Analisis Termal

Diskusi Tugas 2
 Heat Deflection Temperature (HDT)
ASTM D648
◼ Suhu dimana material mulai mengalami perubahan
bentuk akibat pengaruh beban tekuk (0.455 MPa)
dan panas
◼ Sbg batasan suhu aplikasi
◼ semakin tinggi HDT : semakin tahan terhadap
suhu tinggi.
◼ Aplikasi: microwaveable plastics
 Vicat Softening Point (VSP)
ASTM D1525B
◼ Suhu dimana mulai mengalami pelunakan
◼ semakin tinggi VSP maka semakin tahan
temperatur tinggi
Differential Scanning Calorimetry (DSC)
ASTM D3418 (at 10°C/min)
 DSC on Polymer
◼ Glass transition temperature (Tg)
◼ Melting points (Tm)
◼ Crystallization time and temperature (Tc)
◼ Percent crystallinity
◼ Heat capacity
◼ Oxidative stability
◼ Purity
Tg on Polymers
Plasticizers on Plastics
Thermogravimetric Analysis (TGA)
 TGA
◼ Quantify the main composition (inorganic and organic)
◼ Weight percentage of compounds
◼ Degradation temperatures
◼ Thermal stability and decompositions
◼ Residual solvents and VOC
◼ Moisture analysis
◼ Organic and inorganic filler
Polymer/Inorganic Materials Thermal Behaviour
HDPE
Scrap (mix HDPE + MB 5%)
 HDPE

Scrap (HDPE+MB 5%)

 DSC
(Differential Scanning Calorimetry)
Material Tm (oC) Tc (oC) Peak Area Tc
HDPE ABC 135.56 111.29 2715.883
MB Black CDE 127.97 108.31 356.279
HDPE + MB 5% 131.32 114.50 188.699

ASTM D 3418-99
-preliminary thermal: heat up to 200oC (10oC/min), cool down to 50oC (10oC/min), inert N2 gas
-analyze : heat up to 600oC (10oC/min), inert N2 gas
 DSC
(Differential Scanning Calorimetry)
Material Tm (oC) Tc (oC) Peak Area Tc
HDPE ABC 135.56 111.29 2715.88
MB Black CDE 127.97 108.31 356.28
Scrap (HDPE + MB 5%) 131.32 114.50 188.70
Sampel 1 H:B:C (95:5:0) 139.18 108.29 1021.66
Sampel 2 H:B:C (91:5:4) 139.81 106.94 1260.22
Sampel 3 H:B:C (88:5:7) 140.35 106.86 1681.95
PP antishagging SGC 142.11 107.74 2570.54
ASTM D 3418-99
-preliminary thermal: heat up to 200oC (10oC/min), cool down to 50oC (10oC/min), inert N2 gas
-analyze : heat up to 600oC (10oC/min), inert N2 gas
 Recommendation
• Penurunan suhu proses barrel &/ die
• Cooling secara bertahap bukan quenching
• + aditif untuk meningkatkan Tc (nucleating
agent)
 Tugas 3
◼ 1. Buat essai , min 200 words, beri tanggapan dan solusinya
dari sisi keilmuan anda sebagai seorang analis kimia
https://youtu.be/Y555v_pCtIA
https://youtu.be/zjh4zihwMWw
https://youtu.be/KpgcvujGPhs