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'I. LR
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CRANFIELD
INSTITUTE OF TECHNOLOGY
by
by
SUMMARY
Single and double thermal cycle simulation of heat affected zone
(HAZ) structures has been used to study the structural and property changes
produced by submerged arc welding of HY 80 steel. The effectiveness of
the temper bead technique and post-weld heat treatment at 650°C have also
been examined,
PAGE
1. INTRODUCTION 1
2. EXPERIMENTAL 2
2. 1 Materials 2
2.2 Procedure 3
3. RESULTS 5
3. 1 P a r e n t m a t e r i a l and HAZ 5
3.2 P a r e n t plate banding 6
3. 3 Simulated weld HAZ s t r u c t u r e s 7
4. DISCUSSION
4. 1 Simulated weld t h e r m a l c y c l e s 9
4. 2 I n t e r p r e t a t i o n of C h a r p y data 10
4.3 Notch toughness r e q u i r e m e n t for HY 80 in s u b m a r i n e s 11
4.4 Significance of the r e s u l t s 12
5. CONCLUSIONS 15
REFERENCES 17
TABLES
1. M e c h a n i c a l p r o p e r t y data for a s - c y c l e d s i m u l a t e d s p e c i m e n s 20
and the p a r e n t m a t e r i a l
FIGURES
11. Simulated weld HAZ structures produced by single and double cycles,
with initial cycling to 1275°C.
12. Simulated weld HAZ structures produced by single and double cycles,
with initial cycling to 930°C.
13. Simulated weld HAZ structures produced by single and double cycles,
with initial cycling to 765°C.
14. Post-cycle heat treated structures of single and double cycled specimens
with initial cycling to 1275°C.
15. Post-cycle heat treated structures of single and double cycled specimens
with initial cycling to 930°C.
- 1 -
1. INTRODUCTION
After the end of World War II, much effort has been ex|)ended in the
development of high notch-toughness steels, particularly for naval construction.
Considerable experience had been obtained in the marine industry in using the
quenched and tempered STS steel. Test results on low carbon content heats
of this material prompted modification to a low carbon, nickel, chromium,
molybdenum steel which, when quenched and tempered, developed a yield
strength of 550 N/mm.^ (80,000 Ibf/in^) in thicknesses up to 32 mm, with
notch-toughness values, based on the Charpy V-notch impact test, of
68J (50 ft. Ibf) at -84°C. With composition variation to ensure good hard-
enability in different plate thicknesses this steel was referred to as HY 80
and produced in plate form to U. S. military specifications MIL - S - 16216D,
E and F, (Refs. 1-3). The present U.S. military specification, MIL - S -
16216G (Ref. 4), quotes only one composition range for all plate thicknesses.
in the literature.
(a) to establish for a given heat input condition and preheat temperature
the nature of the weld HAZ due to a single-run weld.
(b) by employing double cycle simulation techniques using the same welding
conditions a s in (a), to indicate the general nature of tempering in a
pre-existing HAZ due to the heat flow from a subsequent weld run in
a multi-run weldment and to predict the effectiveness of the temper-
bead technique.
2. EXPERIMENTAL
2. 1. . Materials
The 38inm. thick HY 80 steel plate had the following chemical analysis,
- 3 -
c Mn Si S P Ni Cr Mo V Al N
0.16 0.32 0.30 0.017 0, 006 2.54 1.31 0. 28 0.01 0. 015 0.01
Charpy Energy*
Specimen Yield Strength U.T.S.
at -84°C
Orientation
J ft. Ibf N/mm tonf/in N/mm tonf/in
2. 2. Procedure
2, 2. 1. P r e p a r a t i o n and e x a m i n a t i o n of weld.
10. 7mm X 10. 7mm x 10. 7mm x 83mm and were machined from the mid-
thickness of the plate axially transverse to the rolling direction. Coward,
(Ref. 15), showed that the application of restraint by rigid clamping of the
blanks during simulation of a similar steel did not affect the performance
in the Charpy V-notch impact test. In this present study all blanks were
allowed axial freedom of movement during thermal cycling.
the control thermocouple position and in the through thickness direction of the
original plate. Impact transition curves were determined by testing between
- 196°C and 40°C. A mixture of iso - pentane and liquid nitrogen was used
for tests below room temperature and hot water for tests above room temper-
ature. Test temperatures were estimated to be accurate to 't 3°C.
One simulated blank from each condition was sectioned through the
centre of the thermally cycled zone and the hardness determined using the
Zwick hardness tester with a load of 5kg.
2. 2. 6. Examination of banding
Band width measurement and 0. 5kg load hardness surveys were made
on specimens which had been simulated using the 930°C peak temperature
cycle. Specimens in this condition were chosen because they gave the best
inter-band optical contrast after etching. Electron probe microanalysis was
carried out at the Welding Institute to determine the nature of the microsegre-
gation within the HY 80 steel plate.
3, RESULTS
distinct regions :-
(a) the grain coarsened region extending up to approximately 0. 6mm
from the fusion boundary,
(b) the grain refined region, between 0. 6mm and 2. 5mm from the
fusion boundary, and
(c) the intercritical region, between 2.5mm and 3.0mm from the
fusion boundary.
The results of the 5kg, and 0. 5kg. load hardness traverses are
shown in Fig. 3. The 5kg. results show a continuing increase in hardness
on moving towards the fusion boundary reaching a maximum value of
430 HV5 at the fusion boundary. Large fluctuations superimposed on the
same general trend were obtained with the 0. 5kg. load tests, the fluctuations
being particularly noticeable in the grain refined region. This is thought to
be due to the banded structure of the parent plate resulting from alloying
element segregation.
The existence of banding was not very evident in the parent plate or
after cycling to a peak temperature of 1275°C. However, after cycling to
765°C and 930°C, banding was very noticeable at low magnifications.
Banding in a 930°C peak temperature cycled specimen as revealed by
etching in 2% nital is shown in Fig. 4. Measurement of band width and
hardness gave the following r e s u l t s : -
Band type
Band width (mm) HV 0. 5 HV5 1
Mean Std. Dev. Mean Std. Dev. Mean Std. Dev. 1
Light
0. 056 0. 031 436 7
etching
353 17
Dark
0. 195 0.044 311 11
etching
- 7 -
Weight % in band
Element
Dark etching Light etching Dark etching
Manganese 0. 41 0. 59 0.39
Nickel 2. 20 3. 50 2.31
Chromium: 1. 70 2.40 1.20
Molybdenum 0. 20 0. 26 0. 18
3. 3, 1. Single cycle s i m u l a t i o n
4. DISCUSSION
with those produced by the simulation equipment was generally very good.
However, difficulty was experienced in reproducing the sharp peak in the
1275°C cycle, the electrical characteristics of the simulation equipment
producing a broader peak. This could result in the simulated samples
showing a slight increase in the prior austenite grain size and a more
homogeneous austenite compared with the corresponding region in a weld
heat affected zone.
The Charpy test has been the most widely used method of
assessing fracture toughness in structural steels. Interpretation of the
results can, however, be misleading unless it is based on a vast amount of
experience or else correlated with some other test procedure which gives a
more realistic appraisal of service performance. This is due partly to
the fact that the energy measured by the test does not permit conditions
for initiation and propagation to be distinguished or the critical s t r e s s and
strain parameters responsible for fracture to be separated. The test also
uses impact loading conditions and thus the results will not be directly
applicable to static loading conditions.
For HY80 parent material it was established that the FTE and F T P
temperatures are approximately -68°C and-40°C respectively and that the
NDT temperature (-90^0) correlates well with the 40-45 ft. lb Charpy
temperature (Ref. 21). Winn (Ref. 25) reported a similar correlation for
QT 35 on specimens cut in the rolling direction and this has been confirmed
in recent work at Cranfield (Ref. 26). Thus, the fracture toughness
requirements for the two types of submarines described above can be stated
as follows, based on safe operation at -10 C which is below the lowest
temperature encountered during submerged operation :-
(a) 68J (50 ft. lb. ) minimum at -40°C for non-combatant submarines
(b) 68J (50 ft. lb. ) minimum at -68 C for combatant submarines.
4. 4. 1, Parent material
The HY80 used in the present work easily met the 68J (50 ft. lb. )
minimum Charpy energy at 68°C considered necessary for the more severe
conditions required of combant submarines. Fig. 5 shows that at this
temperature the energy levels were approximately 149 and 115J (110 and
85 ft. lb. ) respectively for the longitudinal and transverse directions. It is
of interest to conapare these values with those reported for QT 35 since
HY80 has recently replaced this steel in the U.K. submarine programme.
Smith and Apps (Refs. 26 and 27) have determined equivalent Charpy energy
values at -60°C of 90 and 61J (66 and 45 ft. lb, ) respectively for the
longitudinal and transverse directions of QT35. Thus, the replacement of
QT35 by HY80 in the U.K. would appear to be justified. Dolby (Ref. 12)
has reported a crack opening displacement transition temperature some
20°C lower for HY80 compared with QT35. The superior notch-toughness
of HY80 has been attributed to the following factors (Ref. 18) :-
(b) the higher Ni content of HY80 which improves the basic properties
of the ferrite
in that the light etching bands were found to contain a higher concentration
of aUoying elements than the dark etching bands. This is in direct contrast
to another examination of banding in HY80 (Ref. 18), in which the dark etching
bands were found to be richer in alloy content. However, in the present work
banding was examined in material that had been thermally cycled above the
upper critical temperature so that the apparent anomaly can be explained by
the fact that the alloy-enriched bands transformed to martensite during
Cooling and thus appeared lighter than the alloy-denuded bands which trans-
formed to a higher temperature transformation product containing more
carbide precipitates.
The results. Fig. 6, show that the transformed HAZ has significantly
lower energy absorption and upper shelf energy compared with the parent plate,
these changes becoming more marked on approaching the fusion boundary. A
similar pattern of results has been reported on other quenched and tempered
low allow steels (Refs. 11, 15, 27-30), Dolby (Ref, 12) has also shown a
significantly reduced resistance to fracture initiation in the transformed HAZ
of HY80. This reduction in fracture toughness is accompanied by marked
increases in proof s t r e s s and hardness (Table 4). The high hardness
associated with predominantly martensitic structures, particularly in the
grain coarsened HAZ, indicates that precautions need to be taken to keep
hydrogen to a minimum in order to avoid HAZ cold cracking.
The Charpy data for the grain coarsened HAZ shows an energy
level slightly in excess of 41J (30 ft. lb. ) at -10 C which is above the 34J
(25 ft, lb. ) level considered necessary to indicate an NDT temperature below
-10 C, Thus, the probability of fractures initiating from small flaws in
the HAZ would appear to be small although more work is necessary to
confirm the correlation between the NDT temperature and the Charpy energy
level at this temperature and to investigate the variation in properties
between different casts of HY80.
to show that the lower Mn/S ratio and the higher Ni content of HY80 increases
the susceptibility to hot cracking, (Ref. 18).
Until these questions are answered it is not possible to state whether post-
weld heat treatment will be beneficial to the weldment as a whole. There is
an economic penalty to be paid for carrying out post-weld heat treatment so
that it is necessary to be able to show substantial benefit before the procedure
can be recommended. Heat treatments at other temperatures and times need
also to be examined in order to determine the optimum combination and the
degree of control which would be required. Accumulated experience with
structures and pressure vessels and information from full scale tests have
supported the position that HY80 weldments generally do not require s t r e s s -
relieving (Ref. 31). The satisfactory performance of the many welded but
non-stress relieved structures and vessels in HY80, stands as undeniable
evidence that the steel generally does not require post-weld heat treatment
(stress-relieving). The present work, although confined to a single cast of
HY80, has more or less substantiated this view.
5. CONCLUSIONS
1. A marked impairment of fracture toughness, as measured by the
Charpy V notch impact test, and hardnesses in excess of 400 HV5 occur in
the grain coarsened and grain refined regions of single-pass weld HAZs in
HY80 using a recommended heat input and preheat temperature of 2.1 kJ/mm
(54 kJ/in) and 120 C respectively. The structures produced are p r e -
dominantly martensitic in character and the mechanical properties
deteriorate with decreasing distance from the fusion boundary.
REFERENCES
H e l l e r , S. R. An evaluation of HY80 s t e e l a s a
F i o r i t i I. , and s t r u c t u r a l m a t e r i a l for s u b m a r i n e s ,
Vasta, J. Naval Eng. J n l . p. 29, F e b r u a r y , 1965.
p. 193, A p r i l , 1965.
B a k e r , R. G. , The m e t a l l u r g i c a l i m p l i c a t i o n s of
Wilkinson, F . , and welding p r a c t i c e a s r e l a t e d to low alloy
Newman, R. P . s t e e l s ; Second Commonwealth Welding
Conference, p. 125, 1965.
TABLE 1 Mechanical property data for as-cycled simulated specimens and the parent material.
M a t e r i a l Condition Te nsile Properties
UTS Reduction Mean H a r d n e s s ,
1st 2nd 0. 2% Proof S t r e s s
N/mm2 (tonf/in^) N/mm^ (tonf/in^) HV5
Cycle Cycle of A r e a
%
1100
1000
900
800
o 700
UJ
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300
200
100 \-
10 20 30 40 50 60 70 80
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