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Journal of Cleaner Production 415 (2023) 137745

Contents lists available at ScienceDirect

Journal of Cleaner Production


journal homepage: www.elsevier.com/locate/jclepro

Assessing the environmental impact of waste management: A comparative


study of CO2 emissions with a focus on recycling and incineration
Marion Christine Unegg a, *, Karl W. Steininger b, Christian Ramsauer a, Mariana Rivera-Aguilar b
a
Institute of Innovation and Industrial Management, Graz University of Technology, Inffeldgasse 11/3, 8010, Graz, Austria
b
Wegener Center for Climate and Global Change, University of Graz, Brandhofgasse 5, 8010, Graz, Austria

A R T I C L E I N F O A B S T R A C T

Handling Editor: Maria Teresa Moreira In waste management, the assessment of CO2 emissions offers the possibility to evaluate and compare the
environmental impact of different waste treatment processes. Here, we compare the performance of waste
Keywords: incineration with alternative thermal treatment scenarios and recycling scenarios to the primary production of
Waste management materials to analyze the respective CO2 emissions. The aim is to determine whether thermal and material
CO2 emissions
recycling of waste results in (net) CO2 surpluses or reductions, thus, showing whether it makes sense for climate
Thermal recovery
ambitions to recover waste, thermally or materially. A case study of an internationally active waste management
Material recovery
Emission reduction company in Austria is analyzed, conducting a life cycle assessment of its thermal and material waste recycling.
On thermal waste treatment the core of the analysis is the comparison with primary energy sources. Using waste
as an energy source, especially in cement plants and the paper industry, has proven to be an effective technology
for reducing CO2 emissions. We also find current practices in material recycling to be of lower CO2 emissions
than alternative primary material supply. Scaling results to the national level we find that for the case of Austria
current waste management practices have the potential to save an equivalent of 2.6% of Austria’s total CO2
emissions (all sectors) for thermal fractions and an equivalent of 1% for material recycling.

1. Introduction either be materially processed and recycled or safely disposed of in


landfills (Federal Ministry of Agriculture, Forestry, Environment and
The Intergovernmental Panel on Climate Change (IPCC) stated in its Water Management, BMLUF, 2009). The substitution for other (fossil)
first Assessment Report, that greenhouse gas (GHG) emissions occur in fuels can reduce system CO2 emissions, but success in this depends on
the waste management sector and thus identified a potential for a pos­ the quantitatively available alternatives it is evaluated against. Another
itive contribution of the sector to greenhouse gas emission mitigation option in waste management is material recycling, and preparing waste
(IPCC, 1990). streams for this purpose. Waste should be materially processed accord­
A reduction of CO2 emissions in waste management is achievable ing to expediency, ecological objectives and best technical possibility. It
either by thermal or material treatment processes. Thermal treatment is is important that the raw materials obtained from waste do not pose a
the process of using waste as a substitute for fossil fuels. By converting higher risk than a comparable primary raw material (Federal Ministry of
waste into refuse-derived-fuel (RDF), higher efficiencies and CO2 emis­ Agriculture, Forestry, Environment and Water Management, BMLUF,
sion reductions can be achieved. In principle, waste incineration works 2009). This will reduce CO2 emissions in primary material supply, with a
under a strong heat emission. Through this, organic materials are net effect subject to evaluation.
transformed into carbon dioxide, CO2, and water vapor by means of Some authors have found thermal treatments for energy recovery to
oxidation of oxygen and are thus released through the chimney of the be the best performing methods to reduce the environmental impact of
respective plant. Waste incineration in some regions of the world is waste management (Herva and Roca, 2013; Cheela et al., 2021; Wang
usually performed just as a means of waste disposal without heat re­ and Nakakubo, 2020; Rajaeifar et al., 2017). Istrate et al. (2020) high­
covery. This leaves a substantial potential unused, as from the inciner­ light uncertainty regarding the impact of incineration on human health
ation electricity and heat can be generated, as common already e.g. in and other authors bring attention to the upstream fossil energy con­
most of Europe. If solid residues remain after incineration, they can sumption which increases the carbon footprint of thermal treatment

* Corresponding author.
E-mail address: marion.unegg@tugraz.at (M.C. Unegg).

https://doi.org/10.1016/j.jclepro.2023.137745
Received 9 December 2022; Received in revised form 22 May 2023; Accepted 6 June 2023
Available online 13 June 2023
0959-6526/© 2023 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

processes (Shadbahr et al., 2022; Pérez et al., 2018). Contrastingly, in the thermal and in the material area of waste recycling, allowed a CO2
Chew et al. (2022) conclude that material treatments would have the emission analysis.
lowest carbon footprint in Malaysia. Finally, a number of authors indi­
cate that an integrated approach combining both thermal and material 2.1. Method for calculating the emission effects of thermal recovery
treatments could lead to the highest reduction potential (Pérez et al., processes
2018; Michel Devadoss et al., 2021; Wang et al., 2020).
Studies aiming to estimate the environmental impact of waste Materials suitable for thermal recovery, which were used for the CO2
management do so at a country level (Chew et al., 2022; Magazzino emission calculations, are described in Table 1.
et al., 2020; Malinauskaite et al., 2017; Michel Devadoss et al., 2021; The respective material inputs for the individual recycling methods
Mühle et al., 2010; Rajaeifar et al., 2017; Shang et al., 2021; Wang and were chosen as the starting points for the calculations. These material
Nakakubo, 2020), city level (Cheela et al., 2021; Herva and Roca, 2013; inputs were assigned an input quantity in tons per year (t/year). Based
Khan et al., 2022; Li et al., 2022; Pérez et al., 2018; Shadbahr et al., on Denner and Kügler (2006),1 the material inputs were assigned a
2022; Wang et al., 2020; Zhou et al., 2015) or global level (Kumar and gigajoule value. CO2 emissions caused by the material input can be
Samadder, 2017). The present research contributes to the body of derived when employing an emission factor, in tons of CO2 per gigajoule
literature by providing a new analytical perspective at a company level (tCO2/GJ) and again depending on the type of the input waste stream.
in the specific context of Austria. The cooperation with a waste man­ The emission factors (EF) were taken from Denner and Kügler (2006)
agement company facilitated access to first-hand material-flow and and Schwarzböck et al. (2016: 415–427). More details to the emission
energy demand data, which allow for more accurate calculations and factors can be found in the Appendix, Section 1. The structure of the
could be useful in setting a benchmark for improved industry standards. thermal recovery method is the same for all three thermal procedures,
The aim of the analysis is to determine whether thermal and material refuse-derived-fuel plants (RDF) waste incineration plants (WIP) and
recycling of waste results in (net) CO2 surpluses or reductions, and thus fluidized bed plants (FBP). The CO2 emissions from the material input
to show whether it makes sense at all for climate ambitions to recover thus are given by
waste, thermally or materially. [ ]
To quantify both potentials, data on thermal and material waste t CO2
CO2 material[t] = GJfactor total [GJ] ∗ EF (1)
treatment was collected from an international waste management en­ GJ
terprise and analyzed to identify the overall potential for CO2 emissions The CO2 amount per ton material input equals the given conversion
reduction of waste management. The waste management industry in factor (GJfactor) times the emission factor (EF) in tons of CO2 per GJ.
Europe today is a highly regulated and relatively advanced sector, which Here a distinction is made between fossil and biogenic CO2 emis­
in recent years has experienced the rise of recycling and Waste-to- sions. Most material streams cause both types of CO2 emissions. The
Energy technologies (Malinauskaite et al., 2017; Rajaeifar et al., 2017). waste fractions with carbon of biogenic origin are to be evaluated as
The preferred waste treatment method, if waste cannot be prevented, climate-neutral (Mauschitz, 2009; Hoffmann et al., 2011; Schwarzböck
should be reuse or recycling. If material recovery of the waste stream is et al., 2016). In a study on the serious discrepancies between science and
not possible, it should either be thermally recovered or – only as the very politics on forest bioenergy, the question was raised whether biogenic
last option – be disposed (European Commission, 2022). Based on the fractions, especially of materials that can be combined with wood, can
circular economy package of the European Union, the criteria waste be considered climate-neutral (Norton et al., 2019). This study by Nor­
avoidance, reuse and recycling should be encouraged (European Com­ ton et al., 2019 could have an effect on the quantification of CO2
mission, 2015). In waste management, the diversity of recycling possi­ emissions of the recycling of waste paper. This approach suggests that
bilities and the differences in input materials result in the composition of biomass from wood can only be considered renewable in the very long
different waste fractions. term, as the CO2 offset can only be balanced back to zero through a
In the analysis of this paper CO2 emissions from material and thermal long-term growth buffer (Norton et al., 2019). For other material and
utilization are quantified and compared to the primary production of the thermally recycled material flows, the issue described by Notron et al.,
different waste fractions and primary energy sources. The results illus­ 2019 plays a relatively minor role. This is because these are already
trate whether there is a potential of waste treatment for anthropogenic waste materials and not, as described in Norton et al., products such as
greenhouse gas emission reduction, and if so, of which magnitude. pellets that are considered to be climate neutral. When waste is incin­
The paper is structured as follows: Section 2 gives an overview about erated, flue gases are produced with an average of about 10 vol percent
the CO2 emission calculations for thermal and material waste recovery. CO2 in the air, which can again be seen as harmful to the climate and
Section 3 reports the CO2 emission effects from the use of waste as a thus underlines the relevance of sustainable waste management with a
substitute fuel and from material recovery. Section 4 discusses the re­ long-term CO2 emission reduction (Treder, 2010). This distinction is also
sults, while Section 5 concludes. applied in the calculation of CO2 emissions of thermal recovery. In order
to be able to classify the previously calculated CO2 emissions of the
2. CO2 emissions of thermal and material waste recovery waste input streams into their fossil and biogenic fractions, the list of
operator data and literature references on carbon contents and biogenic
To quantify CO2 emissions from different waste treatment and use fractions of substitute fuels of the Austrian Water and Waste Management
options, the activities of an internationally active waste management Association, 2004 2 was used.
company were scrutinized. The company is a medium-sized enterprise The fossil and the biogenic CO2 emission share is given by the
with operational plants in various countries. Their core business area is following equation.
in Austria and Central Europe.
The calculations were carried out on the basis of Life Cycle Assess­ CO2X [t] = CO2 material [t] ∗ X share[constant]
(2)
X = fossil or biogenic
ment (LCA). The system boundary was set across all thermal and ma­
terial recycling plants of the company within Austria. The waste stream
(see Fig. 1) was taken into consideration from the moment of the
collection within Austria and from the moment when it entered the plant 1
We refer to this original source as all more recent studies consistently use
for imported waste streams (i.e. crossed the plant gate). From there, the these emission and energy factors, referring to Denner and Kügler (2006).
collection and transport of the waste to the respective treatment and 2
The more recent studies have been found to use this source as well, there­
recycling plant as well as its treatment within the (respective further) fore citing here the original source. However, there is a lack of studies over the
plant were measured. Data on the quantity flows of this company, both last decade, indicating a research gap in studies of the operation of EBS plants.

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M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

Fig. 1. Illustration of the system boundary.

biogenic fractions and the above.


Table 1 [ ]
Types of waste for incineration (analysis based on Federal Ministry Republic of t
CO2 cc = CO2 fossil + CO2 biogenic + CO2 col. + CO2 tra. + CO2 proc. (4)
Austria Agriculture, Regions and Tourism, 2015). year
Plant Material Flow

Incinerators Waste oil & transformer oils


2.1.1. Scenarios for comprehensive net-emission comparison
Inert material The following scenarios have been developed for thermal recovery: a
Sewage sludge anaerobic and aerobic main scenario of current waste recycling flows and two types of alter­
Solvent-water mixture halogen-free native scenarios to compare to, A and B.
Non-hazardous medical waste
The main scenario quantifies the emission effects of the thermal re­
Municipal waste
Municipal waste-like commercial waste covery processes, based on data retrieved for all plants of the case study
European waste management company for the base year 2018. This
Cement plants using substitute Waste oil for thermal utilization main scenario covers the total CO2 emissions, composed of the following
fuels Scrap tire chips fractions: refuse-derived-fuel plants, waste incineration (WIP) and flu­
Recycled plastics
Contaminated sawdust
idized bed plants (FBP). RDF plants mostly supply energy to cement
High-calorific quality-assured substitute fuel plants, while the fluidized bed plants are mostly used in paper mills
produced (Mauschitz, 2018).
The thermal energy is generated by the direct incineration of the
Paper mills with fluidized bed Impregnated wood (RDF-hazardous waste)
respective waste input. In the comparison scenarios, the cement plant is
plants Light fraction residues packaging collection
Municipal waste – residues from waste paper not supplied with alternative fuels (processed from waste) but with hard
processing coal. In the paper industry the fluidized bed furnaces are fired with
Municipal waste – residues from mechanical natural gas. Since the use of waste inputs for thermal processes is of
treatment higher energy efficiency than that from fossil fuels, in order to achieve a
Municipal waste-like commercial waste
thoroughly adequate analysis some energy that is supplied in current
waste stream use (i.e. in the main scenario), but no longer is when fossil
resources of the same energy content are used, needs to be generated by
with the fossil share representing the fossil CO2 share assigned to the another technology, and we assume a district heating gas plant is
individual material flow groups, taken from Austrian Water and Waste employed for this purpose. The delta in the energy supply of the two
Management Association (2004). The numerical value of the fossil CO2 cases in terms of total thermal useful energy is 558 GWh (see Fig. 2).
fraction is a constant number between 0 and 1. To assess the net effect on CO2 emissions arising from the thermal
In order to obtain the comprehensive CO2 emissions, three further recovery process, the following scenarios for comparison are introduced.
activities need to be considered: the collection, the transport and the In scenario A CO2 emissions are determined which would arise from the
processing of the waste for the thermal recycling. equivalent use of energy from fossil fuels. In this scenario A, every
To be able to calculate the CO2 emissions resulting from collection current purchaser of RDF (RDF plants, fluidized bed plants) would then
and transport, emission-factors from Pomberger (2008) were used. The have to switch to other energy sources to generate the required heat or
processing emission factor is composed of the CO2 emissions from the electricity. Scenario A shows in a first step just the CO2 emissions
respective processes at the plant (energy consumption). Electricity implication that results directly by RDF plants and fluidized bed plants
consumption in the company under consideration is measured annually having to switch to fossil alternatives.
at each plant site. These consumptions were converted into a treatment Scenario B is more comprehensive. It not only allows a comparison
factor in kilograms CO2 per ton (Federal Environment Agency Austria, with the equivalent energy input from selected fossil primary energy
2017). sources that would be required to substitute for the treated waste, but
CO2 emissions in the waste collection/transport/processing per ton also takes into consideration that the thermal waste fraction would then
of input thus are given by: be available for other uses, and – given that landfilling is forbidden –
[ ] would need to be employed elsewhere. It is assumed that all is going into
tCO2
CO2 ccol./tran./proc. [t] = emission factorcol./tran./proc. ∗ quentity[t] (3) the waste incineration, thus substituting for fossil inputs in thermal
t input
power plants producing electricity and/or heat. In this scenario B, in
With the CO2 emissions of collection, transport or processing (CO2 addition fewer fossil inputs are used in thermal power plants, since the
col. / tran. / proc.)
included, the relevant emissions can be stated. The waste entire waste stream is now channeled to waste incineration plants (WIP),
collection emissions arise during the gathering of the individual bins on representing the comprehensive alternative scenario for use of treated
the trucks, the transport of the waste in the trucks to the plants and its waste in RDF plants and in fluidized bed plants. The latter allows the net
processing out of the trucks on to the plant. CO2 emission effect to be calculated for the alternative sole thermal
Finally, the total CO2 emissions (CO2 CC) are the sum of the fossil and recovery of waste. Moreover, in scenario B it is assumed that the entire

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M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

Fig. 2. Main scenario (thermal waste treatment) with the energy delta in useful
energy for scenario comparison, which is covered by a district heating gas plant;
GWh data from the case study.

waste stream generated is thermally degraded directly in a waste


incineration plant without any treatment. This incineration process
again generates thermal energy, substituting for processes based on
fossil energy. Scenario B is a direct way to compare the net CO2 emission
effect of current waste treatment (main scenario) versus the alternative
of sole thermal waste treatment in waste incineration (see Figs. 2 and 3).
Fig. 3. Energy volumes for scenario family B, Fossil fuel use instead of RDF (in
[ t ]
GWh), with waste of the plants from the case study going solely to waste
Quentityfossil [t] = TRFvalue total thermal [GJ] ∗ GJemission factor (5)
GJ incineration plants (WIP) substituting for their fossil inputs.

2.1.1.1. Scenario family A: fossil energy sources. The scenario family A In order to obtain a starting point for the scenarios A1 and A2 cal­
has the aim of showing how much fossil energy would be required if culations, the total energy generated for the respective thermal utiliza­
there were no thermal processing and recycling of waste. tion category has been assigned to the respective fossil material input.
There are two variants, A1 and A2, differing in the emission factors The GJ/t value from Mauschitz (2018) was used to determine the
used. While in scenario A1 the emission factors of processing, transport quantity of fossil fuels required per year instead of waste. This is
and collection were each specially weighted and included in the calcu­ calculated as follows:
lation, in scenario A2 a total emission value of Fritsche and Rausch
(2008: 3,12,20) was used. The advantage of the scenario A1 is the CO2 savings or excess [t] = CO2 main scenario [t] − CO2 scenario B [t] (6)
possibility of individually including the transport factor. This allows a The quantity of the respective fossil fuel in tons per year corresponds
closer look at the CO2 emissions generated in this area. However, the to the total energy value of the respective thermal recovery form (TRF)
emission value for the fossil energy carrier natural gas is not precisely in gigajoules multiplied by the value in tons per gigajoule determined
evident from the sources specified for comparison scenario A1. Since from the literature by Mauschitz (2018).
natural gas is needed for the analysis in the comprehensive scenario B in
the cement plant case, scenario A2 was created, in which the results 2.1.1.2. Scenario B: waste incineration of the entire thermal waste
from Fritsche and Rausch (2008: 3,12,20) were used, including gas but fraction. The approach for the calculation of scenario B is based on the
lacking the disaggregated transport emissions. same one taken for the thermal recovery processes. The only difference
The calculation method for scenarios A1 and A2 is based on the fossil is that in the former calculation of scenarios A1 and A2 the total waste
input material, while that for thermal utilization takes a different track. quantities were treated as different fractions of the waste incineration
Important sources in the area of emission factors for comparative sce­ processes (RDF and input for fluidized bed plants). For scenario B the
nario A1 are the Federal Ministry for Sustainability and Tourism (2017), distinction was no longer made between RDF treatment and the fraction
Drosihn et al. (2017) and Nagl et al. (2004). For comparative scenario for fluidized bed plants, as this scenario assumes that waste is no longer
A2, Fritsche and Rausch in particular (2008: 3,12,20) are relevant for treated in this manner. In this case cement plants and paper mills use
determining the emission factors of the fossil fuels for further primary (fossil) energy sources only. Adjustments were made in the
calculations.

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M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

areas of efficiency and the heating value factor. This is necessary recycling but also to obtain information about the CO2 savings or
because substitute fuel processing achieves much higher efficiencies excesses.
leading to a higher waste incineration rate. This also applies to the Calculation of the CO2 savings (if negative excess) in tons per year
calorific value of the separate input materials. By processing the waste [ ]
[ ] quentity
fractions, high, medium and low-calorific RDFs can be produced.
kgCO2
t material flow [t] ∗ EMFsavings t waste input
CO2 material total = (8)
Thus, a higher calorific value can be achieved through this treat­ year 1000
ment. Without this treatment, the calorific value factor was adjusted
accordingly for scenario B. The CO2 savings (if negative excess) of material recovery in tons per
The net CO2 saving (or, if negative, CO2 excess) results from the year correspond to the waste quantity depending upon material flow
subtraction of the main scenario emission from total CO2 emissions of type in tons per year multiplied by the he CO2-savings factor in kilogram
scenario B. per ton waste input (and adjusting to achieve the result in tons).

3. CO2 emission effects from the use of waste as a substitute fuel


2.2. Method for calculating the emission effects of material recovery and material recovery
processes
3.1. Thermal processes
The individual waste streams were also allocated to material flow
groups. Each material flow group was divided into further waste flows. The analysis of CO2 emission-effects is subdivided into thermal and
This subdivision was chosen because there are different waste materials material recovery, as shown in Fig. 4.
in each higher-level material flow group. The respective waste stream The emissions at the treatment sites are taken into account up to the
inputs were assigned to quantities in tons per year. point of recycling or incineration. The CO2 emissions were calculated for
Initially, in the case of material recovery, it is possible to evaluate the the materials used and the upstream manufacturing processes. In the
data directly using the units of mass (ton or kilogram). In addition, case of the energy used the primary and direct emissions were
material recycling plants have no energy extraction and therefore no considered.
efficiencies need to be considered in the calculations. The CO2 emission
values and the CO2 savings values in the literature already include the 3.1.1. Thermal CO2 emission effects
electricity consumption of the processing, the transport routes of an Each of the thermal recycling methods is considered separately and
average truck during collection and the transport of the waste between emissions are produced in relation to the respective fraction of the input
the processing plants. The main sources of CO2emission values from quantity. To determine the total CO2 emissions from thermal recovery,
recycling are Eriksson et al. (2010), Frauenhofer Umsicht (2008) and the all specific CO2 emissions necessary for the thermal energy extraction
Federal Environment Agency of Austria (2010). are calculated for the total input streams quantities. Thus, not only an
Calculation of CO2 emissions in tons per year overview of the total CO2 emissions but also their origins in the
[ ] [ ] respective thermal utilization processes are given.
t quentitymaterial flow [t] ∗ EMFmaterial flow kgCO
t
2

CO2 material total =


year 1000
∗ wasteinput[per year] (7) Table 2
Thermal CO2 emissions coefficients for the main scenario and its respective
The total CO2 emissions of the material recovery process in tons per waste fractions treated in waste incineration plants, refuse derived fuel (RDF)
year are equal to the waste quantity depending upon kind of material plants or fluidized bed plants, and splitting plants.
flow in tons per year multiplied by the individual CO2 emission factor Thermal CO2-emission tCO2/ton input waste stream tCO2/GWh
(EMF) in kilograms per ton waste input and divided by the factor 1000 to
Waste incineration plants 0.38 503
convert the value in tons per year. RDF plants 0.66 117
In the next step the CO2 emissions arising from the primary pro­ RDF for fluidized bed plants 0.62 496
duction of the respective material per year are calculated, in order to be Splitting plants 025 238
able to represent not only the total CO2 emissions from material

Fig. 4. Breakdown of recovery methods.

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M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

The CO2 emissions caused in the case of waste incineration corre­ Table 4
spond to a quantity of 0.38 tons of CO2 per ton of input waste stream (see CO2 emissions of the fossil fuels for scenario A.
Table 2). Scenarios A1 and A2 were drawn up for the waste incineration Material tCO2/ Sources
plant case, in order to obtain a comparative value of how much energy GWh
from fossil fuels would have to be used to provide the same quantity of Hard Coal 436 Mauschitz (2018), Fritsche and Rausch (2008),
thermal energy. Lignite 463 Federal Environment Agency Austria (2017)
Heating oil 336
light
3.1.1.1. Utilization of refuse-derived fuel plants with integration of scenario
Heating oil 369
A1 and A2. A quantity of 0.66 tons of CO2 per ton of input waste stream heavy
is produced for the waste treatment in RDF plants (see Table 2). The Natural Gas 331
factor tons of CO2 per GWh, is considered for the fossil fuels in all
thermal utilization processes, depending on the input (hard coal, lignite,
etc.). Tables 3 and 4 show the CO2 emissions of the fossil fuels. The with all thermal utilization methods, the utilization by fluidized bed
absolute emission levels were calculated based on the thermal energy firing was also evaluated against the fossil scenarios. Since the thermal
from the main scenario. The respective fossil fuel input quantity was recovery processes of the substitute fuel plants and the fluidized bed
calculated from the energy use. plants are relatively similar, the differences between the recovery pro­
The comparative scenarios A1 and A2 were used. In this case, the cesses themselves and the comparison scenarios can be found mainly in
CO2 savings from the use of substitute fuels become apparent. In prac­ the thermal and electrical efficiencies. The specific thermal CO2 emis­
tice, RDF is delivered from the processing plant to the cement plant. By sions per GWh are again particularly interesting in this case with a level
using processed waste as a substitute fuel, the fossil energy sources of 496 t CO2/GWh. In a simple comparison with fossil fuels, it appears
found in nature can be conserved. Another advantage is that by col­ that those from the fluidized bed kilns are much higher. However, here
lecting and processing the RDF locally in Austria, the transport distance again it must be kept in mind that the waste quantity has already been
to the cement plants can be kept much shorter than the transport dis­ produced and cannot be landfilled.
tance of the fossil fuels. Despite the similarity in the CO2 emissions per ton of input material
In order for the input materials to be comparable, based on the and the equally high CO2 emission quantities, the energy analysis re­
original amount of energy created from the combustion of the waste, it veals considerable differences. In fluidized bed firing, as well as in waste
was converted to the amount of energy needed for the fossil fuels to incineration or in the splitting fraction supplied to waste incineration
respectively obtain the same energy output therefore the conversion plants, the loss of energy is considerably higher than in refuse-derived-
factors of Mauschitz (2028) were used in both scenarios. The emission fuel plants. In direct comparison with fluidized bed combustion, this is
calculations are based on the factors in scenario A1 on Drosihn et al. also due to the fact that RDF plants convert thermal energy very effi­
(2017), Nagl et al. (2004) and the Federal Ministry for Sustainability and ciently, with an efficiency of 90%, into thermal energy. The energy
Tourism (2017). For scenario A2 the emissions were calculated based on savings for converting the same thermal energy compared to fossil fuels
the factors of Fritsche and Rausch (2008) and the Federal Ministry for are most evident in RDF firing.
Sustainability and Tourism (2017).
Significant CO2 savings per gigawatt hour can be seen in the specific 3.1.1.3. Evaluation of splitting plants. Splitting plants require a special
CO2 emissions. While the value for the refuse-derived fuel plants is about approach in order to be able to consider the CO2 emissions in thermal
117 tons of CO2 emissions per gigawatt hour, the values for the fossil utilization. The extent to which the respective waste management
fuels are about three to four times higher for the same input quantity of company splits the delivered quantities, could not be precisely traced.
energy (see Tables 2–4). The specific CO2 emissions for heat generation For this reason, the following assumption was made: according to the
are particularly interesting in the case of waste incineration plants. As federal waste management report, 46% of the waste in splitting plants is
the calculated values show, the extraction of heat energy from waste used for thermal recovery. The remainder is deposited in landfills and a
incineration plants can generate either higher or the same CO2 emissions small percentage of about 4% goes to material recovery (Winter, 2010).
as fossil fuels. If waste did not exist, natural gas in particular, with The evaluation of the splitting plants results in 0.25 tons of CO2 per
244–331 tons CO2 per GWh would be preferable here to thermal heat ton of input (see Table 2). The specific CO2 emissions with 238 tCO2/
generation from waste. But with knowledge of the reality in this case, GWh are clearly below those of the fossil energy carriers (in median 375
the waste stream has already been generated. Since the entry into force t CO2/GWh).
of the Federal Law on Landfills (Waste Management Act, on landfill
regulations), a ban has been placed on the dumping of waste that can be 3.1.2. Scenario B: waste incineration of the entire thermal waste fraction
subjected to mechanical-biological treatment (Waste Management Act, In this scenario, it was assumed that the entire waste fraction is sent
AWG, 2016). for thermal recovery. The waste incineration plant generates energy in
the form of electricity and heat. The emissions from the generation of
3.1.1.2. Evaluation of fluidized bed plants. The evaluation of fluidized electricity have been included, but the focus will be on the energy from
bed plants results in 0.62 tons of CO2 per ton of input (see Table 2). As heat and the resulting CO2 emissions. In this scenario B it is assumed that
all waste is incinerated. A deposit of the waste in a landfill is not possible
due to the Austrian Landfill Ordinance 2016 (Waste Management Act,
Table 3 AWG, 2016). The direct incineration of the entire waste input generates
CO2 emissions of the fossil fuels for scenario A1. thermal energy.
Material tCO2/ Sources The thermal energy from the actual scenario and from the compar­
GWh ison scenario result in a delta in the energy supply. This delta is
Hard Coal 376 Mauschitz (2018), Drosihn et al. (2017) compensated in the actual scenario by a district heating gas plant. In the
Lignite 587 Mauschitz (2018), Drosihn et al. (2017) comparison scenario, the cement plant is now supplied with hard coal
Heating oil 326 Mauschitz (2018), Nagl et al. (2004), Federal Ministry
instead of substitute fuels.
light for Sustainability and Tourism (2017)
Heating oil 341 Mauschitz (2018), Nagl et al. (2004), Federal Ministry Hard coal was chosen for the cement plants because most cement
heavy for Sustainability and Tourism (2017) plants in Central and Eastern Europe, which is the focal region for this
Natural Gas 244 Mauschitz (2018), Nagl et al. (2004), Federal Ministry paper, use coal as their primary fuel. Accordingly, the boiler and the
for Sustainability and Tourism (2017) firing systems used are designed for coal. Gas in cement plants is only

6
M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

used to start the firing process and cannot be replaced. The substitution during recycling, on the other hand the CO2 savings compared to the
is the use of coal. In Austria a decrease in the coal used has been ach­ primary product are calculated. For further information about the
ieved from one million GJ to about 670 thousand GJ from 2012 to 2018 emission factors, see Appendix section 2.
(Mauschitz, 2018). Based on the data it can be concluded that waste paper and card­
Natural gas was chosen as a reference material for fluidized bed board are the strongest fractions in terms of input quantity at the waste
furnaces, because paper mills need energy from heat. The majority of management company investigated. It can be noted in the two paper-
paper mills in Europe currently obtain this energy from natural gas. Gas intensive material flow groups that these have the highest CO2 savings
boilers in these power plants have specific service lives. Once this is potential compared to primary production.
reached they are often converted to substitute fuel plants with a fluid­ A high potential of CO2 savings can be identified in the sector of
ized bed furnace as their core component. ferrous metals (FE-metals), due to the fact that the raw material metal
The district heating gas plant was chosen because numerous con­ can be used in the same way as its counterpart from primary production
struction projects are currently being implemented in Austria. These are if it is properly processed. Another fraction to be mentioned is that of
heated either with gas or district heating. recycled plastics. The recycling of plastics not only enables a reduction
It can be determined by analyzing the numerical values whether a in emissions compared to the primary product but also sustainably re­
CO2 saving is achieved by the thermal recovery processes or not. The lieves the environment through the various possibilities of reuse in
analysis of the data and the corresponding calculations were based on production (Federal Environment Agency Austria, 2010).
the same energy quantities in the thermal recovery as in the comparison It must also be considered at this point, that the recycling process
scenario. To compensate for the surplus of energy resulting from the includes its own emissions, which are generated by the recycling process
comparison scenario, the district heating gas plant is calculated as an itself. If these emissions, which occur during the recycling process for
extension in the actual scenario. The CO2 emissions per ton waste input the production of the secondary raw material, are included, we obtain
and respectively the CO2 per ton of former input waste stream, which is the actual CO2 savings of 117,604 tons through recycling for our case
in the comparative scenario no longer used. By analyzing the existing study firm. The upscaling of this number to the overall Austrian market
data, we find, that the thermal processing achieves a CO2 saving of over is derived below, together with the alternative fuel employment results.
311,300 tons per year, respectively 3.57 tons per ton input material (see For the results of CO2 emissions per ton waste input and tons CO2
Table 5). The market share of the waste fraction analyzed is about 15% compared to the primary production see Table 6.
of the whole thermal and material recovery sector in Austria for the year
2020. The saving is equivalent to 0.4% of total (all sector) GHG emis­
3.3. Results for the analysis of the CO2 emission effects through the use of
sions of the country in that year. If the waste fractions analyzed were
thermal and material recovery
representative for the Austrian overall waste sector, the CO2 savings due
to the current waste treatment would thus amount to an equivalent of
The CO2 emission savings resulting from thermal and material re­
2.6% of total (all sector) country emissions.
covery of a fraction of the current waste management sector, covering
15% of the market in 2020, is about 429,000 tons per year. This is
3.2. Material recovery equivalent to roughly 0.6% of the total Austrian annual GHG emissions.
As an interesting mental experiment, it can be noted here that if every
Recycling not only helps to reduce CO2 emissions, but due to the company in the area of this market share made these savings, an emis­
process used it also creates them. In contrast to thermal recovery, the sion saving of 3.6% of Austria’s GHG emissions would be possible.
material recovered waste is not used to generate energy. In this case, Thermal treatment with a CO2 saving of over 311,300 tons is largely
waste materials become raw materials for products again and thus due to the processing of the waste into substitute fuels. CO2 emissions
replace primary materials and avoid the emissions connected to their which are caused by the thermal recovery in incineration plants for
production. Thus, a CO2 saving can be achieved in recycling by com­ waste can be substantially compensated by the use of the substitute fuels
parison with the CO2 emissions from primary production. In the analysis and thus make a relevant CO2 savings in thermal recovery possible.
of this recycling method all direct emission effects were considered. The Material recovery accounts for 117,600 tons of CO2 savings which
CO2 emission factors include those of the electricity demand for Austria, equals a CO2 saving per ton of 1.36 tons per ton input material (see
an average transport route with a standard truck and the processing Fig. 5).
method. The calculation was based primarily on the findings in the
studies by Gromke and Dentzel (2006) and the Federal Environment 4. Discussion
Agency of Austria (2010). Based on these studies data, on the one hand
the CO2 emissions are calculated for the quantities of waste produced Waste management has potential to contribute to the goal of not
exceeding 1.5 ◦ C of warming set in the Paris Agreement (Oxford Uni­
Table 5 versity, 2022; UNFCCC, 2015). Not only emission reductions from the
CO2 emissions arising within the comparison scenario B, allowing derivation of thermal sector by using secondary fuels are important for achieving
the CO2 emission savings by waste treatment as performed by the case study long-term sustainability, but also and in particular recycling and the
waste management company.
Thermal CO2-emissions for tCO2/ton of waste input material Table 6
comparison scenario B (respectively waste input material CO2 emissions per ton waste input and tons CO2 saved when compared to pri­
substituted for) mary production.
Waste incineration only 0.56 Material group tCO2/ton waste t CO2 saving/t input compared to
Coal within the cement plant 2.84 stream primary production
Gas within the fluidized bed plants 2.01
Non-ferrous metals 1.53 6.4
Thermal CO2-emissions for energy tCO2/GWh
Ferrous metals 0.25 2.81
supply delta in scenario B
Paper 0.93 1.28
District heating plant 268
Cardboard 0.93 0.45
Plastics 0.68 3.14
Comparison of the CO2-emissions tCO2/ton input material Old electrical 0.30 3.15
from main scenario to scenario B equipment
CO2- saving 3.57 Wood 0.10 0.67

7
M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

The first relates to the topic of digitization in waste management. Smart-


waste systems, which are currently still in a developing phase should not
only be implemented in practice, but should also be tested for their
validity and applicability to traceable waste paths. Progressive digiti­
zation could make the material flows of waste more comprehensible.
This would also facilitate the collection of data for emission calculations.
The second point for interesting future research would be a further
development of the concept of substitute fuels. Especially in the field of
efficiency in incineration plants, further research with technologies
could possibly reduce greenhouse gas emissions by more efficient
combustion.

5. Conclusion

This analysis calculated the CO2 emissions caused by waste man­


agement, along with the savings achieved by material and thermal
Fig. 5. A comparison of the CO2 emissions which arise through the material
recycling methods, which were quantified by means of comparison
recovery process, related to the CO2 savings through the use of secondary
material out of material recovery instead of primary production and the total
scenarios. The quantitative results are thus case-specific, but generalized
CO2 savings induced by the company through the material recovery process conclusions are appropriate for the orders of magnitude derived.
after the own-emission deduction. Employing the full range of refuse derived fuel plants, fluidized bed
plants, and splitting plants we find a CO2 saving of 3.57 tCO2 per ton of
goal of a zero-waste cycle. In the area of waste treatment, through a waste input material, and a saving of 1.36 tons CO2 per ton of waste for
comparison of the potential alternative scenarios to the main scenario material recycling.
(present situation) we find that the use of fossil fuels can be avoided, A final consideration is that for a long-term reduction of greenhouse
resulting in a CO2 emission reduction. gas emissions, a rethinking and a continuous development of the global
In essence, it can be concluded that a waste management system (waste) economy is inevitable. In this sense, further steps towards sus­
combining thermal and material recovery shows higher CO2 emission tainability should be tackled by investing in future technologies. In
savings compared to a system with only incineration. This finding is addition to technological progress, the educational aspect should also be
consistent with the research of Pérez et al. (2018), Michel Devadoss et al. considered, namely the continuous expansion and sensitization of the
(2021), and Wang and Nakakubo (2020). Although these studies do public’s understanding of the environment.
suggest a combined approach as the most environmentally-friendly
waste management option, only Pérez et al. (2018) considered CRediT authorship contribution statement
Refuse-Derived-Fuels and none of them considered Fluidized-Bed-Plants
in thermal recovery, whereto we expand the analysis. Due to a high Marion Christine Unegg: Conceptualization, Case study imple­
diversity of specific parameters on both the national level (e.g. legal mentation, Data curation, Methodology, Writing – original draft,
regulations and waste treatment techniques) and the assessment method Writing – review & editing. Karl W. Steininger: Supervision, Method­
used, it is not possible to compare the quantitative results of this paper ology, Supervision, Writing – review & editing. Christian Ramsauer:
on a fully detailed level with other studies. However, for a cross-check of Supervision. Mariana Rivera-Aguilar: Extended literature review,
the order of magnitude, Chew et al. (2022) show a possible reduction of writing literature extension in final version, graphical abstract, Writing –
up to 2.2% of Malaysia’s GHG emissions, but the approaches differ in the review & editing.
assessment method used and the waste treatment techniques observed.
There are many opportunities to reach a more sustainable waste Declaration of competing interest
management. So-called smart waste methods are an unavoidable tech­
nology to optimize waste separation for consumers and collection lo­ The authors declare that they have no known competing financial
gistics. CO2 emissions could be further reduced by more efficient waste interests or personal relationships that could have appeared to influence
collection tours and the use of hybrid or hydrogen-powered trucks. In the work reported in this paper.
addition, smart-waste technologies, such as scanning the contents of the
waste bins, could be used to make more efficient journeys. These tech­ Data availability
nologies could have an impact on improved waste management by
transferring know-how. The data that has been used is confidential. It is presented in
There are two major points which are of interest for future studies. aggregate in the article.

Appendix

Section 1: Emission factors for thermal treatment

Waste incineration

Material group Emission factor tCO2/GJ Source

Med. Waste non-hazardous 0.0426 Schwarzböck et al. (2016)


Old varnishes, old paints, dispersions and adhesives non-hazardous 0.0080 Specific measured by the company partner
Waste paints, varnishes, dispersions and adhesives non-hazardous 0.0080
Municipal and similar industrial waste 0.0599 Denner and Kügler (2006)
Sewage sludge aerobic and waste water treatment without hazardous substances 0.0951
(continued on next page)

8
M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

(continued )
Waste incineration

Material group Emission factor tCO2/GJ Source

Inert material 0.0599


Solvent-water-mixture without halogen-free 0.0711
Waste oils for thermal recycling 0.0787
Solvents for thermal recycling 0.0711
RDF generation
EBS hazardous -fine splitting material 0.068 Denner and Kügler (2006)
Solvent mixture halogen-free 0.068
EBS quality assured high-temperature 0.0787
EBS quality assured medical 0.068
Solvent-water mixture without halogenated solvents of which 4000 subcontracted processing 0.068
Waste oils for thermal recycling 0.02243 Specifically measured by the company partner
RDF generation for FDP
Sewage sludge aerobic and anerobic 0.0951 Denner and Kügler (2006)
Waste oils for thermal utilization 0.0787
Solvent-water mixture without halogenated solvents 0.0711
Municipal waste; Residues from waste paper processing 0.0598
Municipal waste; Residues from mechanical waste treatment 0.0598
Municipal and similar commercial wastes 0.0599
Municipal and similar industrial waste 0.0599
RDF hazardous - recyclables - impregnated woods 0.0951
Splitting plants
Med. Non-hazardous waste 0.04 Schwarzböck et al. (2016)
Municipal waste - residues from mechanical processing 0.06 Denner and Kügler (2006)
Municipal and similar industrial waste 0.06
Sewage sludge anerobic 0.10
Residues from mechanical treatment 0.06
Municipal and similar industrial waste 0.06

Section 2: Emission factors for material treatment

Material recovery

Material flow Material group Emission CO2 saving compared Comment Source
group factor kgCO2/t to primary
input production kg/t

Non-ferrous Aluminum 1489.00 6261.00 Rotary current kiln, electricity mix Austria, Federal Environment
metals transport, standard truck Agency Austria
(2010)
FE metals Metal packaging/scrap 247.00 2183.00 100% scrap in an electric furnace, electricity mix Federal Environment
Austria, transport, standard truck Agency Austria
(2010)
Special grades of Printing, wet-strength papers, 933.00 1280.00 IFEU study, values for region south region Gromke und Detzel
recovered (2010)
paper
Waste glass flat glass, windshields 449.00 829.00 Secondary production Federal Environment
Agency Austria
(2010)
Cardboard Various Cardboards 933.00 1280.00 Same emission values as paper, since the fraction at Gromke und Detzel
the partner company is in the same material flow - (2010)
"waste paper"; IFEU study, values for the south
region
ABS/ABS-PC 703.00 3312.00 Secondary production Recyclize, Granulate, Federal Environment
electricity mix Austria, incl. Transport Agency Austria
(2010)
Agricultural films, big bags, 500.00 1190.00 Plastic recycles, incl. electricity, and transport Frauenhofer Umsicht
various technical plastics (2008)
EPP, EPS, Granulates. HDPE, 703.00 3312.00 Secondary production of recyclize, granulate, Federal Environment
mixed plastics, LDPE, PC, PET, Austrian electricity mix, incl. transport Agency Austria
PMMA, PP, PS, PVC, POM, Rolls (2010)
Electrical Electrical appliances without 301.00 1442.00 Part of "total old scrap", for small & large electrical Federal Environment
appliances hazardous properties appliances, electricity mix Austria, with reference to Agency Austria
the content of metals and recyclable plastic, incl. (2010)
transport
Waste wood Various woods 100.00 680.00 Processing of waste wood incl. recycling routes Frauenhofer Umsicht
(ann. electricity and transport (2008)

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M.C. Unegg et al. Journal of Cleaner Production 415 (2023) 137745

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