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    D and F, Coordination

    Uploaded by

    V Sachin

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    © All Rights Reserved
    Download as PDF or read online from Scribd
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    26, The number of P-O-P and P-O-H bonds present respectively in pyrophosporic acid molecule 12 2)2,2 31,4 41,8 27, Pa + NaOH + H:0 + x + y the sum of total P- H bonds in x & y? 13 24 325 42 28, What are A and B in the reactions in respective order. Pa (white) 2 5A; Py (white) 5B. 1) PCls, PCls 2) PCls, PCls 3) PCls, PCls * 4) PCls, PCls 20 2. Statement-I_: Phosphinic acid has more reducing behavior than phosphonic acid ‘Statement-II : Phosphinic acid has two P- H bonds where as phosphonic acid has one P - H bond 1) Tis true and Il is false 2) Lis false and II is true 3) Both I and II are true 4) Both I and Il are false Dinitrogen tetraoxide (Nz04) is a mixed anhydride because it 1) is a mixture of NO; and NOs 2) decomposes into two oxides of nitrogen 3) reacts with water to form nitric acid 4) reacts with water to form two acids Choose the correct answer 4. The ion having most stable configuration Cray 2) CP) 3) Cray) 4) Crag) 2. Pick out the wrong statement 1) Mercury can be stored in iron containers 2) When a silver spoon is kept in a copper ‘sulphate solution, there is no chemical reaction 3) When CuSO, solution is placed in an iron vessel, there is no reaction 4) When ZnSOs is placed in a copper vessel, there is no réaction. 2. Pick out the wrong statement 1) Transition metals show variable oxidation states 2) Transition metals can coordination complexes form several 3) Transition metals always form stoichiometric oxides 4) Transition metals form usually interstitial hydrides Four successive members of first series of transition metals are given below, whose Esq Value has positive sign 1) Fe 2)Co 3)Ni 4cu ‘The principle characteristic of interstitial compounds formed by transition elements is 1) They retain metallic conductivity 2) They are highly reactive 3) They have high melting points, lower than those of pure metals 4) They are very soft 10. 1 2 Which one of the following is the correct increasing order of the magnitude of ionic radii of Ce”, La’, Pm™* and Yb"? 1) Yb" < Pm < La? A + KCI. In this reaction, the wrong statement is 1) KyMnO, acts as an reducing agent 2) Ais a better oxidizing agent than KaMnOs 3) K:MnO, can react with O3 giving A. 4) The oxidation state of Mn in A is lesser than that of Mn in K:MnO4, ‘The number of Cr — Cr bonds and 0 - 0 bonds in Cr0;* is 1)2,1 2)0,0 3)0,1 41,2 Aci Medium >“ KMn0,+KI—J Faintly Alkaline Medium ‘Aand B are respectively 1) KIOs, Ir hb 3) KIOs, KIO 4) la, KIO 1,0} EES CrOF 5 X and Y are respectively 1)2and 10 - 2)8,4 34,8 4) 8,10 21 43, Which of the following is not correct for KxCn 072 1) 6(Cr—) bonds are equivalent 2) Equivalent mass is M/6 in acidic medium 3) Cr O~Crbond angle is more than 100° 4) Its colour is yellow 44, How many mole of K,Cr0r is required to oxidise one mole of ferrous sulphate in acidic medium? 1 1 a yt De a 1 1 i ne DE > 45, Match the following Catalyst Process A)V20s P) Deacon process B)Pt Q) Contact process OFe R) Ostwald process D)Cu 'S) Habers process DAP, B-Q,CR,D-S 2) A-Q, BR, C-S, D-P 3) AR, B-Q, CP, D-S 4) AP, BR, C-S, D-Q ‘The point of dissimilarity between Lanthanides and actinides is 1) They are inner transition elements 2) Three outer most shells are partially filled 3) They show common oxidation state of +3 4) Their radioactive nature Which is correct decreasing order of atomic radii? 1) Ho™ Er* Tm* Yb* 2) Er* Tm" Yb* Ho” 3) Tm™* Yb** Ho” Er” 4) Yb" Ho™* Er’ Tm** La(OH), is more basic than Lu(OH)s because 1) La is more negative than Lu 2) La’ is larger in size than Lu’* 3) ionic character of bond in Lu(OH)s is high 4) all of the above 6. 7. 8. 22 49. Which set does not have pseudo inert gas 1)P-C,Q-A,R-B, S-D configuration 2) P-A, QB, R-C, S-D 1) Pd, Ag* 2) Cd", Zn** 3) P-D, Q-C, R-B, S-A 3) Cu", Fe 4) Au’, Hg” 4)P-B, Q-D, R-D, S-B 20. Which one has the highest negative E°sep . The metal ion which is colourless in aqueous value for its M™"/M? medium is 1)Mn 2)Cr 1) Sc* 2) cr* 3) Ti 4)Cu 3) Fe™* 4) Co** 21. Which one is expected to have highest 3. Which one of the following ions exhibits Tonization energy? colour due to d - d transition and paramagnetism DK 2)Cu as well 3) Ag 4) Au 1) cro 2) Cr.0F 22, Which of the following is incorrect with 3) MnO 4) Mn0; respect to ionisation energies : 1) IE, of Mn > Cr . The nature of Mn,O3, V20s, CrO respectively 2) IE, of Zn> Cu ree ahs 3) IEjof Mn> Fe 1) Acidic, amphoteric, basic 4) IEyof Cr> Ma 2) Acidic, acidic, acidic 23, The principle characteristic of interstitial 2 Busi oo since ‘compounds formed by transition elements is 2) ae — a re eter ey ica ; = . The O.S of Cr in the final product formed by pened Seats meses corset ty reaction between KI and acidified KyCrsOr is 2) They are highly reactive ae aa 3) They have high melting points, but lower a ae than those of pure metals Ne: ‘ ae tle 4) They are very soft va of ts following, fo, ave En mee the ee ; . Dye", cm* 2) Ga", No* cata neta Por pe 3) Eu", Am™* 4) Es, Fm baad el Which of the followis how stabl _ 39 ich of the following pair can show stable a Ss - os a aa 0.8 of +2 and +4 respectively? Li , R)Ni* C)3.87 BM cs a Pe S) Fe** D) 4.89 BM s : Answer Key i 3 2 sr asus 2 16. }7_ | 18 [19 4 eel eal. 2 Choose the correct answer 1 Which of the following complex ions is more likely to be colourless? 1) [Co(H0).}* 2) [Mn(CN)] 3) [CrCl (H20)3] 4) [Ag(NFA)2]" Which one of the following will be able to show geometrical Isomerism? 1) Mayb(square planar) 2) Mazbx( tetrahedral) 3) Magbe (Tetrahedral) 4) Mabed (Square planar) Which statement is not correct in the case of ~ [Co(NHs)é}** complex? 1) Itis octahedral in shape 2) It involves dsp?-hybridization 3) Ithas diamagnetic nature 4) Cois in +3 oxidation state Crystal field stabilization energy for high spin d octahedral complex is 1)-1.8A. 2)-1.24,+P 3) -1.2A, 4) 0.6. Which of the following complex ions is expected to absorb visible light? 1) (Zn(NH3)6* 2) [Se(H20)s(NHs)3)* 3) [Tifen)s(NHs)2]" 4) [Cr(NH3)6)"" ‘The complex used as an anticancer agent is 1) Mer - [Co(NHs)3Chs} 2) Cis - [PtCl(NHs)2] 3) Cis - Ka[PtCBr] 4) Nax[CoCls] Considering HO as a weak field ligand the number of unpaired electrons in [Mn(H:O)4]"* can be (atomic number of Mn =25) 1) Three 2) Five 3) Two 4) Four Write the structural formula for aqua-bromo- bis (ethylenediamine) chromium (IID) chloride 1) [CrBr(H20) (en)]Cl 2) [CrBrx(H20) (en) |Ch 3) [CrBr(H:0) (en):]Ch 4) [CrBr(H20) (en):]Chs 10 1. 2. a. 4 4. 16. Which of the following divalent metal ion form the most stable complexes? 1) Mn" 2) Fe 3) Ni 4) Cu If excess of AgNOs solution is added to 100 ml of 0.024 M_ solution of dichlorobis (ethylene diamine) cobalt (III) chloride, how many moles of AgCI will be precipitated? 1) 0.0012 20.0016 3) 0.0024 4) 0.0048 Which of the given metal ion form high tendency to complex with CO? 1) Sc ari? 3) Mn"? 4) Fe? ‘The IUPAC name of [Ni(NH3)s][NiCla] is 1) Tetrachloronickel(I1)-tetraamminenickel(11) 2) Tetraamminenickel(I1)-tetrachloronickel(I1) 3) Tetraamminenickel(II)-tetrachloronickelate(II) 4) Tetrachloronickel(II)-tetraamminenickelate(0) Among the following metal carbonyls, the C- (O bond order is lowest in 1) [Mn(CO)J" 2) [Fe(CO)s] 3) [Cx(CO)e] 4) [V(CO)s ‘Among the following, the coloured compound is ycuct 2) Ks[Cu(CN)s] 3) CuF, 4) [Cu(CH3CN),]BFs Geometrical shapes of the complexes formed by the reaction of Ni’* with CI, CN” and H20, respectively are 1) Octahedral, tetrahedral and square planar 2) Tetrahedral, square planar and octahedral 3) Square planar, tetrahedral and octahedral 4) Octahedral, square planar and octahedral Crystal field stabilization energy for high spin a octahedral complex is 1)-0.6 Ao 2)-1.8 do 3)-1.6 Ao +P 4)-1.2 Bo 7. 8. 19. a. 23, ‘The CFSE for octahedral [CoCle]* is 18000 em". ‘The CFSE for tetrahedral [CoCl4}* will be 1) 18,000 cm 2) 16,000 cm” 3) 8,000 cm 4) 20,000 cm Which of the following compound show both linkage & ionisation isomerism? 1) {Co(NHs)sNO;] NO 2) [Co(NO2\(Py)> (NHs)2]NOx 3) [Co(NH3).]Ch 4) [Co(NO;)Br(NH;),JCI ‘Number of possible isomers for the complex [Co(en),C1,]C! will be: (en = ethylenediamine) 13 24 3)2 4yi ‘Which of the following complex is most stable among the following :- 1) Nas[Fe(C,0,)s] 2) [Cu(NHs)4]* 3) (Cr (NH)JChs 4) Nas[CoF] How many EDTA (ethylenediaminetetraacetic acid) molecules are required to make an octahedral complex with a Ca* ion? 1) One 2) Two 3) Six 4) Three 2. Which of the following statements is not true about the complex ion [Pt(en),Cla]* ? 1) Ithas two geometrical isomers cis and trans 2) Both the cis and trans isomers display optical activity. 3) Only the cis isomer displays optical activity. 4) Only the cis isomer has non superimposable mirror image The IUPAC name of Ks{Co(C;0,)3} 1) Tripotassium tri(oxalato) cobaltate (III) 2) Potassium tris (oxalato) cobalt (11) 3) Potassium tris (oxalato) cobaltate (Ill) 4) Potassium cobaltotrisoxalate (III) 24 24, In solid CuSO,.5H,O copper is co-ordinated to 1) 4 water molecules 2) 5 water molecules 3) 1 sulphate molecule 4) 1 water molecule ‘The primary valency and secondary valency in [Co(NHs)4 Brz] Cl are respectively 1)42,7 2)42, 6 3)43,7 4) 43,6 26. The incorrect statement regarding Wemers theory is 1) it could explain the number of geometrical isomers 2) it could explain the ionization isomerism 3) it could explain hydrate isomerism 4) it could explain the cause for the colour in the coordination complexes 27. Effective atomic’ number (EAN) for Mn in complex [Mn;(CO)jo] 1)35 2)34 3)37 4) 36 28. Which of the following will exhibit maximum molar conductivity? 1) [Co(NHs)6JCls 2) [Cu(NH).]Ch 3) [Ni(Co), 4) Ka[Fe(CN)«] 29, The inner orbital complex is 1) [Fe (CN)_]* 2) [Fe(H:0)<}* 3) [Co(H:0).}* 4) [Mn (H20)

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