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Water Research 89 (2016) 87e106

Contents lists available at ScienceDirect

Water Research
journal homepage: www.elsevier.com/locate/watres

Review

Desalination and sustainability e An appraisal and current perspective


Veera Gnaneswar Gude
Department of Civil and Environmental Engineering, Mississippi State University, MS 39762, USA

a r t i c l e i n f o a b s t r a c t

Article history: Desalination technologies have evolved and advanced rapidly along with increasing water demands
Received 11 July 2015 around the world since 1950s. Many reviews have focused on the techno-economic and environmental
Received in revised form and ecological issues of the desalination technologies and emphasized the feasibility of desalination
26 October 2015
industry as an alternative to meet the water demands in many water scarce regions. Despite these efforts,
Accepted 5 November 2015
Available online 12 November 2015
many perceptions about desalination processes hinder their applications for potential water supplies.
This article has two specific aims: 1) provide an overview of the desalination trends around the world
and discuss the sustainability components of desalination processes in comparison with other water
Keywords:
Desalination
supply alternatives; and 2) discuss case studies for desalination, and drivers and factors that influence
Sustainability sustainable desalination and other alternative water sources for desalination to increase our current
Environmental impacts understanding on the sensitive and futuristic issues of water supply and resource management options
Socioeconomics for drought facing regions. Although some of the facts and recent developments discussed here show
Water transport that desalination can be affordable and potentially sustainable, contributions that meaningfully address
Social acceptance socio-economic and ecological and environmental issues of desalination processes are urgently required
in this critical era of severe water stress for the present context and the future development of desali-
nation technologies.
© 2015 Elsevier Ltd. All rights reserved.

Contents

1. Introduction (“oilewater” relation) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88


2. Worldwide desalination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
2.1. Desalination technologies and renewable energy sources . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
2.2. Current trends in desalination industry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
2.3. Recent developments in desalination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
3. Sustainability of desalination technologies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
3.1. Economics of desalination and other alternatives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
3.1.1. Conventional water supplies vs. desalination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
3.1.2. Water transportation costs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
3.2. Energy, environmental, and ecological considerations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
3.2.1. Energy budget for a small RO desalination plant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
3.2.2. Environmental issues of desalination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
3.2.3. Environmental emission comparison with large dams and wastewater systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
3.2.4. Ecological impacts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
3.3. Social issues . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
4. Desalination out of desperation e case studies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
4.1. Desalination in California, USA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
4.1.1. Energy requirements for different water supply options in CA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
4.2. Desalination in Australia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
4.3. Desalination in Singapore . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99
4.4. Desalination in China . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99

E-mail addresses: gude@cee.msstate.edu, gudevg@gmail.com.

http://dx.doi.org/10.1016/j.watres.2015.11.012
0043-1354/© 2015 Elsevier Ltd. All rights reserved.
88 V.G. Gude / Water Research 89 (2016) 87e106

4.5. Desalination in Saudi Arabia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100


4.6. Desalination market around the world . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
5. Affordable desalination e a worldwide scenario . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
6. What drives desalination? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
7. Other alternatives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
8. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104

1. Introduction (“oilewater” relation) existing water supply options. Environmental (including energy
and ecological), economic and social aspects of desalination sys-
Water, in general, has evolved as a social and economic com- tems have been discussed. A few case studies have been provided to
modity in many parts of the world (Rogers et al., 1998, 2005) and it elaborate the role of desalination industry in this ever water-
has gained the socioeconomic status of energy sources such as “oil”. challenging and climate changing world.
Water, the primary basis for continued sustenance of all life, cannot
be exactly matched in its quality with any other element present on 2. Worldwide desalination
the Earth. While water and oil have some common features that are
critical to human civilization, a few special characteristics of water While desalination of saline waters has now been accepted as a
as a commodity make it even more precious for our sustainable promising alternative for freshwater source, the energy demands
development: 1) to handle the shortfall of oil resources, there are by the existing desalination technologies for water production
many alternative energy sources that can replace and fill the gap continue to pose challenges in their applications. In general,
between supply and demand, however, the same is impossible for desalination technologies require large quantities of high grade
water, water cannot be replaced with other resources, 2) oil re- thermal energy and/or prime quality electricity for freshwater
serves are finite and non-renewable (at least in human life-cycle separation which results in release of waste heat, greenhouse gas
scale) whereas water resources are renewable and follow certain emissions and concentrates (brine) into the environment. The
cyclic process in which it can neither be destroyed nor created and worldwide desalination capacity is increasing at a steadfast pace
its presence varies along the regions of the world, and 3) oil consuming equivalent amounts of fossil fuel sources with
shortage can be managed in many parts of the world by trans- concomitant greenhouse gas emissions. In 2007, the total installed
porting to the place of need due to its high monetary value for desalination capacity around the world was 47.6 million m3/d, in
economic benefit, which may not be an attractive option for water 2008 it was 58 million m3/d, and in 2011 it reached to 65.2 million
transportation and therefore water issues are local in nature and m3/d and then to 74.8 million m3/d in 2012 which is projected to
are dealt with local water and energy sources (Savenije, 2002). increase to 97.5 million m3/d by the year 2015 (Bennett, 2013).
The importance and value of water has been highly pronounced While global population increased in a linear trend over the past
in recent years due to ever-growing global population, rapid five decades, water production by desalination technologies has
industrialization and urbanization (Gude, 2015a). Over the past taken an exponential path. The production of 1000 tons (m3) per
century, the worldwide population has tripled while the water use day of freshwater by desalination technologies requires 10,000
or water withdrawals increased more than six-fold which suggests tons (toe) of oil per year and results in environmental degradation
increasing water consumption mostly driven by improved living through greenhouse gas emissions and brine discharges
standards and industrialization all over the world. Many regions (Kalogirou, 2005; Gude, 2015a). This situation can be termed as
realize the inadequacy of existing freshwater sources to meet ever “oil for water” or “water for non-renewable energy” sources or
growing water demands. In some cases, sufficient surface and water being named as “the new oil” indicating a pressing demand
ground water sources to even meet current demands for water on the exhaustible fossil fuel reserves around the world. This sit-
supplies are not available. Therefore, the need for utilizing saline uation creates social and economic impacts such as dependence
waters from the oceans and other brackish water sources and the on the oil rich foreign countries and economic instability for both
processes that convert saltwater into freshwater have become oil-rich and water-rich countries. Since oil rich countries will
rational and logical approaches in these regions (Gude and experience high demands for oil supplies and similarly water rich
Nirmalakhandan, 2010). Desalination technologies have been countries for water supplies.
developed over the past 50 years (Semiat, 2000). Desalination
technologies initially were both cost- and energy- prohibitive. 2.1. Desalination technologies and renewable energy sources
However, the impetus to install desalination plants in many coastal
and metropolitan cities for providing freshwater needs stems from: Well established desalination technologies can be classified as
i) the desperate necessity to support the water demands; ii) dra- thermal (phase change) and membrane (non-phase change) pro-
matic improvements in energy consumption by desalination cesses. Thermal processes consist of an evaporator and condenser
technologies; and iii) reduced investment and processing costs for to vaporize freshwater from the feedwater (seawater or brackish
desalination processes. water) under suitable operating temperatures and pressures and
The purpose of this paper is two fold. First, it provides an condense the same to produce freshwater while membrane pro-
overview of the desalination water industry around the world. Then cesses use a physical barrier such as a membrane to separate the
it discusses the sustainability components of desalination from the dissolved salts from the feed water by mechanical or chemical/
perspective of existing alternatives and current scenarios, followed electrical means using a membrane separator between the feed
by an update on the recent approaches to embrace desalination (seawater or brackish water) and product (potable water) (Gude
technologies in water scarce countries and the drivers and factors et al., 2010).
that influence desalination. This article attempts to provide a new Thermal desalination technologies include solar distillation (SD)
perspective on the desalination systems with reference to the such as solar stills and active and passive solar desalination
V.G. Gude / Water Research 89 (2016) 87e106 89

Fig. 1. Desalination using renewable energy sources and coupling schemes.

systems; multi-effect evaporation/distillation (MED); multi-stage biomass based power generation, hydropower and ocean thermal
flash distillation (MSF); thermal vapor compression (TVC) and energy (Bennett, 2011a). Energy storage may become an important
mechanical vapor compression (MVC). Membrane desalination element in these configurations to provide for reliable energy
technologies include electrodialysis (ED) and reverse osmosis (RO). supply that addresses the fluctuating intensity and intermittent
Other hybrid processes combine both thermal and membrane nature of the solar and wind energy sources. Tidal(wave) energy is
separation mechanisms in a single unit or in sequential steps to also intermittent in nature and it needs to be generated and stored
produce potable water which are membrane distillation (MD) and for later use by desalination systems. For more details on energy
reverse osmosis combined with MSF or MED processes. storage applications in desalination, readers are referred to a
Some of the oil-rich countries derive most energy needs for detailed and dedicated assessment presented elsewhere (Gude
desalination from the fossil fuel sources at present, however un- 2015a).
acceptable are their long-term consequences. These supplies are
expected to last in adequate quantities for the present and some 2.2. Current trends in desalination industry
future generations. However, desalination scientists, engineers and
policy makers must consider sustainable alternative energy sources In year 2005, the desalination technology share was dominated
for desalination and make use of this grace period to determine by thermal technologies namely MSF and MED (up to 60%) followed
what is scientifically possible, environmentally acceptable, and by membrane technologies (40%). This situation is now flipped with
technologically feasible. Since desalination technologies are energy membrane based processes accounting for more than 60% market
intensive, use of existing finite fossil fuel sources is not a sustain- share and the remaining share by thermal and hybrid processes.
able and affordable approach. Instead, renewable energy supplies About 70% of the desalination plants installed after the year 2000
derived from solar, wind, geothermal and wave (tidal) energy were membrane desalination plants (National Water Commission,
sources show greater promise for long term sustainability of 2008). Reflecting this trend, current desalination industry repre-
desalination technologies for freshwater production. Fig. 1 shows sents 63% reverse osmosis, 23% of MSF and 8% of MED processes,
the relationship between various renewable energy sources and and the reminder including electrodialysis and other hybrid pro-
desalination technologies (Gude, 2015a). To achieve maximum cesses (Fig. 2A). The compound annual growth rate of the desali-
utilization of energy sources, a suitable energy-desalination nation industry between 1997 and 2008 was 17% and it continues
coupling scheme should be identified. Some desalination technol- to grow. The majority of the desalination capacity is owned by
ogies require the energy source on site and some do not have this municipalities for drinking water supplies and industrial utilities,
requirement (off-site). A few on-site desalination and renewable while the remaining portion is shared by power plants, irrigation,
energy schemes are (i) wind-MVC; (ii) solar thermal-TVC; (iii) solar tourism, military and some other applications (see Fig. 2B)
thermal-MSF; (iv) solar thermal-MED; (v) solar thermal-SD; (vi) (Bennett, 2013).
geothermal-TVC); (vii) geothermal-MSF or MED. Other off-site The specific energy consumption for water production has
schemes are (a) Wind-MVC; (b) Wind-RO; (c) Solar PV-RO; (d) dramatically decreased from 20 kWh in 1970s (Von Medeazza,
Solar PV-MVC; (e) Geothermal-MVC; and (f) Geothermal-RO. Other 2005) to 2.5 kWh in 2010 (Gude, 2011). Desalination costs have
renewable energy sources that could be of potential interest are also reduced significantly since mid-1990s to a cost less than
90 V.G. Gude / Water Research 89 (2016) 87e106

Fig. 2. Desalination industry by technology, users, and cost components (Costs assume a $0.05/kWh electricity cost and an oil price of $60/bbl).

US$0.75 per m3 in 2008 (Fig. 2) (Bennett, 2011b). Technological Among these nanocomposite membranes have reached the
developments and lower specific energy consumption have alle- commercialization status while the others still require significant
viated the freshwater costs. Moreover, several amendments in work towards commercialization. Among the emerging desalina-
membrane and heat transfer materials, and manufacturing prac- tion technologies, adsorption desalination, forward osmosis and
tices also contributed to the lower capital and operating costs with membrane distillation show promise for further developments and
higher productivities (Henthorne and Boysen, 2015). Water pro- will be discussed here briefly and for more information related to
duction costs for dominant desalination technologies are shown in other emerging and alternative desalination processes, the readers
Fig. 2C. The operating and maintenance costs are shown in detail as are encouraged to refer to other recent contributions (Semiat,
well (see Fig. 2C) (GWI, 2012a, b). RO technology is competitive at 2008; Gude et al., 2010; Gude, 2011; Elimelech and Phillip, 2011;
water costs compared to MSF and MED technologies (Kesieme et al., Penata and Garcia-Rodriguez, 2012; Gao et al., 2014; Ghaffour
2013) in the current industry. et al., 2014; Gude, 2015a,b; and Subramani and Jacangelo, 2015).
Adsorption desalination is an emerging and promising tech-
2.3. Recent developments in desalination nology for near future. Adsorption desalination and cooling (ADC)
cycles involve selective adsorption of water vapor from saline water
Desalination research has advanced significantly in recent years and desorption of the same activated by thermal regeneration.
in both membrane and thermal technologies. Several emerging Activated carbon, silica gel and zeolite materials have been utilized
technologies such as forward osmosis, and semi-batch RO pro- as adsorption media due to their high surface area and porous
cesses have been discussed in membrane desalination technologies nature (Ng, 2003). Two beds are typically used in ADC cycles, one
while membrane distillation, humidification and dehumidification, for adsorption and the other for desorption. More details on the
adsorption desalination, pervaporation are receiving increasing operating principles can be found in Ng et al. (2014). Heat recovery
interest (Subramani and Jacangelo, 2015). Advances in membrane between the condenser and the evaporator is also possible in ADC
development include nanocomposite membranes, nanotube process (Ng et al., 2011; 2012). In addition, ADC hybridization with
membranes, aquaporin membranes, graphene based membranes. MED process was also developed (Ng et al., 2011).
V.G. Gude / Water Research 89 (2016) 87e106 91

Membrane distillation (MD) technology has over 50 years of MVC technology could be beneficial as well (Swaminathan, 2015).
history. MD can be considered as hybrid technology which includes Recovery of rubidium from RO concentrate using MD and ion
both membrane and thermal characteristics of desalination pro- exchange process scheme was also reported. (Naidu et al., 2015).
cesses in which freshwater evaporates from hot saline feed water Zero liquid discharge (recovering water from the concentrates) for
on one side of the semipermeable membrane which is condensed eliminating liquid wastes is another recent development using
by the cooling water stream on the other side of the membrane. electrodialysis (electrodialysis metathesis, EDM) process for
Several configurations namely direct contact, sweeping gas, vac- brackish water treatment (Bond et al., 2011; Oren et al., 2010;
uum, and air-gap membrane distillation were developed over the Davis, 2015). Most of the emerging technologies (MD, FO, ED,
years for various desalination and other separation applications in EDM, and EDR) can be employed in zero liquid discharge schemes.
two main configurations of tube type or flat plate (Yarlagadda et al., Energy and cost constraints are the major focus for research in this
2009, 2011; Camacho et al., 2013). Membrane distillation process area. Not much has been reported on the development of energy
can be integrated with forward osmosis and reverse osmosis and recovery devices since these devices are already operating at
crystallization processes to enhance water recovery and/or energy their maximum energy recovery potentials. However, enhanced
efficiency. Since MD is also an energy intensive process, solar or water recovery scheme incorporating brine mixing with feedwater
geothermal sources or other waste process heat can be used as (in a closed-circuit configuration) to optimize both water and
heating medium. The economics can be found to be favorable in energy recovery is an interesting option (Elimelech, 2015; Stover,
some cases. 2015).
Most commonly used membranes in membrane distillation are
PTFE (polytetrafluoroethylene), PP (polypropylene), and PVDF 3. Sustainability of desalination technologies
(polyvinyldenefluoride). PVDF has high hydrophobicity, thermal
resistance and oxidation resistance while PVDF has high mechan- Sustainability of desalination technologies can be assessed by
ical strength with good hydrophobicity and thermal resistance. PP four components which comprise environmental, economic, social
also has good thermal and chemical resistance. Membrane fouling and technological areas. In addition to the other key components,
and wetting have been realized as major obstacles for MD process technical feasibility becomes an important component in the
advancement into commercial applications. Novel membranes or evaluation of desalination processes since they are chemical-, cost-
materials have been introduced recently which include carbon and energy- intensive contributing to environmental emissions and
nanotubes, fluorinated copolymer materials and surface modified technology has a vital role to play in their mitigation. The economic
polyethersulfone (PES) to increase the mechanical strength, impact depends on various factors such as water source availability
porosity and hydrophobicity. Energy and economic issues still and its quality, type of energy source, process technology, labor,
persist which prevent the technology from commercialization operation and maintenance costs, geographical location, and finally
although this technology has already been used in a wide range of on the financial package. The environmental component includes
applications. The future research will need to focus on increasing the greenhouse gas emissions (global warming and acid rain po-
the water recovery, improving energy efficiency with cost mini- tentials), brine and chemical discharges (eutrophication, water
mization objectives. Detailed discussions on various aspects of MD quality and ecological impacts) into the receiving environments
technology have been well discussed by Camacho et al. (2013). and the ecological impacts associated with these environmental
Among the membrane desalination technologies, forward emissions. While the social factors include social acceptance, con-
osmosis (FO) process is being actively pursued recently to increase fidence in quantity and quality of the water sources and their de-
recovery of the water source. The FO process is based on the mands and the acceptance of desalination technologies and trust in
principle that water (solvent) diffuses through a semi-permeable the water providers.
membrane from low concentration region to high concentration
region by a natural process. The amount of water recovery is 3.1. Economics of desalination and other alternatives
facilitated by a high concentration draw solution and the extracted
water needs a separation step for final recovery. The separation 3.1.1. Conventional water supplies vs. desalination
process can be expensive depending on the draw solution charac- Desalination clearly is not a universal solution for freshwater
teristics. The first generation FO draw solution was water and supplies in all water scarce regions. But it has been proven to be a
ammonium bicarbonate (NH4HCO3) mixture (McCutcheon et al., viable alternative for communities facing severe drought and
2005). Several innovations were reported recently such as inclu- increasing urbanization, industrialization and population growth
sion of high surface area and high osmotic pressure, hydrophilic issues. Due to their energy and cost intensive nature, desalination
magnetic nanoparticles (Ling et al., 2010) and polyelectrolytes of technologies are often looked down upon as a potential water
PAA-Na salts (Ge et al., 2012) for efficient recovery of draw solu- supply alternative or viewed as a last resort. However, some recent
tions. More details can be found in a detailed review by Chung et al. concerns over climate change and water scarcity combined with
(2012). For water reuse and desalination, FO could be an energy- industrial development have led many scientists and engineers to
efficient process when compared with RO process provided that consider desalination processes as freshwater supply resources.
the separation process is cost-effective. Current challenges include Desalination costs are influenced by various factors (Zander et al.,
development of highly efficient membranes, cost-effective recy- 2008). A comparison between the conventional (surface and
clable draw solutes, and fouling control suggesting future research ground water sources) and desalination based technologies for
needs in these areas. freshwater supplies may help the engineers and scientists realize
Hybridization appears to be a feasible option for both mem- the pitfalls and the required improvements in desalination to make
brane and thermal desalination processes. Forward osmosis inte- them more acceptable. For instance, a cost comparison between
grated processes with membrane distillation and other low conventional (coagulation-flocculation-sedimentation and filtra-
pressure membrane processes are good examples for desalination tion scheme) and desalination (seawater reverse osmosis, SWRO)
of groundwater, seawater and wastewater in membrane bio- based freshwater supply options shows that conventional water
reactors (Cath et al., 2010; Linares et al., 2014; Li et al., 2015). The supplies are only economical in regions where there are ample
goal of hybridization is to increase water recovery with low spe- sources of surface or ground waters within reasonable distances
cific energy consumption. Integrating membrane distillation with (Table 1) (Gude, 2015b). The low-end water costs indicate these
92 V.G. Gude / Water Research 89 (2016) 87e106

Table 1
Comparison of water costs for conventional and desalination water supply options (Voutchkov, 2011, 2014; Plappally, 2012).

Range Energy requirements (kWh/m3) Water production costs ($/m3)

Conventional water supplies Seawater reverse osmosis (SWRO) Conventional water supplies Seawater reverse osmosis (SWRO)

Low 0.1e0.5 2.5e2.8 0.25e0.75 0.50e0.80


Medium 1.0e2.5 3.0e3.5 0.75e2.50 1.00e1.50
Higha 2.5e4.5 4.0e4.5 2.50e5.00 2.00e4.00
a
Conveyance and distribution costs included, even higher water costs are applied in some countries.

Fig. 3. Comparison of water costs for conventional and transported desalination water supply options.

conditions where the lowest costs for desalination can be reported Fig. 3. Citizens in some of the European countries are having to pay
for brackish water sources. For this scenario, the desalinated water much higher water prices than other developed countries. This has
costs are twice the conventional water supply costs but the specific different contexts which include policy, economic and environ-
energy consumption is quite high (by 5e25 times). In another case mental. Water pricing policy should include the socioeconomic,
where communities experience significant industrial growth and as environmental, sectoral, and structural elements. In developing
a result population increase, the water supply costs can become countries such as China and India, water prices are heavily subsi-
pricy as the technologies need to be updated to meet the increasing dized which actually is not a sustainable measure (Sachs, 2013).
demands and distribution systems need expansion. If brackish or This promotes changes in user behavior mainly irresponsible use
seawater desalination is considered as an option, the costs could be and inefficient resource utilization. Many countries in the Europe
reasonably adjusted due to large scale production and if seawater have revised their water pricing policies to account for the local
desalination is considered, the specific energy consumption will be environmental and socioeconomic elements and to ensure the full
reduced to a factor in the range of 1.4e3.0. In a case where local recovery of the costs incurred in water supply system. An ideal
water sources are inadequate and the population to be served is water pricing policy should also provide proper incentives to
fairly large, both the specific energy consumption and water encourage efficient resource utilization leading to pollution
costs increase significantly (case studies to be discussed in later reduction and resource protection and its longevity. When sub-
sections). In this high-end water costs scenario, the local water sidies applied previously on the water prices were removed in
resources are not adequate to meet the demands and therefore, raw many of the European Union states, water prices were increased by
water has to be imported from water-rich regions and costs also a very high factor (between 5 and 20). For example, water prices in
reflect the water reuse and conservation efforts as well as trans- Hungary went up by 15 times when these subsidies were removed
portation requirements. If seawater desalination is considered as an (Water Prices-Policy issue, 2010).
alternative for this scenario (assuming seawater is available within According to a recent water tariff survey by Global water intel-
reach), the specific energy consumption and water costs can be ligence (2014), global water costs have risen by 4.3% during the last
more attractive when compared to conventional water supply year with an average cost of $2.14/m3 for water and wastewater
option. services combined. The highest water tariff of $10.09/m3 was re-
ported for Aarhus, Denmark while other countries such as
Turkmenistan and Ireland did not have any tariffs. Ukraine expe-
3.1.2. Water transportation costs rienced a steep increase (doubled the water tariffs) while the water
Average water supply costs in various countries are shown in
V.G. Gude / Water Research 89 (2016) 87e106 93

tariffs in Germany and Denmark have fallen significantly due to the desalination may accelerate air pollution due to greenhouse gas
payoff of their investments in the water infrastructure. The water emissions which include carrbon monoxide (CO), nitric oxide
prices in US have increased by 7% over the last year mainly part of (NO), nitrogen dioxide (NO2), and sulfur dioxide (SO2) known to
the planning for reviving aging infrastructure and combatting the have detrimental influence on local public health and environ-
water scarcity due to drought especially in California (Bednorz, ment (Younos, 2005). Desalination plants also utilize significant
2014). amounts of chemicals for pretreatment of saline water and post-
In many urban areas, local water resources are reaching the treatment of desalinated water. Discharge of large amounts of
capacity limits in serving the populations, leaving transportation of chemicals into the coastal waters results in ecological imbalances
desalinated water as a source of water supply. A study estimated and major impacts are usually observed in confined water bodies
costs of the transported freshwater from coastal desalination plants (Lattemann and Ho € pner, 2008; Qdais, 2008). The concentrates
(Zhou and Tol, 2005). For example, the city of Beijing in China could generated from brackish water via an RO process (with 60e85%
transport freshwater from the nearest ocean source located at a recovery) would have a concentration factor that is 2.5e7 times
distance of 135 km and an overall elevation difference in trans- higher and the same for the seawater RO (with 30e50% recovery)
portation of 100 m (see Fig. 3). The water supply cost for this source would be between 1.25 and 2.0 (National Water Commission,
was estimated as $1.13/m3. Similarly for Delhi, India, Riyadh, KSA 2008). Thermal desalination technologies have a wide range of
transported desalinated water costs will be $ 1.90 and $1.60 for recovery ratios between 15 and 50% with a concentration factor
transportation distances of 1050 km, 350 km and elevation differ- of 1.15 (due to cooling water mixing). Table 2 compares chemical,
ences of 500 m and 750 m respectively. A comparison between the biological and physical properties of the RO and MSF desalination
conventional water supply costs and transported desalinated water process concentrates (Chang, 2015; Roberts et al., 2010). Specific
costs shows that the difference is acceptable since the desalinated seawater concentrate properties such as salinity, temperature,
water costs have reached to the levels of conventional water sup- and various chemicals used for coagulation, biocides for con-
plies in recent years but the transportation costs will be unavoid- trolling biological growth, anti-foaming, anti-corrosion and
able. The difference in costs that stems from the transportation cleaning chemicals cause serious environmental concerns for
distance cannot be considered as a hurdle since water must be their proper disposal. About 2 units of concentrate is generated
supplied to the communities at any cost. for every unit of desalinated water produced. Current practice of
handling these concentrates is to discharge them into the coastal
3.2. Energy, environmental, and ecological considerations waters which could have detrimental effects on the aquatic life
and coastal environment. Brine/concentrate disposal technolo-
3.2.1. Energy budget for a small RO desalination plant gies and management options are not as robust and practical as
Water production involves energy utilization and associated desalination technologies and in many cases, brine discharge
environmental emissions (Gude et al., 2011). Energy is required at poses major concerns for disapproval of new inland desalination
various stages of water production (Plappally, 2012). Energy utili- plants and some coastal desalination plants. Continuous recovery
zation in large scale desalination plants can be well managed. For and discharge of the seawater at a specific location may also
example, in MSF and MED processes, the specific energy re- affect the quality of incoming supply water for desalination in
quirements decrease with number of stages which is known as the long run. To mitigate major environmental concerns related
performance ratio. The same applies to membrane processes where to brine/concentrate discharges, concentrates should be pre-
addition of stages increases energy savings as well as water re- diluted with the seawater to minimize the effects related to
covery and often energy budget is enhanced by energy recovery high salt concentrations. Temperature effects can be eliminated
devices. However, for small scale applications such as domestic by proper heat dissipation though cooling towers and by diluti-
uses whether desalination is affordable depends on the overall ing with seawater. Removal or substitution of hazardous sub-
energy budget of the individual domestic unit. A comparison be- stances by implementing alternative treatment methods would
tween the desalination energy utilization with that for other do- alleviate the negative impacts on the environment. In particular,
mestic uses may provide a useful insight on the overall energy biocides such as chlorine may acutely affect non-target organ-
budget of a domestic household. A typical family consisting of four isms in the discharge site, should be replaced or treated prior to
members in the Middle Eastern countries would have a water discharge. Chlorine can be effectively removed by different
consumption rate of nearly 18 m3/month (150 L per person for a chemicals, such as sodium bisulfite as practiced in RO plants,
family of four) and uses about 1200 kWhe of electricity or other while sulfur dioxide and hydrogen peroxide have been suggested
equivalent energy sources per month (Semiat, 2008). A seawater to treat thermal plant reject streams. Filter backwash waters
desalination process (RO process) can deliver the freshwater needs should be treated by sedimentation, dewatering and land depo-
at an energy utilization rate of 140 (kWhth)/month (fuel value) sition, while cleaning solutions should be treated on-site in
excluding water transportation energy needs. The transportation special treatment facilities or discharged to a sanitary sewer
needs for an average distance of 1500 km/month can be met by a system. Recovery of valuable chemicals such as gypsum from the
family car with 160 L of oil consumption per month which is concentrates is an attractive option. Reuse of treated brackish
equivalent to 1500 (kWhth)/month while the electricity needs (for water in irrigation applications is another alternative to reduce
lighting, heating and cooling) are around 1200 kWhe/month which the demands for freshwater sources. Air pollution can be miti-
are equivalent to 2667 (kWhth)/month (with a conversion effi- gated by using natural gas and renewable energy sources. Finally,
ciency of 45%; 1200 kWhe/0.45). From this analysis, desalination improving the desalination process schemes would enhance the
energy needs represent only 9.3% or 5.2% or 3.2% of the trans- energetic and environmental performance of the desalination
portation energy, electricity, and total domestic energy needs processes. For instance, a SWRO plant with a capacity of 100
respectively. This analysis clearly supports the use of desalination million m3 (per year) would require an electrical load of 50 MW
process for affordable freshwater supplies at domestic levels. (Semiat, 2008). A desalination and power plant cogeneration
scheme would operate at a higher efficiency than separate
3.2.2. Environmental issues of desalination desalination and power generation plants. Because the cogene-
Desalination plants can have significant impact (direct or in- ration scheme operates based on the water supply demands
direct) on the environment. Increased use of fossil fuels for which are subject to dayenight and summerewinter fluctuations
94 V.G. Gude / Water Research 89 (2016) 87e106

Table 2
€ pner, 2008; Dawoud and Al Mulla, 2012).
Potential ecological/environmental impacts of the RO and MSF desalination process concentrates (Lattemann and Ho

RO plants MSF plants Environmental/ecological impacts

Physical properties
Salinity and temperature Up to 65,000e85,000 mg/L ambient About 50,000 mg/L þ 5e15  C above Can be harmful; reduces vitality and
seawater temperature ambient biodiversity at higher values; harmless
after good dilution
Plume density Negatively buoyant Positively, neutrally or negatively Can be harmful; can have local impact
buoyant depending on the process, on biodiversity
mixing with cooling water from co-
located power plants and ambient
density stratification
Dissolved oxygen (DO) If well intakes used: typically below Could be below ambient seawater DO
ambient seawater DO because of the because of physical deaeration and use
low DO content of the source water of oxygen scavengers
If open intakes used: approximately the
same as the ambient seawater DO
concentration
Biofouling control additives and by-products
Chlorine If chlorine or other oxidants are used to Approx. 10e25% of source water feed Very toxic for many organisms in the
control biofouling, these are typically dosage, if not neutralized mixing zone, but rapidly degraded,
neutralized before the water enters the THM e RO e MSF
membranes to prevent membrane
damage
Halogenated organics Typically low content below harmful Varying composition and Carcinogenic effects; possible chronic
levels concentrations, typically effects, more persistent, dispersal with
trihalomethanes current, main route of loss is thorough
evaporation
Removal of suspended solids
Coagulants (e.g. iron-III-chloride) May be present if source water is Not present (treatment not required) Non-toxic; increased local
conditioned and the filter backwash turbidity / may disturb
water is not treated. May cause effluent Photosynthesis; possible accumulation
coloration if not equalized prior to in sediments
discharge
Coagulant aids (e.g. polyacrylamide) May be present if source water is Not present (treatment not required)
conditioned and the filter backwash
water is not treated
Scale control additives
Antiscalants acid (H2SO4) Not present (reacts with seawater to Typically low content below toxic levels Poor or moderate degradability þ high
cause harmless compounds, i.e. water (reacts with seawater to cause harmless total loads / accumulation, chronic
and sulfates; the acidity is consumed by compounds, i.e. water and sulfates; the effects, unknown side-effects
the naturally alkaline seawater, so that acidity is consumed by the naturally
the discharge pH is typically similar or alkaline seawater, so that the discharge
slightly lower than that of ambient pH is typically similar or slightly lower
seawater). Typically low content below than that of ambient seawater)
toxic levels
Foam control additives
Antifoaming agents (e.g. polyglycol) Not present (treatment not required) Typically low content below harmful Non-toxic in concentration levels; good
levels degradability
Contaminants due to corrosion Copper e MSF (15e100 mg/L) e Low
acute toxicity for most species; high
danger of accumulation and long term
effects; bioaccumulation
Heavy metals May contain elevated levels of iron, May contain elevated copper and nickel Only traces metals; partly natural
chromium, nickel, molybdenum if low- concentrations if inappropriate seawater components; no toxic or long
quality stainless steel is used materials are used for the heat term effects (except maybe for Ni in
exchangers MSF)
Cleaning chemicals
Cleaning chemicals Alkaline (pH 11e12) or acidic (pH 2e3) Acidic (pH 2) solution containing Highly acidic or alkaline cleaning
solutions with additives such as: corrosion inhibitors such as solutions that may cause toxicity
detergents (e.g. dodecylsulfate), benzotriazole derivates without neutralization, disinfectants
complexing agents (e.g. EDTA), oxidants highly toxic at very low concentrations,
(e.g. sodium perborate), biocides (e.g. detergents moderate toxicity;
formaldehyde) complexing agents very poorly
degradable
MSF cleaning solutions e Low pH,
corrosion inhibitor e Highly acidic
cleaning solutions that cause toxicity
without neutralization low toxicity;
poor degradability

resulting in an energy-efficient process scheme. Gas turbines can 3.2.3. Environmental emission comparison with large dams and
provide higher efficiency with the use of high thermal energy wastewater systems
released in off-gases reducing the actual energy utilization Construction of dams may increase access for water supplies but
compared to other common uses. these contribute to many environmental and ecological issues
V.G. Gude / Water Research 89 (2016) 87e106 95

(Timofti et al., 2011; Lindstrom et al., 2012; Subbaraman et al., proper design details and statistical analyzes making conclusive
2013). One of the main impacts is the loss of habitats since the interpretation of results difficult (Roberts et al., 2010). Assessment
dams serve as barriers for fish migration from one place to the other methodologies should be improved significantly to clearly identify
leading to extinction. Temperature and chemical composition of the ecological impacts (Roberts et al., 2010; Zhou et al., 2011).
water in the reservoirs is also different from the flowing waters. The Comprehensive environmental impact assessment using the
restricted and reduced flow downstream is more saline which framework of integrated coastal management with large number of
makes it less suitable for certain fish and aquatic species while indicators covering most of the critical issues would be helpful
human activities upstream the reservoir could cause accumulation which are generally overlooked under conventional assessments
of nutrients resulting in eutrophication (International Rivers). Also (Liu et al., 2013).
anaerobic conditions in the deep reservoir water causes decom- Pre-treatment of source water is essential for preventing
position of vegetation emitting greenhouse gases over large surface biofouling in membrane processes. Some post-treatment including
areas which also causes higher water losses. disinfection can also cause some health concerns. Recent studies
As a comparison, wastewater treatment by activated sludge report on the adverse impacts of disinfection byproducts (DBPs)
process releases 1500 tons of greenhouse gases (carbon dioxide) for discharged through brine flows into the marine environment.
every 1000 tons of wastewater treated. These emissions are not Disinfection byproducts formed in the pretreatment of membrane
generally considered greenhouse gas emissions (these are consid- processes from the organic compounds such as chloroform, bro-
ered “natural emission cycles” by USEPA). In addition, greenhouse moform, halophenols and other phenols can be detrimental to the
gas emissions for the electricity use in wastewater treatment ac- aquatic life (Agus and Sedlak, 2010). Chronic effect of bromoform as
counts for 0.5e1.1 kg CO2 emissions per unit (m3) of wastewater low as 50 mg/L concentration on oyster larvae were reported while
(Shrestha et al., 2011). Other emissions include NO2, N2O, H2S, and the lethal dosage was reported to be as high as 1000 mg/L (Stewart
CH4 from various process stages. On this basis, water production by et al., 1979). Haloacetic acids are also toxic to species like aquatic
desalination plants should not be a prohibitive option. Moreover, macrophytes and phytoplankton at relatively low concentrations
according to a recent report by the Australia's National Center of (e.g., monochloroacetic acid and monobromoacetic acid inhibited
Excellence for Desalination, the Perth desalination plant has been growth in green algae Scenedesmus subspicatus at concentrations of
providing freshwater for the residents in a most sustainable 7 mg/L and 20 mg/L, respectively (Kuhn and Pattard, 1990)).
manner supported by renewable energy sources with little or no Bromide-rich brines can cause formation of trihalomethanes (Agus
environmental impact. This plant discharges its brines into Cock- et al., 2009; Krasner et al., 2006). Kim et al. (2015) provided a
burn Sound, a confined body of water. This plant has the most- detailed review of the impacts of disinfection byproducts and
monitored brine outfall location in the world which has operated several recommendations were made in this report. These include
for the past several years without any environmental harm. This is systematic evaluation of full-scale seawater desalination plants for
an encouraging report for the current desalination industry. various DBPs, impact of dissolved organic carbon, and other
chemical compounds such as antiscalants (e.g., BaSO4, CaSO4,
3.2.4. Ecological impacts SrSO4, CaCO3, and silica) or antifoaming agents (e.g., acylated pol-
Thermal desalination plants draw the source water equivalent to yglycols, fatty acids and fatty acid esters, silicon-based compounds)
8 or 10 times of the freshwater quantities produced in the plant and the interaction chemistry of the disinfection agents with these
while the reverse osmosis plant draws 3 times the product (Morton chemicals.
et al., 1996). Thermal desalination plants discharge brines at slightly
higher temperatures but their salinity is lower than membrane 3.3. Social issues
desalination plants. It appears that thermal desalination plants
would have higher ecological impacts but the membrane desali- Techno-economic and environmental aspects of the desalina-
nation plants use large quantities of chemicals for pretreatment, tion plants receive considerable attention when compared with the
control of membrane scaling and biofouling. The desalination social issues. Similar to environmental impacts, installation of
brines were previously reported in terms of their salt concentra- desalination plants could have significant social impacts during
tions ignoring the additive chemicals used for the above purposes. construction and operational phases. Social issues for desalination
Although these concentrations are quite small when compared to technologies include lack of public trust and confidence in water
salt concentrations, they have been reported to have direct or in- provider, people's response to dust, noise, and visual amenity im-
direct impacts on the marine aquatic life in a few cases. Chlorine pacts, beach and ocean-based recreational activity impacts,
concentrations should be closely monitored as well. Selection of an disruption to the properties and activities along the pipeline,
ideal location with minimum ecological significance along with low impact on the future residential development, impact on the in-
intake velocities is an important measure to mitigate the ecological dustrial development in the local area, impact on local economic
impacts (Morton et al., 1996). Desalination plants similar to other activity, risk to public safety, disruption of local businesses, and
water supply or treatment systems would have environmental and impact of construction on road users.
ecological impacts during and after construction and in operation A survey was conducted in Australia for four locations namely
stages (Lokiec, 2013). Several measures can be implemented to Binningup, Myalup, Pamelup estate and Pipeline route with over
minimize the environmental and ecological impacts. 333 respondents. About 45% of respondents on this survey had a
It is often very difficult to compare the environmental impacts of very low or low levels of trust while 28% neither trust nor distrust
different water supply options such as surface water sources, the water corporation. When asked about the installation of the
groundwater withdrawal, transported water across long distances desalination plant, 55% of the respondents did not approve the
and brackish water or seawater desalination. These options present seawater desalination project while 23% neither approve nor
complex situations for different locations which cannot be disapprove (SSDP, 2009). A good portion of the respondents
normalized for all the geographical locations around the world. A expressed concerns about the negative impacts on the marine
large body of literature is available on the ecological issues but it is environment during both the construction and operation phases of
quite descriptive and qualitative rather than quantitative and many the project. Also a majority of the respondents mentioned about
studies assessed considering site-specific socioeconomic and the negative impacts on the recreational use of the beach. Other
environmental parameters only. Some studies are deficient in significant opinions expressed over the positive impact that the
96 V.G. Gude / Water Research 89 (2016) 87e106

desalination project might have were about local economy during aesthetical depreciation, inflow and outflow traffic transporting
both construction and operation phases. When asked for sugges- materials.
tions to improve the desalination project, the respondents have Other foreseeable social impacts with desalinated water are
indicated a few important aspects such as noise reduction, visual diverse. First, desalinated water is now introduced as a commodity
and environmental impacts. About 41% of the respondents sug- which might have both positive and negative impacts on the eco-
gested that the desalination plant be located elsewhere which nomic and social status/reforms of a region or country. The fresh-
might have the possibility for inclusion of water transportation water costs through desalination are agreed to be affordable for
costs. Other suggestions included adaptive management, fostering tourism purpose but the same is not acceptable as a domestic water
local employment and further research on environmental impacts. supply source in many regions which can be considered a social
Social issues with desalination technologies also vary with the injustice or a conflict with the most basic human right to have
size of the community. Small communities might have lesser issues access to clean and affordable water supplies. The former use can
when compared with large communities having large number of also have a significant impact on the local energy sources and the
issues (Werner and Scha €fer, 2007). For example, small communities local environment.
are usually located in remote locations where water supply infra-
structure itself does not exist and reliance on transported water is 4. Desalination out of desperation e case studies
common. For these communities, onsite water production via
desalination technologies might seem attractive. The social issues While the value of water sources is underappreciated in many
or concerns with small communities are not insignificant in their parts of the world, water scarcity can present substantial challenges
impact. For example, it is important to have skilled labor to main- for sustainable development. Water scarcity hinders economic
tain the desalination facilities. Especially if the community has a development, detriments human health, leads to environmental
limited access to the electric grid, renewable energy sources have to degradation and promotes political and social instability. Measures
be employed which again demand higher levels of expertise and such as water conservation, improving efficiency of supply and
skills from the operators. Public education and participation is a distribution systems could help but the contribution from these
must. Where the communities did not accept desalination tech- efforts will not be substantial. New water supplies/resources must
nologies as their water supply option, systems introduced in these be identified and developed for reliable and sustainable develop-
communities did not fare well. Where the social impacts were ment of future water supplies since global populations are expected
neglected, such installations resulted in abandonment and to increase by 50% by 2030. Global agencies (including WHO, UNDP,
dysfunctional units. The community should also demonstrate the UNICEF, etc.) expect that 24 of the least developed countries, many
commitment and ownership of the facility to ensure reliable water of them along coastal areas without access to freshwater and
supply both in quantity and quality. For small communities, oper- electricity, need to more than double their efforts to reach the
ative risk and demand satisfaction also become important factors Millennium Development Goals (MDGs) for basic health, sanita-
connected with skill levels and sustainable behavior. tion, and welfare (Gude and Nirmalakhandan, 2010). It is impera-
Sustainable behavior can have a positive impact on the success tive for arid and oil-rich countries in the Middle Eastern region to
of the desalination plants. Respectful use of water sources and rely on desalination technologies for their freshwater supplies. But
proper maintenance of the desalination plants is critical to suste- some other parts of the world rich in water resources earlier are
nance of small communities. Sustainable behavior can be improved now facing serious water source-supply issues. Climate change and
by public education but it can have both positive and negative shifting population demographics, which exacerbate water short-
impacts. Those people that already oppose the desalination tech- ages in certain areas of accelerated population growth, are adding
nologies might become even stubborn in their perspective but the to rapid industrialization where reliable freshwater supplies are
others with uncertain opinion might embrace desalination option. being severely stretched. Seawater represents as an obvious
Another common issue is that communities, in many cases, do not resource to tackle the resulting problem of water scarcity, especially
like to have a physical plant installed in nearby locations or cities in coastal areas. Five case studies can be discussed here: the state of
for various reasons often termed as “Not In My Backyard (NIMBY)”. California in the USA, desalination plants in Australia, sustainable
Construction of large desalination plants involves several in- water supply scheme in Singapore, SoutheNorth water trans-
conveniences to the local communities including closure of recre- portation project and desalination trends in China, and the desa-
ational facilities, local transportation, noise and air pollution and lination plants and water supply in the Kingdom of Saudi Arabia.

Fig. 4. Existing and proposed desalination plants in California, surface water and brackish desalination plants in Florida and Texas.
Fig. 5. California's continuous drought since 2011 and water supply options and relative energy consumption (kWh/m3) for southern California to battle the continuous drought and
simultaneous increase in water demands (water transport from the northern Californian dams and reservoirs, water transport from Colorado River, water reclamation for indirect
water reuse, and desalination of inland brackish water or seawater from pacific ocean and gulf of Mexico (Cooley, 2014).
98 V.G. Gude / Water Research 89 (2016) 87e106

4.1. Desalination in California, USA takes nine times as much energy as surface water treatment and 14
times as much energy as groundwater production. This is based on
Large disparities exist within the United States water source estimated energy consumptions for seawater reverse osmosis
availability. The USA is relatively a water abundant country in ab- desalination process of 3.4 kWh.m3; conventional surface water
solute terms but there are significant regional differences: the treatment (coagulation, flocculation, sedimentation and filtration/
Southwest region of the country is arid and drought-prone while disinfection of 0.36 kWh/m3; and groundwater treatment of
the Northeast and Midwest areas have more precipitation and ac- 0.24 kWh/m3). These numbers are based upon the assumptions
cess to the Great Lakes (which make up the largest surface fresh- that the water sources are readily available within reasonable
water system on Earth). An additional 60.56 billion m3 per year of depths or distances. But this is not the case everywhere. For
water is required by 2020 for municipal and light industrial uses in example, southern California receives surface water from Colorado
USA (Cohen, 2007). In California alone, combined agricultural, ur- River through massive supply pipelines and conveyance systems.
ban, and environmental demands already exceed average supplies Since water has to be supplied through long distances with
by 1.23  109 m3 (326 billion gallons) per year while 50% of the geographic elevations, the energy costs are significant counting
nation's future population growth is forecast to occur in CA, FL, and between 14 and 19 percent of the residential energy costs which
TX e regions already experiencing water shortages. Fig. 4 shows the includes air conditioning. In contrast, a conventional intake system
map of existing desalination plants in California, Florida and Texas of a seawater reverse osmosis facility is only 15 to 20 percent of the
states in the USA. Florida leads the nation in the use of desalination total water production costs. These costs decrease significantly
technology, both in number of facilities using the process (more with the desalination plant capacity. Therefore, it can now be
than 140) and the quantity of potable water produced each day concluded that desalination could be a better alternative in areas
(1.95  106 m3 or 515 million gallons). This is reflective of efforts to where other traditional water supply schemes prove to be energy
meet the needs of the state's increasing population while avoiding or capital (cost) intensive and pose environmental issues.
overuse of traditional drinking water sources, particularly in coastal
areas of central and south Florida. The majority of the source water
4.2. Desalination in Australia
treated at desalination plants in Florida is not saltwater, but
brackish ground water or surface water. A few Florida water plants
Australia is the driest continent inhabited in the world
draw their source water from coastal seawater. The Tampa Bay
(Australian Government National Water Commission, 2005). It's
Seawater Desalination Facility is the only large-scale reverse
water supply sources are continuously being jeopardized due to
osmosis facility in the state using a coastal surface water source.
climate change patterns of severe droughts followed by forest fires
However, seawater desalination technology is being considered for
and floods. The continent experienced worst drought for many
application in other areas such as the Coquina Coast project in
years since early 2000s (Hall et al., 2011). Similar to California in
Flagler County in Northeast Florida where land-based and novel
USA, 10e15 years of low rainfall (El Saliby et al., 2009) what is
ship-based approaches are being considered. Texas is in a severe
known as “millennium drought” (most dry period in more than 100
drought, with groundwater supplies predicted to decline by 30%
years) has been the cause for the urgent rise of desalination plants
over the next 50 years. At the same time, the population of Texas is
in Australia. Fig. 6 shows the precipitation levels over the past 55
predicted to grow by 21 million, which will further stress the de-
years (1950e2005) (Bureau of Meteorology) and the desalination
mands for freshwater. With dwindling surface and ground water
plant locations and their capacities in Australia (Griffin, 2013). The
sources, it is necessary for Texas to examine alternative methods of
first major desalination plant was commissioned in 2006 in the city
providing freshwater. One option is to desalinate the abundant
of Perth which produces a 45 million m3 per year. A second desa-
supply of brackish groundwater.
lination plant produces about 50 million m3 per year which will be
expanded to double its capacity due to continued drought. Adelaide
4.1.1. Energy requirements for different water supply options in CA
installed a 100 million m3 per year plant and another one in the
The state of California has been experiencing a historical record
state of Queensland, a 48 million m3 plant is built. Above all, the
of drought that is considered worst in the past 1200 years. Fig. 5
most expensive and controversial plant was commissioned in
shows the drought trends in various parts of the USA and a
Melbourne at a capacity of 150 million m3/d ($3.6 billion invest-
recent noticeable severe drought trend for California. Texas is not
ment). But when the drought situation has been alleviated with
too far from this situation. The demand for water supplies in Florida
recent excess rainfalls some of the plants are not operating round
originates from the economic development and population growth.
the clock or some extended periods. However, by building this
This situation which is also common in some parts of Texas and
particular plant in the state of Victoria, the water supply security for
Florida forces many legal administrators, engineers and scientists
to consider desalination as a freshwater supply alternative since
inexhaustible sources of seawater are available along the coastal
lines for these states. In California, other alternatives of water reuse
and conservation practices have been implemented in recent years
to battle the drought conditions. Between April 2013 and April
2015, water use decreased by 13.5%. In April 2015, Gov. Jerry Brown
has urged a 25% percent reduction in urban water use. Residential
water use accounts for 12% of total use in the state and commu-
nities with highest per capita water use are forced to cut the daily
consumption by 36%. Further, the California's drought resulted in
announcing a $1 billion desalination plant, slated to begin con-
verting Pacific seawater into 0.19  106 m3 (50 million gallons) of
potable water daily by 2016 which will be the largest desalination
plant in the Western Hemisphere.
Energy requirements for different water supply options are
shown in Fig. 5 (NOAA, 2015). Seawater desalination in California Fig. 6. Drought in Australia, desalination plant locations and costs.
V.G. Gude / Water Research 89 (2016) 87e106 99

the most populated city was enhanced albeit at high capital costs high end use. The country has set a target of becoming water self-
which could have been reduced significantly if the decision- sufficient by the year 2061. To achieve this, a sustainable strategy
construction process was delayed for over a year (Traves and with four major elements has been adopted (Fig. 7). These are
Davies, 2008; Water Services Association of Australia, 2008; ‘water catchment (i)’, ‘reclaimed water (ii)’ ‘desalination (iii)’ and
Water Services Association of Australia Ltd, 2013). Renewable en- ‘imported water (iv)’ (Xie, 2006; Khoo, 2009; Luan, 2010). The local
ergy sources such as wind farms have been utilized at many of water catchment area includes a comprehensive network of drains,
these plants (WSAA, 2011). The Australia's annual investment in rivers and canals and 17 reservoirs which occupy about 65% of the
water supply and sources is about $2 billion per year equivalent to land area. This is planned to be enlarged to 90% of the land area by
$81 per capita per year (Australian dollars). The average residential 2061 to increase the local water catchment for beneficial uses
water use has decreased from 243 L per capita per day in 2003 to making this project the largest in the world for an urban setting
191 L per capita per day in 2007 (WSAA, 2012). The country has (Wong, 2011). Reclaimed water also known as “NEWater’ is a
invested significantly in water conservation, water reuse, recycling, recycled water program that collects wastewater effluents and
and reclamation, and rainwater harvesting as a strategic plan for processes it through advanced treatment schemes such as mem-
mitigating the impacts of droughts as well as allocating large res- brane filtration (ultrafiltration followed by reverse osmosis) and UV
ervoirs as water storage vessels. Although the recent drought disinfection for reuse purposes. This treatment scheme provides
conditions disappeared, these will return in time and Australia is water quality which exceeds the WHO (world health organization)
prepared with its sophisticated infrastructure and management guidelines for drinking water quality. This NEWater system
policies to provide sustainable water supplies with confidence network consists of four major used water treatment plants (Bedok
(WSAA, 2013; Radcliffe, 2015). e 86,000 m3/d; Kranji 55,000 m3/d; Ulu Pandan e 150,000 m3/
Desalination is not the ultimate solution for many communities d and Changi e 230,000 m3/d) which meets up to 30% of the cur-
in Australia where it can have detrimental environmental impacts rent nation's water demand. The third element is the desalination
on the concentrate receiving environment. Water recycling through processes installed to treat seawater to produce freshwater at two
indirect potable reuse is a potential option to reduce the need for major desalination plants with a total capacity of 460,000 m3/d but
high desalination capacities. However, there could be a high op- only operating at 230,000 m3/d which is 10% of the current water
position from the local communities. As a part of the efforts to needs. The fourth and the most significant water supply option for
convince the public and encourage high social acceptance for water Singapore is imported water. Nearly 1.1 million m3/d of water is
recycling alternatives (indirect potable reuse) over desalination transported from Malaysia through causeway system. The 2061
(because treatment costs and energy requirements for wastewater water self-sufficiency strategic plan for the country is to provide for
recycling are lower) for water source supplies, several campaigns 100% water needs independently by the first three strategic ele-
were implemented. A comparison between the two options was ments -by increasing the NEWater supplies to 50% and desalination
prepared as shown in Table 3 (National Water Commission, 2008). capacity to 30% and local water catchment to 20%. Singapore also
Despite several successful attempts on the public educational invested significantly into programs to enhance the efforts of public
campaigns, indirect potable reuse was an unacceptable option for education and water conservation (Tortajada and Joshi, 2013).
public leaving desalination as the primary technology for water
supply. 4.4. Desalination in China

4.3. Desalination in Singapore 550 of the China's 600 largest cities are experiencing severe
water stress today listing the country as one of the 13 water poorest
Singapore (land area e 700 km2 and annual precipitation e countries in the world (Macedonio et al., 2012). China is home to
2400 mm) is home to 5.5 million population with a water demand 20% of the world's population but only 7% of its freshwater (Sachs,
of nearly 2 million m3/d. The country depends on its water needs on 2013). Per capita water resources available in China are 2200 m3
Johor, Malaysia protected by a bilateral agreement made in 1961 which places China at 121st among other nations in the world and
(Tan et al., 2009). It's annual investments in water supplies and this volume is expected to decrease to 1700 m3 within the next 50
sources are $ 609 million equivalent to $117 per capita per day. The years (Liu and Chen, 2001). Similar to the USA, China's precipita-
average water tariffs are about $1.88 per m3, and $2.38 per m3 for tion, surface and groundwater supplies are concentrated in the

Table 3
Comparison of desalination and water recycling schemes in Australia (National Water Commission, 2008).

Item Desalination Water recycling

Example Kwinana Desalination Plant, Perth, Western Australia Western Corridor Recycling Project, Queensland
Plant location Kwinana Industrial Precinct Located at existing wastewater treatment plants
(Luggage Point, Bundamba, Gibson Island, Oxley)
Intake structure Sub-surface collector wells Collection basin prior to discharge pump station
Intake structure capacity 2e2.5  product water capacity 1.2e1.3  product water capacity
Feed water Seawater Secondary treated municipal wastewater
Total dissolved solids, 26,000e40,000 mg/L 600e1500 mg/L
in feedwater (TDS)
Treatment process Process mechanical screening, chemical flocculation and filtration Mechanical screening followed by chlorination and
to remove microorganisms, suspended solids and particles membrane filtration to control biological fouling and
Reverse osmosis to remove dissolved solids remove microorganisms and particles
Chlorination, chemical stabilization and fluoridation to prepare Reverse osmosis to remove dissolved solids
water for distribution system Advanced oxidation (UV þ H2O2 or Ozone) to disinfect
parasites and remove small organic molecules
Chlorination and chemical stabilization to prepare
water for discharge in the environment
Product distribution Return to large node in drinking water distribution system Supplied to power stations and used to recharge
Wivenhoe dam
100 V.G. Gude / Water Research 89 (2016) 87e106

Fig. 7. Sustainable water supply strategic plan for Singapore: (i) local catchment areas; (ii) wastewater reclamation and reuse; (iii) desalination; and (iv) water transport (map of
catchment areas in the inset).

South, whereas the Northern part of the country is drought-prone. revenues increased steadily over the recent years (Fig. 8D) despite
About 80% of the surface and groundwater is available in Yangtze the energy requirements and associated environmental emissions
River and southern parts of china where 54% of the population (Peng, 2015).
resides in nearly 35% area of the whole country (Zhou and Tol,
2004). The water scarcity issues in northern China have been 4.5. Desalination in Saudi Arabia
complicated by the upstream and downstream use conflicts and
political issues (Cai, 2008). The Chinese government is attempting Saudi Arabia withdraws about 20,000  106 m3 annually despite
to address this uneven distribution through an ambitious $60 its annual renewable water capacity of only 2400  106 m3
billion South-to-North water transfer project (Liu and Zheng, (Kajenthira et al., 2012). It is the largest country in the world
2002), which aims to divert water from the Yangtze River to drier without rivers and lakes (Llamas and Custudio, 2003) and has a
regions in the North, where major cities like Beijing and Tianjin are population of 25.7 million. About 80% of the water supplies are met
located with the hopes of attaining economic prosperity and sta- with the non-renewable groundwater sources which require
bility in more populous northern region where the per capita share desalination due to high salinity. Saudi Arabia has the largest share
of regional water has declined to near-crisis levels (shown in (17%) of the worldwide desalination capacity. The country needs to
Fig. 8A). The water transport system consists of an extensive system increase the daily desalination capacity by 6  106 m3 which may
of tunnels, dams, reservoirs and canals, all connecting and diverting cost up to 200 billion dollars (Mezher et al., 2011). Between 2012
water from China's largest rivers e including the Yangtze, Yellow and 2015, the desalination capacity was expected to grow by 9.5
and Hai River. At its peak capacity, the entire system can move percent annually. The Saline Water Conversion Corporation (SWCC)
nearly 45 billion m3 of water annually. First proposed by Mao plans to invest $11.7 billion in capital expenditures and $4.5 billion
Zedong in 1952, the project was officially approved in 2002. The in operations expenditures through 2020, highlighting the vast
first stage of construction, the 717 mile (1155 km) long eastern opportunities for desalination technology development and engi-
route, was completed in 2013. This project had to face many criti- neering, procurement, and construction firms (KSA, 2013).
cisms due to enormous environmental damage that it created Saline Water Conversion Corporation in Saudi Arabia con-
through mining, construction and environmental pollution and structed the world's largest desalination in Ras Al-Khair, an in-
increased potential of floods and droughts in some areas and with dustrial city with a capacity of 0.728  106 m3 per day in 2014
displacement of many people from their homes (Futuretimeline, (Water technology 2015a). The hybrid desalination plant consists of
2015). After all this, it appears that by 2050 southern China may 8-MSF units and 17-RO units. The MSF units have a capacity of
not be in a position to transport water to the northern region since 0.606  106 m3 per day while the RO units hold a capacity of
the region has already begun to experience drought weathers 0.257  106 m3 per day. This project also houses 2650 MW com-
leaving desalination an option. The central government's Special bined cycle power plant. The project construction cost was SAR
Plan for Seawater Utilization calls for producing 3.05  106 m3 (807 27bn which is approximately $7.2bn (Water technology 2015b).
million gallons) a day of purified seawater by 2020 e roughly There are six major projects expected to tender during the
quadruple the country's current desalination capacity. Fig. 8B 2015e2016 timeframe. The largest is the Jubail thermal and reverse
shows the energy requirements for various water supply options osmosis (hybrid) project estimated to be worth US$ 3 billion (GWI,
including groundwater supplies, local and distance water trans- 2015). The remaining five projects are all saline water conversion
portation and brackish or seawater desalination in China. It is clear plants utilizing reverse osmosis; they include Rabigh Phase 4, US$
that seawater desalination requires about 9 times higher energy 1.2 billion; Umluj SWRO, US$ 30 million; Aqeer SWRO, US$ 20
requirements when compared to groundwater supply source. million; and, South Dhahran SWRO, US$ 200 million. For this to
However, it can be noticed that the desalination costs have been happen, developments in engineering services, membrane and
reduced significantly over the recent years from 12.5 RMB/m3 in thermal desalination technologies and efficient utilization of solar
1995 to 5 RMB/m3 in 2015 (Fig. 8C) while the desalination market energy should be pursued. Wastewater treatment also needs
V.G. Gude / Water Research 89 (2016) 87e106 101

Fig. 8. Water transfer project in China. (A) Red lines show the southenorth water transportation project for transferring water from Yangtze River to Beijing and Tianjin major cities;
(B) energy requirements for various water supply options; (C) trends in desalination costs between years 1995 and 2015; and (D) desalination market value over the recent years.
(For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)

investments of nearly $23.9 billion in capital expenditures and desalination are Caribbean Islands, Morocco, Spain, Oman, Iran,
$11.9 billion in operations expenditures between 2012 and 2020. Egypt, Bahrain, Turkey, Algeria and Jordan which completes the top
Saudi's wastewater treatment capacity is expected to expand by 20 desalination markets in the recent years. Advancement of
12.8 percent annually as well. Water reuse should be given a high desalination industry also promotes the economic growth and local
priority considering the water scarcity and the economic growth. employment security for the nations. In many of these countries
Saudi Arabia is the third-largest per capita water user in the world the need for desalination industry arises since there are simply not
(SAMC, 2010), yet currently treats and reuses only 18% of the total adequate freshwater sources or they are heavily polluted rendering
wastewater produced (Al-Musallam, 2006; U.S.-SABC, 2009, 2010; them not suitable for potable uses.
Kajenthira et al., 2011). Kajenthira et al. (2012) suggested that
implementation of increased water conservation and reuse across 5. Affordable desalination e a worldwide scenario
the oil and natural gas sectors could conserve up to 29% of total
industrial water withdrawals at costs recovered over 0e30 years, At present, one third of the world population is lacking access to
depending on the specific improvement. This study also indicated clean water and by 2025, 1.8 billion people will experience absolute
that increasing wastewater treatment and reuse in six high-altitude water scarcity, and two thirds of the global population will be living
inland cities (Macca, Taif, Medina, Khamis, Abha, and Riyadh) could under water-stressed conditions (Macedonio et al., 2012). Many
save a further $225 million (2009 dollars) and conserve 2% of Saudi parts of the world are reaching a critical situation of water scarcity.
Arabia's annual electricity consumption. Water scarcity is classified into physical water scarcity and eco-
nomic water scarcity (Rijsberman, 2006). Physical water scarcity
4.6. Desalination market around the world means that there are simply no adequate water resources to meet
the current needs. The economic water scarcity refers to a situation
The top desalination markets between 2010 and 2013 were where the water sources are available in abundance (water
listed as Saudi Arabia ($1e5.16 billion); USA ($2e4.42 billion) and resource availability is higher than the withdrawal, or the resource
Australia ($3e3.24 billion) followed by Israel, Kuwait, Libya and capacity is underutilized) but the mechanisms to acquire access to
UAE at $2.5 billion; $2.480 billion; $2.44 billion; and $2.2 billion these sources have not been established or are influenced by hu-
respectively (GWI, 2010). China and India, the most populated man, institutional, and financial capital limitations. This could be
countries would have unprecedented demand for the desalination because of the economic issues, polluted water resources and po-
industry to meet the ever growing water supply needs. These litical and social and climatic issues. In most cases the economic
countries were at $1.52 billion and $1.3 billion respectively fol- water scarcity refers to a situation where the affordability to obtain
lowed by Chile with $1.2 billion. Other countries in most need for clean water has been jeopardized due to economic issues. Physical
102 V.G. Gude / Water Research 89 (2016) 87e106

water scarcity is currently experienced in southwestern region of product (GNP) per capita. Thus countries in this quadrant, such as
the United States which includes California, Arizona, New Mexico the arid but rich Gulf oil states, can afford the high cost of clean
and Texas and Mexico, Middle Eastern and North African countries water supply even when this includes large-scale seawater desali-
(MENA region) and southeastern European countries, Southern nation. These countries may enjoy the desalinated water, despite
India, Pakistan, Mongolia, Afghanistan, Kazakhstan, Turkmenistan, their extreme first order scarcity due to availability of ample non-
Uzbekistan, Tajikistan and western Australia. Economic water renewable energy sources and inexhaustible seawater sources.
scarcity is experienced in central and Latin America including The bottom left area depicts poor regions with ample water re-
Caribbean region, South and central Africa, North India, some parts sources. In these regions the cost of desalinated water supply may
of China and some other Asian countries. In some of these coun- be low, but as the GNP is also low even these comparatively low
tries, desalination supported by renewable energy sources could be costs may become a significant burden. These countries do not
implemented as a sustainable option but many non-technological suffer from first-order scarcity. Because of second-order scarcity
barriers need to be overcome. and particularly low financial capacity, desalination may not be an
As it was discussed before, the energy requirements for desali- attractive alternative. Examples of such countries would include
nation have fallen significantly in recent years. Although the energy Congo, Madagascar, or Bangladesh. The worst situation, however, is
budget for domestic desalination units appears to be reasonable, depicted by the upper left quadrant. This is the situation where the
many communities around the world cannot afford these energy per capita cost of sustainable clean water to all people at all times
demands and associated costs. Fig. 9 depicts the desalinated water would require high cost per capita, and in which such costs would
affordability around the world. The vertical axis presents the cost be a large share of the per capita GNP. Thus, regions in this situation
per capita of desalinated water to all at all times. The horizontal axis may find that the costs of sustainable clean water are unaffordable
depicts the ability to pay for water and it increases from left to right. for their citizens and especially through desalination technologies.
Four basic quadrants can be identified. The bottom right quadrant The countries most prone to this situation are, naturally, poor
depicts situations where the costs of supplying water in a sus- countries in arid or semi-arid regions. Such countries may have had
tainable manner are low, and countries' ability to pay is high. These relatively high adaptive capacity, as demonstrated by traditional
situations are limited largely to rich humid regions, particularly in societal institutions and infrastructures, and yet may not have the
Western Europe and North America. In these countries the main financial resources to cope with rapid increases in population or
cost may pertain to assuring adequate water quality and pollution pollution due to a weak economic base. Desalination alternative
prevention. The top right quadrant pertains to regions where the may not be meaningful for many low income countries due to very
per capita cost of clean water supply is high, but as these regions are low GNP where other meaningful indicators could make more
rich these costs are still only a small share of the total gross national sense (Feitelson and Chenoweth, 2002).

Fig. 9. Water desalination affordability around the world (These water tariffs include water and wastewater fixed costs, water variable costs, wastewater variable costs and total
sales tax (GWI)).
V.G. Gude / Water Research 89 (2016) 87e106 103

Comparison of current worldwide water supply costs could environmental opposition (concern for greenhouse gas emissions
provide a different perspective as shown in Fig. 9. Many developed and marine environment), water reuse and recycling programs,
countries such as Canada and USA and many European countries high capital costs, high energy costs, and political instability and
have high freshwater costs. Water supply costs (tariffs including fluctuating drought period which will not allow for a critical eval-
wastewater disposal) of as high as 9.7 $/m3 were also reported (e.g., uation of the future needs of a community. Cost is perceived to be
Copenhagen, Denmark). These data are collected from GWI data- the major hurdle for the desalination plants to produce freshwater.
base (GWI, 2014). The water costs in highly populated (such as It is estimated that freshwater supply costs could be 5 to 6 times
China, India, and Pakistan and Bangladesh) and poor countries are higher even with favorable financial package. Despite these high
barely minimum and often water supplies are available free of cost. costs, several desalination projects are currently being planned to
The citizens in these countries may not be willing to pay the high replace some part of the water supply that Southern California now
costs of desalinated water. It is interesting to note that the water draws from the Colorado River. Because the cost analysis shows
costs (mostly supplied by desalination processes) in some of the that desalinated water is cost-effective for this region which is
Middle Eastern countries are very low with Jeddah in Saudi Arabia stricken by continuous droughts recently.
charging about 0.03 $/m3 (Zetland and Gasson, 2013). The water
prices are heavily subsidized in some of these countries despite the 7. Other alternatives
use of large quantities of non-renewable energy sources. A reason
for this could be that desalination plants are often combined with Other potential sources for water supplies are brackish water
power production schemes reducing the water costs significantly. sources available in local aquifers, produced waters from oil and gas
The governance of the country also influences water costs. How- industries and recycled water from wastewater treatment plants.
ever, there is no clear relationship between the wealth and the These can be considered as non-conventional water sources for
water costs of a nation. For example, the water costs for Gent, water desalination in that the water composition and salt levels are
Belgium are 7.43 $/m3 in 2011 but the water prices in Egypt are significantly different from seawater sources and the technologies
$0.04/m3. The low water prices could possibly be related to low required to treat these are also different. For example, ground
capital and labor costs in Egypt. However, based on the GNP, (brackish) water has a greater tendency to precipitate sulfate (for
Belgium has a GNP per capita which is 14 times higher than that for example, gypsum), carbonate (for example, calcite), and silicate
Egyptians while the water costs are 188 higher for Gent, Belgium scales. The dissolved solids concentration of saline groundwaters
(Zetland and Gasson, 2013). typically is less than that of seawater. The tendency of saline
groundwater to form scale is important to its suitability for use in
6. What drives desalination? desalination. Saline groundwater also may contain some constitu-
ents, such as arsenic, elevated radioactive compounds, and dis-
Considering the freshwater costs from desalination alone, they solved organic material, at greater concentrations than in seawater.
have dramatically decreased over the past decades due to the im- Although a relatively large body of information exists on the
provements in process schemes, materials for construction and chemical behavior of solutes within desalination systems, relatively
other significant improvements in membrane materials, water flux, little research has been undertaken on the chemical suitability of
durability and costs and energy recovery possibilities. However, the water from various aquifers as sources for desalination.
desalination costs and market implementation are affected by Brackish water desalination may have less environmental im-
external factors such as population growth, climate change, envi- pacts based on life cycle analysis. This is mainly due to the fact that
ronmental emissions, and economic downturn or growth some of the brackish water sources have lower salt concentrations
(Masciangioli et al., 2004). Many countries will be affected by these which reduces the energy demands for salt separation and asso-
external factors in their ability to afford for desalinated water. ciated environmental emissions (Mun ~ oz and Fern andez-Alba,
Fig. 10 shows how external factors affect the per capita costs and 2008). Energy and environmental impacts may vary by location
the ability to pay for desalinated water costs. Other factors that because brackish water sources have a wide range of dissolved
influence the desalination industry positively for a coastal com- solids concentrations (between 1000 mg/L to 150,000 mg/L). For
munity will be saltwater intrusion issues due excess groundwater example, seawater desalination may have an energy and air emis-
pumping, industrial expansion, population growth, tourism in- sion footprint of 1.5e2.4 times larger than that of imported water in
dustry growth, cheap energy sources (as in oil rich countries) California which can reduce the environmental impacts of brackish
subsidized environmental emissions fee, and most importantly water desalination (between 53 and 66%) in comparison. If the
water shortages and continued drought periods. The factors that annual water needs (326 m3) of a typical Californian were to be met
might inhibit the growth of the desalination market will be the with imported water, it will require 5.8 GJ of energy with associated
360 kg of CO2 equivalent emissions while seawater desalination
may require 14 GJ and release 800 kg of CO2 equivalent emissions.
Interestingly, water desalination using solar thermal energy has
lower greenhouse gas emissions than that of imported or recycled
water as discussed in Stokes and Horvath (2009).
Although brackish water sources are attractive for desalination,
it should be noted that these sources are not infinite unlike
seawater sources. Increased extraction of groundwater may result
in a situation termed as “water mining” due to the fact that
groundwater aquifers recharge at a much slower rate than they are
consumed. This may result in land subsidence. If brackish
groundwater sources are exploited for domestic water supplies,
continued extraction of brackish water in coastal communities may
result in saltwater intrusion into groundwater aquifers which
eventually increases energy consumption for the desalination
Fig. 10. Energy, environmental and economic drivers of desalination industry. process along with environmental emissions.
104 V.G. Gude / Water Research 89 (2016) 87e106

Produced waters are different from groundwater sources since from the desalination plants can be reduced by utilizing
they are a byproduct of various energy production operations and renewable energy sources and by modifying the process
its extraction is inevitable. These can serve as excellent sources for schemes to use less toxic chemicals, freshwater production
desalination processes. However, the salt concentrations are often through desalination systems can become an affordable, sus-
10e20 times higher than the seawater sources but vary between tainable, and environmentally-benign approach in the near
100 mg/L and 400, 000 mg/L of total dissolved solids (Guerra et al., future.
2011). This fact poses significant limitations for existing desalina-  The environmental, economic and social components of desa-
tion technologies because they are not designed for this type of lination sustainability are similar in nature to other water sup-
brackish water source. Other significant issue with produced wa- ply and wastewater treatment alternatives. As the economic and
ters is that they contain high concentrations of organic compounds social issues related to desalination are more flexible in nature,
which may also affect the performance of desalination environmental and ecological issues need more non-biased and
technologies. comprehensive investigations. For regions where desalination is
Water reuse is emerging as a promising non-conventional water the most feasible alternative, the environmental issues demand
resource (Molinos-Senante et al., 2011). However, proper assess- serious consideration.
ment of reuse options are essential to determine its suitability. As  A new perspective needs to be adopted to deal with the water
shown in Table 3, comparison between the water recycling process scarcity issues and the crisis around the most drought stricken
treatment and the desalination process schemes shows that areas to promote desalination as alternative or primary water
advanced treatment of wastewater effluents need additional pro- supply process. Engineers and scientists along with the policy
cess steps to deliver water quality suitable for most indirect potable makers and regulators are urged to exercise caution in evalu-
uses (National Water Commission, 2008). This indicates the po- ating the desalination process as an option for meeting the
tential for higher environmental emissions associated with them. water demands.
In the case of desalination plants, the salt concentrations are  A well-informed, unbiased and objective assessment with
generally higher and with water recovery this is expected to be reference to other available options is necessary to design a
even higher. However, with proper dilution and pre-treatment of scientifically feasible, economically affordable and environ-
the brine discharge from the desalination outfalls, the ecological mentally friendly water supply scheme for a local community.
and environmental impacts can be mitigated. This can only become possible with availability of more detailed
studies addressing ecological and environmental impacts of
8. Conclusions desalination processes at small and large scale applications. The
effects of various chemicals used in Pre- and Post-treatment of
Once considered as energy- and cost-intensive technology for desalination process streams on the consumers as well as the
freshwater production, desalination has now become a promising receiving water bodies should be studied in detail.
alternative for providing freshwater needs around the world. The  Since desalination is not a sustainable alternative for all situa-
desalination industry is projected to experience unprecedented tions, other alternatives such as water reuse and rainwater
growth concurrently with population growth and rapid industri- harvesting should also be actively pursued because these op-
alization all over the world. The following areas need to be given tions carry a different set of environmental benefits.
proper consideration while planning for new desalination plants:
Acknowledgments
 Desalination costs have declined significantly for both thermal
and membrane technologies over the past decades. Significant This research was supported the Department of Civil and Envi-
cost reductions have been achieved, especially for RO technol- ronmental Engineering (CEE), the Bagley College of Engineering
ogy, favored by growth rate, plant capacity, higher permeation (BCoE), and The Office of Research and Economic Development
rates and improvements in membrane materials. However, (ORED) at Mississippi State University. The author acknowledges
further reduction in desalinated water costs in the future is quite the funding support from the United States Environmental Pro-
a challenging task despite the continuous improvements in tection Agency (USEPA) through P3 (People, Planet, and Prosperity)
membrane and energy recovery technologies since the equip- Phase I Awards SU835721 and SU835722.
ment, raw materials, and energy costs are rapidly rising. Hence,
greater understanding of water scarcity scenarios and discov- References
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