Ex.

No:01 RECRYSTALLIZATION

Report: The given impure aspirin sample was purified and its melting point
was found to 134C.

Ex.No:03 DETERMINATION OF ACID VALUE

LEFT HAND SIDE

Standardization of potassium hydroxide:

Strength of potassium hydroxide = 0.1072M
Determination of Acid value:
S.No Content of Volume of Indicator
iodine flask Burette reading potassium & Endpoint
Initial Final hydroxide
volume volume
1. 10 g of ground 0 ml 8.9 ml 8.9 ml – 0.6 Phenolphthalein
nut oil & 50 ml ml = 8.3 ml & Appearance
mixture of of pale pink
ethanol and colour
ether
2. 50 ml mixture of 0 ml 0.6 ml
ethanol and
ether

5.61 x Volume of potassium hydroxide consumed x

Acid value of given Strength of potassium hydroxide
sample = _______________________________________________________
weight of substance (gm)

5.61 x 8.3 ml x 0.1072 M

Acid value of given
________________________________________________
sample =
10 gm

Acid value of given sample = 0.499

Report: The acid value of the given oil sample was found to be 0.499
Ex.No:04 DETERMINATION OF SAPONIFICATION VALUE
LEFT HAND SIDE

Standardization of hydrochloric acid:

Strength of hydrochloric acid = 0.5208 M
Determination of Saponification value:
S.No Content of Volume of Indicator
iodine flask Burette reading hydrochloric & Endpoint
Initial Final acid
volume volume
1. 2 g of Castrol oil 0 ml 22.8 ml 37.4 ml – 22.8 Phenolphthalein
& 25 ml of 0.5 ml = 14.6 ml & Appearance
M ethanolic of pale pink
potassium colour
hydroxide
solution
2. 25 ml of 0.5 M 0 ml 37.4 ml
ethanolic
potassium
hydroxide
solution

28.05 x Volume of hydrochloric acid consumed x

Saponification
Strength of hydrochloric acid
value of given
_______________________________________________________
sample =
weight of substance (gm)

Saponification 28.05 x 14.6 ml x 0.5208 M

value of given _______________________________________________________
sample = 2 gm
Saponification value of given sample = 106.64

Report: The saponification value of the given oil sample was found to be 106.64
Ex.No:05 DETERMINATION OF IODINE VALUE
LEFT HAND SIDE

Standardization of sodium thiosulphate:

Strength of sodium thiosulphate = 0.1022M
Determination of Iodine value:
S.No Content of Volume of Indicator
conical flask Burette reading sodium & Endpoint
Initial Final thiosulphate
volume volume
1. 0.2 g of Castrol 0 ml 17.6 ml 30. ml – 17.6 Starch
oil & 10 ml of ml = 12.9 ml mucilage &
carbon disappearance
tetrachloride & of blue colour
20 ml of iodine
monochloride &
15 ml of
potassium
iodide solution
2. 10 ml of carbon 0 ml 30.5 ml
tetrachloride &
20 ml of iodine
monochloride &
15 ml of
potassium
iodide solution

1.269 x Volume of sodium thiosulphate consumed x

Iodine value of Strength of sodium thiosulphate
given sample = _______________________________________________________
weight of substance (gm)

1.269 x 12.9 ml x 0.1022 M

Iodine value of
_______________________________________________
given sample =
0.2 gm

Iodine value of given sample = 8.365

Report: The iodine value of the given oil sample was found to be 8.365
Ex.No:06 PREPARATION OF BENZANILIDE
Melting point of of benzalinide was found to be 160C

Ex.No:07 PREPARATION OF 2.4.6-TRIBOMOANILINE

Melting point of 2,4,6-tribromoanline was found to be 118C

Ex.No:09 PREPARATION OF DINITROBENZENE

Melting point of m-dinitrobenzene was found to be 88C

Ex.No:10 PREPARATION OF BENZOIC ACID

Melting point of benzoic acid was found to be 122C

Ex.No:11 PREPARATION OF SALICYLIC ACID

Melting point of salicyclic acid was found to be 158C

Ex.No:12 PREPARATION OF 1-PHENYL AZO-2-NAPTHOL

Melting point of 1-phenyazo-2-naphthol was found to be 162C

Ex.No:13 PREPARATION OF BENZIL

Melting point of benzil was found to be 94C

Ex.No:14 PREPARATION OF DIBENZALACETONE

Melting point of dibenzalacetone was found to be 110C

Ex.No:15 PREPARATION OF CINNAMIC ACID

Melting point of cinnamic acid was found to be 132C