Capacity 70000.

00 MT/yr
8750.00 kg/hr
Operational Hours 8000.00 hr/yr
Feed Flow Rate 15000.00 kg/hr
Glycerol/Water 2.00

Mixer M-101

Stream 1 (Crude Glycerol)

Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 12000.00 0.80 130.43 0.48
Methanol 150.00 0.01 4.69 0.02
Water 2250.00 0.15 125.00 0.46
NaCl 600.00 0.04 10.26 0.04
15000.00 1.00 270.38 1.00

Electrodeionization

Stream 3
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 12000.00 0.27 130.43 0.07
Methanol 150.00 0.00 4.69 0.00
Water 32250.00 0.72 1791.67 0.92
NaCl 600.00 0.01 10.26 0.01
45000.00 1.00 1937.05 1.00

Distillation Column D-201

Component Top Bottom

Glycerol 0.995
Methanol 1.000
Water 0.995
NaCl

Stream 9
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 60.00 0.002 0.65 0.000
Methanol 150.00 0.005 4.69 0.003
Water 32088.75 0.993 1782.71 0.997
NaCl 0.00 0.000 0.00 0.000
32298.75 1.000 1788.05 1.000
Hydrogen Stream
H2/Glycerol 5.00

Stream 17 (Pure Hydrogen)

Component Mass Flow Mass Fr. Mole FlowMole Fr.
Hydrogen 1297.83 1.000 648.91 1.000

Reactor R-301

Conversion 81.5% Rxn # Extent

Selectivity 77.83 1 105.77
2 104.43

Stream 20
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Hydrogen 1297.83 1.000 648.91 1.000

Separator F-301

Stream 22
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 2208.90 0.185 24.01 0.104
Water 1858.64 0.156 103.26 0.447
Hydrogen 0.00 0.000 0.00 0.000
Acetol 94.32 0.008 1.27 0.006
Propylene Glycol 7778.03 0.651 102.34 0.443
Total 11939.90 1.00 230.88 1.00

Separator F-302

Stream 25
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 0.00 0.000 0.00 0.000
Water 196.19 0.548 10.90 0.836
Hydrogen 0.00 0.000 0.00 0.000
Acetol 4.87 0.014 0.07 0.005
Propylene Glycol 157.15 0.439 2.07 0.159
Total 358.20 1.00 13.03 1.00
Separator F-303

Stream 29
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 0.00 0.000 0.00 0.000
Water 10.33 0.860 0.57 0.963
Hydrogen 0.00 0.000 0.00 0.000
Acetol 0.10 0.008 0.00 0.002
Propylene Glycol 1.59 0.132 0.02 0.035
Total 12.01 1.00 0.60 1.00

Mixer M-401

Stream 32
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 2208.90 0.179 24.01 0.098
Water 2065.16 0.168 114.73 0.469
Acetol 99.29 0.008 1.34 0.005
Propylene Glycol 7936.76 0.645 104.43 0.427
Total 12310.11 1.00 244.51 1.00

Distillation Tower D-401

Component Top Bottom

Glycerol
Water
Acetol
Propylene Glycol

Stream
Component Mass Flow Mass Fr. Mole FlowMole Fr.
Glycerol 0.00 0.000 0.000
Water 0.00 0.000 0.000
Acetol 0.00 0.000 0.000
Propylene Glycol 0.00 0.000 0.000
Total 0.00 0.00 0.00
 Stream 2 (Fresh Water) Stream 12 (R
Component Mass Flow Mass Fr. Mole Flow Mole Fr. Component
Glycerol 0.00 0.00 0.00 0.00 Glycerol
Methanol 0.00 0.00 0.00 0.00 Methanol
Water 30000.00 1.00 1666.67 1.00 Water
NaCl 0.00 0.00 0.00 0.00 NaCl
30000.00 1.00 1666.67 1.00

Stream 4 Stream
Component Mass Flow Mass Fr. Mole Flow Mole Fr. Component
Glycerol 0.00 0.00 0.00 0.00 Glycerol
Methanol 0.00 0.00 0.00 0.00 Methanol
Water 0.00 0.00 0.00 0.00 Water
NaCl 600.00 1.00 10.26 1.00 NaCl
600.00 1.00 10.26 1.00

Stream 14
Component Mass Flow Mass Fr. Mole Flow Mole Fr.
Glycerol 11940.00 0.99 129.78 0.94
Methanol 0.00 0.00 0.00 0.00
Water 161.25 0.01 8.96 0.06
NaCl 0.00 0.00 0.00 0.00
12101.25 1.00 138.74 1.00
 Stream 31 (Recycle Hydrogen)
Component Mass Flow Mass Fr. Mole Flow Mole Fr.
Hydrogen 0.00 1.000 0.00 1.000

Stream 21
Component Mass Flow Mass Fr. Mole Flow Mole Fr.
Glycerol 2208.90 0.165 24.01 0.030
Water 2065.16 0.154 114.73 0.145
Hydrogen 1088.96 0.081 544.48 0.690
Acetol 99.29 0.007 1.34 0.002
Propylene Glycol 7936.76 0.592 104.43 0.132
Total 13399.08 1.00 789.00 1.00

Stream 23
Component Mass Flow Mass Fr. Mole Flow Mole Fr.
Glycerol 0.00 0.000 0.00 0.000
Water 206.52 0.142 11.47 0.021
Hydrogen 1088.96 0.746 544.48 0.976
Acetol 4.96 0.003 0.07 0.000
Propylene Glycol 158.74 0.109 2.09 0.003
Total 1459.18 1.00 558.11 1.00

Stream 26
Component Mass Flow Mass Fr. Mole Flow Mole Fr.
Glycerol 0.00 0.000 0.00 0.000
Water 10.33 0.009 0.57 0.001
Hydrogen 1088.96 0.989 544.48 0.999
Acetol 0.10 0.000 0.00 0.000
Propylene Glycol 1.59 0.001 0.02 0.000
Total 1100.98 1.00 545.08 1.00
 Stream 30
Component Mass Flow Mass Fr. Mole Flow Mole Fr.
Glycerol 0.00 0.000 0.00 0.000
Water 0.00 0.000 0.00 0.000
Hydrogen 1088.96 0.989 544.48 1.000
Acetol 0.00 0.000 0.00 0.000
Propylene Glycol 0.00 0.000 0.00 0.000
Total 1088.96 0.99 544.48 1.00

Stream
Component Mass Flow Mass Fr. Mole Flow Mole Fr.
Glycerol 0.00 0.000 0.000
Water 0.00 0.000 0.000
Acetol 0.00 0.000 0.000
Propylene Glycol 0.00 0.000 0.000
Total 0.00 0.00 0.00
 Component Molar Flow
Glycerol 92.00
Methanol 32.00
Water 18.00
NaCl 58.50
Hydrogen 2.00
Acetol 74.00
Propylene Gly76.00
Stream 12 (Recycle)
Mass Flow Mass Fr. Mole Flow Mole Fr.
0.00
0.00
1.00
0.00
0.00 1.00 0.00 0.00

Stream 5
Mass Flow Mass Fr. Mole Flow Mole Fr. Component Stream 4
12000.00 0.27 130.43 0.07 Glycerol 0.00
150.00 0.00 4.69 0.00 Methanol 0.00
32250.00 0.73 1791.67 0.93 Water 0.00
0.00 0.00 0.00 0.00 NaCl 1.00
44400.00 1.00 1926.79 1.00
Component Sep
Glycerol 0.00
Water 0.10
Hydrogen 1.00
Acetol 0.05
Propylene Gl0.02

Component Sep
Glycerol 0.00
Water 0.05
Hydrogen 1.00
Acetol 0.02
Propylene Gl0.01
Component Sep
Glycerol 0.00
Water 0.00
Hydrogen 1.00
Acetol 0.00
Propylene Gl0.00
Molar Flow