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Cronifer 1925 hMo is a superaustenitic stainless steel develo- ● virtual immunity under practical conditions to chloride-ion
ped by ThyssenKrupp VDM. By increasing the molybdenum stress-corrosion cracking
and nitrogen contents of Cronifer 1925 LC, a material with
● excellent general corrosion resistance in a wide range of
markedly improved properties was obtained. In particular,
media, both oxidizing and reducing
Cronifer 1925 hMo shows significantly higher resistance to
localized corrosion in halide media, with superior mechanical ● improved mechanical properties over Cronifer 1925 LC –
properties. alloy 904 L
● improved metallurgical stability over similar grades with
Cronifer 1925 hMo is characterized by:
only 18 % nickel
● very high resistance to pitting and crevice corrosion in hali-
de media and in H2S containing sour environments ● approved for pressure vessels by VdTÜV from -196 to
400 ˚C (-320 to 750 ˚F), and by ASME
Designations and standards
D W.-Nr. 1.4529
X1NiCrMoCuN 25-20-7 *
DIN EN 10028 -7 10028 -7
10088 -1 10088 -2 10088 -3 10088-2 10088-3
VdTÜV 502 502 502 502 502
BAM Material listed
in Sec. 6 of the BAM List
F
NF EN X1NiCrMoCuN 25-20-7 10088 -1 10088 -2 10088 -3 10088 -2 10088-3
UK
BS EN X1NiCrMoCuN 25-20-7 10088 -1 10088 -2 10088 -3 10088 -2 10088-3
ISO
Chemical composition
Ni Cr Fe C Mn Si Cu Mo P S N
Physical properties
0 32
Mechanical properties
The following properties are applicable to Cronifer 1925 hMo The values are valid for longitudinal and transverse
in the solution-annealed condition. (if size is sufficiently large) specimens.
Product 0.2 % Yield strength 1.0 % Yield strength Tensile strength Elongation
Rp0.2 Rp1.0 Rm A50
N/mm2 ksi N/mm2 ksi N/mm2 ksi %
Table 4 – Minimum mechanical properties (except for wire products) in the solution-annealed condition at room temperature according to ASTM.
Temperature 0.2 % Yield strength 1.0 % Yield strength Temperature Max. allowable stress values
Rp0.2 Rp1.0 N/mm2 ksi
°C °F N/mm 2
ksi N/mm 2
ksi °C °F 1) 1)
193 200 <235> <34.1> <284> <41.2> 138 100 26.9 23.5
100 212 <230 <33.4 <270 <39.1 193 200 <24.1 <26.9
200 392 <190 <27.6 <225 <32.6 100 212 <163> <185> <23.6> <26.8>
204 400 <189> <27.4> <224> <32.5> 149 300 <21.5 <26.2
300 572 <170 <24.7 <205 <29.7 200 392 <138> <172> <19.9> <24.9>
316 600 <169> <24.5> <202> <29.3> 204 400 <19.7 <24.8
400 752 <160 <23.2 <190 <27.6 260 500 <18.7 <23.7
< > values determined by interpolation or from graphs/diagrams 300 572 <125> <159> <18.2> <23.0>
Table 5 – Minimum short-time mechanical properties in the solution- 316 600 <18.0 <22.8
annealed condition at elevated temperatures according to VdTÜV data
343 650 <17.7 <22.4
sheet 502.
371 700 <17.5 <22.0
ISO V-notch impact toughness 400 752 <120> <149> <17.4 <21.6
Average value at RT: Notes:
longitudinal and transverse 150 J/cm2 < > values determined by interpolation or from graphs/diagrams
1)
Due to the relatively low yield strength of this material, the higher stress values
were established at temperatures where the short-time tensile properties
govern to permit the use of these alloys where slightly greater deformation is
acceptable. The higher stress values exceed 66 2/3 %, but do not exceed 90 %
of the yield strength at temperature. Use of these stresses may result in dimen
sional changes due to permanent strain. The higher stress values are not
recommended for flanges of gasketed joints or other applications where slight
amounts of distortion can cause leakage or malfunction.
Fig. 1– Critical Pitting Temperature (CPT) of Cronifer 1925 hMo in Fig.3– Isocorrosion diagram of Cronifer 1925 hMo - alloy 926 in lightly
10 % FeCI3 • 6 H2O test (acc. to ASTM G-48 C), compared to selected aerated, technical grade sulphuric acid based on immersion test results
stainless steels and nickel alloys. over at least 120 h.
6 Cronifer ® 1925 hMo – alloy 926
● components for flue-gas desulphurization plants, such as For heating up, workpieces may be charged into the furnace
dampers and stacks. at maximum working temperature. When the furnace has
returned to temperature, the workpieces should be soaked
● evaporators, heat exchangers, filters and mixers used in for 60 minutes per 100 mm (4 in.) of thickness. At the end
the manufacture of phosphoric acid of
● sulphuric acid distribution systems and coolers this period it should be withdrawn immediately and worked
within the above temperature range.
● concentration and crystallization of salts by evaporation
Solution annealing is required after hot working to ensure
● condensers and piping systems in power stations using maximum corrosion resistance and optimum properties.
polluted cooling waters
● containers for transportation of aggressive chemicals Cold working
For cold working the material should be in the solution-anne-
● production of organic derivatives with acid chloride aled condition. Like all austenitic chromium-nickel stainless
catalysts steels, Cronifer 1925 hMo rapidly work hardens. This should
● reverse-osmosis desalination plant be taken into account when selecting forming equipment.
Interstage annealing may be necessary with high degrees of
Fabrication and heat treatment cold forming.
Cronifer 1925 hMo can readily be hot and cold worked and After cold reductions of more than 15 %, a solution anneal is
machined. Hot and cold working, however, require high- required before use.
power machines, owing to the high strength of the material.
Heat treatment
Heating Solution heat treatment should be carried out in the
Workpieces must be clean and free from all kinds of contam- temperature range 1150 to 1200 ˚C (2100 to 2190 ˚F).
inants before and during any heat treatment. Water quenching is recommended for thicknesses above
Cronifer 1925 hMo may become embrittled if heated in the about 1.5 mm (1/16 in.), and is essential for maximum corro-
presence of contaminants such as sulphur, phosphorus, lead sion resistance. Below 1.5 mm, rapid air cooling may suffi-
and other low-melting-point metals. Sources of such con- ce.
tam-inants include marking and temperature-indicating For any thermal treatment the material should be charged
paints and crayons, lubricating grease, fluids and fuels. into the furnace at maximum heat treatment temperature
observing the precautions concerning cleanliness mentioned
earlier under ‘Heating’.
7
Filler metal
For the gas-shielded welding processes, the following filler
metals are recommended:
Bare electrodes: Nicrofer S 5923 – FM 59
W.-No. 2.4607
SG-NiCr23Mo16
AWS A5.14: ERNiCrMo-13
Straightbutt
Straight buttweld
weld
or
Sheet thickness
Sheet thickness up mm
up to 2.5 to 2.5
(<mm
0.10 in.) Nicrofer S 6020 – FM 625
W.-No. 2.4831
Single-Vweld
Single-V weld SG-NiCr21Mo9Nb
AWS A5.14: ERNiCrMo-3
60 --70°
60 70° Sheet/platethickness
Sheet/plate
thickness
2.5 2.5
- 15 mm - 15– mm
(0.1 5/8 in.)
Covered electrodes: W.-No. 2.4609
EL-NiCr22Mo16
AWS A5.11: ENiCrMo-13
approx.22mm
approx. mm
up to 2 mm
0 - 2 mm (0 – .08 in.) or
W.-No. 2.4621
Single-Uweld
Single-U weld EL-NiCr20Mo9Nb
1155°° Platethickness
Plate thickness
12-25mm
12-25 mm(1/2 – 1 in.) AWS A5.11: ENiCrMo-3
R=6
R=6
Welding parameters and influences (heat input)
Care should be taken that the work is performed with a deli-
approx.22mm
approx. mm approx. 1.5 mmapprox. 1.5 mm
(.06 in.) berately chosen, low heat input as indicated in Table 8 by
way of example. Use of the stringer bead technique should
Double-Vweld
Double-V weld be aimed at. Interpass temperature should be kept below
Platethickness
Plate thickness 150 °C (300 °F).
60 --70°
60 70° 16--25
16 25mm
mm(5/8 – 1 in.)
The welding parameters should be monitored as a matter of
principle.
The heat input Q may be calculated as follows:
upto
up to22mm
mm
approx.22mm
approx. mm (< .08 in.) U = arc voltage, volts
U x I x 60
Q = (kJ/cm) I = welding current, amps
v x 1000 v = welding speed, cm/min.
Double-Uweld
Double-U weld
1155°°
above
Plate 25 mm
thickness Consultation with ThyssenKrupp VDM’s Welding Laboratory
>plate
25 mmthickness
(> 1 in.)
is recommended.
R=6
R=6
Postweld treatment
(brushing, pickling and thermal treatments)
2 mm
2 mm
approx.22mm
approx. mm (.08 in.) Brushing with a stainless steel wire brush immediatly after
welding, i.e. while the metal is still hot generally results
in removal of heat tint and produces the desired surface
condition without additional pickling.
Pickling, if required or prescribed, however, would generally
be the last operation performed on the weldment. Also refer
to the information under ‘Descaling and pickling’.
Fig. 4 – Edge preparation for welding of nickel alloys and special
stainless steels. Neither pre- nor postweld thermal treatments are required.
9
Sheet/ Welding Filler metal Welding parameters Welding Flux/ Plasma- Plasma-
plate process Diameter Speed Root pass Intermediate and speed shielding gas rate nozzle
thick- final passes gas diameter
ness rate
mm mm m/min. A V A V cm/min. l/min. l/min. mm
GTAW 8 – 10
6.0 Manual 2.0 – 2.4 100 –110 10 120 – 130 12 10 – 15 Ar W31)
GTAW 8 – 10
8.0 Manual 2.4 110 –120 11 130 – 140 12 10 – 15 Ar W31)
GTAW 8 – 10
10.0 Manual 2.4 110 –120 11 130 – 140 12 10 – 15 Ar W31)
GTAW 8 – 10
3.0 Autom. 1.2 0.5 manual 150 10 25 Ar W31)
GTAW 15 – 20
5.0 Autom. 1.2 0.5 manual 150 10 25 Ar W31)
GTAW 15 – 20
2.0 Hot wire 1.0 0.3 180 10 80 Ar W31)
GTAW 15 – 20
10.0 Hot wire 1.2 0.45 manual 250 12 40 Ar W31)
GTAW 15 – 20
4.0 Plasma 1.2 0.5 165 25 25 Ar W31) Ar W31) 3.2
arc 30 3.0
6.0 Plasma 1.2 0.5 190 –200 25 25 Ar W31) Ar W31) 3.2
arc 30 3.5
8.0 MIG/MAG 1.0 approx. GTAW 130 –140 23 –27 24 –30 MAG2)
GMAW 8 MIG: argon
18 –20
10.0 MIG/MAG 1.2 approx. GTAW 130 –150 23 –27 20 –26 MAG2)
GMAW 5 MIG: argon
18 –20
12.0 Submerged 1.6 and backing GTAW 240 –280 28 45 –55 highly
arc basic
20.0 Submerged 1.6 and backing GTAW 240 –280 28 45 –55 highly
arc basic
6.0 SMAW 2.5 40 – 70 approx. 40 –70 approx.
21 21
8.0 SMAW 2.5–3.25 40 – 70 approx. 70 –100 aprrox.
21 22
16.0 SMAW 4.0 90 – 130 approx.
22
1)
Argon or argon + max. 3 % hydrogen
2)
For MAG welding use of the shielding gas Cronigon He30S or Argomag-Ni, for example is recommended.
In all gas-shielded welding operations, ensure adequate back shielding.
These figures are only a guide and are intended to facilitate setting of the welding machines.
Welding process Heat input per unit length Welding process Heat input per unit length
kJ/cm kJ/cm
GTAW, manual, fully mechanised max. 8 GMAW, MIC/MAG, manual, fully mechanised max. 11
Hot wire GTAW max. 6 SMAW, manual metal arc (MMA) max. 7
Plasma arc max. 10 Submerged arc max. 10
Product Weight Thickness o. d.1) i. d.1) 0.02 ≤ 0.10 4 – 200 4) 300 400
kg mm mm mm
> 0.10 ≤ 0.20 4 – 350 4)
300 400 500
Disc ≤ 10000 ≤ 300 ≤ 3000 > 0.20 ≤ 0.25 4 – 750 400 500 600
Ring ≤ 13000 ≤ 200 ≤ 2500 on request > 0.25 ≤ 0.60 5 – 750 400 500 600
The information contained in this data sheet is based on results of research and
development work available at the time of printing and does not provide any
guarantee of particular characteristics or fit. ThyssenKrupp VDM reserves the right
to make changes without notice. The data sheet has been compiled to the best
knowledge of ThyssenKrupp VDM and is given without any liability on the part of
ThyssenKrupp VDM. ThyssenKrupp VDM is only liable according to the terms of the
sales contract and in particular to the General Conditions of Sales in case of any
delivery from ThyssenKrupp VDM.
As updates of data sheets are not automatically send out, when issued,
ThyssenKrupp VDM recommends to request the latest edition of required data
sheets either by phone +49 (0)2392 55 - 2493, by fax +49 (0)2392 55 - 2111 or
by E-mail under info@tks-vdm.thyssenkrupp.com.
February 2003 Edition.
This edition supersedes material data sheet no. 5002, dated September 1999.
Imprint
Date of publication
February 2003
Publisher
VDM Metals GmbH
Plettenberger Straße 2
58791 Werdohl
Germany
Disclaimer
All information contained in this data sheet are based on the results of research and
development work carried out by VDM Metals GmbH, and the data contained in the
specifications and standards listed available at the time of printing. The information
does not represent a guarantee of specific properties. VDM Metals reserves the
right to change information without notice. All information contained in this data
sheet is compiled to the best of our knowledge and is provided without liability.
Deliveries and services are subject exclusively to the relevant contractual conditions
and the General Terms and Conditions issued by VDM Metals GmbH. Use of the
most up-to-date version of this data sheet is the responsibility of the customer.
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www.vdm-metals.com