100 = 106 N
 10 m 
3GM 2 1  3GM 2 1 Sol:10 (10 + m) =    1
   MV02   MV 2  0 .5 2 .7 
5R 2 20R 2
m
3GM GM 3GM V 2  m  20  10  10
     2 .7
5R 2R 20R 2
10  2.7 270
GM V 2 GM  m  = 15.88235
   V= = 100m/s 1 .7 17
20R 2 10R
= 15.88 gram
3
Sri Chaitanya IIT Academy Chemistry Sol. 21-2-24 11th JEE MAINS NM
1. C
Sol (Theory Based)
2. C
128
Sol.  0.5
128  2
3. C
Sol. (Theory Based)
Lower the value of K, lower the advancement of Reaction
4. D
Sol. To decrease pH from 6 to 4, solution should be concentrated 100 times.
5. B
Sol. Based on Le-chatelier’s principle
6. B
Sol. (Theory Based)
7. B
Sol.
NH3  HCl 
 NH4Cl
1 
 NH 3  Left  M
15 
 Buffer solution
1
 NH 4Cl   M 
15 
pOH  pKb  log

C.A
W .B
pOH  4.75
p H  14  4.75
 9.25
8. C
Sol. Acid 
 Conjugate Base
(Strong) (Weak)
Acidic strength  Ka
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9.
Sol. C
0.5
p H  4.5  log
0.5
p H  4.5
pOH  14  4.5
 9.5
10.
Sol. A (Theory Based)
11.
Sol. B
( Ksp) BaCO3   Ba 2  CO32 
Ksp 5.1109
 Ba 2    = 5.1105 M
  CO 2  10 4
 3 
12.
Sol. A (Theory Based)
13.
Sol. D
Based on Le-chatelier principle.
14. A
Sol. K p  kc ( RT )Δng
Δng  1
K p  K c / RT
Kp 1

Kc RT
15. D
Sol. NH 4 HS ( s )  NH 3 ( g )  H 2 S ( g )
at  (0.50 x ) x
Total P at   0.84atm
0.50  x  x  0.84
x  0.17
Kp  ( pNH 3 )  ( pH2S )
Kp  0.67  0.17
Kp  0.113

16. A
1
Sol. SO3 ( g )  SO2 ( g )  O2 ( g ) K c  4.9 102
2
2SO2 ( g )  O2  2SO3 ( g ) Kc'
2
 1 
Kc'   2 
 416
 4.9 10 
17. C
Sol. 2 AB3 ( g )  A2 ( g )  3B2 ( g )
At t = 0 8 mole 0 0
x 3x
at  (8  x)
2 2
x
 2
2
So, x  4
 Aeq  2  AB3 eq  4
[B]eq  6
2666
Kc   27
4 4
18. D
K2 .K33
Sol. K4  Theory Based 
K1
19. D
N 2O 4 (g)  2NO 2 (g)
Sol.
Let initial moles 1 0
at  (1  ) 2
total mole at 
 (1  ) moles
Þ N 2 O4 
1    P & Þ 
2
PT
1    T NO 2
(1  )
(Þ NO 2 ) 2
Kp 
Þ N 2 O4
4  PT
2
(1  )
  0.71
%   71 %

20. A
Sol. nPCl5  5 mole
n Ar  4 mole
total moles  9 moles .
9  0.082  610
PTotal   4.5atm
100
5  4.5
Þ PCl5   2.5 atm
9
4 45
ÞAr   2 atm
9
 PCl5 g   PCl3  g  Cl2  g 
at   2.5  p  atm Þatm Þatm
Ptotal  2  5  Þ  Þ  Þ  ÞAr
1.5  1.5
Now k p   2.25
1

Numerical
1. Ans.0.2
Sol. (Theory Based)
2. Ans.0.0108
Sol. CaF2  Ca 2   2F
K sp  s  (2 s) 2
K sp  4 s3
2.34  103  103

 s  3  104 M
78  100
So, K sp  0.0108
3. Ans 108
Sol. A3B2  3 A2  2 B3
Ksp  (3s )3  (2s ) 2
 27 s3  4 s 2
 108s5
4. Ans 03
Sol. (Theory Based)
5. Ans 12
X(g)  Y (g) + Z(g) Kp1  3
Sol. Let initial moles 1 0 0
at equilibrium (1  )  
  
 pT1   2 pT1
 1  
Kp1   .........(1)
1   1  2
  pT1
1  
A(g)  2 B(g) Kp 2  1
Let initial moles 1 0
at equilibrium (1  ) 2
2
 2 
  pT2 
1 
Kp2    ........(2)
1  
   pT2
1  
Divide Eq n  (1) by Eq n  (2)
PT1 : PT2  12 :1

6. Ans 4
Sol. Let moles of NH3 added  a mole
Ag   2 NH 3  [Ag(NH3 )2 ]
at t  0 0.8M a/2
a 
at t   5  108   1.6  0.8
2 
0.8
Kf   108  a  4
2
a 
5  108   1.6 
2 
7. Ans 02
Sol. ' 1
Keq 
Keq
 x  108
1 L

20 10 7
x  2.24  2
8. Ans 125
Sol.
2 NOCl (g)  2 NO(g)  Cl2 (g)
at t  0 2M 0 0
x
at t  teq (2  x) M xM M
2
 x = 0.4 M
2
(0.4)  0.2
Kc 
(1.6) 2
K c  12.5  103
K c  125  104
9. Ans 9000
Sol. M1V1  M 2V2
101  1  102  V2
V2  10 L
Water added = 10 – 1 = 9L = 9000mL

10. Ans 186
Sol.
total mili mole of H +ion=14
 14  103
14
[H + ] 
1000
pH  1.86
pH  186  102

Sri Chaitanya IIT Academy Maths Sol. 21-2-24 11th JEE MAINS NM
1.
Sol. Total ways to invite
 7c1 +7c2 +…+7c7
=  27  1 =127
2.
11!
Sol. Total ways to arrange letters of word "Examination" 
2!2!2!
3.
Sol. Ways to, arrange suck that all persons of Same nationality are together =3! × 8! × 4! × 4!
I1I2 ....I8 A1A 2A3A 4 E1E 2E3E 4
   
4.
Sol. Ways to Permute such that 5 boys and it 5 girls are at alternate pos n .
Case-1 Girls at odd G1B1 G 2B2 G3B3 G 4B4 G 5B5
 5!  5!
Case-2 Girls at even B1G1 B2G 2 B3G3 B4G 4 B5G5
 5! 5!
Total ways =  5!×5! + (5!× 5!) = 2 × 5!× 5!
5.
Sol. 2 n P4  n 1P4
2
n!

 n  1!
 n  4  !  n  1  4 !
2
n!

 n  1 n!
 n  4 !  n  3 n  4 !
n 1
2
n3
2n  6  n  1
n7
6.
Sol. ( x  1)3  8  0
( x  1)3  8
 x  1  2, 2, 22
x  1,1  2,1  22
7.
 z4 
Sol. Re   1/ 2
 2z  i 
let z  x  iy
 x  iy  4  1
Re  
 2  x  iy   i  2
  x  4   iy ) 
Re  1/ 2
  2 x   i 12 y  1 
 
  x  4   iy  2 x   i  2 y  1   1 / 2
Re  
  2 x   i  2 y  1  2 x  i  2 y  1  
 
2   x  4   y  2 y  1 1
 
4 x 2  12 y  1) 2 2
 4 x 2  16 x  4 y 2  2 y  4 x 2  4 y 2  1  4 y
 16 x  2 y  1  0
8.
Sol. ei  ei 2  ...ein  1
e
i  2 n 
1
( n n 1
i  
e 2 1
 n  n  1 
cos   1
 2 
n  n  1
 2m
2
4m

n(n  1)
9.
7
Sol. | z |  6,arg 
6
z = |z|ei
7
i
 6.e 6
 3 3  3i

10.
1 1 i 1 i
Sol. Z = × 
1 i 1 i 2
1 i
Z=
2
11.
2
Sol.  lies on | z  z0  r 2
2
  z0  r 2
   z0    z0  r 2  
 
   2
   z   z r
0  0 
 
 
2
|  |2  z0  z 0   z0  r 2 ......(1)
1 2
lies on z  z0  4r 2

2
1
 z0  4r 2

  
1 1
   z0    z0   4r 2
   
 
 
1 z0  z0  2
    z0  4r 2
2 2 2
|| || ||
 
 1  z0   z 0    | z0 |2  4r 2 |  |2 .........(2)
(1)  (2)
  1 |  |   r 1  4 |  | 
 |  |2 1  z0
2 2 2 2
 |  | 1 1  z   r  4  
2 2 2 2
0
  r  4  
 r 2
 |  | 1  1 
2
2 2 2
 2
 
 r2  2
 
|  | 1     r 1  4 |  |2
2
 2 
 
 
7 |  |2  1
1

7
12.
Sol.
zn  1
zn 1  0
1, z1 z2  zn 1roots
 z n  1   z  1 z  z1  z  zn1 

ln  z n  1  ln  z  1  ln  z  z1   ln  z  z2    ln  z  z1   ln  z  zn 1 
differentiating both sides w.r .t . x
 n  z n 1 
1 1 1 1 1
  
zn 1 z  1 z  z1 z  z2 z  zn 1
z 3
n  3n 1 1 1 1 1
   
3n 1 3  1 3  z1 3  z2 3  zn 1
 n  3n 1 1  1 1 1
 n    
 3  1 2  3  z1 3  z2 3  zn 1
 
13.
 
n
Sol. 1  x  x 2  a0  a1x  a2 x 2  a3 x3  .  a2n x 2n
 put x  1
3n  a0  a1  a2  a3    a2n ....(1)
put x  w
 
n
1  w  w2  a0  a1w  a2 w2  a3w3   x  2 ....(2)
put x  w2
 
n
1  w2  w  a0  a1w2  a2 w  a36   .....(3)
(1)  (2)  (3)
3n  0  0  3  a0  a3  a6  
a0  a3  a6  .........  3n1
14.
z  z  z   z1  1   z2  2    z3  3  6
Sol. 1 2 3
 z1  1  z2  2  z3  3  6
 1  2  3  6 
 12
15.
10
Sol.  2k  2k  
 i  cos 11
 i sin
11 

k 1
10
  2k   
 i  ei     i  z1  z2  ....  z10 
k 1
11 
we know
1  z1  z2  ........  z10  0
Put in  A 
 i  1  i
16.
PF1  PF2  2a
p
Sol.
(1,0) (z) (0,1)
z 1  z  i  2
17.
Sol. No of integers between m & n is n-m-1 now each of n-m-1 elements has two choices
that is, they will be selected or not.
Therefore no. of subsets of set a having m & n as least is and greatest element
respectively is = n  m  1C0  n  m  1C1  .....  n  m  1C n  m  1
 2nm1
18.
Sol. Each place of n  digit no.Can be chosen in 3 ways
 3  3  3  ......  3  3n
n  times
3n  900 as n  I 
Smallest value of n  7
19.
Sol. Total ways such that exactly two letters are to be kept in right envelope
 4C2  1 1
=6
20.
Sol. Total ways to divide 52 Cards among 4 players equally
(52)!
(13!) 4  4!

Numerical
1. Ans.
Sol. z  z  z  2
1 2 3
2
Now z1  z2  z3 0
   
  z1  z2  z3   z1  z 2  z 3  0
 
 
   
  | z1 |    z1 z 2  z1 z2  0
2
 
 
   
 2 z1    z1 z 2  z1 z2   z1
2 2
 
 
2 2 2
z1  z2  z2  z3  z1  z3  4  4  4
 12
2. Ans.
Sol.
For minimum z  [A1, A 2 ]
| z |  | z  (cos   sin ) |  | z  2(ei ) | 1  0  1

 (2)

3. Ans
Sol.
4. Ans
Sol.
   
5 5
1  w  w2  1  w  w2
 (2)5   2 w2 
5
 32  w2   321
 32  w  w2   32  1  32

5. Ans
Sol. x  y  2 & 2y  2  4
y 1
x  3
x 2  y 2  10
6. Ans
Sol. 2  nC  nC  nC
5 4 6
nC5 nC6
2 1
nC4 n
C4
 n  5  1  1  n!
2  n  4 !4!
5  n  6 !6 !  n!
sol
n  7,14
n  14 n7
( n  13)
7. Ans
Sol. A, c, E , K , L, T
A
 ..........5!

c ........  5!

E
......5!

k
...........  5!

L
........  5!

TACE    2!
TACKE   1!
TACKLE  1!
Rank  604
8. Ans
Sol. DELHI
D  LH 
5!
  60(order fixed, so consider these identical )
2!
9. Ans
Sol. no. of diagonals  44
n  n  3
 44
2
n 2  3n  88  0
 n  11 n  8  0
n  11, 8
n  11
10. Ans.
Sol. Case-1. 3 alike, 1 different
4!
= 1C1 × 5C1 × = 20
3!
Case.-2 2 + 1 + 1 kind
4!
= 1C1 × 5C2× = 120
2!
Case -3. All different
6
C4  4! = 360
Total arrangements = 500


Final PCM 21-2-24 Sol

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Sri Chaitanya IIT Academy WRT-3 21-2-24 JEE MAINS 11th NM

Pressure at point A = Pressure at point B  GMm

pOH  pKb  log

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

2.34  103  103

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

 z n  1   z  1 z  z1  z  zn1 

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

For minimum z  [A1, A 2 ]

| z |  | z  (cos   sin ) |  | z  2(ei ) | 1  0  1

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

 32  w  w2   32  1  32

CHANDIGARH: SCO 369-370, SECTOR 34A. TEL: 0172-4185157

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