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Whythe stablephaseof Fe atLow TIisBc

The phane has


basicmodificathusiferomagetic(鐵磁性
.

a ho
)

and
paramagneti ( 順磁性 )
ε

ferromagnetat13 stable C is at ow
Tiparamag netic is
-

stable at
high ⼚

The
change fom ferromagnetic called seconde
-

to
paramagnetic is
order transformation , the starting from 1773 ko
(

teomperafare is

several hurdral
degrees apove 973 k )

* Two -

Componeat systemg
.

Eomsidering singlephasd biuary


the
sy stem
,

a For ideal solutom .


⑤F 后r nonideal solutioui

G G餐 XA G 星 XB
TahTe GA RT laaA
=
+
,

4
-

= .

catopyofmixing (G te )
aGB :
13 T lna
.
=

activity
13
G =

GXA +
G 号 XB + RT ( λ AluXA +λ B ' laXB ]

G =

IGXA }TlaXA ) +XB ( G 号 + 3Tln (13 ]


GA GA
"

If = + 1 TlnXA

GB G 管 RTluXB
= +

- G=
- GA
{ RTlMXAG
GA

G GY RTlaXB = -
=

o deviation -Ga'XA and aB > xs


positire :GA < XA anda3
negativedeviation XB
0
<

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