Chapter 7 : Chemical Energetic

7.1 Enthalpy Changes

A. Definition of Standard enthalpy change of ……

formation

combustion

neutralisation

atomisation

ionisation
energy

electron
affinity

hydration

solution

lattice energy

bond energy
B. Write the thermochemical equations to represent the …………………………………………………………………………………….
standard enthalpy change of formation for the following
substances. 11. Hg(l) → Hg(g)
1. NH3 (-46.1 kJ mol-1) …………………………………………………………………………………….

12. O(g) + e- → O ̄ (g)

…………………………………………………………………………………..
2. CaCO3 (-1207 kJ mol-1)
13. ½O2(g) → O(g)
……………………………………………………………………………………

3. NO2 (+34 kJ mol-1) 14. Cu(s) + S(s) → CuS(s)

…………………………………………………………………………………….

15. C2H5OH(l) + 3O2(g) → 2CO2(g) + 3H2O(l)

4. CCl4 (-107 kJ mol-1) ……………………………………………………………………………………

D. Write balanced equations to show the following

enthalpy changes.
5. CH3COOH (-484.5 kJ mol-1) 1. Combustion of methanol

2. Combustion of magnesium

C. Name the enthalpy changes shown by the following

equations. 3. Combustion of sulphur dioxide
1 3
1. PH3(g) + 2O2(g) → P4H10(s) + H2O(l)
4 2
4. Formation of benzene
…………………………………………………………………………………

2. NaCl(s) → Na+(aq) + Cl ̄ (aq) 5. Atomisation of chlorine

…………………………………………………………………………………..

3. 4NH3(g) + 5H2O(l) → 4NO(g) + 6H2O(l) 6. Atomisation of sodium

…………………………………………………………………………………….
7. Second ionisation energy of calcium
4. Cl ̄ (g) → Cl ̄ (aq)
…………………………………………………………………………………….
8. First electron affinity of hydrogen
- 2-
5. S ̄ (g) + e → S (g)
……………………………………………………………………………………. 9. Hydration of zinc ion.
6. HF(aq) + NaOH(aq) → NaF(aq) + H2O(l)
……………………………………………………………………………………… 10. Solution of lead(II) bromide

7. Mg(s) → Mg(g)
11. third ionisation energies of iron
……………………………………………………………………………………

8. N2(g) → 2N(g) 12. Bond energy of hydrogen chloride.

…………………………………………………………………………………….

9. Al2+(g) → Al3+(g) + e-1 13. First ionisation energy of potassium

…………………………………………………………………………………….
14. Neutralisation of nitric acid and ammonia
10. C(g) + 2H2(g) + ½O2(g) → CH3OH
15. Formation of potassium manganate(VII)