Professional Documents
Culture Documents
A
Abrasive blast cleaning 322
Absorptive index, of unalloyed copper 450
Acceleration (activation) 147
Acetate solution, corrosion by 412
Acetate solvents
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Acetic acid
corrosion by 405(T)
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Acetone
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Acetylene
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Acid corrosion 404(F,T)
Acid dipping 326(F) 332
Activation energy, for volume diffusion 235
Adhesive bonding 303 318(F,T)
Admiralty metal brass. See also Brasses, tin.
composition 7
description 7
Aesthetics, copper and copper alloy consumption in U.S. (1977) 3(T)
Age hardening. See Precipitation heat treatment.
Aging 249 255
of beryllium copper-nickel 72C 563
of beryllium copper 21C 562
of bronzes, aluminum, wrought 513
Aging (Cont.)
of copper alloys, high-copper 471 473 475(F) 476 477
529 530(F) 532 533 534(F)
535 536(F)
of copper-nickels 560
of coppers, 99.3 min 467
effect on electrical conductivity 4
equipment 250 254(F)
interrupted 255
Agitation 12
Air bending in a press brake 209(F)
Alcohols
corrosion by 409 411(T)
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Aldehydes
corrosion by 409 410(T)
corrosion ratings, wrought copper alloys 393(T)
Alkaline cleaning 325(T)
Alkalis, corrosion by 407(T)
Alkylamines, corrosion ratings, wrought copper alloys 393(T)
Alloying, effect on electrical conductivity 4(F)
Alloy terminology 6
Alpha-beta brass
composition 7
description 7
Alpha-brass 247
corrosion 419(T) 421(F) 424(F)
extrusion 221
stress-corrosion cracking 419(T) 421(F)
techniques used for studying stress-corrosion cracking of 426(T)
Alpha phase 103
of copper-aluminum alloys 48(F) 51
of copper-beryllium alloys 53
of copper-tin alloys 46
description 7
effect on copper-zinc alloys 37(F) 39(F,T)
Alumina, corrosion ratings, wrought copper alloys 393(T)
Aluminum
alloying element effect on electrical conductivity of copper 182(F)
atom diameter size difference 36(T)
content effect on stress-corrosion cracking 423(F)
content effect on weldability 278
corrosion ratings, atmospheric 10- and 20- year exposures 396(T)
effect on electrical conductivity of oxygen-free
high-conductivity copper 4(F)
effect on electrical resistivity as solute addition 4(T)
physical properties 31(T)
solubility in copper 36(T)
solubility limits in copper alloys 4(T)
unalloyed, physical properties 4(T) 5(T)
Aluminum alloys
copper as alloying element 168
machinability 6(F) 265(F)
physcial properties 4(T) 5(T)
Aluminum brass. See Brasses.
Aluminum bronze. See Bronzes, aluminum.
Aluminum bronze hardfacing alloys 150(T)
Aluminum chloride
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Aluminum hydroxide, corrosion ratings, wrought copper alloys 393(T)
Aluminum sulfate, corrosion ratings, cast copper alloys 98(T)
Aluminum sulfate/alum, corrosion ratings, wrought copper alloys 393(T)
American Wire Gauge (AWG) system 68 70(T) 71(T) 72(T) 73(T)
74(T) 75(T)
Amines, corrosion by 412
Amine system service, corrosion 408(T) 409
Ammonia
causing stress-corrosion cracking 391
corrosion by 412(T)
in SCC test environment 424(F) 425(F) 426(F) 427
Ammonia, aqueous 419
Ammonia, dry
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Ammonia, moist
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Ammonium chloride
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Ammonium compounds, causing stress-corrosion cracking 391
Ammonium hydroxide
corrosion by 94 407
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Ammonium nitrate
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Ammonium sulfate
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Ammonium sulfide, for corrosion testing 416
Ammunition 195 198(F)
Anhydrous ammonia (NH3), corrosion by 408(T)
Aniline and aniline dyes
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Anneal, definition 8
Annealing 5 6 242(F) 243(F) 248(T)
249(T) 250(F) 251(F,T)
of brasses (C20100–C28000) 482(F) 483(F) 484(F) 485 486(F)
487(F) 488(F) 489 490(F)
of brasses, leaded (C31200–C38500) 490 491 492 493 494(F)
495(F) 496 497(F) 498
of brasses, tin (C40400–C48600) 498 499 500 501 502
503(F) 504 505(F) 506
of bronzes, aluminum (C60800–C64210) 510 511 512 513 514
515 516 517(F) 518 555
557 558 559
of bronzes, manganese (C86100–86800) 540 541 542
Annealing (Cont.)
of bronzes, silicon (C64700–C66100) 518 519
castings 247
of copper alloys, high-copper (C16200–C19900) 470 471 475 476 478
479 480(T) 481
of copper-beryllium alloys 47(T) 52(F) 53
of copper-nickels (C70100–C72950) 522 523 524 525
of copper-zinc alloys 41(T) 43(F) 45
of coppers, 99.3 min. (C10100–C15815) 453 456 457 459(F) 460
462 463(F) 464 465 466
467 468 469
definition 8
of nickel silvers (C73500–C79830) 526 527 528
Arsenic
alloying element effect on electrical conductivity of copper 182(F)
atom diameter size difference 36(T)
content effect on phosphorus-deoxidized arsenical copper 7
content effect on stress-corrosion cracking 423
effect on electrical resistivity as solute addition 4(T)
solubility in copper 36(T)
solubility limits in copper alloys 4(T)
Arsenical copper. See also Copper, 99.3 min. corrosion 414
Asphalt
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Atmosphere, corrosion by 395(F,T) 412(T)
Atmosphere, industrial, corrosion ratings, wrought copper alloys 393(T)
Atmosphere, marine, corrosion ratings, wrought copper alloys 393(T)
Atmosphere, protective 251
Atmosphere, rural, corrosion ratings, wrought copper alloys 393(T)
Atmospheric testing 415
Atomization
of bronze powders 233(F)
of copper alloy powder 232(F)
copper powder production 105 106(T) 223(F) 229(F,T)
Autocatalytic plating. See Electroless copper plating.
B
Barium carbonate, corrosion ratings, wrought copper alloys 393(T)
Barium chloride
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Barium hydroxide, corrosion ratings, wrought copper alloys 393(T)
Barium sulfate, corrosion ratings, wrought copper alloys 393(T)
Barium sulfide, corrosion ratings, cast copper alloys 98(T)
Bars
bending of 208(F)
mechanical properties castings 94
rotary swaging 211(F)
Base-metal erosion 6
Bath smelting 11(F)
Bearings 162(T)
bronze P/M, compacting pressure and compression ratios 235(T)
bronze P/M, microstructure 108(F,T)
bronze P/M, self-lubricating 107(F,T)
bronze P/M sintered, MPIF specifications properties and
compositions 108 109(T)
bronze self-lubricating, shapes 108(F)
diluted bronze, MPIF specifications, properties and
compositions 108 110(T)
iron-copper-carbon, specification 108
microbearings 234
P/M processing 225 237
Beer
corrosion by 409
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Beet sugar syrup
corrosion by 409 412(T)
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Bellows, flexible hose 195 197(F)
Bending 199(F,T)
rod, bars, and shapes 208(F)
Bending fatigue curves 441(F) 442(F) 443(F) 444(F)
Bending pressure 210(F)
Bending stress 441
Bend test 415
Benzene
corrosion by 409
corrosion ratings, wrought copper alloys 393(T)
Benzine
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Benzoic acid, corrosion ratings, wrought copper alloys 393(T)
Benzol
corrosion by 409
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Beryllide phase, of copper alloys high-copper, wrought 356
Beryllides 356
Beryllium
alloying element effect on electrical conductivity of copper 182(F)
atom diameter size difference 36(T)
content effect on weldability 278
effect on electrical conductivity of oxygen-
free high-conductivity copper 4(F)
effect on electrical resistivity as solute addition 4(T)
solubility in copper 36(T)
solubility limits in copper alloys 4(T)
Beryllium-containing alloys, pickling 321
Beryllium copper. See also Copper alloys, high-copper.
Beryllium copper
composition 7
description and properties 7
heat treatment 253(F,T) 258(F,T) 259(F)
Beta-brass
environments causing stress corrosion cracking 419(T)
extrusion 221
forgeability 215
stress-corrosion cracking 422(T)
Beta phase
of copper alloys, high-copper 357
of copper-aluminum alloys 48(F) 51
of copper-beryllium alloys 53
of copper-tin alloys 46
of copper-zinc alloys 37(F) 39(F,T)
description 7
Beta-prime phase
of copper-aluminum alloys 52
of copper-zinc alloys 37(F) 39(F,T)
Biofouling 166 385 401 402(F)
and bronzes, aluminum 92
and copper-nickels 92
Bioleaching 12
Bismuth
atom diameter size difference 36(T)
content effect on copper alloy machinability 266
content effect on weldability 278 299
Bismuth (Cont.)
solubility in copper 36(T)
Black liquor, sulfate process, corrosion rations, wrought copper alloys 393(T)
Black nickel 329
Bleaching powder (wet), corrosion ratings, wrought copper alloys 393(T)
Blister copper 10 11(F) 33
Blow holes 148 149(F)
Boiling point
of brasses 482
of unalloyed copper 448
Borax
corrosion ratings, wrought copper alloys 393(T)
as wet cover flux 175 176(T)
Bordeaux mixture, corrosion ratings, wrought copper alloys 393(T)
Boric acid
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Boring 271(T) 272(F)
Bornite 10
Boron
deoxidation of copper 183
deoxidation of copper alloys 182(F)
effect on electrical resistivity as solute addition 4(T)
solubility limits in copper alloys 4(T)
Bottom setting 220
Boundary lubrication 107
Brasses (C201xx–C280xx) 64 85 90
alloying elements effect 64
applications 64
applications, marine and marine-related service 166(T)
brazing 303(T) 304
color description 6(T)
commercial forms 55(T)
composition 3 7 14(T) 18(T) 55(T)
57(T) 277(T) 297(T)
corrosion 64 386(F) 389 396(F) 397
398 405 408(T) 412 413
414
cross-reference for international alloy designations 29(T)
Brasses, special
applications 162
corrosion 393(T)
Brasses, tin (C40400–C48600) 64
applications, marine and marine-related service 166(T)
brazing 304
commercial forms 56(T)
composition 14(T) 19(T) 56(T) 57(T) 277(T)
297(T)
corrosion 13 64 386 389 412(T)
414(T)
cross-reference for international alloy designations 29(T)
environment causing stress-corrosion cracking 419(T)
fabrication 13
as filler metal for GMAW 280(T)
forgeability 215(T) 504 505 506
formability 204 498 499 500 501
502 504 505 506
heat treatment 498 499 500 501 502
503(F) 504 505(F) 506
machinability 56(T) 65 498 499 500
501 502 504 505 506
mechanical properties 56(T) 58(T) 61(T) 498(T) 499(T)
500(T) 501(T) 502(T) 503(F,T) 504(T)
505(F,T) 506(F,T)
microstructure 504 505 506
physical properties 57(T) 277(T) 297(T) 498(T) 499(T)
500(T) 501(T) 502(T) 503(F,T) 504(T)
505(T) 506(T)
previous trade name 19(T)
techniques used for studying stress-corrosion cracking 426(T)
UNS designation number range 14(T)
weldability 276(T) 277(T) 280(T) 285(T) 297(T)
498 499 500 501 502
504 505 506
weldability, dissimilar metals 295(T)
Brasses, white, melting 184
Brazing (Cont.)
furnaces 307
induction 306(T) 309(F)
joint clearance and design 305(T)
nickel silvers, wrought 303(T) 304
process selection 305(F,T)
resistance 306(T) 311(F)
surface preparation 305
torch brazing 306(T) 307(F)
Breaking strength, of hard-drawn copper and copper alloy round wire 69 71(T)
Bright dipping 320(T) 326 327(F) 332
Bright rolling 322(T)
Brinell hardness
equivalent hardness numbers for cartidge brass 589(T)
equivalent hardness numbers for coppers 588(T)
international temper designations 28
Brines, corrosion rating, wrought copper alloys 393(T)
British standard, alloy designation system 28(T) 29(T) 30(T)
Bromine, corrosion by 410
Bromine, dry, corrosion ratings, wrought copper alloys 393(T)
Bromine, moist, corrosion ratings, wrought copper alloys 393(T)
Bronzes
corrosion 405
description 7
diffusion constant in copper 235(T)
mechanical properties 440
plating 136 139(T)
powder
applications 106(T) 107(F,T)
compacting pressure and compression ratios 235(T)
composition 112(T)
mechanical properties 112(T)
physical properties 107(T) 112(T) 233(T)
porous filters 109 111(F,T)
prealloyed 106 238 239(F)
pressing characteristics 107(F)
production 233(F,T)
spherical 89/11 233(F) 234
structural parts 110 112(F,T)
Bronzes (Cont.)
sintering 236(T) 237(F) 239(F)
Bronzes, alpha-aluminum 262(F)
Bronzes, aluminum (C60800–C64210 and C95200–C95900) 91
applications 65 91 93 103 163(T)
166
applications, marine and marine-related service 166(T)
brazing 303(T) 304
casting processes used 89(T)
color description 6(T)
commercial forms 56(T)
composition 3 14(T) 20(T) 25(T) 56(T)
57(T) 89(T) 91 277(T) 297(T)
corrosion 93 98(T) 386 393(T) 396(F)
398 400(T) 405 414 555
556 557 558 559
cross-reference for international alloy designations 29(T) 30(T)
cross-reference of designations 30(T)
dendrite arm spacing 361(F)
description 7
descriptive names and designations 89(T)
environment causing stress-corrosion cracking 419(T)
extrusion 221
fabrications 13
feeding range 190
as filler metal for GMAW 280(T)
as filler metal for SMAW 280(T)
forgeability 215(T) 217 511 513 514
516
formability 204 510 511 513 514
515 516 517 518
gases present 180(T)
hardfacing alloys used as wear-resistant coatings 150(T)
heat treatment 248 262(F,T) 510 511 512
513 514 515 516 517(F)
518 555 557 558 559
machinability 56(T) 101(T) 510 511 512
513 514 515 516 517
555 556 557 558 559
C
Cadmium
alloying element effect on electrical conductivity of copper 182(F)
atom diameter size difference 36(T)
content effect on weldability 278
effect on electrical conductivity of oxygen-
free high-conductivity copper 4(F)
effect on electrical resistivity as solute addition 4(T)
physical properties 31(T)
solubility in copper 36(T)
solubility limits in copper alloys 4(T)
Cadmium copper
composition 7
description 7
Cadmium electroplating 328
Cakes 68
Calcium
alloying element effect on electrical conductivity of copper 182(F)
effect on electrical resistivity as solute addition 4(T)
solubility limits in copper alloys 4(T)
Calcium bisulfate
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Calcium chloride
corrosion by 408(T)
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Calcium hydroxide
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Calcium hypochlorite
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Cane-sugar syrups
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Cannizzaro reaction 140
Carbolic acid (phenol), corrosion ratings, wrought copper alloys 393(T)
Carbon
as copper deoxidizer 183
and degassing 177 180(T)
pure, physical properties 5(T)
Carbonated beverages
corrosion ratings, cast copper alloys 98(T)
corrosion ratings, wrought copper alloys 393(T)
Carbon dioxide
corrosion by 410
corrosion ratings, cast copper alloys 98(T) 99(T)
corrosion ratings, wrought copper alloys 393(T)
Carbonic acid, corroding copper alloys 100
Carbon monoxide, corrosion by 410
Carbon steel
corrosion ratings, atmospheric 10- and 20-year exposures 396(T)
physical properties 4(T) 5(T)
Carbon tetrachloride
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 393(T)
Cartridge brass. See also Brasses (C205xx –C280xx).
composition 7
equivalent hardness numbers 589(T)
hardness numbers, equivalent values 589(T)
product forms 7
Cast copper alloys. See Copper alloys (cast).
Casting 5
alloying additions effects 17
of beryllium copper-nickel 72C 563
of beryllium copper 21C 562
of brasses, silicon (C87300–C87800) 545
of bronzes, manganese (C86100–C86800) 541
of bronzes, silicon (C87300–C87800) 545
characteristics 171(T)
of copper alloys, high-copper (C81400–C82800) 530 531 532 533 535
536
copper and copper alloys 92(T)
of copper-nickels (C96200–C96950) 560
degassing 176(F,T)
electromagnetic 361
feeding 190(F,T)
flow rates 187(F,T)
fluxing 174(F,T) 177(F) 178(F) 179(F)
gating 187(F,T)
grain refining 183(F)
of nickel silvers (C97300–C97800) 560
pouring temperatures 185(T)
process selection 186(T)
production processes 184(T)
solidification ranges 171(T)
Castings, annealing of 247
Cast irons, copper as alloying element 168
Castor oil, corrosion ratings, wrought copper alloys 393(T)
Catalyst predip 146
Catalyst promotion (conditioning) 146
Copper (Cont.)
and Powder metallurgy processing 6
as alloying element 168
composition 3
consumption end uses by function in U.S. (1997) 3(T)
corrosion 398(T)
corrosion in refined organic acid 407(T)
corrosion in various soils 397(F)
corrosion ratings, atmospheric 10- and 20-year exposures 396(T)
corrosion resistance 3
descriptive terminology 6
designators in Comité Européen de Normalisation system 28(T)
diffusion constant in copper 235(T)
fabrication 5(F)
fabricator classes 10(F) 13
group 3
high-conductivity 30(T) 68
history and development 3
mechanical properties 5(F)
phosphorus-deoxidized, low-residual phosphorus 34
physical properties 3(F,T) 31(T)
product forms 10
production 3 10(F)
production from oxidized minerals 12
production from scrap 10(F) 12
production from sulfide materials 10(F)
sintering 236(T)
solubility of solutes in 35 37(T) 38(F)
workability 5
Copper alloy plating 136(T)
Copper alloy powders. See also Powder metallurgy processing 105(F,T)
applications 106(T) 110
brass 110 112(T) 113(F)
bronze 107(F,T) 111(F) 112(F,T)
characteristics 106(T)
compaction 106
copper-lead 112
copper-nickel 111
Copper-aluminum alloys. See also Bronzes, aluminum 46(T) 47(F) 48(F) 49(F) 50(F)
51
advantages of rapid solidification 363(T)
aluminum as solid-solution strengthener of copper 47(F) 51
binary phase diagram 48(F) 51 370(F)
cooling rate effect on hardness 49(F) 52
crystal structure data 370(F)
designations in Comité Européen de Normalisation system 28(T)
heat treatment effect on hardness 46(T) 52
heat treatment effect on mechanical properties 46(T) 52
microstructure 48(F) 49(F) 50(F) 51 121(F)
quenching temperature effect on hardness 48(F) 52
stress-corrosion cracking 422(T)
techniques used for studying stress-corrosion cracking 426(T)
tempering effect on hardness 49(F) 52
Copper-aluminum-iron alloys, phase diagram 379(F)
Copper-aluminum-manganese alloys, phase diagram 380(F)
Copper-aluminum-nickel alloys
applications 122
composition 121
for shape memory alloys 121
mechanical properties 121(T)
physical properties 121(T) 122
shape memory properties 121(T)
Copper-aluminum-silicon alloys, corrosion 405
Copper-aluminum-zinc alloys, phase diagram 380(F) 381(F)
Copper-ammonia system, potential/pH diagram 420(F)
Copper-antimony alloys, binary phase diagram and crystal structure data 376(F)
Copper-antimony-tin alloys, phase diagram 382(F)
Copper-arsenic alloys, binary phase diagram and crystal structure data 370(F)
Copper-base brush materials 113 115(T)
Copper-base contact materials 113 115(T)
Copper-base dispersion-strengthened materials 115(F,T)
Copper-base friction materials 112(T) 114(F)
Copper-base leaded alloys 46(F)
machinability 46(F) 47(F) 50
microstructure 46 (F)
Copper-nickels (Cont.)
fabrication 13
feeding range 190
as filler metal for GMAW 280(T)
as filler metal for SMAW 280(T)
forgeability 215(T)
formability 204 522 523 524 525
gases present 180(T)
heat treatment 242 522 523 524 525
560
interdiffusion 236
machinability 56(T) 101(T) 521 522 523
524 525 559 560
mechanical properties, cast 96(T) 97(T) 98(T) 559 560
mechanical properties, wrought 56(T) 58(T) 61(T) 65 521(T)
522(F,T) 523(F,T) 524(T) 525(T)
melting 184
melt refining 175
microstructure 267
physical properties, cast 92 96(T) 101(T) 559 560
physical properties, wrought 57(T) 65(F) 277(T) 297(T) 521(T)
522(F,T) 523(T) 524(T) 525(T)
pickling 321
pouring temperatures 185(T)
P/M parts 111
previous trade names 21(T)
soldering 303(T)
UNS designation number range 14(T)
UNS number 6(T)
weldability 276(T) 277(T) 280(T) 281 285(T)
292(T) 296 297(T) 299 522
523 524 525 559
weldability, dissimilar metals 294(T) 295(T)
Copper-nickel-tin alloys
phase diagram 381(F)
spinodal hardening 260
Copper-nickel-zinc alloys
designations in Comité Européen de Normalisation system 28(T)
phase diagram 382(F)
Corrosion (Cont.)
oxide film 385
oxidizing conditions more damaging 385
pitting 388 389(F)
ratings, cast copper alloys in corrosive media 98(T)
ratings of wrought copper alloys in corrosive media 392(T)
resistant coatings of copper alloys 150
salt 408(T)
testing 414(T)
testing, specifications 414
of tubular products 154 155(T)
types 387(F,T)
velocity effects 399(F,T)
of unalloyed copper 451
water as cause 398(F,T)
water line attack 388
Corrosion fatigue 391(F)
characteristics and preventive measures 387(T)
Corrosion resistance. See also Coatings 4 15
copper and copper alloy consumption in U.S. (1997) 3(T)
Corrosion-resistant copper alloy coatings 150(T)
Cottonseed oil
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Creep, of soldered joints 316(F) 317(F,T)
Creep-rupture characteristics
of alloys, high-temperature 431 433(F)
of brasses (C20100–C28000) 484 485(F) 486 488(F)
of brasses, tin (C40400–C48600) 503(T)
of bronzes, aluminum (C95200–C95900) 555(F) 556 557(F) 558
Creep stress
of brasses, semi-red (C84200–C84800) 538
of brasses, silicon (C87300–C87800) 545
of bronzes, manganese (C86100–C86800) 540 541(F) 542 543(F) 544(F)
of bronzes, silicon (C87300–C87800) 545
Creosote
corrosion by 409
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Crevice corrosion 388 389(F) 415
Critical temperature 37(F) 39 40
Cryogenics 430(F,T) 432(T)
Cupronickels. See Copper-nickels.
Cuprous oxide 385
Cutting, of sheet and strip 79(F)
D
Damping capacity, of brasses, wrought 486 488(F)
Dealloying. See also Dealuminization; Denickelification; Dezincification. 5 390(F) 391(F) 392 397
415 427 428
characteristics and preventive measures 387(T)
Dealuminization 350(F)
Decorative plating-on-plastic (POP) 142 145 146 147 148
149
Deep-drawing brass, description 7
Deformation twinning 66
Degassing 176(F,T)
auxiliary methods 180
inert gas fluxing 178 180(F) 181(F)
methods 178(F)
oxidation-deoxidation practice 178 180(F)
solid degassing fluxes 179 181(F)
testing for gases 177 179(F) 180(F)
vacuum method 180
zinc flaring 178 180(F)
Degree of order 40
Delta phase, in copper-tin alloys 46
Dendrite arm spacing 360(F)
Dendrites 85 360(F,T)
Density (Cont.)
copper-lead P/M parts 112
copper-nickel P/M parts 111
of copper-nickels (C70100–C72950) 57(T) 521 522 524 525
559
of coppers, 99.3 min. (C10100–C15815) 57(T) 453 456 457 458
460(F) 461 463 464 465
466 467 468 469 529
of copper-zinc alloys 57(T) 519 520 521
of diluted bronze sintered bearings 110(T)
effect on bronze P/M compact strength 107(F)
of electrolytic copper powder 225(T) 229(F)
of graphite-copper brush materials 115(T)
of nickel silvers 57(T) 525 526 527 528
560 561
of P/M copper parts 105
of P/M products 222 230
of powder compact 234(F,T)
of pure copper P/M parts 107(F)
of sintered bronze bearings 109(T)
of special alloys (C99300–C99750) 561 562
of unalloyed copper 446(T) 447(F)
Deoxidation of copper alloys 181(F)
Deoxidized copper, high residual phosphorus (DHP).
See Coppers, 99.3 min.
Deoxidized low-phosphorus copper. See also Coppers, 99.3 min.
mechanical properties 34(T)
oxygen content 34(T)
physical properties 34(T)
Designation systems
for copper and copper alloys 14(T) 15(T) 23(T)
for tempers 14 26(T)
Deutsches Institut für Normung (DIN), temper designation system 28
Dew point 251
Dezincification 5 93 100 349(F) 386(F)
390(F) 391(F) 392 403
of admiralty metal brass 7
after chromium electroplating 328
Dezincification (Cont.)
by sulfur compounds 410
and electrolytic alkaline cleaning 325
and soil corrosion 397
and stress-corrosion cracking 392
Die casting 187
technical factors in casting method choice for copper alloys 186(T)
Dies, special 206
Diffusion 235
Diffusion bonding 299
Diffusion coefficients 235(F)
Diffusion welding 299
Dip brazing 306(T) 312(F)
Directional solidification 190(F) 192
Discontinuous precipitation 357
Dislocation slip systems 5
Dispersion hardening 5(F)
Dispersion-strengthened copper powder, applications 106(T)
Dispersion strengthening, of copper and copper alloys, wrought 66
Dissimilar metals
brazing 304
welding 294(T) 295(T)
Dissociated ammonia 251 252
Domain boundary 39 40(F)
Domains 39 40(F)
Downtherm “A,” corrosion ratings, wrought copper alloys 394(T)
Draw bending 209(F)
Drawing 5 201(F) 204(F)
Drawing brass, description 7
Drawing ratio 36(T) 39(F)
Drawn stress relieved (DSR), definition 9
Drilling 271(F)
with mandrel swaging 211(F)
Dry abrasive cleaning 322
Dynamic corrosion tests 414(T)
Dynamic liquid viscosity, of unalloyed copper 452
E
Ears 203 204(F)
Elastic modulus
of beryllium copper-nickel 72C 563
of beryllium copper 21C 562
of brasses (C20100–C28000) 481 482 483 484 485
486 488 489
of brasses, leaded (C31200–C38500) 490 491 492 493 494
495 496 497
of brasses, red (C83300–C83810) 536 537(F) 538
of brasses, semi-red (C84200–C84800) 538
of brasses, silicon (C87300–C87800) 543 544 545 546
of brasses, tin (C40400–C48600) 498 499 500 501 502
503 504 505 506
of brasses, yellow (C85200–C85800) 539
of bronzes, aluminum (C60800–C64210) 510 511(T) 512 513(T) 514
515(T) 516 517 555 556
557 558
of bronzes, leaded phosphor (C53400–C54400) 509
F
Fabrication characteristics 5(F)
Fatigue 440(F,T)
microstructure 443 (F)
and processing 443 (F)
property relationships 443(F)
specifications 441
Fatigue (Cont.)
and temper 440(T)
testing 441 (F,T)
Fatigue life 431(F) 433(F)
Fatigue strength of brasses (C20100–C28000) 482 484 485 486 487(T)
488
of brasses, leaded (C31200–C38500) 495
of brasses, red (C83300–C83810) 537(F)
of brasses, semi-red (C84200–C84800) 538
of brasses, silicon (C87300–C87800) 545
of brasses, tin (C40400–C48600) 503 504
of bronzes, aluminum (C60800–C64210) 510 511 512 513(T) 514
515 516 555 556 557
558
of bronzes, leaded tin (C92200–C94500) 547 549(F) 551 552(F) 553
554
of bronzes, manganese (C86100–C86800) 540 542(F)
Ferric sulfate
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Ferrous chloride
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Ferrous sulfate
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
to inhibit corrosion 402
Fick’s law 235
Filler metals 279(T)
for brazing 304 (T) 308 311
Film-induced cleavage (FIC) 427
Filters, of porous P/M bronze 109 111(F,T)
Filtration 183
Final polishing, equipment requirements, speed, and lubricants 324(T)
Finishing processes 320(T)
Finish polishing, for microexamination 338
Fire cracking 244 247
Fire-refined copper, description 7
Flash 213 215 216 217 220
Flash smelting 11(F)
Flash welding (FW) 296 298
Fluorine, corrosion by 410
Fluxes 174(F,T) 177(F) 178(F) 179(F)
for brazing 305 306(T) 309
melt refining 175(F,T) 177(F) 178(F)
mold 176
neutral cover 174(T)
oxidizing 174 175(F)
reducing 175(T)
soldering 313
Fluxing 174(F,T) 177(F) 178(F) 179(F)
chlorine 176
and melting 184
Foil 159(T) 166
applications 166
characteristics 73 76(T)
Forging 5 213(F,T)
advantages 82
applications 82
of brasses (C20100–C28000) 490
of brasses, leaded (C31200–38500) 495 497
Forming (Cont.)
of bronzes, leaded phosphor (C53400–C54400) 509
Freon
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Freshwater, corrosion by 398 414(T)
Fretting 389
characteristics and preventive measures 387(T)
Friction coefficient
of coppers, 99.3 min. (C10100-) 458
of unalloyed copper 452(T)
Friction materials, copper-base 112(T) 114(F)
Friction welding 299
Fuel oil
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Functional plating-on-plastic (POP) 142(T) 145 146 147 148
149
Furfural
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Furnace brazing 305(F,T)
Furnaces 172(F) 176
batch-type atmosphere 249
bell 250 254(F)
for brazing 307
continuous atmosphere 250 253(F)
continuous conveyer 253(F)
electric induction coreless type 173(F)
electric induction, core type 173(F)
electric induction, lift swing 174(F)
forced-convection 250
for sintering 240
fuel-fired 172(F) 176
induction 173(F) 232
open-flame 173
pit retort 250 254(F)
reverberatory 10 12(F)
G
Gallium
effect on electrical resistivity as solute addition 4(T)
solubility limits in copper alloys 4(T)
Galvanic activation, with electroless plating 331
Galvanic corrosion 387 388(T) 400(T)
characteristics and preventive measures 387(T)
Galvanic plating 331
Galvanic series in seawater 388(T)
Gamma phase
of copper alloys, high-copper 357
of copper-aluminum alloys 48(F) 51
of copper-tin alloys 46
Gas-atomized copper powders 229(F,T)
Gases, corrosion by 410(F) 412(T)
Gas metal arc welding (GMAW) 6 276(T) 277(T) 278 279
280(T) 281(T) 284 285(T) 286
289(T) 291 293(T) 295(T)
Gasoline
corrosion by 409 411(T)
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Gassing 6
Gas tungsten arc welding (GTAW) 6 276(T) 277(T) 278 279
280(T) 281(F) 286(T) 287 288
289(T) 290(F,T) 291 292(T) 294(T)
Gating systems 187(F,T)
Gelatin
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
General buffing, equipment requirements, speed, and lubricants 324(T)
General corrosion 387
General thinning, characteristics and preventive measures 387(T)
Germanium
effect on electrical resistivity as solute addition 4(T)
solubility limits in copper alloys 4(T)
Gilding. See also Brasses.
Gilding, 95%
applications 8
composition 8
Glucose
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Glue
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Glycerin
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Gold
atom diameter size difference 36(T)
effect on electrical resistivity as solute addition 4(T)
physical properties 31(T)
solubility in copper 36(T)
solubility limits in copper alloys 4(T)
unalloyed, physical properties 4(T) 5(T)
Gold electroless plating 331
Gold electroplating 328
Gold immersion plating 331
Grain-boundary diffusion coefficients 235
Grain growth 243(F) 244(F) 245(F) 246(F) 247(F)
248(T)
Grain refining 183(F)
Grain size 6
and annealing 243
drawing and stretch forming of annealed strip 203(T)
effect on copper-zinc alloys 36 38(F)
effect on drawing and stretch forming 203
effect on electrical conductivity 4
effect on heat-treated material properties 255
effect on machinability 268
effect on stress-corrosion cracking 423(F)
effect on tensile strength of strip 77(F)
for sheet and strip 78(T)
Grain structure 363(F,T)
Gray iron, galvanic corrosion 401(T)
H
Hall coefficient, of brasses, wrought 487
Hall effect
of coppers, 99.3 min., wrought 459
of unalloyed copper 448
Hall-Petch relationship 6
Halogen gases, corrosion by 410
Hard drawing, wire 69 71(T) 75(T)
Hardening precipitates, of copper alloys, high-copper, wrought 357
Hardfacing alloys 150(T)
Hardness
of beryllium copper-nickel 72C 562(F)
of beryllium copper 21C 562(F)
of brasses (C20100–C28000) 481 482(T) 483(T) 484(T) 485
486(T) 487(T) 488(F) 489(F,T)
of brasses, leaded (C31200–C38500) 490 491(T) 492(F,T) 493(T) 494(T)
495(T) 496(T) 497(F)
of brasses, red and leaded red 95(T) 536 537(F) 538
of brasses, semi-red and leaded semi-red 95(T) 538
of brasses, silicon 95(T) 543 545 546
of brasses, tin (C40400–C48600) 498(T) 499(T) 500(T) 501(T) 502(T)
503(F,T) 504(T) 505(T) 506(T)
of brasses, yellow and leaded yellow 95(T) 539
of bronzes, aluminum (C60800–C64210) 96(T) 510 511(T) 512(T) 513(T)
514 515(T) 516 517(T) 555
556 557 558
of bronzes, leaded phosphor (C53400–C54400) 509(T)
Hardness (Cont.)
551 552 553 554
of bronzes, manganese and leaded manganese 95(T) 540 541 542(F) 543
of bronzes, nickel-tin (C94700–C94900) 96(T)
Hydrochloric acid
corrosion by 405(T)
corrosion ratings, cast copper alloys 99(T)
Hydrochloric acid (muriatic), corrosion ratings, wrought copper alloys 394(T)
Hydrocyanic acid
corrosion by 406 407(T)
corrosion ratings, wrought copper alloys 394(T)
Hydrodynamic lubrication 107 108(F)
Hydrodynamic pressure, in bronze P/M bearings 107 108(F)
Hydrofluoric acid
corrosion by 405(T)
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Hydrofluosilicic acid
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Hydrogen
corrosion by 410 (F)
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
and degassing 176 179(F) 180(T)
Hydrogen embrittlement 4 230(F) 246
Hydrogen overvoltage
of coppers, 99.3 min 459
of unalloyed copper 448
Hydrogen peroxide
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Hydrogen sulfide
corrosion by 410
corrosion ratings, cast copper alloys 99(T)
corrosion ratings, wrought copper alloys 394(T)
Hydrometallurgical powder 106(T)
Hydrometallurgical processing, of copper powder 105 106(T) 231(F,T)
Hydroxide solutions, corrosion by 413