Professional Documents
Culture Documents
Vijay P. Singh, Ph.D., D.Sc., D. Eng. (Hon.), Ph.D. (Hon.), D. Sc. (Hon.), P.E., P.H., Hon.
D. WRE, Academician (GFA), is a Distinguished Professor and Caroline & William N. Lehrer
Distinguished Chair in Water Engineering in the Department of Biological and Agricultural
Engineering and Zachry Department of Civil Engineering at Texas A&M University. He holds
a B.Tech degree from U.P. University of Agriculture and Technology, a Master’s Degree from
the University of Guelph, a Ph.D. from Colorado State University, and a D.Sc. from the
University of the Witwatersrand. One of today’s leading experts in the field of hydrology, Dr.
Singh specializes in surface water hydrology, groundwater hydrology, hydraulics, irrigation
engineering, environmental quality, and water resources. He has published 25 books and has
edited over 58 books, and has published hundreds of journal articles. He has been the Editor-
in-Chief of the Journal of Hydrologic Engineering, ASCE; is currently serving as Editor-in-
Chief of Open Agriculture, and Journal of Agricultural research, and Journal of Groundwater
Research and is on the editorial boards of numerous journals. He is also serving as Editor-in-
Chief of Water Science and Technology Book Series as well as World Water Resources Book
series. He has received more than 75 national and international awards.
Second Edition to replace the classic 1964 edition edited by Ven Te Chow
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Dedicated to
Hydrologists and Water Scientists
Emanuele Baratti
M. C. Acreman
Department DICAM
Centre for Ecology and Hydrology
University of Bologna
Crowmarsh Gifford
Bologna, Italy
Wallingford, United Kingdom
Donald E. Barbe
Lauren Adams Department of Civil and Environmental Engineering
Center for Watershed Sciences University of New Orleans
University of California, Davis New Orleans, Louisiana
Davis, California
Robert Bastian
U.S. Environmental Protection Agency
Mohammad Z. Al-Hamdan
Washington, D.C.
Universities Space Research Association
NASA/Marshall Space Flight Center Peter Bauer-Gottwein
National Space Science and Technology Center Department of Environmental Engineering
Huntsville, Alabama Technical University of Denmark
Kongens Lyngby, Denmark
Douglas Alsdorf
Byrd Polar and Climate Research Center Hiroko Kato Beaudoing
The Ohio State University Earth System Science Interdisciplinary Center
Columbus, Ohio University of Maryland
College Park, Maryland
Devendra M. Amatya Beijing Normal University
Center for Forested Wetlands Research Research and Development Centre
Southern Research Station, USDA Forest Service Nippon Koei Co. Ltd.
Cordesville, South Carolina (Consulting Engineers)
Tsukuba, Japan
Daniel P. Ames Katherine Y. Bell
Department of Civil and Environmental Engineering Water Reuse Global Practice Leader, MWH Global
Brigham Young University Nashville, Tennessee
Provo, Utah
Joerg Uwe Belz
Michael Anderson Department of Hydrometry and Hydrological Survey Federal Institute of Hydrology
State Climatologist, California Department of Water Resources Koblenz, Germany
Sacramento, California
Lars Bengtsson
Department of Water Resources Engineering
Mazdak Arabi
Lund Institute of Technology
Department of Civil and Environmental Engineering
Lund University
Colorado State University
Lund, Sweden
Fort Collins, Colorado
Ronny Berndtsson
Mustafa M. Aral Department of Water Resources Engineering
School of Civil and Environmental Engineering and Center for Middle Eastern Studies
Georgia Institute of Technology Lund University
Atlanta, Georgia Lund, Sweden
vii
James F. Cruise
Ximing Cai
Department of Civil and Environmental Engineering
Department of Civil and Environmental Engineering
University of Alabama in Huntsville
University of Illinois at Urbana-Champaign
Huntsville, Alabama
Urbana, Illinois
Allegra K. da Silva
Darryl E. Carlyle-Moses
Water Reuse Practice Leader - Rocky Mountain Region, MWH Global
Department of Geography and Environmental Studies
Denver, Colorado
Thompson Rivers University
Kamloops, Canada Baptiste Dafflon
Earth Sciences Division
Attilio Castellarin Lawrence Berkeley National Laboratory
Department of Civil, Chemical, Environmental and Materials Engineering - DICAM Berkeley, California
ALMA MATER STUDIORUM - Università di Bologna
Bologna, Italy Kumer Pial Das
Department of Mathematics
Serena Ceola
Lamar University
Department of Civil, Chemical, Environmental and Materials Engineering - DICAM
Beaumont, Texas
ALMA MATER STUDIORUM - Università di Bologna
Bologna, Italy Claus Davidsen
Department of Environmental Engineering
Cem P. Cetinkaya
Technical University of Denmark
Dokuz Eylül University
Kongens Lyngby, Denmark
Water Resources Management Research & Application Center (SUMER)
Izmir, Turkey Rodrigo Cauduro Dias de Paiva
Maria A. Charina Institute of Hydraulic Research
Water Problems Institute of the Russian Academy of Sciences Federal University of Rio Grande do Sul
Moscow, Russia Porto Alegre, Brazil
xvii
xix
xxi
Foreword xlix
Preface li
Acknowledgments lv
xxiii
52.14 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52-14
Acknowledgment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52-14
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52-15
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117-6
Useful Websites . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117-6
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131-3
Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I-1
Looking back when Ven Te Chow published his Handbook of Applied Hydrology in 1964, it was
without any doubt a landmark event for the water sector. Using his personal status as one of
the world’s leading water experts, he successfully managed to convince leading world authori-
ties on different aspects of water to contribute chapters in their areas of expertise. After the
book was published, it was universally acknowledged to be the most definitive and authorita-
tive text available on water resources management for well over a decade. This mammoth book
at 1,467 pages summarized and elaborated all the latest thinking and developments in different
areas of water.
It was a tribute to Chow’s encyclopaedic knowledge and versatility that he wrote several
chapters on very different topics himself. Later on, he confided to me that a few of the chapters
did not meet his high standards and thus he had to substantially rewrite them. Looked from
any direction, the depth and quality of the Handbook was a major contribution which ensured
that almost a generation of professionals used the text whenever they needed reliable informa-
tion on any aspect of water.
The Handbook was directly responsible for forging a lifelong friendship between Chow and
myself. When the book was published, I was starting my career at the University of Strathclyde,
Glasgow, as a lecturer. One of the British water journals requested me to write a review of all
the water texts available and suggest 3 to 4 that I considered the best and most useful. In the
mid-sixties, it was possible to read all the texts on water that were available since the number
was rather limited.
After I published my assessment in late 1964, I received a letter from a somewhat annoyed
Chow since this list did not include his latest tome Handbook of Applied Hydrology. I explained
to him that I did not omit the book deliberately. I fact, I knew the book was published and
available in the United States. Thus, I had written to McGraw-Hill asking if I could get a copy
of the book for my assessment purposes. McGraw-Hill responded by saying that the book was
indeed available in the United States but it would not be available in the United Kingdom for
another six months.
Chow, being the gentleman he was, immediately apologized for his letter. Shortly thereafter,
I moved to Canada. In the sixties, when I was a Director in the Government of Canada, Chow
invited me to come to the University of Illinois and give a talk during a meeting of the hydrol-
ogy professors in Urbana.
In early 1970, when Chow was considering the possibility of creating an interdisciplinary
and multisectoral professional water association, the International Water Resources
Association, he contacted me and requested me if I could be a founding member and help him
to establish a Canadian chapter of the new Association. We remained very good friends until
his untimely death.
There have been exponential scientific and technological developments in all water-related
areas, especially during the post-1980 period. Thus, advances in knowledge had made the
Handbook obsolete by the early 1980s. It is indeed a tribute to Chow’s genius that the book had
remained useful for such a long period.
xlix
I am delighted that Prof. Vijay P. Singh, Distinguished Professor and Caroline and William
N. Lehrer Distinguished Chair in Water Engineering, Texas A&M University, College Station,
Texas, is completely rewriting and updating Chow’s Handbook. Prof. Singh is a prominent
international authority in hydrologic sciences, and, in my view, he is easily within the top 0.1%
of all global water-related researchers. Only a person of Prof. Singh’s stature can undertake
such a Herculean task.
Following Chow’s footsteps mean these are big shoes to fill. From the manuscript, it is obvi-
ous to me that Prof. Singh has not only filled the big shoes completely but he has achieved
almost the impossible with panache and style.
Even with knowledge advancing at a significantly higher rate at present, compared to when
Chow first published the book in 1964, I have no doubt that the new and updated version of
this Handbook will remain the authoritative text for at least a decade. The new text is a fitting
memory and tribute to Chow’s enduring legacy, and also a fitting confirmation of Prof. Singh’s
global stature.
Singapore
October 18, 2015
Asit K. Biswas
Distinguished Visiting Professor
Lee Kuan Yew School of Public Policy
National University of Singapore
The original Handbook of Applied Hydrology, edited by V.T. Chow, was published in 1964.
The Handbook has had a major influence on hydrology. Since then it has been widely used as
a reference book and has inspired numerous hydrologists by its depth and breadth of coverage.
During the intervening period of over 50 years hydrology has witnessed phenomenal develop-
ment in both depth and breadth, with the result that it has become a full-fledged geophysical
science while still serving as a basis for engineering applications. The development has
occurred along four main lines. First, the 1960s witnessed the birth of a digital revolution and
the computing prowess has since expanded exponentially. Now-a-days portable laptops are
manyfold more powerful than a large computer that then filled an entire room. The enormous
computing capability permitted the birth of digital or numerical hydrology. Beginning with
the development of the Stanford Watershed Model in 1966, a large number of watershed mod-
els, simulating virtually the entire hydrologic cycle, were developed. One can easily count in
the world over one hundred watershed hydrology models in use these days. The development
of watershed models is still continuing, encompassing simulation of other aspects that are
associated with hydrology, such as atmospheric or hydrometeorological processes, hydraulics,
climate change, ecosystems, geo-biochemistry, and human interactions. Another area has been
the solution of hydrodynamic equations, be those of surface water, subsurface water, ground-
water, or water quality. Because of computers, it is now possible to simulate any component of
the hydrologic cycle in great detail and do inverse modeling as well.
Second, a tremendous growth in the development of new methods of solution, both deter-
ministic and stochastic, has occurred. On the deterministic side, new transform techniques,
optimization techniques, artificial intelligence methods, data mining, and numerical schemes
were developed. On the stochastic side, developments have been even greater. Examples are
copula theory, entropy theory, chaos theory, network theory, fractals, scaling theory, Monte
Carlo simulation, and so on.
Third, techniques for novel data collection, processing, storage, archiving, retrieval, and
sharing have reached unprecedented heights. Remote sensing methods, such as radar and
satellite technologies are now providing spatial data that were not even imagined prior to 1964.
Information technology is providing means for dissemination of information in seconds, per-
mitting hydrology to get closer to people as for example is happening in applications at farm-
ing scale. Another example is social hydrology, an emerging area that is gaining wide
recognition these days.
Fourth, new theories and new concepts have been developed, facilitated greatly by the afore-
mentioned three areas. We have witnessed the evolution of new concepts in geomorphology
and, more importantly, application of these concepts in watershed hydrology, hydrogeological
characterization, hydrometeorology, cryosphere, glaciology, geo-bio-chemical transport, land
use change, climate change, ecosystems science, medical hydrology, and the list goes on. In
some areas, developments have been so large that together they have given rise to new branch-
es of hydrology that were not even heard of prior to 1964.
It is, therefore, now appropriate to pause and take a stock of where we were, where we have
been and where the multiple disciplines that make hydrology should be going. This philosophy
served as the motivation for preparing the layout for the second version of the Handbook of
Applied Hydrology. The word “Applied” is important here. The emphasis in this version has
been on the application at the expense of deep science and mathematics. With these consider-
ations in mind, the subject matter of the handbook is divided into ten parts each containing a
li
number of chapters. The First Part is on fundamentals and contains three chapters that deal
with the hydrologic cycle, watersheds, river basins, land use, and water balance. This part
attempts to set the context for the handbook. For the science and engineering of hydrology to
progress, data and their collection and accessibility are the foundation. Therefore, the Second
Part of this handbook deals with data collection and processing. It comprises seven chapters
that discuss hydrometeorological data, streamflow data, rating curves, hydrologic information
systems, remote sensing and geographical information systems. This part is concluded with a
discussion on design of hydrologic networks.
Hydrologic analyses and syntheses entail tools from mathematics, statistics, physics, biolo-
gy, chemistry, information science, and social-economic science. Like hydrology, these areas
have witnessed enormous developments. Fortunately, hydrologists have been quite savvy and
open minded to borrow techniques from other disciplines and apply them in hydrology. Thus,
Part Three spans twenty six chapters and presents these methods. These chapters deal with
artificial neural networks; fuzzy logic; evolutionary computing; relevance vector machines;
harmonic analysis and wavelets; outlier analysis; infilling of missing records; regression analy-
sis; time series analysis; change detection and nonstationarity; spatial analysis and geostatisti-
cal methods; frequency distributions; model calibration and validation; sensitivity analysis;
Bayesian methods; optimization methods; nonparametric methods; uncertainty analysis and
decision making; risk-reliability assessment; scaling and fractals; nonlinear dynamics and
chaos; copula modeling; entropy theory; entropy production extremum principles; data-based
mechanistic modeling; decomposition methods; network theory; and hydroeconomic analysis.
Experimental and field data and a variety of methods to analyze them have helped uncover
hydrologic mysteries and better understand and model hydrologic processes. Therefore, Part
Four containing twenty six chapters is focused on hydrologic processes and modeling.
Beginning with a discussion of weather and climate, these chapters go on to discuss hydrocli-
matology; spatial and temporal analysis of precipitation; snowpack characteristics; precipita-
tion modeling; evapotranspiration; interception; detention and depression storage;
geomorphological characteristics; infiltration; soil moisture and the vadose zone; hydrogeo-
logic characterization; groundwater modeling; watershed runoff; streamflow generation;
snowmelt runoff generation; glacial melting; reservoir and channel routing; water logging and
salinization; surface water-groundwater interaction; saltwater intrusion; land subsidence;
hydraulic fracturing; catchment classification; rainfall-runoff modeling; continuous watershed
modeling; and calibration and evaluation of watershed models. The concluding chapter deals
with feasibility, engineering, and process models.
With growing awareness of the environment, water, air and soil quality started to receive
increasing attention in the 1970s and onwards. To that end, sediment and pollutant transport
are dealt with in Part Five that comprises nine chapters. Beginning with a discussion of water
quality, the chapters go on to discuss soil erosion; channel erosion and sediment transport;
sedimentation of floodplains, lakes and reservoirs; pollutant transport in surface water, vadose
zone and ground water; and salinization and salinity management in watersheds. The con-
cluding chapter discusses transport of biochemicals and microorganisms.
The availability of data and appropriate statistical methods facilitated analysis of extremes.
Part Six, therefore, includes nine chapters that discuss hydrometeorological and hydrologic
extremes. The subject matter includes atmospheric rivers; hurricanes and typhoons; extreme
rainfall; floods; flood frequency analysis; regional hydrological modeling and regional fre-
quency analysis; risk, reliability, return periods and hydrologic design; drought characteristics;
and analysis of low flow and drought.
In hydrology, many schools of thought are applied. One school emphasizes systems
approach where intrinsic system details are not considered in detail. This school of thought
was pervasive in the 1950s through the 1970s but the subject is still of great importance.
Therefore, systems hydrology constitutes the theme of Part Seven which contains twelve chap-
ters. These chapters discuss isotope hydrology; lake hydrology; urban hydrology; agricultural
hydrology; forest hydrology; coastal hydrology; wetland hydrology; arid zone hydrology; karst
hydrology; cryospheric hydrology; hydrology for transportation systems; and large-scale and
global hydrology.
Part Eight deals with the hydrology of large river basins and basins of lakes and seas span-
ning thirty-two chapters. The large river basins included are those of the Amazon River;
Parana (Rio de la Plata) River; Orinoco River; Nile River; Congo River; Zambezi River;
Euphrates and Tigris Rivers; Yangtze River; Yellow River; Mekong River; Yenisei River; Lena
River; Brahmaputra River; Ganga River; Narmada River; Indus River; Mississippi River;
Colorado River; Columbia River; St. Lawrence River; Rhine River; Danube River; Ob River;
Po River; Thames River; and Murray Darling River. The basins of the Great Lakes System and
the African Great Lakes are described in two chapters. The last four chapters on the basins of
the Aral Sea; the Baltic Sea; the Black Sea; and the Caspian Sea conclude this part.
Because the Handbook emphasizes application, Part Nine comprising twenty six chapters is
devoted to applications and design. Beginning with a discussion of design rainfall, the chapters
go on to discuss probable maximum precipitation; prediction in ungaged basins; stochastic
streamflow simulation and forecasting; flood forecasting and flash and real-time flood fore-
casting; reservoir design, regulation and operation; floodplain management; stormwater
management and low impact development; flood proofing and infrastructure development;
environmental flows; drainage and culvert design; wetland and river restoration; institutional
framework for water management; virtual water, water footprint, and peak water; transbound-
ary water management; integrated river basin management; conflict resolution; long distance
water transfer; the Indian river linking program; irrigation scheduling and management;
rainwater harvesting and groundwater recharge; reuse-reclaimed water in managed aquifer
recharge; and river bank filtration. This part is concluded with a discussion on the assessment
of climate change impacts and water resources.
Where the multiple disciplines of hydrology progress to is partly conjectured in the con-
cluding Part Ten that deals with the future in six chapters. These chapters discuss human
impacts on hydrology, climate change and its impact on the hydrologic cycle, human-hydrol-
ogy systems modeling, variability of hydrological processes and systems in a changing envi-
ronment, extraterrestrial water, and water security. This part is concluded with a discussion of
grand challenges.
It is hoped that the Handbook will become useful to college faculty, graduate students,
and researchers as well as practitioners in hydrology, water science and engineering, water
resources management, urban development, hydrometeorology, geosciences, environmental
and ecological sciences, and agricultural and forest sciences.
Vijay P. Singh
Texas A&M University
College Station, Texas
This Handbook is a result of the collective effort of the authors who have contributed the
chapters. It has been my privilege and honor to have known most of the authors for a long
time. They have long been at the forefront of hydrologic research and teaching or practice and
their rich experience and knowledge are hopefully reflected in the chapters they have written.
Their contribution symbolizes their love of labor and their desire to contribute to advancing
hydrology, for their time and effort are ad honorem. I am much grateful to the authors for
accepting my invitation to write the chapters and their cooperation during the preparation of
the Handbook. Without them, this Handbook would not have come to fruition, and it clearly
belongs to them.
I would like to express my deep gratitude to the members of two advisory boards: aca-
demic and practitioners. When the Handbook was being conceptualized, I often turned to
them for their advice on the chapter layout and identifying potential chapter authors. They
were more than willing to help and responded to my request promptly.
The chapters were peer reviewed and finding three or more reviewers for each of 156 chap-
ters was a challenge. They are too numerous to mention here, but I am grateful for the review-
ers’ constructive reviews.
I would like to acknowledge my family (wife Anita, son Vinay, daughter Arti, and grandsons
Ronin, Kayden and Davin) for their support and affection while I worked on this handbook
project. Without them, my task of completing the handbook would have been much more
difficult.
Finally, I want to express my gratitude to the McGraw-Hill staff, particularly Lauren
Poplawski, who were always willing to help and provide advice and suggestions.
lv
ABSTRACT of hydronium ions that are highly mobile and can wreak havoc. A positively
charged water molecule is a hydronium ion.
Hydrology can be called as the study of the hydrologic cycle. There are sev-
If we look at the structure of the water molecule, then it is found that the
eral biogeochemical cycles in nature that are interactive, but the dominant
hydrogen atoms are tied to the oxygen atom in a V-shaped arrangement at an
among these cycles is probably the hydrologic cycle. This chapter discusses
angle of 105° resulting in an asymmetrical configuration. This also means that
the hydrologic cycle and its association with carbon and nitrogen cycles. It
the shared electrons are closer to oxygen than to hydrogen and the charges are
also discusses the impact of climate change on the hydrologic cycle. Before
not evenly divided. This phenomenon is characterized as polarity. Thus, there
discussing the hydrologic cycle, it will be useful to discuss the characteristics
are two sides of the configuration, one side on which hydrogen atoms are
of water at a more fundamental level that impact the behavior of water at
located and the other opposite side. The hydrogen side tends to be electro-
large scales.
positive and the opposite side electronegative. When water changes from liq-
uid to solid or vapor or vice versa, the water molecules arrange themselves in
1.1 CHARACTERISTICS OF WATER
distinctly different patterns during the phase change. When water becomes ice,
Water is the most common substance on earth and covers more than 70% of the molecular arrangement of ice results in an increase in volume and a
its surface. It is vital for life on earth and for that matter anywhere in the decrease in density. The pattern of molecules is highly organized and is in a
universe. Water is a simple compound where each water molecule is com- rigid geometric form. When water freezes to ice, there occurs an expansion of
posed of two hydrogen (H) atoms and one oxygen (O) atom. This atomic molecules, causing ice to float on water. In the case of liquid water, water mol-
structure causes the water molecules to have unique electrochemical proper- ecules organize themselves in small groups of joint particles. It is this property
ties. Each hydrogen atom shares its single electron with the oxygen atom, and that permits water to move and flow. The molecules of water vapor tend not to
thus these atoms are bonded together as H-O-H. If we consider two water form bonds among themselves and are in a state of high energy, causing mol-
molecules, then it is seen that there occurs an attraction between a hydrogen ecules to be moving.
atom of one water molecule and the oxygen atom of another molecule. The The polarity characteristic is the cause for the attraction of water molecules
bonding between these molecules has low energy and is often referred to as to electrostatically charged ions and colloidal surfaces. This is how hydration
hydrogen bonding (Brady and Weil, 2008). This bonding is responsible for occurs. For example, cations, such as Na+, K+, and Ca2+, get hydrated because
polymerization of water as well as water’s high boiling point, specific heat, and of their attraction to the negative or oxygen end of water molecules. Likewise,
viscosity in comparison with other hydrogen-containing compounds. It is the negatively charged clay surfaces attract water through the positive or hydro-
structure of water molecule that determines its ability to influence soil pro- gen end of molecules. Salt gets dissolved in water because its ionic compo-
cesses as well as its existence as a liquid at temperatures observed on Earth, nents have more attraction for water molecules than for each other.
and makes it a powerful solvent. The bulk water, what is usually discussed in Water is found to have three phases: solid (as snow and ice), liquid, and
hydrology, is the collection of water molecules. The arrangement of these vapor. It is found in the liquid phase and the solid phase on the land surface
molecules, that constitutes the bulk water, is still being debated. and beneath, in the liquid phase only in the oceans and seas, and in the vapor
The retention and movement of water in soils are partly caused by two phase in the atmosphere. Recently, another phase, which is beyond these
forces: cohesion and adhesion. Cohesion is the attraction of water molecules three phases, has been discovered (Pollack, 2013). This is the fourth phase
for each other, and adhesion is the attraction of water molecules for solid and is referred to the “exclusion zone” (EZ).
surfaces. In soil water, adhesion is also called adsorption. In the soil, the water The EZ forms next to the many submerged materials and is unexpectedly a
molecules are attached to solid surfaces by virtue of adhesion. These water large zone of water. It derives its name from the fact that it excludes practically
molecules are attached to other water molecules by virtue of cohesion, and everything. It contains a lot of charge and its characteristics are different from
these are attached to other molecules farther away from the solids, and so on. those of the bulk water. There are many water-related mysteries or phenomena
Thus, through forces of cohesion and adhesion, the water is retained and it in nature that we observe but we do not understand them well, because they
moves through the soil. The forces of cohesion and adhesion are also respon- comprise the EZ that we do not quite understand. In his masterpiece book,
sible for another property of water, called surface tension, commonly Pollack (2013) details such phenomena and the social behavior of water.
observed at the liquid-air interfaces. Surface tension together with adhesion Examples of such mysteries include water serving as a glue when building sand
causes capillarity (the ability of a liquid to flow in narrow spaces without the castles from wet sand, tsunami waves traveling very long distances before
assistance of, and in opposition to, external forces like gravity). petering out, slipperiness of ice, swelling upon bruising or breakage, freezing
It is known that electrons and protons are the elementary units of charge warm water, flow of water upward from plant roots through narrow columns,
and they have opposite charges, that is, one has a positive charge, while the cracking of concrete by upwelling tree roots, spreading of droplets on surfaces,
other has a negative charge. Electrons and protons play a central role in deter- walking on water, formation of isolated clouds, floating of ice, consistency of
mining how water behaves. Since the oxygen atom has a charge of –2 and each yogurt, migration of microspheres away from the center in a beaker of water,
hydrogen atom has a plus charge, the water molecule is reduced to have no the bridge made up of water, and floating water droplets, among others. These
charge or is neutral, since the negative and positive units of charge cancel each phenomena entail crowds of water molecules, not water at the molecular level.
other. When protons latch on to water molecules, the result is the formation Nevertheless, they defy easy explanation and show that we know little about
1-3
the interaction of water molecules with other water molecules or water’s social 1.3 HYDROLOGIC CYCLE
behavior. Surprisingly, we understand little about Earth’s most common sub-
There are two systems through and between which the water moves: Earth
stance—water. Water has some unique properties that no other liquid on Earth
and atmosphere. Earth can be divided into oceans and seas, and the land part.
seems to enjoy. It has high specific heat, conducts heat more easily, has a neural
Oceans and seas form what is called the hydrosphere. The land part, also
pH, is a universal solvent, has high surface tension, exists in all three phases,
called land sphere, is divided into the land surface part and subsurface part
occupies larger volume upon freezing, and has maximum density at 4°C.
that includes unsaturated (soils) and saturated parts (geologic formations).
The land surface also includes water bodies, such as lakes and reservoirs,
1.2 DEFINITION OF HYDROLOGY
wetlands, canals and rivers, channels, and lagoons. The unsaturated part is
referred to as pedosphere and the saturated part as lithosphere. The charac-
Hydrology deals with bulk water primarily in liquid, gaseous, and solid teristics of water movement, distribution, occurrence, and storage are differ-
phases. This means that hydrology incorporates the study of snow and gla- ent in these spheres, and to understand these characteristics, this partitioning
ciers. It deals with both quality and quantity that vary in space and time, so is essential. The interconnectivity of these spheres is essential for water mov-
hydrology deals with how water is distributed. Water occurs over the land ing through the hydrologic cycle.
surface, in soil, and in geological formations. Water is dynamic, so hydrology On the continents, the water evaporates from the hydrosphere, pedo-
deals with the movement of water (surface and subsurface). Water can be sphere, and lithosphere, and is transpired by vegetation and plants into the
stored in lakes and reservoirs as well as in subterranean environment, so atmosphere. The water vapor moves in the atmosphere, and under suitable
hydrology deals with the storage of water. The occurrence, distribution, conditions, it condenses and precipitates over the land surface and over
movement, and storage of water quality and quantity are not always entirely oceans and seas. The liquid part of the precipitated water (or melted snow
deterministic, so hydrology encompasses their statistical characteristics. and ice) runs off in part over the land surface and in part into the pedosphere
Thus, hydrology can be defined as the science that deals with the space, time from where water either transpires/evaporates back to the atmosphere or
and frequency characteristics of the occurrence, distribution, movement, and percolates to groundwater (or lithosphere). Evaporation takes place from
storage of the quantity and quality of the waters of the Earth. open surfaces (rivers, lakes, wetlands, etc.) as well. The water that is not
Frequently, hydrology is partitioned into surface-water hydrology, vadose reevaporated back to the atmosphere continues to the oceans, where a net
zone hydrology, groundwater hydrology, and snow and glacier hydrology. In evaporation takes place. Conversely, a net precipitation occurs over the con-
all of these partitions, both water quantity and quality are dealt with. To tinents. This endless circulation of water from the hydrosphere and land
emphasize quality aspects, water quality hydrology is sometimes considered a sphere to the atmosphere and back is called the hydrologic cycle. It has no
separate branch. Likewise, other partitions of hydrology are agricultural beginning and no end.
hydrology, forest hydrology, wetland hydrology, environmental hydrology, The hydrologic cycle can be viewed as a natural machine, a constantly run-
ecosystems hydrology, atmospheric hydrology, arid lands hydrology, coastal ning, distillation and pumping system. The primary source of energy for the
hydrology, urban hydrology, and geohydrology. These partitions point to the operation of this machine is the Sun that supplies heat energy. In Fig. 1.1, the
broad scope and the interdisciplinary nature of hydrology. Also, these branch- spatial and temporal averages of these energy components are illustrated. Of
es are not entirely insulated from each other. Hydrology should be viewed in particular importance for hydrology is the loss of heat energy from the Earth’s
a broader context, for water is sometimes on the surface and at other times, it surface. The 29% share of heat loss can be further subdivided into 22% loss as
is below the surface but then again it reappears on the surface. latent heat and 7% loss as sensible heat. It should be emphasized that there are
Depending upon the methods of analysis and synthesis, hydrology is also huge variations from the average picture both in time (diurnal, seasonal, and
divided into different branches, such as mathematical hydrology, numerical yearly) and in space. Together with the force of gravity, this energy keeps the
hydrology, digital hydrology, systems hydrology, parametric hydrology, water moving as evaporation and transpiration from the earth to the atmo-
empirical hydrology, statistical hydrology, and stochastic hydrology. Based on sphere, as condensation and precipitation from the atmosphere to the earth,
the emphasis of scientific concepts, hydrology can be divided into physical and as streamflow and groundwater from the Earth to the oceans. Thus, the
hydrology, chemical hydrology, and biological hydrology. hydrologic cycle encompasses three major systems with the hydrosphere as
30% reflected
and scattered 70% radiated
(342 W/m2)
100%
26% reflected
and scattered 65% radiated
109% absorbed
96% radiated
26% absorbed 5% lost back down
Earth’s
to space
atmosphere
29% lost
as latent
4% reflected Greenhouse and
effect sensible
heat
Back
radiation
Earth’s
surface 47% absorbed
Precipitation
on land
Surface Evaporation from land
runoff Precipitation
Evapotranspiration on ocean
Freshwater
storage Evaporation
Lake Sub
Infiltration sur
fac
e flow Evaporation from ocean
Lake
Surface outflow
Groundwater flow
Groundwater outflow
Ocean
Groundwater
storage
Ocean
storage
Figure 1.2 The hydrologic cycle [Source: http://water.usgs.gov].
the major source of water, the atmosphere as the deliverer of water, and the land surface, replenishing soil moisture, and percolating down to recharge
land sphere as user of water. groundwater. Part of the infiltrated water includes subsurface runoff or inter-
It may be noted that water is transported, temporarily stored, and may flow, and groundwater runoff or baseflow. Part of rainfall and snowmelt runs
change state in each sphere. Consider, for example, the atmosphere where off over the land surface, joins streamflow, and eventually joins the sea.
water occurs as vapor flow, stored as vapor storage in the atmosphere, and Streamflow includes surface runoff as well as subsurface runoff. It may be
condenses and precipitates under change of state from vapor to either that of noted that these different components have different time scales and their
liquid or solid. Much more water stays in storage for longer periods of time significance is different at different scales.
than in movement through the hydrologic cycle.
1.5 SCHEMATIC REPRESENTATION OF THE
1.4 COMPONENTS OF THE HYDROLOGIC CYCLE HYDROLOGIC CYCLE
The major components of the hydrologic cycle are precipitation, evaporation, The hydrologic cycle can be illustrated as shown in Fig. 1.2, depicting the
infiltration, groundwater, and streamflow. Precipitation includes all forms of various components and their principal directions of flow. This, however, does
water that falls from the atmosphere, including rainfall, snowfall, hail, sleet, not provide any information on the relative significance of these components
drizzle, dew, and fog. Rainfall and snowfall constitute the main forms of pre- which varies with the space (watershed, land system, and global) and time
cipitation. Snow is a form of stored water that remains where it falls until scales. The cycle is truly an endless circulation at the global scale, but not
melting occurs. Each year, approximately 505,000 km3 (121,000 mi3) of water necessarily so at smaller scales. At the global scale, the atmosphere, the hydro-
falls as precipitation of which about 78% [approximately 398,000 km3 (95,000 sphere, and the land sphere are connected and interactive, as shown in Fig. 1.3.
mi3)] falls over the oceans. The precipitation falling as rain is about 107,000 The major components of the cycle at this spatial scale are precipitation,
km3 (26,000 mi3) and as snow is about 1000 km3 (240 mi3). Precipitation is evaporation and transpiration, and streamflow. The time scale is also much
partitioned into four parts: (1) interception, (2) evaporation, (3) infiltration, larger and hence more transient components, such as infiltration, surface
and (3) runoff. Part of precipitation is intercepted by trees, buildings, and other runoff, interception, etc., become embedded in other components. The global
abstract objects. Most of this portion is evaporated to the atmosphere. A small scale hydrologic cycle is a closed system and it is normally neither modeled
portion of snow also evaporates. Oceans contribute about 86% of global nor used for water resources planning and management at this scale. The
evaporation that reduces oceanic temperature through evaporative cooling. general circulation models are, however, employed for climate impact studies.
Part of rainfall fills surficial depressions, forming small ponds, where some Of greater significance is the hydrologic cycle at the watershed scale which
water infiltrates and some evaporates. Another part of rainfall infiltrates the can be quite small or very large. At this spatial scale, all components of the
Precipitation
Evaporation
Figure 1.3 A global schematic of the hydrologic cycle [Source: Singh, 1992].
Precipitation Global
Global Global
ET weather CO2
systems variations
10,000 Km
Development
Land system Surface of major
runoff river rasins
Soil
1000 Km formation
Runoff
Exfiltration Infiltration cycle
Space
Mesoscale Drainage
100 Km weather Mesoscale network
systems soil Soil formation
Subsurface (floods) moisture erosion
Subsurface system variation Shallow
runoff 10 Km
ground
Stream Nutrient water
flow cycles circulation
Upward
Percolation 1 Km Thunder
moisture
(recharge) storm
movement
Time Log/
Local
Ground water 2 4 6 8 10 12 14 16 second
Aquifer system runoff
Second Minute Day Year Century One million One billion
years years
Figure 1.4 A schematic of the hydrologic cycle of the earth system [Source: Singh, 1992].
Figure 1.5 Spatial and temporal scales of hydrologic processes and cycle
[Source: National Researach Council, 1991].
hydrologic cycle play their role, but the significance of their role depends on
the time scale. For example, at small time scales, evapotranspiration may not
be significant, but infiltration plays a dominant role. The reverse happens at The spatial and temporal scales of some hydrologic processes and cycles are
the large time scale. If the watershed is forested or highly urbanized, then shown in Fig. 1.5.
interception may be significant. At a large watershed scale, the hydrologic
cycle is illustrated in Fig. 1.4. 1.6.2 Spatial Scales
Spatial scales that are important for hydrologic investigations are hillslope,
catchment, basin, regional, continental, and global. At the global scale, the
1.6 SCALES IN HYDROLOGIC CYCLE
atmosphere, the hydrosphere, and the land and lithosphere are strongly con-
The significance of the components of the hydrologic cycle is closely con- nected through the processes of precipitation, evaporation, and runoff. Global
nected with their space and time scales. Further, mathematical relationships fluxes and circulation patterns are investigated at this scale and are important
describing the different components depend on the scale. Therefore, these for assessing the impact of climate change on the hydrologic cycle. Figure 1.2
scales play a critical role when simulating the cycle or the components shows a global view of the hydrologic cycle.
thereof. The catchment scale has a very broad range, ranging from a few square
kilometers to tens of thousands of kilometers. For small catchments, the pro-
1.6.1 Time Scales cesses of precipitation, runoff, infiltration, soil moisture, and runoff are most
The components of the hydrologic cycle have vastly different time scales of important. As catchment becomes large, groundwater in most cases also plays
movement and residence times. The residence time of a reservoir is the an important role.
average time the water will spend in the reservoir (i.e., the storage divided
by the flux through the reservoir), and thus is also a measure of the age of
1.7 IMPACT OF CLIMATE CHANGE ON THE
water of that reservoir. For example, the rate at which surface runoff moves HYDROLOGIC CYCLE
is very high as compared with that of groundwater. Likewise, the residence
time of surface water is a small fraction of that of groundwater. Groundwater It is now widely accepted that as a result of anthropogenic influences, there is
may reside for over 10,000 years below the earth’s surface before leaving, global warming and the climate is changing. The increased emission of green-
whereas water spends about 2–6 months in rivers, about 1–2 months in the house gases is considered to be the principal cause of increase in Earth’s tem-
soil, and only a little over a week in the atmosphere. These times play a perature. This is supported by measured temperature data series as well as
critical role in numerical simulation of the hydrologic cycle. The time step paleoclimatological records. The implications of climatic change for the hydro-
should be sufficiently small so that the variations in the component pro- logic cycle are many. The increase in temperature would cause higher evapo-
cesses are captured in sufficient detail without putting undue burden on transpiration; changes in patterns, timing, intensity, and distribution of
data collection and computational efforts. Shiklomanov (1999) has pre- precipitation; melting of polar ice caps and recession of glaciers; more fre-
sented the estimated periods of renewal of water resources on the earth, as quently occurring droughts; increased frequency of flooding; higher melting
shown in Table 1.1. of polar ice and glaciers; sea water level rise; inundation of islands of low eleva-
tions as well as cities adjacent to seas; changes in vegetation dynamics; ecosys-
tem health; and so on. These changes are already being witnessed. Nevertheless,
Table 1.1 Periods of Water Resources Renewal on the Earth it is not understood with acceptable degree of certainty as to what, where, and
how much changes are or will occur. On the other hand, an increase in tem-
Water of hydrosphere and land sphere Period of renewal
perature may mean greater precipitation, some of which may occur in the form
World Ocean 2,500 years of snow at the poles, leading to an additional accumulation of ice.
Groundwater 1,400 years
Since the three spheres constitute a continuum, changes in the land sphere
and lithosphere would cause a change in the climate. For example, changes in
Polar ice 9,700 years vegetation mean changes in evapotranspiration, soil moisture, albedo and
Mountain glaciers 1,600 years radiation balance; burning of fossil fuels; increased use of water day-to-day
Ground ice of the permafrost zone 10,000 years
needs; increased irrigation; increased industrial activities; and large-scale
water transfer between basins would contribute to climate change. Climate
Lakes 17 years change manifests itself in changed patterns of spatial and temporal variability
Bogs 5 years in the components of the hydrologic cycle.
Soil moisture 1 year
Channel network 16 days 1.8 INFLUENCE OF HUMAN ACTIVITIES AND LAND USE
CHANGES ON HYDROLOGIC CYCLE
Atmospheric moisture 8 days
There are a multitude of changes, minor or major, caused in watersheds by
Biological water Several hours
human activities. These changes influence virtually all components of the
[Source: Shiklomanov, 1999] hydrologic cycle. The watershed changes can be either point or nonpoint
changes. Examples of point changes are structural changes, such as dam con- peak of outflow from the reservoir and the volume of flow downstream may
struction, channel improvement, and detention storage, and these changes be considerably reduced if the reservoir water is diverted elsewhere. Channel
affect watershed response in terms of evaporation, seepage, residence time, improvements include straightening of the channel, removal of vegetation,
etc. Examples of nonpoint land use changes, that affect catchment response, lining of the channel, maintenance of bends, or increasing slope. These
include forestry, agriculture, mining, and urbanization. The seriousness of changes may translate into decreased channel roughness increasing flow
hydrologic consequences depends on the magnitude of watershed changes. velocity and hence peak discharge. Depending upon the bed material, infiltra-
There is growing need to quantify the impact of man-made changes on the tion through the bed and banks also modifies flow characteristics.
hydrologic cycle in order to anticipate and minimize the potential environ-
mental detriment and to satisfy water resources requirements of the society. 1.9 RELATION BETWEEN HYDROLOGIC CYCLE AND
Agricultural operations exercise a significant influence on the hydrologic CARBON AND NITROGEN CYCLES
response of watersheds. Agriculture alters land cover, influencing evapotrans-
piration; changes upper soil layers, altering infiltration, soil moisture, leach- The hydrologic cycle is a biogeochemical cycle. The movement of water over
ing and evaporation; irrigating land, causing recharge and changing water and below the Earth is fundamental to the cycling of biogeochemicals. This
table; applying fertilizers, causing soil and water pollution; and tilling the soil, suggests that the hydrologic cycle not only impacts other biogeochemical
causing soil erosion by wind and water. These changes lead to changes in cycles, such as the carbon cycle and the nitrogen cycle, but is also impacted
evapotranspiration, overland flow, channel flow, and infiltration. by them in a feedback system. Consider, for example, runoff and streamflow.
Urbanization transforms forested and agricultural land into urban areas Eroded sediment and phosphorus are carried by surface runoff to streams
where houses, roads, schools, buildings, shopping malls, parks, parking lots, and rivers and further on to water bodies. Phosphorus, applied to agricul-
sewers, etc., are constructed. Urbanized lands are dominated by paved or tural lands through fertilizer in excess of what plants consume, is carried by
impervious surfaces that reduce infiltration and evapotranspiration and surface runoff to lakes and reservoirs, and that causes eutrophication.
increase storm water. The hydrologic effects of urbanization include increases Likewise, nitrogen is transported by surface runoff and groundwater and
in the volume and peak of direct runoff for a given rainfall; reduction in time streamflow to water bodies. As an example, the water has become hypoxic in
of travel resulting in lower lag time and lower time of concentration; diminu- the Gulf of Mexico as a result of nitrates from fertilizer being transported by
tion of baseflow; reduction in infiltration; increase in the withdrawal of runoff from agricultural lands to rivers and then by the Mississippi. Transport
groundwater; increase in pollution of rivers and aquifers; endangering the of eroded sediment and dissolved salts causes salinity of the oceans and seas.
ecology; and increase in temperature of urban areas, causing a change in
1.9.1 Carbon Cycle
microclimate.
The principal forest activities are afforestation (planting trees), deforesta- Carbon is ubiquitous in all living things as well as is part of nonliving things,
tion (cutting trees), and management. Forest management includes road con- such as ocean, air, and earth. Fossil fuels, such as coal and oil, are made of
struction, erosion control and water management, electrification, and chemical carbon. By joining oxygen, it forms carbon dioxide that is present in the
sprays. The immediate effect of these activities is the change in vegetal cover. atmosphere. The movement of carbon back and forth among biosphere,
Deforestation virtually eliminates the interception of precipitation. Forest litter atmosphere, hydrosphere, and geosphere defines the carbon cycle, as shown
removal changes infiltration capacity of the soil and has a pronounced effect in Fig. 1.6. It is one of the biogeochemical cycles and consists of various
on raindrop impact and the resulting soil erosion. With the loss of vegetative sinks and stores of carbon and processes by which sources and sinks
cover, evapotranspiration decreases. These changes increase direct runoff, exchange carbon.
reduce surface roughness, and decrease recharge to groundwater. The carbon cycle is a closed system, suggesting a fixed amount of carbon in
Typical structural changes include a dam, a weir, levees, spurs, dykes, dredg- the world. The processes in the carbon cycle are interactive. Fossil fuel burn-
ing, channel improvement works, etc. A dam reservoir, in general, reduces the ing and land use change are two of the important processes impacting the
Sunlight
Auto and
factory
CO2 cycle emissions
Photosynthesis
Plant
respiration
Animal
respiration
Organic carbon
Root
Decay
respiration
organisms Dead organisms
and waste products
Ocean
Fossils and fossil fuels uptake
balance of carbon. Oceans contain the greatest amount of actively cycled nitrogen into compounds, such as nitrate or ammonia, which can be used by
carbon in the world. Only the lithosphere stores more carbon than oceans. plants. This “fixed” nitrogen (or reactive nitrogen) is a limiting factor for plant
The geologic component of the carbon cycle operates more slowly than other growth in both managed and wild environments.
parts of the global carbon cycle. Carbon leaves the geosphere in several ways, The nitrogen cycle, as shown in Fig. 1.7, is the process by which nitrogen is
for example, during the metamorphosis of carbonate rocks. transformed to various chemical forms through biological and physical pro-
In the atmosphere, carbon exists primarily in gaseous form as carbon diox- cesses. Important processes in the nitrogen cycle include fixation, ammonifi-
ide (CO2) and methane. Both these gases absorb and retain heat in the atmo- cation, nitrification, and denitrification. The nitrogen cycle constitutes an
sphere, and are partly responsible for the greenhouse effect. In comparison important component of the ecosystem. The nitrogen cycle has hydrologic
with carbon dioxide, methane produces a large greenhouse effect per volume, significance because the availability of nitrogen affects the rate of key ecosys-
but it exists in much lower concentration and is more short-lived. This tem processes, including primary production and decomposition. When
explains why carbon dioxide is a more important greenhouse gas than meth- plant and animal wastes decompose, they add nitrogen to the soil. Bacteria in
ane. Carbon dioxide traps heat in the atmosphere, and were it not for it and the soil convert those forms of nitrogen into forms that plants can use. Plants
other greenhouse gases, the earth would be a frozen planet. Because of so use the nitrogen in the soil to grow. People and animals eat plants; then ani-
much more emission of carbon dioxide to the atmosphere, we are experienc- mal and plant residues return nitrogen to the soil again, completing the cycle.
ing global warming. Human activities, such as fossil fuel combustion, use of artificial nitrogen
Plants employ carbon dioxide and sunlight to make their own food fertilizers, and release of nitrogen in wastewater, significantly impact the
through the process of photosynthesis, and carbon becomes part of plants. On global nitrogen cycle.
burning fossil fuels, most of the carbon enters the atmosphere as carbon Nitrogen enters the nitrogen cycle from different sources: (1) air through
dioxide. Living beings release CO2 back to the atmosphere during respiration. several unique types of microorganisms that can convert N2 gas to inorganic
Large exchange of CO2 also takes place between the hydrosphere and the forms usable by plants; (2) manure and decaying of plant materials; (3) appli-
atmosphere. The dissolved CO2 in the oceans is used by marine biota for cation of commercial nitrogen fertilizers; and (4) as inorganic nitrogen from
photosynthesis, thus carbon dioxide is entering the oceanic biosphere as well. the atmosphere and factories. It leaves the cycle in four ways: (1) denitrification,
Also, from the atmosphere carbon dioxide directly dissolves into water bodies (2) bacteria change nitrate in the soil to atmospheric nitrogen, (3) volatilization,
(oceans, lakes, reservoirs, etc.) as well as dissolves in precipitation as rain- and (4) turning urea fertilizers and manures on the soil surface into gases.
drops. When dissolved in water, it reacts with water molecules and forms Nitrogen reenters the cycle through one of the aforementioned processes or
carbonic acid that contributes to the ocean acidity. Carbon leaves the terres- through other processes. As shown in Fig. 1.7, nitrogen changes from organic
trial biosphere in different ways and at different time scales. For example, matter in the soil, to bacteria, to plants, and back to the organic matter.
combustion releases organic carbon rapidly into the atmosphere. Carbon Nitrogen is present in the environment in a variety of chemical forms:
stored in soil can remain there for up to thousands of years before being organic nitrogen, ammonium (NH4+), nitrite (NO2−), nitrate (NO3−), nitrous
washed into rivers by erosion or released into the atmosphere through soil oxide (N2O), nitric oxide (NO), or inorganic nitrogen gas (N2). Figure 1.7
respiration. shows how these processes fit together to form the nitrogen cycle.
The main component of the nitrogen cycle starts with the element nitrogen
1.9.2 Nitrogen Cycle in the air. Upon interaction with oxygen, several compounds, such as nitric
Nitrogen (N2) is a colorless, odorless, nontoxic gas, and is essential for all oxide (NO) and nitrogen dioxide (NO2) are formed. Eventually nitrogen
known forms of life on Earth. Being close to 78%, it is the largest constituent dioxide may react with water in rain to form nitric acid (HNO3), which may
of the atmosphere, but this form is relatively nonreactive and unusable by be utilized by plants as a nutrient. Nitrogen in the air becomes part of the
plants. Nitrogen in plants is used in chlorophyll molecules, which are essential biological matter through bacterial action and algae through a process called
for photosynthesis and plant growth. Natural fixation converts gaseous nitrogen fixation. Legume plants, such as clover, alfalfa, and soybeans, form
nodules on the roots, where nitrogen-fixing bacteria take nitrogen from the 1.10 CONCLUSION
air and convert it into ammonia (NH3). The main source of nitrogen in soils
The hydrologic cycle is receiving a lot of attention these days from various
is from organic matter, which largely arises from plant and animal residues.
quarters of the society, partly because of climate change; frequently occurring
The conversion of ammonia to nitrate is performed primarily by soil-living
natural disasters, such as floods and droughts; increasing demand for water;
bacteria and other nitrifying bacteria. Onsite sewage facilities, such as septic
and the growing recognition of water-energy-food nexus. Even laymen are
tanks, release large amounts of nitrogen into the environment by discharging
now talking about the specter of climate change and the hydrologic cycle.
through drain fields into the ground.
Fortunately, in primary and junior high schools, the hydrologic cycle is being
Ammonia (NH3) is highly toxic to fish, and the level of ammonia discharged
taught and this is causing an interest in water issues and climate change at the
from wastewater-treatment facilities must be closely monitored. Nitrogen and
grass root level. The hydrologic cycle is fundamental to other cycles and it is
hydrogen react under great pressure and temperature in the presence of a
important that the cycle is managed properly. The fate of human civilization
catalyst to make ammonia. The reaction of ammonia and nitric acid produces
and economic prosperity will depend on how well water is managed. Ancient
ammonium nitrate, which may be used as a fertilizer. Animal wastes when
civilizations understood this dependence well. It is now time to learn from
decomposed also return to the Earth as nitrates. Nitrate is a concern for water
them and begin a concerted effort to respect nature and its fundamental ele-
quality when it is converted to the nitrate (NO3–) form because nitrate is very
ments, especially air, water, and soil.
mobile and easily moves with water in the soil. High levels of nitrates can be
toxic to newborns, causing anoxia or internal suffocation.
REFERENCES
Denitrification is the reduction of nitrates back into the largely inert N2 gas,
completing the nitrogen cycle. This process is performed by some bacterial Brady, N. C. and R. R. Weil, The Nature and Properties of Soils, Pearson/
species in anaerobic conditions. Nitrous oxide gas (N2O) is a side product of Prentice Hall, Columbus, OH, 2008.
this reaction. It is also produced as a result of agricultural fertilization, bio- PhysicalGeography.net, Introduction to the Hydrosphere, http:www.
mass burning, cattle and feedlots, and industrial sources. Nitrous oxide is also physicalgeography.net/fundamentals/8n.html. Accessed on April 20, 2015.
a greenhouse gas and is currently the third largest contributor to global National Research Council. Opportunities in the Hydrologic Sciences,
warming, after carbon dioxide and methane. Although not as abundant in the National Academy of Sciences, National Academy Press, Washington, D.C.,
atmosphere as carbon dioxide, for an equivalent mass, it is nearly 300 times 1991.
more potent in its ability to warm the planet. Pollack, G. H., The Fourth Phase of Water: Beyond Solid, Liquid and Vapor,
In the atmosphere, ammonia (NH3) acts as an aerosol, decreases air quality Ebner & Sons Publishers, Seattle, Washington, D.C., 2013, p. 357.
and clings to water droplets, eventually resulting in nitric acid (HNO3) that Shiklomanov, I. A., World Water Resources: Modern Assessment and
produces acid rain. Ammonia and nitrous oxides actively alter atmospheric Outlook for the 21st Century (Prepared in the framework of IHP, UNESCO),
chemistry. They are precursors of tropospheric ozone production, which con- State Hydrology Institute, St. Petersburg, Russia, 1999.
tributes to smog and acid rain, damages plants, and increases nitrogen inputs Singh, V. P., Elementary Hydrology, Prentice Hall, Englewood Cliffs,
to ecosystems. New Jersey, 1992.