ADVANCED PATTERN

CUMULATIVE TEST-1 (ACT-1)

TARGET : JEE (MAIN+ADVANCED) 2020
DATE : 28-04-2019 SET-1 COURSE : VIJETA (01JPB, 02JPB, 05JPA)
HINTS & SOLUTIONS
PAPER-1 

PART : I MATHEMATICS
5. If  cos ec
1
1
  
1  4 4 .................

1. Which of the following.................

 1 log2 x  0  x  1
Sol. Let cos ec 1  1  4 4   
| log2 x |
Sol. y = =  1 log x  0  0  x  1  cos ec   1  4 4
log2 x  2
1
1 2
 tan   2
 2 
32  x  32– x cos ec 2   1 2 4
2. Let f(x) = .................
32 x  32– x – 82  2    2  1   2  1 
   tan 1  2
1
  tan  
Sol. Clearly m in solution of 32+x + 32–x – 82 = 0  1  4  1   1   2  1 2  1 
1 1
3x +
3x
=9+
9
   cos ec 1  
1  4 4   tan 1  2  1  tan 1  2  1 

x = 2, – 2
m = 2, – 2
  cos ec
1
1
 
1  4 4  tan 1 3  tan 1 1  tan 1 5  tan 1 3

m=2  26 + 17  n=±9  cos ec 1 1  4 4   tan 1  3  tan 1 1    tan 1  5   tan 1  3    tan 1 7  tan 1 5 
m=–2  n = ±9
  
(m, n) = (2, 9), (2, – 9), (–2, 9),(–2, –9)   tan 1 1 
2 4
3. Which of the following.................  a  1, b  4
1
Sol. (A) (1 + cosx) sin2 x = x2 +
x2  1
k x  1,   x  2
1 6. If g(x) =  2 .................
 (1 + cosx)(1 – cos2 x) = x2 +
2 mx  2 , 2  x  5
x
LHS < 2 while RHS  2 Sol. K 3 = 2m + 2
so no solution k
M=
2 44 2 3
(B) sin2 x =
2 k
K 3 = +2
=1± 2  [0, 1] hence no solution 3
(C) LHS  [–1, 1] 1 1
 2k = 2 3 m= K+m= 3+
RHS  2
2 2
(D) sin2x = 1 + [sin2x] + 1 + [–cos2x] 7. If the function f(x) .................
= 2 + [sin2x] + [–cos2x] 1 1 x

LHS must be integer so sin2x = 0, 1, –1

Sol. g '(y)   f '(x)  2e 2
 x2  x  1
f '(x)
case-1 when sin2x = 0  LHS  RHS
 LHS  RHS 1
case-2 when sin2x = 1  g '(y)  1 x
.............(1)
case-3 when sin2x = –1  cos2x = 0 2 2
2e  x  x 1
 LHS  RHS 1 x
2
x 2 x3 7
 y  f (x)  4e 1 x   
4. If the range of the................. 2 3 6
Sol. by considering all four quadrants one by one, we get then  x=1
Range of f(x) as {–2, 0, 4}
 7 1 1
 (B) and (D) option are correct g '     
 6  2 1 11 5
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8. Consider the functions................. 12. Let f(x) = x2 – 2bx.................
log0.3  x  1
Sol. for Domain of f(x)  0 and x  1  0
 x  4  x  2  Sol. f (x)  x 2  2abx  4a  0
  x  2
 0
 x  4  x  2  ef ( x)  1 sin  f (x) 
Lim  Lim
x  x   x 

 x  2  0 x 

 x  4  x  2  f (x) f (x)
Lim  Lim
Domain of f(x) is [2, 4) x  x   x x  
for domain of g(x)

x2 + 4x  2x2 + 3 and x2 + 4x  N & 2x2 + 3  W (x  )(x  ) (x  )(x  )

Lim  Lim
x2 – 4x + 3  0
x  x  x  x 
x [1, 3]        
 Domain of g(x) is {1, 2, 3}
for Domain of h(x) ; log3(x2 – 6x + 11)  1
D=0  4b 2  16a  0
x2 – 6x + 11 3  b²  4a  0, a  0
x2 – 6x + 8 0 a=0  b=0 (0, 0)
 Domain of h(x); x  [2, 4]
S=2+3+1+2+3+2+3+4
a = –1  b = ±2 (–1, ±2)

= 5 + 6 + 9 = 20 a=–4  b = ±4 (–4, ±4)

S Hence 5 ordered pairs.

 5
4
13. The number of integral.................
10. If y  f  x satisfies.................
 3 3 
Sol.  Range of sin–1 x + tan–1 x is
Sol. Putting X  x  1 and Z = z – 1
 f  X  f  Z   f  X  Z   4 , 4  integral values of

f  X  h  f  X ‘k’ are 2.
f '  X   lim
h 0 h 14. If the number of.................
f  X   f h   f  X  Sol.  e2x + ex – 2 = 0
  lim
h h
 (ex + 2) (ex – 1) = 0  ex = 1
f  h  f  0 
 lim only one solution
h 0 h
= f '  0   4  f '  X   4  f  X   4X  c
 f  x   4x  f  2   8 15. f 1  x  is equal.................

11. If 0 <  < 1 and f(x) ................. Sol. (B)

x 4 – 4x2
Sol. log | x  2 | y= 2
0
|x|  4 + log2 y = x4 – 4x2 + 4
 |x| > 0  x  0 ; x  2
 x2 – 2 = ± 4  log2 y
 log |x – 2|  0
|x – 2|  1
 x2 = 2 + 4  log2 y
–1  x – 2  1
1x3
 x= 2  4  log2 y
 x  [1, 2)  (2, 3]
 a = 1, b = 2, c = 2, d = 3
f–1(x) = 2  4  log2 x

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 16. The set A is equal.................
PART : II PHYSICS
sin x  4
Sol. g  x  
sin x  2
19. A point object …………..
6 cos x  
 g x   2
 0  x   ,  n2 n n  n1
 sin x  2 2  Sol.  1  2
v (u) R
 g(x) is increasing function, hence one-one function.
A
 Range is  g    ,g    lie  5,  2 i r
 2 
O u P C

n1 n2
17. The correct relation.................
B

n2 n2  n1 n1
 
18. The correct relation................. v R u
Sol. (17 to 18) (a) if n1 > n2  v is – ve  (a)

At x = 1
2n1 n1 n1 2 1 1
(b)   ;  
v R u v R u
lim f  x   lim 1  h  1 if R > u  v is -ve
x 1 h 0

lim f  x  lim a sin 1 h b a sin b 1

x 1

20. At t = 0 spring …………..

lim f x  lim  a  sin 1 1  h  b    a  sin 1  b  1 Sol. At t = 0 system is in equilibrium position and perform SHM
h 0

For continuity a + sin-1(1 + b) = 1 …(1) 2m

with time period = T = 2
3K
Similarly at x = -1 c + cos-1(-1+d) = 1 …(2)
T 5T
Differentiating, we get length of spring is minimum at , ...........
4 4
 1 3T 7T
 ,  2  x  1 length of spring is maximum at , ...........
2 4 4
 1 x  d length of spring is natural length and it acceleation is zero at
1,
 1  x  0 T 3T
f '(x)   a time t = 0, , ...........
1, 0  x 1 2 2
 1
 , 1 x  2 21 . For the situation …………..
2
 1   x  b   KP
Sol. E due to dipole at location of ‘Q’ is E = 3
r
1 2
  1  1   d  1  1  d  1
2 KPQ
1   1  d  F=
r3
1   
Also  1  b  1   pE
2
1  1  b 
22. P.E. of a system …………..

 Sol. Let in the system there be q1, q2 and system of other n – 2

From (1) and (2), a =1 and c
 1 charges (suppose we call it Q)
2
100J = U(q1q2) + U(q1Q) + U(q2Q) +UQ
90 J= U(q2Q) +UQ
82 J= UQ
Using all above relations we get U(q1Q) = 9J, U(q2Q) = 8J
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23. At the closed ………….. 28. xy plane is …………..
Sol. At closed end there are Displacement node and 1
2 5 2 
pressure antinode. 2usin  2
Sol. T= = = 1 sec.
g 10
24. Figure here …………..
Sol. D moves down as shown During this time its y displacement is

 1 
sy = (u cos ) t = 5 2   (1) = 5 m
 2

1 1  qE 
Also, at mean position as stretched length is and s x = ax t2 = t2
2 2  m 
maximum, elastic potential energy is maximum as well.

1  1000  10–6  104 

=   (1)2 = 5 m
25. A ray of light is ………….. 2  1 
Sol.  =  ( – 1) A
= (1.5 – 1) 1 + (2 – 1) 2 = 0.5 + 2 = 2.5
Net displacement = s2x  sy2
26. An object of …………..

hi f v v = 5 2 = 5 × 1.414 = 7 m
Sol.   hi = - h0  h0
h0 f f

v
 |hi | =  h0  h0 -  vf 29. Two cylinder …………..
f
v C 
|hi| = h0  h0 f  v – Sol. nCP 30 = nC VT T = 30  P   42
f  CV 
So h2 = h0 = 1 cm
From second eq. v2 = 2f
30. The sound loudness …………..
Or When v  0, u  0 & hi  h0 so h2 = h0 = 1 cm
Image of same height is obtained when  4
Sol. 1 = 10 log 2 = 10 log
v = 2f so v2 = 2f 0 0

27. A solid hemisphere ………….. 2 – 1 = 10 log4

Sol.
2 = 10 + 10 log4 = 10 + 6 = 16

31. A standing wave …………..

1 2
Sol. Total mechanical energy of vibration =
E1sin 30 + E1 + E1sin 30 = E0
 2 dm v
2E1 = E0
dm =  dx,  = 103 kg/m3 (0.04) m2
E0
E1 =
2  = 40 kg/m

E0 ds
Thus reamaining field = v(x) = = 5 mm sin x (– sin (200 t)
2 dt

1
Total mechanical energy =  v 2 (x)dx
 = 10 joules.
2

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32. A container ………….. PART : III CHEMISTRY
Sol. H × 10 = 50 × 80
H = 400 cal/sec. 37. Select the correct ………….

when spray is working, Sol. (C) for monoclinic system abc &
(50 + 2t)80 = 400 t     90,   120
4000 + 160 t = 400 t
(D) packing fraction of BCC is 68%
4000 = 240 t

400 39. If heat of formation of PCl3 (g) ………….

t=
24 1 3
Sol. P4 (s)  Cl2 (g)  PCl3 (g); H  140
50 4 2
t=
3 1 3 
140    320   120  – 3  (B – E)P–Cl
50 20 4 2 
t = – 10 = sec.
3 3 120
So x = 20.
(B – E)P–Cl   40 kJ / mole
3
1 3
33. The adiabatic ………….. P4 (s)  H2 (g)  PH3 (g) ; H  8
4 2
 
Sol. P1 V1 = P2 V2
1 3 
1 × V = (0.355) (2V)
8    320   216  – 3  (B – E)P –H
 4 2 
  1.5
(B – E)P–H  132kJ / mole
34. The speed of …………..
H2  2H ; H  216
P PV
Sol. V= =  448 m/s
 m 216
 ( Hf )H   108 kJ / mole
2
 m
where     
 V Cl2  2Cl ; H  120

120
35. If object starts …………..  ( Hf )Cl   60 kJ / mole
2
d1 d2
Sol. Apperent distance (t) = + + d3
n1 / n3 n2 / n3
40. Three complexes are ………….
but n1 = n3 = 1 & n2 = 3/2
1
d1 d2 Sol. Order of 0 : (R) > (Q) > (P) ; 0 
d= + + d3 abs
1 3/2
but d2 and d3 are constant when only object is moving. VI

So d = d1 +0 + 0  vI = v0 = 12 cm/sec.

Order of abs : R < Q < P

4
36. If n3 = and …………..   
3 Blue Green Yellow
d1 d2   
Sol. d = + +d
1/ 4 / 3 9/8 3 Colour Transmitted Yellow orangeRed Violet

3v1
v = +0+0 41. Which of the following ………….
4
Sol. Meso compounds are those which has plane of symmetry but
3
v = × 12 = 9 cm/sec. are optical isomers.
4

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42. In which of the following …………. 47. Calculate pH of 1 M ………….
Sol. (C) alkyl halides (R-X) when reacts with aq. KOH  
Sol. CNaq.  H2O HCNaq.  OHaq. ;
gives alcohol.
Kw
CH3 – CH – CH3
aq. KOH
CH3 – CH – CH3 K h1   104
K aHCN
Cl OH
 
CH3 COO aq.  H2 O CH3 COOHaq.  OHaq. ;

Br I Kw
(D) dry acetone
K h2   109
+ NaI + NaCl K aCH COOH
3

(Finkelstein reaction)
OH   
CK h1  CK h2

43. How many Bravais lattices …………. = 1 10 4  1 10 9 = 10–2

Sol. It is orthorhombic which has SC, BC, FC & EC type of unit 48. How many following compounds………….
cells Sol. Aliphatic aldehydes, formic acid and -hydroxy carbonyl
Hence Bravais lattice = 4
compounds will give positive fehling test.

44. How many geometrical isomer(s) …………. 49. How many of the following………….

Sol. [Ma2 b2cd]  6 G.I. and 2 is optically active. Sol. Carbonyl compound having sp3 hydrogen atom can give aldol

reaction.

45. An element has body………….

50. If the optical rotation produced………….

ZM
Sol. d (M in amu)
a3 CH3
Cl H
Sol. is a meso compound.
2M
2 H Cl
(3)3
CH3
M = 27 amu

Mass of unit cell = 54 amu

51. High spin complex [FeCl6]3– has………….

500 Sol.
46. An aqueous m solution………….
81

nsolute 1000 500

Sol. m =    Due to wf no pairing takes place.
n solvent 18 81

nsolute 1
 52. Unpaired electron(s) in………….
nsolvent 9
_
Po  Ps n 1 Sol. [FeCl6]3– Cl–  wf (unpaired e = 5) no paring but CN sf
RLVP = = solute 
Po nTotal 10
pairing takes place so unpaired electron=1
% decrease in vapour pressure = 10%

Relative humidity = 90%

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 PAPER-2 1  cos 2 x
2. (P) lim 2
.................
PART : I MATHEMATICS x 0
ex  ex  x
1  cos 2x 2 sin 2x
Sol. (P) lim 2  lim 2
1. (P) Number of solution................. x 0
e  e  x x 0 2xex  e x  1
x x

4 cos 2x
 lim
2 x2 2
x0
4 x e  2e x  e x
4 1 4
  4
0  2 1  1 1
1/ x
 (3 / x)  1 
(Q) lim  
Sol. (P) x  0  (3 / x)  1 

 1  (3 / x)  1  
 exp  lim    1 
 x0 x  (3 / x)  1  
 2x  2/3
 exp  lim   e  p + q = 5
 x  0 x( 3 – x) 
sin–1 1  x  x 2 = –32 x2 – 16x 1
(1  x 2 )1/ 3 – (1– 2x) 4
(R) im
Domain of sin–1 1  x  x 2 is [–1, 0] x 0 x  x2
 1 1  
–1 1  x  x 2 is   ,    x2   x 4  4 – 1 
Range of sin 3 2  1   ....  – 1–    4x 2  .... 
   3   2 2! 
 
Number of solution are two. im  
x 0 x  x2
(Q) log3(5 + 8log49 (7)) = log3(5 + 8.(1/2)) = log3 9 = 2 1
=
2
1
(R) x +  2, x > 0 x  2 sin x
x (S)  lim
x 0
x  2 sin x  1  sin 2 x  x  1
2
2
 a – 3a + 3 > 1

a2 – 3a + 2 > 0  lim
(x  2 sin x)  x 2  2 sin x  1  sin2 x  x  1 
2 2
x 0 x  2 sin x  1  sin x  x  1
(a – 1) (a – 2) > 0 2(x  2 sin x)
 lim
a  (– , 1)  (2, ) x 0 x 2  x  2 sin x  sin2 x
2(1  2 cos x) 23
 least positive integeral value of 'a' is 3  lim  2
x 0 2x  1  2 cos x  2 sin x cos x 3

3. If f : R → R is defined.................

x e x  e  x ; x  0
Sol. f  x   e  e x  
 0; x0
(S)
For x  0 , f  x   ex  e x
–2 –1 1 2
 f '  x   ex  e  x  0 , x  0

x – {x} + 2x = 3{x} – 1  f(x) is st. increasing in  0, 

3x + 1 = 4{x}
 Range of f(x) in 0,  is  f  0  ,f    
3x  1
{x} = no solution i.e. Range is  0, 
4
for x < 0, f(x) = 0

 many one function and range of f(x) is  0, 

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4. Which of the following................. 12. If f : R  R is a.................
Sol. (A,B,C,D)
x
(i) x2 – 5 > 0 Sol. f(x) – f  x  =
2 2
x  (–  – 5 ) ( 5 ,)  
(ii) log4(x2 –5) > 0  x2 – 5 > 1 x x x
f –f
 x2 – 6 > 0   4 = 4
2  
x  (–  , – 6 ) ( 6 , )

2
(iii) log1/5 log4(x – 5)  0
 log4(x2 – 5)  1  x –f x  = x
f
n–1   n n
 (x2 – 5)  4 2   2  2
 x  [–3, 3] on adding f(x) – f  x  = x  1  1  ......  1 
  (iii) is
from (i) (ii)  n
2 
2 4


2n 
 x  [–3, – 6 )  ( 6 , 3]   x 
lim  f ( x ) – f  n   = x = h(x)
n  2 
5. Which of the following................. 
Sol. (A, B, C)
Option (A), (C) obvious. 13. If exhaustive interval.................
Option (D) limiting value = sin 1 3–x x 1 1
But functional value = 1, so it is discontinuous. Sol. – >
2
7. Number of integral................. Let f(x) = 3–x – x 1
Sol. For one point of non differentiability, g(x)
= (x – 1)(x2 – ax + 1) = 0 f '(x) = – 1 – 1 <0
 x2 – ax + 1 = 0 2 3– x 2 x 1
Should have non real roots or x2 – ax + 1 = 0 has both roots Domain [–1, 3]
x=1 So, Range [–2, 2]
 D<0 or a = 2
2
 a   2, 2 

8. Let f(x) = [tan2 x][cot2 x] ................. –1 3

Sol. f(x) = [tan2 x][cot2 x]
–2
Will be discontinuous at x =  ,  , 3 , , 5 , 3 , 7 .
4 2 4 4 2 4 3–x x 1 1
and – = at
9. If tan–1A = tan–1................. 2
Sol. tan–1A – tan–11 = tan–1(A2 + )
31
A –1 2 x=1–
=A + 
1 A 8
  31 
  = A – 1 – A2 which gives  = –1 only so x
 –1, 1– 
1 A  8 

10. If number of solution................. so a = – 1, b = 31

Sol. [2x] – [x + 1] = 2x
– [x + 1] = {2x} 14. If range of values.................
0  {2x} < 1, – [x + 1] = 0 Sol. [sin–1 x] = 1 and [cos–1 x] = 0
–1 x<0 
1  sin–1x  and 0  cos–1x < 1
– 2  2x < 0 2
[2x] = – 2, – 1 
1 sin1  x  sin  cos1 < x  1
2x = – 2, –1  x = – 1, – 2
2 
3 [sin1, sin ]
So  = 2,  =– 2
2 
a = 1, b =
 = – 2, 2  = – 3 2
15. The number of.................
11. For (cot–1 x)2 – 5(cot–1 x) ................. Sol. As shown in the figure, f  x  is non differentiable at 5 points.
Sol. (cot–1x – 2)(cot–1x – 3) < 0
 2 < cot–1 x < 3  x  (cot3, cot2)
–1
as cot x is decreasing
so a = 3, b = 2

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16. The value of ................. 20. The given figure ………….
1 1 1 Sol. If k , spring can be assumed as unstretchable string.
Sol. f  x    ....... 
n2 n2  2 n2  2n  1
Terms of the sequence are decreasing and number of terms 21. A vessel is partly ………….
are (2n + 2) Sol.
2n  2 2n  2
 f  x 
n2  2n  1 n2
 1 Change in unoccupied volume
2n  1  
2  n  1  n  = vvv T – vLL T
Now, lim  lim
n 
n  2
n  2n  1 2 1 23. When object ‘O’ ………….
n 1  2
n n Sol. The above lens mirror combination is an equivalent
converging mirror.
Similarly  lim
2  n  1
 lim
2   =2
n  1
n 
n 2 n  n
25. A solid non-conducting ………….
Sol. Electric field at a distance x from centre
n  3n 1
17. If lim n
.................
x
n 1 n
n
n  x  2  n  3 3 Ex =
30
1
Sol. lim n
divided N and D by 3n  n Energy density at a distance x = 1\2 0 × E x2 = 1/2. 0 ×
n
 x  2
1
n
3 2 .x2
3 n
902
1 1
lim =  lim  0 R
n  3 n n 2 .x 2 Q2
Total energy =
 1/ 2 0  4 x 2 .dx =
x 2
n
0
920 400 R
lim    0  –1 < x < 5  x = 0,1,2,3,4
n 
 3  x=5
10
AM = =2 26. The linear charge ………….
5 /2
18. The number of real.................
Sol. Since
Sol . p =
 2dp
0
sin  [d ir ec t i on ĵ ]

x 2  3x  2  0  0  tan1 x 2  3x  2  y
2
++++ +++
4x  x 2  3  0  0  cos 1 4x  x 2  3 
 ++ +
Since + +
– x
2 –– –
–– –
– – –
 0 < L.H.S    The given equation has no solution
/2
PART : II PHYSICS =
 2 ( 0 s i n  R d . 2R) s i n 
19. An object O ………….
0
Sol. Initially the image is formed at infinity.
(P) As  increases the focal length decreases. Hence
/2
the object is at a distance larger than focal length.  
= 2 0 R 2 d = 2 0 R 2
Therefore final image is real. Also final image
becomes smaller in size in comparision to size of
 (1  cos2)
0
2=
 
image before the change was made.
(Q) If the radius of curvature is doubled, the focal R 2  0
length increases. Hence the object is at a distance
lesser than focal length. Therefore final image is 27. If the electric ………….
virtual. Also final image becomes smaller in size in (2,1,9)
comparision to size of image before the change
was made. Sol. V(0,0,0)  V(2,1,9) =
 y2 dx  2xydy
(R) Due to insertion of slab the effective object for lens (0,0,0 )
shifts right wards. Hence final image is virtual. Also
final image becomes smaller in size in comparision (2,1,9)
to size of image before the change was made. (2,1,9)
(S) The object comes to centre of curvature of right =
 d(xy 2 ) = xy 2 (0,0,0 ) = 2.
spherical surface as a result. Hence the final image (0,0,0)
is virtual. Also final image becomes smaller in size
in comparision to size of image before the change
was made.

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28. There is uniformly …………. 33. A small ball ………….
Sol. Conserving mechanical energy 1
R
2 2
 3 KQq KQq  + m 2 x dx = KQq m  R
KQq 1 Sol . m v 2r = 
2 R

R   
 mv 2 2 0 2R 2
R 2 Substituting values,
putting values, V = 6m/s vr2 = 2 + 1 = 3
vt = r = 1
29. An object of ………….
Sol. 2T cos37° = Mg Vr2  Vt2
vnet = = 31 = 2 m/sec.
 1 T
3  2d    25 34. A charged particle ………….
  Sol. Work done by electric field = gain in K.E. of the particle.
1
30. A closed organ ………….  1 × 10–6 [4 × 105 – V] = × 4 × 10–3 × [200 – 100]
Sol. Equation of stationary wave from closed end = a sink x 2
cos t
 V = 2 × 105 V Ans. 2

Now at x =
7 35. A man starting ………….
Sol. As we know that light travels in a path such as to reach from
one point to another in shortest possible time.
Therefore, the man must travel along that path on which
light would have travelled in moving from P to Q.
By Snell's law;
sini 2 1
  sin r = . sin i
sinr 1 2
3 4 4
sin r = . =
5 3 5
7 Q
=
km
4 10 6km
53º
2  3km
Amplitude = a sin kx = a sin
 7 A
km

37º
2 7 
5

= a sin = a sin =a
 47 2 P
P

31. A traveling sound ………….  r = 53º

Sol. (b) max. velocity particle = A = kA=50×2×10–2 = 1  AQ = 10 Km.
wave velocity /k From P to A :
5
32. The dispersive …………. t1 =
3
10 5
1  1 1  From A to Q : t2 = =
Sol. = (n  1)    4 2
f  R1 R2  5 5 25
T = t1 + t2 = + = hr. = 250 minutes
3 2 6
df  1 1  36. A man of ………….
  =    dn 
Sol.
f2  R1 R2  Bulb

 differentiating both sides

3h
df  1 1   1 1 
  (n  1)    =   dn h
f  R1 R2   R1 R2  x (y–x)
y
dn y–x y
 df = f =
n1 h 3h
3y – 3x = y
but dn = nv  nR
2y = 3x
nv  nR 3x
 df= f  df =  f  fv  fR =  f y=
n1 2
dy 3 dx 3
=  0.04  10 = –0.4 cm = = V
dt 2 dt 2
dy dx 3 V
– = V–V=
dt dt 2 2
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 PART : III CHEMISTRY 44. How many of the following………….
37. Match the following …………. Sol. (c) Reducing nature (in gaseous state) : Li<Na<K<Rb< Cs
Sol The formula for CFSE in octahedral field is : (i) Solubility in water : LiF < LiCl < LiBr < LiI
CFSE = –0.4× (number of electrons in t2g)
+0.6×number of electrons in eg) + P × (number of extra
45. Depression of freezing point………….
pairings compared to normal filling of electrons)
Sol. For urea, Tf = Kf × m
Where octahedral crystal field splitting energy and P = Tf 1.8
pairing energy  Kf = = = 1.8
(A) K4[Fe(CN)6] is 3d6, strong field ligand: t2g6 eg0 with two
m 1
extra pairings Now, for CH3COOH
(B) [MnCl6]4 is 3d5, weak field ligand: t2g3 eg2 with no extra Tf = i × Kf × m  i = 1.1
pairing
(C) [Ni(H2O)6]SO4 is 3d8, weak field ligand: t2g6 eg2 with no Thus, i=1+ so  = 0.1
+ –3
extra pairing Now, [H ] = C = 0.01 × 0.1 = 10 M
(D) [Cr(H2O)6]2is 3d4, weak field ligand: t2g3 eg1 with no  pH = 3
extra pairing.

39. Which of the following …………. 46. Among the following ………….
Sol. Li[AlH4] is Lithium tetrahydridoaluminate(III) Sol. (iii) [FeF6]3– (v) [Cr(H2O)6]2+ (vi) [Mn(H2O)6]2+
[Pt(NH3)6]Cl4 is Hexaammineplatinum(IV) chloride

40. Select the correct ………….

+ 47. How many of the following………….
Sol. (A) Sol. (a), (c),(e),(g),(h)
All are facts.

49. N2H4 is a diprotic base………….

+ +
Sol. pKa of N2H 62+ = pKw – pKb of N2H5+
= pKw – pKb2
= 14 – 16.7 = – 2.7
Ka of N2H62+ = 2 × 103 > 1
N2H62+ is a strong acid
(1) NO2 / SCN (5) NO2 / SCN (9)
(2) ONO / SCN (6) ONO / SCN (10) pH  1
Mirror images of
(3) NO2 / NCS (7) NO2 / NCS (11)
(5), (6), (7), (8)
(4) ONO NCS (8) ONO / NCS (12) 50. For a gaseous reaction………….
* Only cis isomer is optically active.
2+
Sol. A + 3B 2C
(C) Complex(A) [Ni(en)3]  3 chelate ring G = H – TS
2 optical isomer = –90 – 400 × (–0.200)
= –90 + 80 = – 10 KJ.
0 G.I. 1 3
41. Which of the following………….  For A B C
Sol. Correct product of B is phenol.
2 2
G = – 5 KJ
43. What is the ratio of ………….
Sol. Mg(OH)2 Mg2+ + 2OH– 51. The number of possible………….
x 2x + 3y Sol. This is the case of compound having similar ends
Al(OH)3 Al3+ + 3OH–
 chiral isomers = 2n–1 = 24–1 = 23 = 8
y 3y + 2x
Since Ksp of Mg(OH)2 > Ksp of Al(OH)3 Enantiomeric pairs = 4
 x >> y  2x + 3y ~
– 2x
52. Identify number of………….
4 × 10–12 = [Mg2+][OH–]2
= x × (2x)2 Sol. (i), (iii), (iv), (vi) and (vii) having L-configuration.
 x = 10–4
Similarly 1 × 10–33 = [Al3+][OH–]3 53. Find out number of………….
1 × 10–33 = y × (2x)3
– 21 Sol. (i), (ii) and (iv) having cis configuration.
 y = 10
8
x 54. How many statement(s) ………….
Thus = 8 × 1017
y Sol. (a, f, g)
+17 –17
 Ans. = 8 × 10 × 10 =8
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 ADVANCED PATTERN
CUMULATIVE TEST-1 (ACT-1)
TARGET : JEE (MAIN+ADVANCED) 2020
DATE : 28-04-2019 SET-1 COURSE : VIJETA (01JPB, 02JPB, 05JPA)

ANSWER KEY
SET-1
PAPER-1
PART : I MATHEMATICS
1. (ACD) 2. (AD) 3. (ABCD) 4. (BD) 5. (BC) 6. (CD) 7. (02)
8. (05) 9. (21) 10. (24) 11. (14) 12. (05) 13. (10) 14. (12)
15. (B) 16. (A) 17. (B) 18. (A)

PART : II PHYSICS
19. (AB) 20. (AD) 21. (BC) 22. (AB) 23. (AD) 24. (ABC) 25. (25)
26. (10) 27. (20) 28. (07) 29. (42) 30. (16) 31. (10) 32. (20)
33. (B) 34. (C) 35. (C) 36. (A)

PART : III CHEMISTRY

37. (AB) 38. (ABC) 39. (CD) 40. (ABCD) 41. (AC) 42. (AB) 43. (04)
44. (02) 45. (12) 46. (90) 47. (12) 48. (02) 49. (07) 50. (00)
51. (A) 52. (B) 53. (B) 54. (C)

PAPER-2
PART : I MATHEMATICS
1. (B) 2. (C) 3. (BC) 4. (ABCD) 5. (ABC) 6. (ABC) 7. (4)
8. (7) 9. (–1) 10. (–1) 11. (7) 12. (3) 13. (–7) 14. (0)
15. (5) 16. (2) 17. (2) 18. (0)

PART : II PHYSICS
19. (B) 20. (A) 21. (AD) 22. (C) 23. (ABCD) 24. (BC) 25. (5)
26. (1) 27. (2) 28. (6) 29. (8) 30. (6) 31. (1) 32. (4)
33. (2) 34. (2) 35. (4) 36. (2)

PART : III CHEMISTRY

37. (C) 38. (B) 39. (AC) 40. (ABD) 41. (ACD) 42. (AB) 43. (8)

44. (7) 45. (3) 46. (3) 47. (5) 48. (4) 49. (1) 50. (5)
51. (4) 52. (5) 53. (3) 54. (3)

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