Introduction To General Organic and Biochemistry 10th Edition Bettelheim Test Bank Download

Introduction to General Organic and Biochemistry
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CHAPTER 6 — SOLUTIONS AND COLLOIDS
MULTIPLE CHOICE
1. The term solution is synonymous with which of the following?

a. compound c. heterogeneous mixture
b. element d. homogeneous mixture
ANS: D PTS: 1
TOP: 6.1 - WHAT DO WE NEED TO KNOW AS WE BEGIN?
2. Which of the following is a solution?

a. blood plasma c. milk
b. cigarette smoke d. none of these
ANS: D PTS: 1
3. Which of the following is intermediate between homogenous and heterogeneous mixtures?

a. alloys c. plastics
b. colloidal dispersions d. polymers
ANS: B PTS: 1
4. Which of the following cannot serve as a solvent in a solution?

a. a gas c. a solid
b. a liquid d. None, all can serve as solvents.
ANS: D PTS: 1
TOP: 6.2 - WHAT ARE THE MOST COMMON TYPES OF SOLUTIONS?
5. Which of the following cannot serve as a solute in a solution?

a. a gas c. a solid
b. a liquid d. None, all can serve as solutes.
ANS: D PTS: 1
6. The term alloy is applied to which of the following solvent/solute combinations?

a. liquid/solid c. solid/solid
b. liquid/liquid d. none of these
ANS: C PTS: 1
7. Which of the following combinations will always result in a solution?

a. gas + gas c. solid + solid
b. liquid + liquid d. none of these
ANS: A PTS: 1
8. In a solution of a gas in a liquid, the gas is called which of the following?

a. concentrate c. solute
b. dissolvate d. solvent
ANS: C PTS: 1
9. In a solution of a solid in a liquid, the liquid is called which of the following?

b. dissolver d. solvent
ANS: C PTS: 1
10. In a solution of a solid in a liquid, the solid is called which of the following?
b. dissolvate d. solvent
ANS: C PTS: 1
11. When alcohol is dissolved in water which is the solute?

a. the alcohol
b. the water
c. the compound present in larger amount
d. the compound present in smaller amount
ANS: C PTS: 1
12. When dealing with solutions which of the following laws is not applicable?
a. law of conservation of energy
b. law of conservation of mass
c. law of constant composition
d. None, all of the above laws are applicable.
ANS: C PTS: 1
TOP: 6.3 - WHAT ARE THE DISTINGUISHING CHARACTERISTICS OF SOLUTIONS?
13. A chemist has a sample which is known to be a solution. Which of the following might be used to
separate the components of the solution?
a. distillation c. either a or b
b. filtration d. neither a nor b
ANS: A PTS: 1
a. chromatography c. either a or b
b. filtration d. neither a nor b
ANS: A PTS: 1
a. chromatography c. either a or b
b. distillation d. neither a nor b
ANS: C PTS: 1
16. Rainwater is naturally slightly acidic. Which gas causes this?

a. N2 c. CO2
b. O2 d. SO2
ANS: C PTS: 1
17. When a certain clear red-brown liquid passes through a filtering apparatus no material is collected on
the filter. What can be said about this liquid?
a. It is an element.
b. It is a compound.
c. It is a solution.
d. We cannot determine if it is an element, a compound or a solution.
ANS: D PTS: 1
18. When a certain clear red-brown liquid is distilled we recover a clear liquid and a red-brown solid?
What can be said about the red-brown liquid?
a. It is an element.
b. It is a compound.
c. It is a solution.
d. We cannot determine if it is an element, a compound or a solution.
ANS: C PTS: 1
19. A beaker of salt water has some solid salt at the bottom? What type of solution is in the beaker?
a. a saturated solution c. an unsaturated solution
b. a supersaturated solution d. We cannot tell.
ANS: A PTS: 1 TOP: 6.4 - WHAT FACTORS AFFECT SOLUBILITY?
20. A student is preparing a sugar water solution to make rock candy. When the student continues to add
sugar to the solution the sugar dissolves. Which kind of solution does the student have?
ANS: C PTS: 1 TOP: 6.4 - WHAT FACTORS AFFECT SOLUBILITY?
21. A student is preparing a sugar water solution to make rock candy. When the student continues to add
sugar to the solution no additional sugar dissolves. Which kind of solution does the student have?
22. A student is preparing a sugar water solution to make rock candy. When the student adds some sugar
to the solution a large amount of sugar crystallizes. Which kind of solution does the student have?
ANS: B PTS: 1 TOP: 6.4 - WHAT FACTORS AFFECT SOLUBILITY?
23. The term miscible is applied to which of the following solvent/solute combinations?
a. liquid/gas c. liquid/solid
b. liquid/liquid d. none of these
24. Which of the following pairs of liquids are miscible in all proportions?
a. ethanol and water c. gasoline and water
b. ethanol and oil d. none of these
25. When considering the solubility of a particular solute in a particular solvent the term “like dissolves
like” generally refers to which of the following properties?
a. formula weight c. both a and b
b. molecular shape d. neither a nor b
ANS: D PTS: 1 TOP: 6.4 - WHAT FACTORS AFFECT SOLUBILITY?
26. When considering the solubility of a particular solute in a particular solvent the term “like dissolves
like” generally refers to which of the following properties?
a. formula weight c. both a and b
b. molecular polarity d. neither a nor b
27. Water is generally a good solvent for which of the following types of compounds?
a. ionic compounds c. both a and b
b. polar compounds d. neither a nor b
28. Water is generally a good solvent for which of the following types of compounds?
a. nonpolar compounds c. both a and b
b. polar compounds d. neither a nor b
29. Which of the following is true regarding the solubility of liquids and solids?
a. Solubility always decreases as temperature increases.
b. Solubility always increases as temperature increases.
c. Solubility usually decreases as temperature increases.
d. Solubility usually increases as temperature increases.
30. Which of the following is true regarding the solubility of gases in liquids?
a. Solubility decreases as temperature increases.
b. Solubility increases as temperature increases.
c. Solubility is unaffected by changes in temperature.
31. Which of the following is true regarding the solubility of liquids and solids?
a. Pressure has virtually no effect on the solubility of liquids or solids.
b. Solubility always decreases as pressure decreases.
c. Solubility always increases as pressure decreases.
d. Solubility usually decreases as pressure decreases.
32. Which of the following is true regarding the solubility of gases?

a. Solubility always decreases as pressure increases.
b. Solubility always increases as pressure increases.
c. Solubility usually decreases as pressure increases.
d. Solubility usually increases as pressure increases.
33. Which of the following laws describes the relationship between pressure and the solubility of gases?
a. Avogadro’s c. Dalton’s
b. Boyle’s d. Henry’s
34. Appreciable amounts of sugar can be dissolved in which of the following solvents?
a. benzene (C6H6) c. both a and b
b. water d. neither a nor b
35. Appreciable amounts of solid iodine, I2, can be dissolved in which of the following solvents?
a. benzene c. both a and b
b. water d. neither a nor b
36. Water is likely to be a poor solvent for which types of molecules?

a. molecules which can form hydrogen bonds
b. nonpolar molecules
c. polar molecules
d. None, water is considered a universal solvent.
37. Thermal pollution generally means refers to which of the following?

a. the decrease in the O2 content of warm water as compared to cold water
b. the increase in the O2 content of cold water as compared to warm water
c. both a and b
d. neither a nor b
38. Which of the following gases is associated with the bends?

a. CO2 c. N2
b. NO2 d. O2
39. Which of the following terms can be used to quantitatively describe the concentration of a solution?
a. concentrated c. molarity
b. dilute d. all of these
ANS: C PTS: 1
TOP: 6.5 - WHAT ARE THE MOST COMMON UNITS FOR CONCENTRATION?
40. Suppose you prepare a solution by mixing a known volume of ethanol (density = 0.789 g/mL) with a
known volume of water (density = 1.00 g/mL). Which of the following can be determined from the
information given?
a. %(w/w) c. Both a and b can be determined.
b. %(w/v) d. Neither a nor b can be determined.
ANS: A PTS: 1
41. A salt water solution is 3.0% (w/w). How much salt is there in a sample which weighs 250 grams?
a. 1.2 grams c. 3.0 grams
b. 1.5 grams d. 7.5 grams
ANS: D PTS: 1
42. What is the mass of salt in a 400.-gram sample of salt water which is 1.50% (w/w)?
a. 1.50 grams c. 3.00 grams
b. 2.67 grams d. 6.00 grams
ANS: D PTS: 1
43. What is the %(w/w) of a salt solution prepared by dissolving 7.5 g of salt in 242.5 g of water?
a. 0.030% c. 0.75%
b. 0.30% d. 3.0%
ANS: D PTS: 1
44. A glycine solution is 2.50%(w/w). How much glycine is there in a sample which has a mass of 250.
g?
a. 1.25 g c. 6.25 g
b. 5.00 g d. 12.5 g
ANS: C PTS: 1
45. What is the mass of glycine in a 400.-g sample of a solution which is 2.5%(w/w)?
a. 1.0 g c. 10. g
b. 2.5 g d. 25 g
ANS: C PTS: 1
46. What is the %(w/w) of a salt solution prepared by dissolving 35.0 g of NaCl in 115 g of water?
a. 2.33% c. 23.3%
b. 3.04% d. 30.4%
ANS: C PTS: 1
47. If a solution is prepared by dissolving 7.7 g of lithium iodide, LiI, in enough water to make 400. mL of
solution, what is the %(w/v) of LiI?
a. 0.96% c. 3.9%
b. 1.9% d. 7.7%
ANS: B PTS: 1
48. Saline solutions (NaCl in water) used to deliver intravenous drugs are 0.89%(w/v). What mass of
NaCl is found in 500. mL of such a solution?
a. 0.45 g c. 4.5 g
b. 0.89 g d. 8.9 g
ANS: C PTS: 1
49. The label on a 750 mL bottle of wine states that its alcohol content is 12%(v/v). What volume alcohol
is present in the bottle?
a. 9.0 mL c. 120 mL
b. 90. mL d. 180 mL
ANS: B PTS: 1
50. A 750 mL bottle of vodka is labeled as 60.0 proof. What is its alcohol content?
a. 113 mL c. 450. mL
b. 225 mL d. 600. mL
ANS: B PTS: 1
51. A bottle of vodka is labeled as 60. proof. What is its alcohol content expressed as (v/v)%?
a. 7.5% c. 30.%
b. 15% d. 60.%
ANS: C PTS: 1
52. Which of the following is the definition of molarity?

a. moles of solute/1000 grams of solvent
b. moles of solute/liter of solution
c. moles of solute/liter of solvent
d. moles of solvent/1000 grams of solute
ANS: B PTS: 1
53. If we know the solute and the molarity of a solution which other concentration unit can we readily
determine without any other measurements?
a. %(w/w) c. %(v/v)
b. %(w/v) d. all of these
ANS: B PTS: 1
54. Even if we know the solute, molarity and density of a solution, which of the following concentration
units cannot be readily determined without any other measurements?
a. %(w/w) c. %(v/v)
b. %(w/v) d. all of these
ANS: C PTS: 1
55. Which piece of glassware do we need to accurately measure the total volume of a solution of a specific
molarity?
a. a graduated cylinder
b. a volumetric flask
c. a volumetric pipet
d. Any of these would be appropriate.
ANS: B PTS: 1
56. Which laboratory equipment is needed to prepare solutions of known %(w/v)?

a. a balance c. both a and b
b. a volumetric flask d. Neither a nor b
ANS: C PTS: 1
57. Which laboratory equipment is needed to prepare solutions of known %(w/w)?

a. a balance c. both a and b
b. a volumetric flask d. neither a nor b
ANS: A PTS: 1
58. Which laboratory equipment is needed to prepare solutions of known %(v/v)?

a. a graduated cylinder c. both a and b
b. a volumetric flask d. neither a nor b
ANS: C PTS: 1
59. Which of the following concentration units will not change if the solution is heated?
a. %(w/w) c. both . and b
b. %(w/v) d. neither a nor b
ANS: A PTS: 1
60. Which of the following concentration units will not change if the solution is heated?
a. molarity c. both a and b
b. %(w/v) d. neither a nor b
ANS: D PTS: 1
61. A typical sample of brass is 67% (w/w) copper and 33% (w/w) zinc. How many moles of zinc are
dissolved in 67 grams of copper?
a. 0.33 mol c. 0.67 mol
b. 0.50 mol d. 1.0 mol
ANS: B PTS: 1
62. A typical sample of brass is 67% (w/w) copper and 33% (w/w) zinc, and has a density of 8.40 g/mL.
What is the molarity of this solution?
a. 33 M c. 88 M
b. 42 M d. 67 M
ANS: B PTS: 1
63. If we wish to prepare 250. mL of 0.200 M BaCl2, how much solid is BaCl2 is needed?
a. 4.17 g c. 10.4 g
b. 5.21 g d. 20.8 g
ANS: C PTS: 1
64. If we wish to prepare a 0.50 M solution of NaCl, how much water must be added to 1.0 mole of NaCl?
a. 2.0 mol
b. 2.0 L
c. 2.0  103 g
d. Enough water to make 2.0 L of solution.
ANS: D PTS: 1
65. A solution is prepared by dissolving 3.50 grams of NH4Cl in enough water to make 250. mL of
solution. What is the concentration of this solution?
a. 0.0327 M c. 0.131 M
b. 0.0654 M d. 0.262 M
ANS: D PTS: 1
66. A solution is prepared by dissolving 4.40 g of KSCN in enough water to make 340. mL of solution.
What is the concentration of the solution?
a. 0.0440 M c. 0.119 M
b. 0.0543 M d. 0.133 M
ANS: D PTS: 1
67. What is the mass of NaCl in a 0.500 L bottle of 2.00 M NaCl?

a. 29.3 g c. 117 g
b. 58.5 g d. 234 g
ANS: B PTS: 1
68. What is the mass of BaCl2 in a 0.250 L bottle of 0.200 M BaCl2?

a. 5.21 g c. 41.7 g
b. 10.4 g d. 52.1 g
ANS: B PTS: 1
69. A certain wine contains 0.0100 M NaHSO3 as a preservative. What mass of NaHSO3 is in a 750 mL
bottle of this wine?
a. 0.39 g c. 0.78 g
b. 0.70 g d. 1.5 g
ANS: C PTS: 1
70. Which must we do when preparing a solution of specific molarity?

a. Carefully weigh the solute, carefully weigh the solvent.
b. Carefully weigh the solute, carefully measure the volume of solvent.
c. Carefully weigh the solute, fill the volumetric flask to the mark.
d. None of the above is the correct procedure.
ANS: C PTS: 1
71. How many moles of solute are contained in 500. mL of 0.50 M KCl?
a. 0.25 c. 1.0
b. 0.50 d. 2.0
ANS: A PTS: 1
72. A solution of iodine in carbon tetrachloride is 0.100 M. How much carbon tetrachloride must be
added to 50.0 mL of this solution to reduce the concentration to 0.0250 M? [Assume volumes are
additive.]
a. 50.0 mL c. 150. mL
b. 100. mL d. 200. mL
ANS: C PTS: 1
73. A solution of acetic acid is labeled 15%(w/v). How much water must be added to 30. mL of this
solution to reduce the concentration to 5.0%(w/v)? [Assume volumes are additive.]
a. 30. mL c. 90. mL
b. 60. mL d. 120 mL
ANS: B PTS: 1
74. A saline solution is 5.00%(w/v). How much water must be added to 50.0 mL this solution to reduce
the concentration of the solution to 1.0%(w/v)? [Assume volumes are additive.]
a. 50.0 mL c. 200. mL
b. 100. mL d. 250. mL
ANS: C PTS: 1
75. What volume of 12.0 M HCl must be used to make 300. mL of 0.600 M HCl?
a. 1.50 mL c. 15.0 mL
b. 2.40 mL d. 24.0 mL
ANS: C PTS: 1
76. Assuming that the volumes are additive, what volume of water must be added to 35.0 mL of 12.0 M
HCl to make a solution which is 3.00 M?
a. 70.0 mL c. 105 mL
b. 87.5 mL d. 140 mL
ANS: C PTS: 1
77. A stockroom attendant has a 15.0%(w/v) solution of KOH. What volume of this solution should she
use if she needs to prepare 20.0 mL of a 10.0%(w/v) solution?
a. 6.67 mL c. 13.3 mL
b. 7.50 mL d. 15.0 mL
ANS: C PTS: 1
78. Assuming that the volumes are additive, what volume of water must be added to 35.0 mL of
15.0%(w/v) KOH to make a solution which is 10.0%(w/v)?
a. 15.0 mL c. 23.3 mL
b. 17.5 mL d. 52.5 mL
ANS: B PTS: 1
79. A solution of NaCl has a sodium ion concentration of 150. ppm. What is the chloride ion
concentration in this solution?
a. 97.0 ppm c. 232 ppm
b. 150. ppm d. 300. ppm
ANS: C PTS: 1
80. A solution of NaCl has a chloride ion concentration of 150. ppm. What is the sodium ion
concentration in this solution?
a. 97.0 ppm c. 232 ppm
b. 150. ppm d. 300. ppm
ANS: A PTS: 1
81. A solution has a concentration of 15 ppm. Which of the following is another way to describe the
concentration of this solution?
a. 0.015 ppb c. 1500 ppb
b. 0.15 ppb d. 15000 ppb
ANS: D PTS: 1
82. The unit 1 ppm is equivalent to which of the following?

a. 1000 ppb c. both a and b
b. 0.0001% d. neither a nor b
ANS: C PTS: 1
83. Which of these properties of water is one which makes it such a good solvent?
a. its boiling point c. its high surface tension
b. its high specific heat d. its hydrogen bonding ability
ANS: D PTS: 1
TOP: 6.6 - WHY IS WATER SUCH A GOOD SOLVENT?
84. The term water of hydration is applied to which to which of the following?
a. water molecules required to dissolve a solid
b. water molecules associated with ions in solution
c. water molecules associated with a salt in the solid state
d. none of the above
ANS: C PTS: 1
85. Which of the following is true of the formula weights of a material which exists in both anhydrous and
hydrated forms?
a. They have the same formula weight.
b. The hydrated form always has a lower formula weight.
c. The hydrated form always has a higher formula weight.
d. We cannot make any general statement about the formula weights of the two forms.
ANS: C PTS: 1
86. What is the molar mass of CuSO4·5H2O?

a. 90.0 g/mol c. 159.6 g/mol
b. 177.6 g/mol d. 249.6 g/mol
ANS: D PTS: 1
87. Which of the following is associated with gout?

a. anhydrous calcium sulfate c. calcium sulfate dihydrate
b. anhydrous sodium urate d. sodium urate monohydrate
ANS: D PTS: 1
88. Which of the following is a description of an anhydrous salt?

a. a salt which is insoluble in water
b. a salt which is soluble in water
c. a salt with no water incorporated in its crystal structure
d. a salt with water incorporated in its crystal structure
ANS: C PTS: 1
89. Which of the following is a description of a hydrated salt?

a. a salt which is insoluble in water
b. a salt which is soluble in water
c. a salt with no water incorporated in its crystal structure
d. a salt with water incorporated in its crystal structure
ANS: D PTS: 1
90. Which of the following is true of a solid which is hygroscopic?

a. It will gain weight when exposed to a damp environment.
b. It may change its color upon being exposed to a damp environment.
c. both a and b
d. neither a nor b
ANS: C PTS: 1
91. Which of the following is true of electrolytes?

a. All electrolytes have mobile ions.
b. All electrolytes contain equal numbers of cations and anions.
c. both a and b
d. neither a nor b
ANS: A PTS: 1

a. All electrolytes have water as a solvent.
b. All electrolytes contain equal numbers of cations and anions.
c. both a and b
d. neither a nor b
ANS: D PTS: 1

a. All electrolytes have water as a solvent.
b. All electrolytes contain cations and anions.
c. both a and b
d. neither a nor b
ANS: B PTS: 1
94. Which of the following happens when NaCl dissolves in water?

a. The chloride ions are attracted to the negative end of the water dipole.
b. Sodium and chloride ions form covalent bonds with water molecules.
c. The sodium ions are attracted to the negative end of the water dipole.
d. The sodium ions are attracted to the positive end of the water dipole.
ANS: C PTS: 1
95. Which of the following is relates the name of an electrode to its sign?
a. The anode is the positive electrode.
b. The cathode is the negative electrode.
c. both a and b
d. neither a nor b
ANS: C PTS: 1
96. Which of the following relates the name of an electrode to its sign?
a. The anode is the negative electrode.
b. The cathode is the positive electrode.
c. both a and b
d. neither a nor b
ANS: D PTS: 1
- -
97. Of the ions Cl , Na+, NH4+ and NO3 , which will move towards the anode?
a. only chloride ions
b. only sodium ions
c. both chloride ions and nitrate ions
d. both the sodium ion and ammonium ions
ANS: C PTS: 1
- -
98. Of the ions Cl , Na+, NH4+ and NO3 , which will move towards the cathode?
a. only chloride ions
b. only sodium ions
c. both chloride ions and nitrate ions
d. both the sodium ion and ammonium ions
ANS: D PTS: 1
99. Which of the following is true of all strong electrolytes?

a. They are all ionic compounds. c. both a and b
b. They all dissociate completely. d. neither a nor b
ANS: C PTS: 1
100. Which of the following is a weak electrolyte?

a. HCl c. both a and b
b. CH3COOH d. neither of them
ANS: B PTS: 1
101. Which of the following is a weak electrolyte?

a. CO2 c. both a and b
b. CH3COOH d. neither of them
ANS: C PTS: 1
102. Which of the following solutions will have the higher electrical conductivity?
a. 0.1 M NaCl c. Both a and b have the same conductivity.
b. 0.2 M NaCl d. Neither conducts electricity.
ANS: B PTS: 1
103. Which of the following solutions will have the highest electrical conductivity?
a. 0.1 M NaCl c. 0.1 M AlCl3
b. 0.1 M BaCl2 d. All have the same conductivity.
ANS: C PTS: 1
104. Which of the following solutions will have the highest electrical conductivity?
a. 0.1 M Na3PO4 c. 0.1 M NaH2PO4
b. 0.1 M Na2HPO4 d. All have the same conductivity.
ANS: A PTS: 1
105. Which of the following will have the highest electrical conductivity?
a. 0.1 M NaCl c. 0.3 M CH3COOH
b. 0.2 M NaCl d. 0.4 M CH3COOH
ANS: B PTS: 1
106. Which of the following will have the highest electrical conductivity?
a. 0.1 M NaCl c. 0.3 M NaC2H3O2
b. 0.2 M NaCl d. 0.4 M NaC2H3O2
ANS: D PTS: 1
107. Which of the following is true when HCl(g) dissolves in water?

a. The HCl(g) reacts with the water. c. both a and b
b. The solution is a strong electrolyte. d. neither a nor b
ANS: C PTS: 1
108. Which of the following is true of glucose, C6H12O6, when it dissolves in water?
a. It dissociates into ions.
b. It forms covalent bonds with water.
c. It forms hydrogen bonds with water.
d. None of the above, glucose does not dissolve in water.
ANS: C PTS: 1
109. Which of the following is true of methanol, CH3OH, when it dissolves in water?
a. It dissociates into ions.
b. It forms covalent bonds with water.
c. It forms hydrogen bonds with water.
d. None of the above, methanol does not dissolve in water.
ANS: C PTS: 1
110. Assuming that the solvent is the same in all cases, which of the following has the largest particles?
a. a colloid c. a solution
b. a suspension d. the pure solvent
ANS: B PTS: 1 TOP: 6.7 - WHAT ARE COLLOIDS?
111. What is the maximum diameter of solute particles in a true solution?

a. 1 pm c. 1 ìm
b. 1 nm d. 1 mm
112. How big is 1 nm?

a. 1  10–12 m c. 1  10–6 m
b. 1  10–9 m d. 1  10–3 m
113. Which of the following is associated with colloidal particles?
a. They are smaller than 1 nm. c. both a and b
b. They scatter light. d. neither a nor b
114. Which of the following is an example of a colloid in which a gas is dispersed in a liquid?
a. butter c. mayonnaise
b. marshmallows d. whipped cream
ANS: D PTS: 1 TOP: 6.7 - WHAT ARE COLLOIDS?
115. Which of the following is an example of a colloid in which a liquid is dispersed in a liquid?
a. butter c. mayonnaise
b. marshmallows d. whipped cream
ANS: A PTS: 1 TOP: 6.7 - WHAT ARE COLLOIDS?
116. The Tyndall effect is associated with which of the following?

a. keeping colloidal particles from settling
b. light scattering by colloidal particles
c. both a and b
d. neither a nor b
117. Which of the following factors cause colloidal particles to remain in solution without settling?
a. Colloidal particles are of the same size of solvent molecules.
b. Colloidal particles have large solvation layers.
c. both a and b
d. neither a nor b
118. Which of the following factors cause colloidal particles to remain in solution without settling?
a. Colloidal particles acquire a charge on their large surface areas.
b. Colloidal particles have large solvation layers.
c. both a and b
d. neither a nor b
ANS: C PTS: 1 TOP: 6.7 - WHAT ARE COLLOIDS?
119. Which of the following techniques can be used to decrease the stability of an aqueous colloidal
dispersion?
a. addition of a material which has great affinity for water
b. addition of an electrolyte
c. both a and b
d. neither a nor b
ANS: C PTS: 1 TOP: 6.7 - WHAT ARE COLLOIDS?
120. Which of the following techniques can be used to decrease the stability of an aqueous colloidal
dispersion?
a. addition of an electrolyte
b. dilution of the system by addition of water
c. both a and b
d. neither a nor b
ANS: A PTS: 1 TOP: 6.7 - WHAT ARE COLLOIDS?
121. Which of the following will have the lowest freezing point?
b. 0.1 M BaCl2 d. All have the same freezing point.
ANS: C PTS: 1 TOP: 6.8 - WHAT IS A COLLIGATIVE PROPERTY?
a. 0.1 M ethylene glycol, C2H6O2 c. 0.1 M sucrose, C12H22O11
b. 0.1 M glucose, C6H12O6 d. All have the same freezing point.
ANS: D PTS: 1 TOP: 6.8 - WHAT IS A COLLIGATIVE PROPERTY?
a. 0.1 M acetic acid, HC2H3O2 c. 0.1 M hydrofluoric acid, HF
b. 0.1 M hydrochloric acid, HCl d. All have the same freezing point.
ANS: B PTS: 1 TOP: 6.8 - WHAT IS A COLLIGATIVE PROPERTY?
124. Given three solutions, each of which contains 1.0 g of solute dissolved in 100 mL of water, which of
the following solutes will cause the solution to have the lowest freezing point?
a. ribose, C5H10O5 c. sucrose, C12H22O11
b. glucose, C6H12O6 d. All have the same freezing point.
ANS: A PTS: 1 TOP: 6.8 - WHAT IS A COLLIGATIVE PROPERTY?
125. A solution is prepared by dissolving 215 grams of methanol, CH3OH, in 1000. grams of water. What
is the freezing point of this solution? [The freezing point depression constant for water is 1.86°C/mole
solute in 1000g of water]
a. –6.72°C c. –25.0°C
b. –12.5°C d. -40.3°C
126. A solution is prepared by dissolving 53.5 grams of ammonium chloride, NH4Cl in 4000. grams of
water? What is the freezing point of this solution? [The freezing point depression constant for water
is 1.86°C/mole solute in 1000g of water]
a. –0.37°C c. –0.93°C
b. –0.47°C d. –1.86°C
127. A solution is prepared by dissolving 104.1 grams of barium chloride, BaCl2 in 1000. grams of water?
What is the freezing point of this solution? [The freezing point depression constant for water is
1.86°C/mole solute in 1000g of water]
a. –1.86°C c. –3.72°C
b. –2.79°C d. –5.58°C
128. A solution is prepared by dissolving 215 grams of methanol, CH3OH, in 1000. grams of water. What
is the boiling point of this solution? [The boiling point elevation constant for water is 0.52°C/mole
solute in 1000 g of water]
a. 93.0°C c. 103.5°C
b. 96.5°C d. 107.0°C
129. A solution is prepared by dissolving 53.5 grams of ammonium chloride, NH4Cl in 4000. grams of
water? What is the boiling point of this solution? [The boiling point elevation constant for water is
a. 100.13°C c. 100.39°C
b. 100.26°C d. 100.52°C
130. A solution is prepared by dissolving 104.1 grams of barium chloride, BaCl2 in 1000. grams of water?
What is the boiling point of this solution? [The boiling point elevation constant for water is
a. 100.26°C c. 100.78°C
b. 100.52°C d. 101.04°C
131. Which of the following solutions has the highest osmolarity?

b. 0.1 M BaCl2 d. All have the same osmolarity.
132. Which of the following solutions has the highest osmolarity?

b. 0.15 M BaCl2 d. All have the same osmolarity.
133. What is the osmolarity of a 3.3%(w/v) Na3PO4 solution?

a. 0.20 osmolar c. 0.80 osmolar
b. 0.40 osmolar d. 1.6 osmolar
134. Given three solutions, each of which contains 1.0 g of solute dissolved in 100 mL of water, which of
the following solutes will cause the solution to have the highest osmolarity?
a. ribose, C5H10O5
b. glucose, C6H12O6
c. sucrose, C12H22O11
d. None, they all have the same osmolarity.
135. Which of the following aqueous solutions will have the highest osmolarity?
a. 0.1 M ethylene glycol, C2H6O2 c. 0.1 M sucrose, C12H22O11
b. 0.1 M glucose, C6H12O6 d. All have the same osmolarity.
136. Which of the following is associated with cells in a hypertonic solution?

a. crenation c. reverse osmosis
b. hemolysis d. none of these
137. Which of the following is associated with cells in a hypotonic solution?

138. Which of the following is associated with cells in an isotonic solution?

139. Which of the following is associated with the desalinization of water?

140. Which of the following solutions is isotonic with a 0.15 M NaCl solution?
a. 0.15 M glucose, C6H12O6 c. 0.10 M aluminum chloride, AlCl3
b. 0.30 M glucose, C6H12O6 d. none of these
141. Which of the following solutions of glucose is isotonic with a 0.15 M NaCl solution?
a. 0.15% c. 1.5%
b. 0.55% d. 5.5%
142. Which of the following aqueous solutions of Na2SO4 is isotonic with a 0.15 M NaCl solution?
a. 0.05 M c. 0.15 M
b. 0.10 M d. none of these
143. Which of the following aqueous solutions of Na2SO4 is hypotonic with respect to a 0.15 M NaCl
solution?
a. 0.05 M c. 0.15 M
144. Which of the following aqueous solutions of Na2SO4 is hypertonic with respect to a 0.15 M NaCl
solution?
a. 0.05 M c. 0.15 M
145. Isotonic saline is 0.89% NaCl (w/v). Suppose you wanted to make 1.0 L of isotonic solution of KCl.
What mass of KCl would you need?
a. 8.9 g c. 23 g
b. 11 g d. 75 g
146. Isotonic saline is 0.89% NaCl (w/v). Suppose you wanted to make 1.0 L of isotonic solution of
NH4Cl. What mass of NH4Cl would you need?
a. 1.6 g c. 8.9 g
b. 8.1 g d. 54 g
147. Which of the following is true when comparing a dialysis membrane with an osmotic semipermeable
membrane?
a. Both membranes allow solute particles to pass through.
b. The osmotic membrane has larger openings.
c. both a and b
d. neither a nor b
148. Which of the following is true when comparing a dialysis membrane with an osmotic semipermeable
membrane?
a. Both membranes allow solvent particles to pass through.
b. The osmotic membrane has larger openings.
c. both a and b
d. neither a nor b
149. Which of the following can pass through a dialysis membrane?

a. colloidal particles c. small molecules
b. macromolecules d. all of them
150. Which of the following can pass through a dialysis membrane?

a. colloidal particles c. small molecules
b. macromolecules d. none of them
151. In reverse the osmosis of sea water to produce drinking water approximately what is the typical
residual concentration of salt in the drinking water which is produced?
a. 0 c. 400 ppm
b. 40 ppm d. 4000 ppm
152. In hemodialysis the osmotic pressure of the dialysis solution is adjusted to prevent the loss of which of
the following from blood?
a. Na+ c. both a and b
b. glucose d. neither a nor b
Consider the following image of a separatory funnel.

153. Which of the following correctly describes the contents of the funnel?
a. The two liquids are insoluble in each other.
b. The two liquids are miscible.
c. The mixture is homogeneous.
d. All of these are correct.
154. Which of the following correctly describes the contents of the funnel?
a. Both liquids are nonpolar.
b. Both liquids are polar.
c. One liquid is polar and the other nonpolar.
d. Impossible to determine polarity from the data given.
155. If the liquid on the bottom is water, what might be the identity of the liquid on the top?
a. C5H12 only
b. CH3OH only
c. C6H6 only
d. a or c
e. a, b or c
Consider the following graph.

156. Approximately what mass of A will dissolve in 100 mL of water at 75 °C?
a. 25 g c. 55 g
b. 40 g d. 70 g
157. Which substance is the most soluble in 100 mL of water at 10 °C?

a. A
b. B
c. C
158. Which substance is the most soluble in 100 mL of water at 80 °C?

a. A
b. B
c. C
159. Which substance exhibits solubility behavior that is similar to that of a gas?
a. A
b. B
c. C
d. None of the substances listed show this behavior.
The following shows the beginning of the laboratory preparation of a aqueous solution of the
hypothetical compound AB (150.5 g/mol).
160. Which letter indicates the solute?
a. A
b. B
c. C
ANS: C PTS: 1
161. Which letter indicates the solvent?

a. A
b. B
c. C
ANS: B PTS: 1
162. What will be the molarity of the solution when the preparation is complete?
a. 51.0 M c. 0.339 M
b. 0.00510 M d. 0.00339 M
ANS: C PTS: 1
163. If the volume of the volumetric flask had been 500. mL instead of 100. mL and the amount of AB had
be 25.5 g, how would the molarity of the resulting have been affected?
a. increased by a factor of 5
b. reduced by a factor of 5
c. increased by a factor of 10
d. decreased by a factor of 10
e. It would be unchanged.
ANS: E PTS: 1
164. When the solution is prepared which of the following correctly describes this process?
a. 5.10 g of AB is dissolved in 100.0 mL of water and the solution is thoroughly mixed.
b. 5.10 g of AB is dissolved in water and enough water is added to produce 100.0 mL of
solution.
c. 5.10 g of AB is dissolved in 94.90 mL of water and the solution is thoroughly mixed.
d. 5.10 g of AB is dissolved in water and enough water is added to product 105.0 mL of
solution.
ANS: B PTS: 1

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CHAPTER 6 — SOLUTIONS AND COLLOIDS

1. The term solution is synonymous with which of the following?

2. Which of the following is a solution?

3. Which of the following is intermediate between homogenous and heterogeneous mixtures?

4. Which of the following cannot serve as a solvent in a solution?

5. Which of the following cannot serve as a solute in a solution?

6. The term alloy is applied to which of the following solvent/solute combinations?

7. Which of the following combinations will always result in a solution?

8. In a solution of a gas in a liquid, the gas is called which of the following?

9. In a solution of a solid in a liquid, the liquid is called which of the following?

11. When alcohol is dissolved in water which is the solute?

16. Rainwater is naturally slightly acidic. Which gas causes this?

32. Which of the following is true regarding the solubility of gases?

36. Water is likely to be a poor solvent for which types of molecules?

37. Thermal pollution generally means refers to which of the following?

38. Which of the following gases is associated with the bends?

52. Which of the following is the definition of molarity?

56. Which laboratory equipment is needed to prepare solutions of known %(w/v)?

57. Which laboratory equipment is needed to prepare solutions of known %(w/w)?

58. Which laboratory equipment is needed to prepare solutions of known %(v/v)?

67. What is the mass of NaCl in a 0.500 L bottle of 2.00 M NaCl?

68. What is the mass of BaCl2 in a 0.250 L bottle of 0.200 M BaCl2?

70. Which must we do when preparing a solution of specific molarity?

82. The unit 1 ppm is equivalent to which of the following?

86. What is the molar mass of CuSO4·5H2O?

87. Which of the following is associated with gout?

88. Which of the following is a description of an anhydrous salt?

89. Which of the following is a description of a hydrated salt?

90. Which of the following is true of a solid which is hygroscopic?

91. Which of the following is true of electrolytes?

92. Which of the following is true of electrolytes?

93. Which of the following is true of electrolytes?

94. Which of the following happens when NaCl dissolves in water?

99. Which of the following is true of all strong electrolytes?

100. Which of the following is a weak electrolyte?

101. Which of the following is a weak electrolyte?

107. Which of the following is true when HCl(g) dissolves in water?

111. What is the maximum diameter of solute particles in a true solution?

112. How big is 1 nm?

116. The Tyndall effect is associated with which of the following?

131. Which of the following solutions has the highest osmolarity?

132. Which of the following solutions has the highest osmolarity?

133. What is the osmolarity of a 3.3%(w/v) Na3PO4 solution?

136. Which of the following is associated with cells in a hypertonic solution?

137. Which of the following is associated with cells in a hypotonic solution?

138. Which of the following is associated with cells in an isotonic solution?

139. Which of the following is associated with the desalinization of water?

149. Which of the following can pass through a dialysis membrane?

150. Which of the following can pass through a dialysis membrane?

Consider the following image of a separatory funnel.

Consider the following graph.

157. Which substance is the most soluble in 100 mL of water at 10 °C?

158. Which substance is the most soluble in 100 mL of water at 80 °C?

161. Which letter indicates the solvent?

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