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Which of the following compounds contain(s) no covalent
bond(s)?
KCl, PH3, O2, B2H6, H2SO4

(2018 Main)

A KCl, B2H6, PH3

B KCl, H2SO4

C KCl

D KCl, B2H6
Which of the following compounds contain(s) no covalent
bond(s)?
KCl, PH3, O2, B2H6, H2SO4

A KCl, B2H6, PH3

B KCl, H2SO4

C KCl

D KCl, B2H6
Which one of the following molecules is expected to exhibit
diamagnetic behaviour?

(2013 Main)

A C2

B N2

C O2

D S2
Which one of the following molecules is expected to exhibit
diamagnetic behaviour?

A C2

B N2

C O2

D S2
Solution :
Solution:
KCl is the only ionic compound. The structure of PH3, O2, B2 H6and H2SO4
are given below:
The nodal plane in the π-bond of ethene is located in

(2002, 3M)

A the molecular plane

B a plane parallel to the molecular plane

C a plane perpendicular to the molecular plane which bisects the

carbon-carbon σ-bond at right angle

D a plane perpendicular to the molecular plane which contains

the carbon-carbon σ-bond
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The nodal plane in the π-bond of ethene is located in

A the molecular plane

B a plane parallel to the molecular plane

C a plane perpendicular to the molecular plane which bisects the

carbon-carbon σ-bond at right angle

D a plane perpendicular to the molecular plane which contains

the carbon-carbon σ-bond
Solution :
Amongst H2O, H2S, H2Se and H2Te, the one with the
highest boiling point is

(2000, 1M)

A H2O because of hydrogen bonding

B H2Te because of higher molecular weight

C H2S because of hydrogen bonding

D H2Se because of lower molecular weight

Amongst H2O, H2S, H2Se and H2Te, the one with the
highest boiling point is

A H2O because of hydrogen bonding

B H2Te because of higher molecular weight

C H2S because of hydrogen bonding

D H2Se because of lower molecular weight

Solution:
Due to the presence of Hydrogen bonding in water , it has
highest boiling point.
Arrange the following compounds in order of increasing
dipole moment, toluene (I), m-dichlorobenzene (II), o-
dichlorobenzene (III), p-dichlorobenzene (IV)

(1996, 1M)
A I < IV < II < III

B IV< I < II < III

C IV< I < III < II

D IV< II < I < III

Arrange the following compounds in order of increasing
dipole moment, toluene (I), m-dichlorobenzene (II), o-
dichlorobenzene (III), p-dichlorobenzene (IV)

A I < IV < II < III

B IV< I < II < III

C IV< I < III < II

D IV< II < I < III

Solution: p-dichlorobenzene is non-polar
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The correct statements among I to III are :
I. Valence bond theory cannot explain the color exhibited
by transition metal complexes.
II. Valence bond theory can predict quantitatively the
magnetic properties of transition metal complexes.
III. Valence bond theory cannot distinguish ligands as
weak and strong field ones.
(2019 Main, 9 April II)
A II and III only B I, II and III

C I and II only
D I and III only
The correct statements among I to III are :
I. Valence bond theory cannot explain the color exhibited
by transition metal complexes.
II. Valence bond theory can predict quantitatively the
magnetic properties of transition metal complexes.
III. Valence bond theory cannot distinguish ligands as
weak and strong field ones.

A II and III only B I, II and III

C I and II only
D I and III only
Solution :
Among the given statements, correct statements are I and
III only. Valence bond theory (VBT) cannot explain the
colour exhibited by transition metal complexes. This theory
cannot distinguish ligands as weak and strong field ones.
The correct statement about ICl5 and ICl4- is

(2019 Main, 8 April II)

A ICl5 is square pyramidal and ICl4- is tetrahedral

B ICl5 is square pyramidal and ICl4- is square planar

C Both are isostructural

D ICl5 is trigonal bipyramidal and ICl4- is tetrahedral

The correct statement about ICl5 and ICl4- is

A ICl5 is square pyramidal and ICl4- is tetrahedral

B ICl5 is square pyramidal and ICl4- is square planar

C Both are isostructural

D ICl5 is trigonal bipyramidal and ICl4- is tetrahedral

Solution :
As sum ing that Hund’s rule is violated, the bond order and
magnetic nature of the diatomic molecule B2 is

(2010)

A 1 and diamagnetic

B 0 and diamagnetic

C 1 and paramagnetic

D 0 and paramagnetic
As sum ing that Hund’s rule is violated, the bond order and
magnetic nature of the diatomic molecule B2 is

A 1 and diamagnetic

B 0 and diamagnetic

C 1 and paramagnetic

D 0 and paramagnetic
Solution:
Which of the following are isoelectronic and isostructural ?
NO3- , CO32-, ClO3- , SO3

(2003, 1M)

A NO3- , CO32-

B SO3 , NO3-

C ClO3-, CO32-

D CO32-,SO3
Which of the following are isoelectronic and isostructural ?
NO3- , CO32-, ClO3- , SO3

A NO3- , CO32-

B SO3 , NO3-

C ClO3-, CO32-

D CO32-,SO3
Solution :

NO3- and CO32- both have 32 electrons, central atom

sp2 hybridised, triangular planar.
Specify the coordination geometry around and
hybridisation of N and B atoms in a 1 : 1 complex of BF3 and
NH3.

(2002, 3M)

A N : tetrahedral, sp3 ; B: tetrahedral, sp3

B N : pyramidal, sp3; B: pyramidal, sp3

C N: pyramidal, sp3; B: planar, sp2

D N: pyramidal, sp3; B: tetrahedral, sp3

Specify the coordination ge om e try around and
hybridisation of N and B atoms in a 1 : 1 complex of BF3 and
NH3.

A N : tetrahedral, sp3 ; B: tetrahedral, sp3

B N : pyramidal, sp3; B: pyramidal, sp3

C N: pyramidal, sp3; B: planar, sp2

D N: pyramidal, sp3; B: tetrahedral, sp3

Solution :
According to molecular orbital theory, which of the
following is true with respect to Li2+ and Li2-?

(2019 Main, 9Jan I)

A Both are unstable

B Li2+ is unstable and Li2- is stable

C Both are stable

D Li2+ is stable and Li2- is unstable

According to molecular orbital theory, which of the
following is true with respect to Li2+ and Li2-?

A Both are unstable

B Li2+ is unstable and Li2- is stable

C Both are stable

D Li2+ is stable and Li2- is unstable

 Solution :

Here, Na of Li2+ < Na of Li2- .

In which of the following pairs of molecules/ions both the
species are not likely to exist?

(2013 Main)

A H2+ , He22+

B H2-, He22-

C H22+,He2

D H2-,He22+
In which of the following pairs of molecules/ions both the
species are not likely to exist?

A H2+ , He22+

B H2-, He22-

C H22+,He2

D H2-,He22+
Solution :
Species having zero or negative bond order do not exist.
H22+ ( 1+ 1-2 =0) σ1s0
Bond order = 0
Molecular shape of SF4 , CF4 and XeF4 are

(2000, 1M)

A the same, with 2, 0 and 1 lone pair of electrons respectively

B the same, with 1, 1 and 1 lone pair of electrons respectively

C different, with 0, 1 and 2 lone pair of electrons respectively

D different, with 1, 0 and 2 lone pair of electrons respectively

Molecular shape of SF4 , CF4 and XeF4 are

A the same, with 2, 0 and 1 lone pair of electrons respectively

B the same, with 1, 1 and 1 lone pair of electrons respectively

C different, with 0, 1 and 2 lone pair of electrons respectively

D different, with 1, 0 and 2 lone pair of electrons respectively

Solution :
Assuming 2s-2p mixing is NOT operative, the
paramagnetic species among the following is :

JEE advanced 2014

A Be2

B B2

C C2

D N2
Assuming 2s-2p mixing is NOT operative, the
paramagnetic species among the following is :

A Be2

B B2

C C2

D N2
Solution:
The compound(s) with TWO lone pairs of electrons on the
central atom is(are)

JEE advanced
2016
A BrF5

B ClF3

C XeF4

D SF4
The compound(s) with TWO lone pairs of electrons on the
central atom is(are)

JEE Advanced 2016

A BrF5

B ClF3

C XeF4

D SF4
Solution:
Of the species, NO, NO+, NO2+ and NO–, the one with
minimum bond strength is

JEE(Main)-2020

A NO+ B NO

C NO2+
D NO–
Of the species, NO, NO+, NO2+ and NO–, the one with
minimum bond strength is

A NO+ B NO

C NO2+
D NO–
Each of the following options contains a set of four
molecules, Identify the option(s) where all four
molecules passes permanent dipole moment at room
temperature

NO2, NH3, POCl3, CH3CI JEE advanced 2019

A

B BF3, O3, SF6, XeF6

C BeCl2, CO2, BCl3, CHCl3

D SO2, C6H5CI, H2Se, BrF5

Each of the following options contains a set of four
molecules, Identify the option(s) where all four
molecules passes permanent dipole moment at room
temperature

A NO2, NH3, POCl3, CH3CI

B BF3, O3, SF6, XeF6

C BeCl2, CO2, BCl3, CHCl3

D SO2, C6H5CI, H2Se, BrF5

Solution:
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