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NATIONAL
ADVISORY
FORAERONA1
TECHNICAL NOTE 3273
COMPRESSIBILITY
FACTOR,DENSITY,SPECIFICHEAT,EN’THALPY,
ENTROPY,FREE-ENERGYFUNCTION,
VISCOSITY,
AND
TBERMALCONDUCTIVITY
OF STEAM
NationalBureauof Standards
Washhgton
August1956
,Q
‘i’
U-
J.,L,j
./l--‘1 G-*
-i’-& &u’ ./
COMl?R&WBUJTY
FACTOR,
DENSITY,
SPECIFIC
HEAT,ENTEUFY,
ENTROPY,
FREE-ENERGY
FUNCTION,
VISCOSITY,
AND
THERMAL
CONDUCTIVITY
OF STEAM
Ey.LillaFano,JohnH. Hubbell,
andCharles
W. Beckett
Thetablesof therm&1properties
of stesmthathavebeenprepared
in an NBS-NACA
serieshave&en groupedtogetherhere. Theyinclude,
fortherealgas,thecomp~ssibiUty factor,thedensity,t~ specfiic
heatat constantpressue,theenthslpy,theentro~,thefree-energy
function,theviscosi@,andthethemal conductivity. Fortheideal
gas,thespecific heat,enthslpy,
entro~,andfree-energyfunction
sre
given.Forthetablesgivenin dimensionlessform,conversion
factors
. to somefrequentlyusedtits aregiven.
Thetabular entriesforthecmupressibility
factoranddensity sre
,’. forpressures rangingfrom1 to 300atmospheres.Thet
therangefrom380°K, or justabovecondensation, Tra-s
to 850 cover
K. Thetabu-
lsr entries
forthespecific heat,enthalpy,entro~,andfree-ener~
functionsreforpressures ranging
fran1 to 100atmospheresandfor
temperaturesup to 850°K. ‘lheviscosity
aridthermalconductivity
sx’e
tabulatedas a functionof pressure.
INTRODUCTION
.,. —-—
—. .—— — -.. —— —-———
2 NACATN 3273
B, C, D virialcoefficients
in l/V series,
functions
of temperature
b viscosity
Covolume,
cm3g
/
.
% heatcapacity
at constant
pressure,
various
units
kt
NACATN 32’73 3
%0 heatcapacity
at constant
pressure
foridealgas,various
units
%0 internal
ener~ for1 moleof gasin ideal-gas
Vsrious
units“
stateat 0° K,
F freeenergypermolein standard
state,various
units
F“ freeener~ &r molein standard
state(ideal
gasat 1 atmos-
phereforgaseous
Wbstsmces),various
units
H enthslpy
permole,various
units
H“ enthalpy
permolein standsrd
state(ideal
gasat 1 atmosphere
forgaseoussubstsmces
),variousunits
k thermal
conduct
ivity,various
units
k“ thermal
conductivity
extrapolated
to zeropressure
k“ thermal
conductivity
at 0° C extrapo=ted
to zeropressure
M molecular
weight
N= Prandtl
myiber,Cpqk
I
2 pressu, ah
R gasconstant,R’~, 4.55465cm3atm/”Kg
R’ cm3 s,*m/”K
gasconstant, ~le
s entropy
permole,various
units
so entropy
for1 molein stsmdard
state(ideslgasat 1 atmosphere
forgaseoussubstances
),various
units.
T absolute
tempera-, %
‘o
temperature
at standard
conditioti, K or 491.688”R
273.16°
t = l/T,%-1
.
4 NACATN 3273
specific cm3 g
volume, f
/
function
in theoryof viscosity,
V -5
v
compressibility
factor
viscosity,
micropoises
density,
g as
I
temperature-volume
function
useI@yes’ data(refs.
investigated.
Kennedychoseto
.—. — .
NACATN 3273 5
V3RIALREeRE~ ON OF PVTDATAFORSTEAM
As iswellknown,thecompressibilityfactorZ of an imperfect
gascanbe represented BC+ — + %...
as Z = 1 + - .,wheretheVirial
v v # ~3
coefficients
B, C, D, . . . arefunctions of temperature,
depending
6 NACATN 3273
on two-body,
three-bdy, four-body,. . . interactions,respectively.
E theintermol..eculsr
potentisl functionfora gaswereknown,thevirial ‘
coefficientscould,in principle,be calculated. However, theinter-
molecularpotentialis notlnmwnexactly evenforthesimplest gases,and .
onemusttherefore resortto appro@mate modelsof thispotential. One
widelyusedmodelis theLennard-Jones potential, whichrepresents the
attractiveandrepulsive energiesbetween twomoleculesas proportional.
to theinversesixthandtweMthpower,res~ctively, of theintermolecu-
larseparation. Thispotential, however, appliesonlyto spherical non-
polarmoleculesad therefore cannotbe usedin the caseofwater.A
betterrepresentation
istheStochayerpotential, whichis essentially
a Lennard-Jones
potential.withan additional termrepresentingtheinter-
actionbetweentwopointdipoles..stockmsyer (ref.12)andRowldnson
(ref.13)havecomptied secondvirislc~fficientsB on thebasisof
thispotential. Thesecoefficients arefunctions of temperatureand
involvea xumiber
ofparameters whichmustbe determined foreachparticu-
largasfrm experimental results.Rowlinson (ref.14)hasalsoshown
thatthechsmgein thesecond virialcoefficients dueto thecomplexity
andfinitesizeof thechsrgedistribution forwateris -.
Recently,Rqtl.inson
(ref.15)hascomputed thethirdvirialcoef -
ficientC on thebasisoftheStockmayer potentisl.As he pointsout,
inthiscase,itmayno longerbe truethatthedifference dueto the ,
fini.tesizeof thechargedistribution
is small,since,aswas shown
by Bird,Spotz,andHirschfelder(ref.16),thevaluesof thethirdvir- ,
ialcoefficient arequitesensitive
to thedetails ofthe sha~ ofthe
intermolecularpotentisl.
A comparison
betweenthevaluesof thesecondvirialcoefficients
computedon thebasisoftheStoclmayer potentisLandthe“experimentsJ.”
valuesof B showsverysatisfactory agreementbetween3@2°and&Xl”K.
Thecalculatedvaluesof B wereobtained usingtheconstsntssuggested
by RowlJnson(ref.14)@ by tablespublished by Bird,Spotz,and
IHrschfelder(ref.16). Theexperimental valuesof B wereobtainedby
usingthevaluesof Z calculated onthebasisof Keyes’equations
(ref.5) at verylowpressure.In thiscase,the compressibilityfactor
canbe representedshply as Z = 1 + ~ P, fromwhich B canbe easily
RT
derived.As shownin figure3, at verylowpressure, theplotsof Z
versusP obtained fromKeyes’eqyation andfromtheStockmayerpotential
arepracticallycoincident.
As shownby Rowlinson
(ref.15),however,
thea$peement
isverybad
inthe caseofthethirdtirialcoefficientC. Thedisagreement
between
calculatedandexperimental.
valuesof C decreases,
however,
with
increasingt&rperatures,
theexperimental
andcalculated
valuesof C
beingat leastofthessmeorderofmagnitudeaboveabout750°K. It
v
DISCUSSION
ANDREXJABIIXTY
OF TABLES
factor Z (table
Table1.-Thevaluesof thecompressibility 1)
werecomputed
on thebasisof I&yes’equation
(ref.5)
(1)
where
T temperature,
%S
8 NACATN 3273
v specific cm3/ g
volume,
W= V-8
P density,l/v, g/cd
5 = 2.0624e~ (-0.38P)
v~=l%o.lyt x 104t2)
exp (1’.42k
W2=0
75.364-27.50590
$2 =
1#
Pl = Z(VbT)RT/Vl
.— —.—— —
M
mm m 3273 9
. A IleW
valueof specific
volme V2 maybe obtained
as
‘2= Z(VA+
Thisnewvalue V2 iS inturnsubstitutedin equations(1)to obtain
a newvalueof Thisvalueof Z correspondsto a pressure
whichis,in general,
muchcloserto thedesired
Vahle-P “t&l-thepressureP1 obtainedby firstapproximation.
P - P2
V3=V2+P2 - PI(V2- vi)
P- P~
If— is less than O.0CM)5,
then V3 is sufficiently
closeto the
P
truesoltiionof eqyations (1)forthepurpose(consistencyof 1 pert
P- P2
in 10,000).13?~ is notm.dficiently
small,thenfurther approxi-
mationstepsmustbe usedby inserting.
V3 in equations(1)- c~
outtheaboveprocedure aa faras necesssry.
In general,threecomptia-
tionsof equations
(1)weresufficient. ThestartingvsluesV1 were
takenforconveniencefromKoch’stables(refs.2 snd3) exceptin the
regionwhere 0.990<Z < 1, where V1 wastakena8 RT/P.
~=+=2-ZRT
10 NACATN 3273
~%?
—= c&+&+7P4+5#3 (2)
R
‘P = AP.+BP%CP4+l& (3) ~
and
A~=
J
5m
~
Becauseofthetedious
natureof thecalculations
required
in usi~
Kkyes’correlating
equations(1),thederived
thermodynamic
quantities
. ————
NACATN 3273 n
wereobtained through
theearlier correlation
of theheatcapacities
(ref.8) by Keyes,~th, md Gerrywhichwasfoundto M quitecon-
sistentwiththecorrelationof thedataof state.As a checkof the
consistencyof thetwoapparentlyindependent
calculations,
thefree-
ener~ function (table
6)was computedfrm both
m=
-m ~ J Pz-lw
P
-—=-
()
al? NIA4
—-—
RTRTR
Tablesl’(a)
andT(b).-Theviscosityq at 1 atmosphere
(tableT(a))
was computedaccording
to theequations
givenby Bo~, Brooks,and
Walker(ref.19)
v = 0.361JII
- 10.2 for T S &)OOK
39.37T3/2
~ for T~800° K
= 33.15-T + 0.001151312
.
12 rum m 3273
where T is temperature
in % and q is inmicropoises. Figurek(a)
showsa deviation
plotof thecalculatedvsluesandof theexperimental.
resultsby various
authors(refs.
19 to 25).
The&Lscosityq at higherpressures
(tabley(b))was computed ,>
according
to Enskogtheoryfromtheequation
givenby Gardnerin a dis-
cussion
d reference 26:
I i- O.175tIp
‘WC=l + O.8651b2p2
where
% l-atmosphere
viscosity
at !2°K, poises
P density,
g cm3
/
and
where
M molecular
weight
T temperature,
%
Thevalues of densityup to 850°K weretdcenfromtable2; above850°K
theyweretakenfromthe stesmtablesin reference 1. Figure4(b)shows
a plotof thedeviations betweenthecalculatedvaluesand.,
theexperi-
mentalresults by variousauthors(refs.25 and27to @).
Thedepartures
fromthetabulatedvaluesofthe low-pressurevis-
cositydatafor steamareshownin figure4(a)to he lessthan4 percent.
The scatter
of thereliablemeasureme
ntsat elevatedQressures
is higher
(approdmatel.y
10 percent)
as is indicated
in fi- !(b)
.
Table8.-Thedimensionless
thermalconductivity
k/koO wa8 com-
putedfrantheequations
)
k = k“ + 1.097X 10-5(~oo.934xm%/T4 1
II
— — —— ..——..—
NACATN 3~ 13
.
k“ = 1.5J+66@/2
~ 10-5
~+ 1737.3~o-12/T
T
where
k thermalconductivi~,
calcm-lsec-l
%@_
k“ themdl.
conductivity
extrapolated
to zeropressure
T temperature,
‘K
P pressure,
atm
. .. .. .. —.—.
.—— .—z ——. —.— —— . .—— — ——. .
14 mcAm 3273
National of Stadmis,
13ureau
Washington,
D. C.,August26,1955.
— ——
NACATN 3273 15
.
lwFERENms
. 1. Keenan,
JosephH.,andKeyes,Erederick
G.: l?hemmdymmic
Properties
. JohnWiley& Sons,Inc.,1936.
of St-esm.
tafeln.R. Oldenbourg
2. Koch,w.: Wasserdampf (llerHn),
1937.
“3. Koch,W.,andSclmidt,
E.: Wasserdsmpftafeln.
DritteAuflage,
R. Oldenbourg
(Miinchen),
1952.
4. Goff,JohnA.,andGratch,S.: Low-Pressure
Properties
ofWater
F. Heating,
worn-160to Z%2?” pipingandw Conditioning,
vol.18,
Feb.194-6,pp.I-25-136.
5. Keyes,F. G.: Consistency
of theThermodynamic
M% forWaterSub-
stanceVaporPhaseto 550°C. Jour.Chem.~S., vol.17,nO.10,
Ott. 1949,pp 923-934.
●
16 NACA
TN3273
E. Stockmayer,
W. H.: SecondVirialCoefficientsofPolarGases.Jour.
Chem.Phys.,vol.9, no.5,May 1941,pp. 398-k)2,and no.M?,Dec.
1941,pp.86>870.
13. Rowl.inson,
J. S.: TheSecondVirialCoefficients
of PolsrGases.
Trti. Fsraday SOC.
, vol.XLV,pt.10,no.322,Oct.1949,
PP.974-984.
14. Rowlinson,
J. S.: TheLatticeEnergyof IceandtheSecondVirial
of Water.Trans.Faraday
Coefficient Sot., vol.~VII,
.- Pt.2,
no.338,Feb.1951,pp.120-@3. - -
15. Rowlinson, of PolsrGases;
J. S.: TheThirdVirialCoefficients
Jour.Chem.~SO, VO1.19,no.7, July1951,pp. 827-831.
16. Bird,R. B.,Spotz,E. L.,andlllrschfelder,
J. O.: TheThirdVirisL
Coefficient
forNon-PolarGases.Jour.Chem.~S., VO1.18,
rio.
10,Oct.l_950,pp.1395-lk02.
17. Glatt,L.,Adams,J. H.,andJohnston,
H. L.: Thermodynamic
Prop-
ertiesofthe~0 Molecule forSpectroscopic
Ihta. Tech.
Rep.316-8,OhioStateUniv.Res.Foundation,1953. ●
—.
M
NACATN 3273 17
38. Benedict,
W. S.,Claassen,
H. H.,andShaw,J. H.: Absorption
Spectrm
ofWaterVaporE!etween
4.5and13 Microns.Res.PaperRP2347,Jour.
Res.,Nat.Eur.Standsxds,
vol.49,no.2,Aug.19>2,pp.91-132.
39. Wagnan,
Ikmal.d
D.,Hlpatrick,JohnE.,et al.: Heats,IkeeEnergies, *
andEquilibriaConstants
of Sme Reactions
Involving02,~, ~0,
c, co,co~,andCH4. Res.Pa~r RP1634,Jour.Res.,Nat.~.
Standards,
vol.34,no.2,Feb.1945,pp.143-161.
40.Rossini,l&ederick
D.,Pitzer,
K&methS.
, et al.: Sslected
Values
of Physical
andTherm&&ynamic
Properties
of Hydrocarbons
andRelated
compounds
. Res.Project
44,A.P.I.,Carnegie
Press(Pittsburgh),
1953.
41. Rossini, FrederickD.,Pitzer,
Kenneth
S.,et al.: Selected
Values
of Propertiesof Hydrocarbons.
Cir.No.461,Nat.Bur.Skndsxds,
U. S. Govt.PrintingOffice,
Nov.1947.
42. ~Wki?X3,
G. A., Solberg,H. L.,andSibbiti,
W. L.: UnitsandCon-
version
Factors
forAbsolute
Viscosity.
PowerPlantEng.,Vol 45,
●
no.H, Nov.1941,pp.62-65.
43. Benedict,
w. s., and Hilsenrath,
Joseph:Tablesof CompressibiMty “
andDepsityofAir. ReP.u92, Nat.13ur.S-t*dSj Ikc.1, 1951.
-——
NACATN 3273 19
TAm?,
1.-~ rAcRmz.
Pv/ia
Fcmmw.M
I
% lti Ma-b Zoatn 4oa’h %
I
380 .98591 176 684
390 .98767 145 702
400 .98912 320 720
410 .99032 10I 738
420 .99133 86 756
430 .99219 75 774
440 .99294 6 792
450 .99359 % 810
460 .99415 92 .93377 672 828
470 .99465 u .94048 3m 846
480 .99509 39 .94617 m 864
490 .99548 35 .95105 423 .89209 10$5 882
500 .99583 31 .95528 %9 .90274 m7 900
510 .99614 a .95897 326 .91176 m 918
520 .99642 E .96223 m .91953 673 936
530 .99667 23 .96511 2SI .92626 m .83225 1Q3 954
540 .99690 a .96768 al .9321.5 5a .84838 2367 972
550 .99711 19 .96999 m .93736 K? .86205 2174 990
560 .99730 u .97207 W .94198 423 .87379 ma 1008
570 .99747 26 .97395 170 .94611 372 .88400 m 1026
580 .99763 14 .97565 255 .94983 335 .89295 792 1044
590 .99777 33 .9n20 142 .95318 344 .90087 75 1062
600 .99790 22 .978b2 234 .95622 277 .90792 m 1080
610 .99802 22 .97992 229 .95899 2s .91425 m 1098
620 .99814 10 .98111 220 .96152 232 .91995 % 1116
630 .99824 10 .98221 2!32 .96384 222 .92511 m 1134
640 .99834 9 .98323 44 .96596 m .92980 422 1152
650 .99843 9 .98417 E5 .96791 m .93402 30s 1170
660 .99852 8 .98503 Q .96969 w .93787 3s-5 1188
670 .99860 7 .98584 E .97137 255 .94143 329 1206
680 .99867 7 .98659 70 .97292 144 .94472 30 1224
690 .99874 6 .98729 & .97436 234 .94777 m 1242
700 .99880 6 .98795 62 .97570 m .95060 263 1260
710 .99886 6 .98856 S7 .97695 m .95323 245 1278
720 .99892 5 .98913 H .97813 220 .95568 2?3 1296
730 .99897 5 .98967 52 .97923 203 .95797 a4 1314
740 .b9902 5 .99018 47 .98026 97 .96011 m 1332
750 .99907 4 .99065 45 .98123 w .96211 m 1350
760 .99911 4 .99110 42 .98213 86 .96399 277 1368
770 .99915 4 .99152 40 .98299 m .96576 2M 1386
780 .99919 4 .99192 37 .98379 76 .96742 m 1404
790 .99923 4 .99229 36 .98455 72 .96898 147 1422
Boo .99927 3 .99265 33 .98527 b9 .97045 239 1440
810 .99930 3 .99298 32 .98595 64 .97184 231 1458
820 .99933 3 .99330 30 .98659 62 .97315 224 1476
830 .99936 3 .99360 29 .98720 S-3 .97439 227 1494
840 .99939 3 .99389 z-l .98778 54 .97556 222 1512
850 .99942 .99416 .98832 .97667 1530
!cABm
2.-IamzI!l
p OFSIEAM .
[Valwin+5]
380 .00058604
-m 684
390 .00056999
-3.506 702
400 .00055493
-1419 720
410 .00054074
-3342 738
420 .00052732
-m 756
430 .00051462
-m 774
440 .00050254
-12m 792
450 .00049105
-W5 810
460 .00048010
-IrM .0051115-1445 828
470 .00046965
-%9 .0049670-2327 846
480 .00045966
-$% .0048343-m
490 .00045011
-916 .0047114-3247 .010045 -317 %
500 .00044095
-878 .0045967-Ian .0097284-2m2 900
510 .00043217
-s43 .0044892-1U32 .0094433-m 918
520 - alo
.00042374 .0043880-s3 .0091835-23M 936
530 .00041564
-779 .0042923-W7 .0089447-2223 .019910 --m 954 3
540 .00040785
-m .0042016–W2 .0087236-2QK .019170 -647 972
550 .00040035
-722 .0041154-m .0085174-m? .018523 -576 990
560 -en
.00039313 .0040333-m4 .0083242-m7 .017947 -m 1008
570 .00038616
-672 .0039549-m .0081425-1717 .017429 -472 1026 .
580 .00037944
-648 .0038799-m .0079708-1677 .016957 -434 1044
590 .00037296
-626 .0038081-m .0078081-3545 .016523 -m? 1062
600 .00036670
-w .0037392-w .0076536-1472 .016121 -374 1080
610 .00036064
-s6 .0036730-636 .0075064-14JE .015747 -393 1098
620 .00035478
-%7 .0036094-633 .0073659-3344 .015397 -m 1116
630 .00034911
–34a .0035481-m .0072335-U&5 .015068 -320 1134
640 .00034363
-92 .0034891-m .0071029-3234 .014758 -.2%? 1152
650 .00033831
- m .0034321-550 .0069795-m4 .014466 -27a 1170
660 .00033315
-m .0033771-31 .0068611-Im .014188 -26 1188
670 .00032815
-464 .0033240- m .0067471-lC% .013923 -is 1206
680 -m
.00032331 .0032726-497 .0066372-ma .013671 1224
690 .00031860
-451 .0032229- 4Q .0065314-1U22 .013429 ->1 1242
700 .00031403
–444 .0031748-*467 .0064292-%6 .013198 -223 1260
710 .00030959
-4?2 .0031281-4s2 .0063306-953 .012976 -213 1278
720 .00030527
-a .0030829-439 .0062351-923 .012763 -2C5 1296
730 .00030107
-41m .0030390-426 .0061428-m4 .012558 -197 1314
740 .00029699
-m .0029964-424 .0060534-a% .012361 -144 1332
750 ,00029301
-386 .0029550-m .0059668-09 .012171 -Ie4 1350
760 - m
.00028915 .0029148-393 .0058829-S15 .011987 -In 1368
770 .00028538
-367 .0028758-m .0058014-m .011810 -237 1386
780 .00028171
-359 .0028377-369 .0057224- 7m .011638 -P% 1404
790 .00027813
-349 .0028008- S@ .0056456-747 .011473 -262 1422
800 .000274M-339 .0027648-353 .0055709-725 .011312 -356 1440
810 .00027125
-332 .0027297-341 .0054984-m .011156 -350 1458
820 .00026793
-324 .0026956-333 .0054278-W .011006 -147 1476
830 .00026469
- 33s .0026623-m .0053591-w .010859 -142 1494
840 :00026154
-m .0026298-326 .0052922-m .010717 -In 1512
850 .00025845 .0025982 .0052271 .010579 1530
M
NACATN 3273 23
—— — .— —— .— ... ..— —
26 NACATN 3273
mRLE3.-8PmrFIc
H ~R/ OFm-concmba
. mma
4.-?ml!Jm#
(’-%0)%
/ OFmw”l
. [
“K I 1 ah I M) ah I EO atm 4oabn I ‘?R
1.
mBIE4.-EmfAIFP(Ii
- ~?) oFmBAM-c!Onduaed
h
“K 4oabJl 60a-bll @atan 100* “R
K (k!Z1.68f3°
T$= 2j’3.16” R).
w
NACATN 3273
mEIE5.-EmKm E@ oFm!EPM
.
...———- .— — —- —— --————-
—-—— ——— .— I
—. ——... —. —— —____ ._. .— —__ _
30 mc~ m 3273
!lAliLE
5.-E%CROPY
13/ROFSILEAM
- Conclnd.ed
-. . .——
NACATN 3273 31
. m 6.-HEE-mmuxf
FUNCWION
-(F- ~O)/RT OF EWEPM
32 m m 3273
1.
——— —
M
NAC!A
m 3273 33
!MElW7..
VfEm3m q oFmmM “
Valuas
[ inpicas1
10-5 x
% ~ % “K n %
t
%tr4.as
bdOW373.l&
K refer
to ViEWSi@ d vqor mar maturation
~saura.
!cAEIz
7.- VIan8rm 7J clFslmM—conclAea
(b)At d.evdd pressmas.
8.-~w~f
TABLS k~ CIFSJ!EAM
[ % I o-8bn
Hndt labn 4Etm 7um % I
—.—
NACA
m 3273 37
m 9.-EPEcnIc
Ekm,mfmm,aFmE-mmfx
mmn!m,m EFmmY
cmm!mMmm@AI-OMmAm
Th2m9.-~c IIwc,
EmKm?r,a
mEF-Em2tm
PmCmm,m EmKm’Y
aFmEAMm maAIAA8mAm—cOmldd
‘% %0
T-
EP-EQ”
%
R15i2
Kc
: %
1200 5.2555 19.5385 1%59 24.4569 X-?7 28.9046 !262 2160
1300 5.3960 2L4884 1%$9 24.8156 3372 29.3308 w 2340
1400 5.5286 23.4883 m’Pl 25.1527 31B5 29.7356 w 2520
1500 5.6526 25.5353 am’ 25.4712 3FZ2 30.1213 X& 2700
1600 5.7678 27.6260 73332 25.n34 m 30.4899 2880
1700 5.8743 29.7572 Z2m 26.0613 2752 30.8428 N 300
1800 5.9725 3L9260 22m 26.3364 =6 31.1814 - 3A
1900 6.0628 34.1291 22350 26.6000 Z532 3L5067 SZS2 3420
2000 6.1460 36.3641 22641 26.8532 2438 3L8199 3017 3600
2100 6.2224 38.6282 2i920 27.0970 Z35Jl 32.1216 mu 3780
2200 6.2928 40.9192 23259 27.3320 2272 32.4127 m 3960
2300 6.3576 43.2350 Z33Es 27.5591 22% 32.6939 2nB 4140
2400 6.4174 45.5735 as% 27.n87 212a 32.9657 26Yl 4320
2500 6.4727 47.9331 m 27.99E 2W 33.2288 2%9 4500
2600 6.5238 50.3120 m 28.1978 2034 33.4837 2472 4680
2700 45n2 52.7091 24139 28.3982 lW 33.7308 2393 4860
2800 6.61.53 55.1230 26?93 28.5930 26% 33.9706 2329 5040
2900 6.6563 57.5523 z- 28.7824 2845 34.2035 22!s 5220
3000 6.6945 59.9962 4m3 28.9669 3552 34.4298 M 5400
.
NACATN 3273 39
Valueof R
For Forpressure
in -
density
in- atm kgfcmp lmll
Hg lb/sqin.
Fortemperatures
in %
g/m3 4.5%6 4.70600 3,461.54 66.9353
3
molecm 82.0567 84.7832 62,363.1 1,205.91
/
mole/liter .0&2@-4 .0847809 62.3613 1.20587
lb/cuft .0729579 .0753821_ 55.4480 1.07219
lb mole/cu
ft 1.31441 I.35808 998.952 19.3166
Fortemperatures
in % ~
g/cm3 2.53037 2.61444 1,923.08 37.1863
3
molecm 45.5871 47.1018 34,646.2 G9 .950
I
mole/liter .0455858 .0471005 34.6452 .669928
lb/cuft .0405322 .0418789 30.8044 .595661
lb mol..e/cu
ft .73022.8 ● 754489 554.973 10.7314
40 mm m 3273
lb ft-3 62.4283
(b)Fortable7
To convert Hming thedimensions Multiply
tabulated To indicated
below by
vail.ue”
of —
q in poises T kg br-lm-l 3.6000x 102
or g sec-1 cm-l- slughr-1ft-l 7.5188
lb see-lft-l 6.7I97X 10-2
.— ——— —.— .-
VI
NACATN 3273 41
.
TABm 11..
- CONVERSION
FA~RS FORTAEIES2 TO 9 - Concluded
(d)Fortables4 and9
(e)Fortables3, 5, 6, M9
To convert HZwingthedhensions Multiply
tabulated To indicated
below
vzllue
of
~“/R, So/R, C& so, calmole““ (orO@ ‘:8a9
Cp R) @% CPJ‘J Ca g-’“ (0’‘c-’) .110301
I
s g-l‘-1 (or‘C-1) .461X0
- F“ - Eoo)/~, -(F“ - EO”)/T,
(
-(F- EOO)\RT-(F- Eo”)/T ‘:::9
‘E&::::’~: :;-9
I
—. —. _
TABLE12.- GEamAL mlrvEmIolilMm’oFa
+-l-+-i
Ill 10 ~+’ 1
I lD!+I I ur~ I 1o-6 I 10-3
I 1A
m
10-7
m
K+
in.
to Obtdn->
4
lm 1 0.01 0.3937
I I 103 I I 39.37
I 1 h. I 2.5JUxxyn \ 0.02-1 ] 1 o!cm333333I 0.CW777778 I
I lft I W.wl I o.*ckl I X2 1 ] 0.33333333\
lyl 9LM183 0.91440183 “36 3 Ill
TABLEIi?,-GR!ERALCONVERSIONF~ - Contlmmd
1 II* 1, m 1 O,am
lti Zm.m 3.7@3a 1.
I I I
~ COHV’EREIOH
FM?I.YRS
- COrrtimEd
Multiply by appropriate
entry
s w lb metrictall ton
J to ~~
Multiply by apprqn’iate
entry
$ to o~
gd
/
K/d UJau h. 1.3)/au
ft lb/gal
1 lb/Cru
rt o.ol&x8j%g o,ol&Ma2 5.7m370 x 10-h 1 o.13X&t%
(f)Forumiiwd presmre
. .
mlt:m.mtie.=~ &ym/cr# tar ad kg(vt.
)/m2 Q& in.H,(J lb(vt.
)/eqin.
J
1 &yuEJc# 1 @ x lf+ T.w%17 x 10-4
0.SW9233x lo-g1.o197162 2.Hc3SU x l.o-~1.kA3533 x 10-5
1 atn 1,013,
m 1.o13@ 1 1.0332E75 @3 a.m.m lMs@X6
lmm 1,333.2237
1,33322TT
x 10-31.313-wx 10-3 1.3397W3x @ 1 0.om~ O.wm
1 lb(vt.
)/q in. 68,*7.X oX@34nl o.c&wyp o.~ 2. V4T3 2.0* 1
mrz..- ——-—
(dkmitsti -
Utirw Wti= .= e-~ Lb. Jti iub. Jfmla @fmola ~ .~-v~ “q.~
~. d.ea&n-v/blmJ10
I
L S** 1 6.02sS3
X& 6.wa#X @ 1.43wJl
x# 6.2%222
X # 6.2W7X + 5.03%l x IN
1 nbm. j/mOlo l.m x lo-1~ 1 0.5%+55 o.e39x.s l.o%kq x U@ 1.0XM!6x 10+ Om!l x 10-~
1 *~ 6:9.590
X 2J@~ 4.W 4.*3 1 4.3*1x ld b.mw x 10+ o.%m3
1 ini.
OwtI’UQ.T- l.bz%axK+ $,51’1.1 %,XM 23,dl.1 1.UW+I 1 .9Jo-p.cc
a
tiply by
to
appropriate
1 em, S/g %
o~~
entry
abe. J/g ‘C
1
int.J/g %
0.W39
@/E
o.ww%
Oc 1. T.a od/g ‘c
O.a%w
Btu/lb%
0. Q5-W9
“1 id. J/g Oc l.uxlhs~ 1 0.3$043 o.2@3@ 0.-9
1 C@! 00 4.M?40 4.1833 1 0.9993M 0.s9934.6
‘8
U
M I
— —
1.0( I
1
-_-— -— -- —. U300”c.
-
\
.9(
.8(
.7(
1-
K
\
> \\
n .6(
: \
\
\
.5( — ‘— Kennedy, 1950 (ref. 6)
Present correlation \
.4(
.X
I I I I
‘+
.2( ---
Iuo zoo 500 400
P,atm
.90-
.80-
,70–
r
.60-
O Kirillln and Rurn]anzw, t950(mf.7)
present correlatlan
XH?c_
s
.40
.30 I I I I I I I I I 1
d
NACATN3273
1.00
. — Ke~, 1949(ref.5)
— — Stockmayer,1941(ref.12)
.99 ‘-— Kennedy,1950, (ref. 6)
.98
.97
.96
+
a
\
>
&
. A .95
.
.94
,93
.92
.9I
/
.90 I
o 50 100 15-0 200 290 300 350 400
PRESSUR< atm
.
Figure3.- Comparison
of variously
derived
compressibility
factors
for
stesm.
——. —
. ...— —...—.— .—.
6.70
J % T~ ‘-r- ‘Or&R~q~W, UP t.93atm, 1934 (mf.22)
4.0
— O BorJllo, Brooks,& Walker 1951 (ref. 19)
/!
* / 0
‘s+=
0 Hawkins, Solberg,~ Potter, 193S(ref, 23
2Q— o
8 Braunel~ Llnke, 1930( rgf,24) o
—--=-00 0 Speyerer, 1925(ref. 21)
1% o Slawart, 1936 (ref. 25)
~. e ~P e 0 0 0
/
o
‘a
if
2
u
Q 0 0
o
w
-2JJ
—
0
- 1/
0
-4.0—
0
I I I I I I I I I I I I
3m m 700 m Ilm 130a 15cKJ
T, %
e 14
+::
#m
10.00 ,
I I
, ‘1—-’/ I 1
PRE66URE 6YMBOL
I
e
d . ●
;
+
s16v#vtT, 1936(Iefa2S 527)
e : p
26.1 am 0 +
46.2 ; 4$
6.00 –
55.9
74.8
●
@
e ●$ x
o 0
88.0 e ❑
+
I 07.6 ● m <~.+ +
LLl I 22.2 K “dapx+a
148,3 0
17Z6 ● ?J& * + . .-’ “
f 207.9 6 mm.
g 261.7 Q 0 M— *
go u:+ O*9 ~ : + a+
JACKSON, 1949 (ref. =),
e .* * +-
15.4 atm e
* 23.7 k -r
~ +
w * +4+ :
TIMROTH, 1640(ref. 28) ,%
-5.00– 97. I atm # @ Q
~27. / + +-+ ~]
x
x +
:.4:$ e
345.2 : F
+-
-10.00
500 600 700 800 900
T,‘K
‘f?’’””~
f501#o.--~~’’’
o
{ -----
0
—— —-- _— - --— —--, ———
Timroth
—---
~ Varg~ftlk,
—-. ---
1940 (ref. 32)
-—
0
-5,0 I I I I
400 500 600 700 800
T,”K
E
~bs- &b
for stesm (table 8). percat d~e, x 100.
kb i
$
59
T, “c
400 600 800
I I I
\
\
2.( \
— Present correlation \
——– Rubln,[9=(ref. 34)
\
\
\
\
\
\
\
\
\
\
--—”
I otm
I.(
Figure6.- I!randtlnmnberforsteam.
/ 9
/=: ●
o 9=X%’ --y 9
I 4 I I
000 7 x x
$
1000 2000 3000 4000 5000
. 1- . T, “K
Figure 8.- Comparison of Ldeal-@s free-eneqg functions variously computed. A . !lkbul,atd - c-th~.
I
m’
P