Chemistry (P-2) Question Paper

Major Test – 4 : Chemistry (Paper - 2) Code - 21
PART (B) : CHEMISTRY

SECTION-1 : (Maximum Marks : 18)
 This section contains SIX (06) questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, BOTH INCLUSIVE.
 For each question, enter the correct integer corresponding to the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : –1 In all other cases.
19. The general electronic configuration of outer most and penultimate shell is given as
(n 1)s2 (n 1)p6 (n 1)d x ns 2 . Then for an element with n = 4 and x = 6. The number of unpaired
electrons in the divalent cation of the given element in isolated gaseous state is
20. A compound exists in the gaseous state both as a monomer (A) and dimer (A2). The molecular weight
of the monomer is 48 amu. In an experiment, 96 g of the compound was confined in a vessel of volume
33.6 litres and heated to 273° C. Calculate the pressure (in atm) developed, if the compound exists as
a dimer to the extent of 50 per cent by weight, under these conditions. (R = 0.082)
21. Calculate the millimoles of Br2 produced when 10 ml of 0.1 M BrO3 reacts with excess of Br  .
22. Find out the total number of cyclic isomers of C6H12, which are optically active?
SPACE FOR ROUGH WORK
CENTERS: MUMBAI / DELHI / AKOLA / LUCKNOW / NAGPUR / NASHIK / PUNE / GOA / BOKARO / DUBAI # 9
23. How many of the given molecule/species are chiral :

Cl
CH3
Cl Cl
(I) (II) (III) H3C
C
OH
Br OH
OH Br
COOH CH3
(IV) HOOC (V) (VI) H C
3
OH F F
OH
Cl
(VII) (VIII) (IX) CH4

HO
OH
24. The number of diastereoisomers (excluding enantiomers) for 1-bromo-2-chloro-3-iodocyclopropane.
 This section contains SIX (06) questions.

 Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct
answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chose (i.e. the question is unanswered);
Negative Marks : –2 In all other cases
25. Ionisation energy order is CORRECT for:

(A) Sc3+ > Sc2+ > Sc+ (B) Sc3+ > Ti4+ > V5+
(C) Sc > Y > La (D) Sc > Ca > K
26. A solution is prepared by dissolving a solid mixture of K2C2O4 and KHC2O4. A 10 mL portion of this
solution required 10 mL of 0.05 M KOH solution. In a separate analysis, 10 mL of the same stock
solution required 25 mL of a 0.10 M HCl solution. Find out correct statement(s)?
(A) The mixture has K2C2O4 and KHC2O4 is 2 : 1 molar ration.
(B) The mixture has equimolar amounts of the two salts.
(C) 5 mL of the same stock solution would require 15 mL of a 0.02 M acidified dichromate solution.
(D) 8 mL of the same stock solution would require 24 mL of a 0.02 M acidified permanganate
solution.
27. Following two equilibrium is simultaneously established in a container

PCl5  g  PCl3  g   Cl 2  g 
CO  g   Cl 2  g  COCl 2  g 
If some Ni(s) is introduced in the container forming Ni(CO)4 (g) then at new equilibrium
(A) PCl3 concentration will increase (B) PCl3 concentration will decrease
(C) Cl2 concentration will remain same (D) CO concentration will remain same
28. Choose correct statement(s).

(A) Conjugate of a weak acid is a strong base
(B) Conjugate of a weak acid is a weak base
(C) Conjugate of a weak base is a strong acid
(D) Conjugate of a weak base is a weak acid
29. Which of the following is/are correct order?
(A) Stability of carbocation > C6H5CH 2 > H2C CH CH 2
COOH COOH
NO 2
(B) Acidic strength <
NO 2
NH 2
(C) Basic strength >

N
H
NH 2 NH 2
(D)
Bond length (C – N) <
H2C O
30. Which of the following compounds is optically inactive ?

Cl Br Br Cl
OH
(A) (B)
OH
CH3 I I H3C
Br
OHC CH3 CH 3O CH3
(C) (D) C
F CN Br CH 2Br
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the
second decimal place; e.g. 6.25, 7.00, 0.33, 30.27, 127.30) designated to enter the answer.
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.
31. One mole ideal nonoatomic gas is heated according to path AB and AC. If temperature of state B and
q
state C are equal. Calculate AC .
q AB
32. What will be the pH of an aqueous solution of 1.0 M ammonium formate?

Given : pKa = 3.8 and pKb = 4.8
33. To measure the quantity of MnCl2 dissolved in an aqueous solution, it was completely converted to
KMnO4 using the reaction,
MnCl2 + K2S2O8 + H2O  KMnO4 + H2SO4 + HCl (equation not balanced).
Few drops of concentrated HCl were added to this solution and gently warmed. Further, oxalic acid
(225 mg) was added in portions till the colour of the permanganate ion disappeared. The quantity of
MnCl2 (in mg) present in the initial solution is _________ . (Atomic mass of Mn = 55 and Cl = 35.5)
34. How many cyclopentane structures (including stereoisomers) are possible for C7H14 ?
35. Find total number of optical active isomers in following reaction is?
H3C CH3
Cl 2 / hv
Mixture of monochlorinated products
36. Consider following compounds :
 
Number of compounds which are more basic than HC  C Na are :

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Major Test – 4 : Chemistry (Paper - 2) Code - 21

PART (B) : CHEMISTRY

SPACE FOR ROUGH WORK

23. How many of the given molecule/species are chiral :

(VII) (VIII) (IX) CH4

24. The number of diastereoisomers (excluding enantiomers) for 1-bromo-2-chloro-3-iodocyclopropane.

SPACE FOR ROUGH WORK

SECTION-2 : (Maximum Marks : 24)

 This section contains SIX (06) questions.

25. Ionisation energy order is CORRECT for:

SPACE FOR ROUGH WORK

27. Following two equilibrium is simultaneously established in a container

28. Choose correct statement(s).

SPACE FOR ROUGH WORK

29. Which of the following is/are correct order?

(A) Stability of carbocation > C6H5CH 2 > H2C CH CH 2

(B) Acidic strength <

(C) Basic strength >

SPACE FOR ROUGH WORK

30. Which of the following compounds is optically inactive ?

SPACE FOR ROUGH WORK

SECTION-3 : (Maximum Marks : 24)

32. What will be the pH of an aqueous solution of 1.0 M ammonium formate?

SPACE FOR ROUGH WORK

36. Consider following compounds :

SPACE FOR ROUGH WORK

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