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    Chem

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    Ashwina Jaikrishnan

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    © All Rights Reserved
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    of 17
    LEVEL-I (MAIN) [eae e (Theory Questions) ; Straight Objective Type Quetone _ Fundamental particles 1. The value of e/m for an electron is 1) 1.78 x 108 cfg 2) 1.6724 x 10° cg 3) 0.005486 c/g 4) 1.00866 c/g F 2. The nucleus of tritium consists of 1)'1 proton + 1 neutron 2) 1 proton + 3 neutrons 3) 1 proton + zero neutrons 4) 1 proton + 2 neutrons 3. Sodium ion is isoelectronic with the atom: E 1) Mg 2 ar 3) Ne 4yN> 4. The charge of an electron is 1.6 x 10-9 coulombs, What will be the value of charge on Na* ion 1) 16 x10-%C 2)3.2x 10°C 3) 24 x 109 C 4) 11 x 16 x 10-9 C Nature of light, POT, PEE 5. In electromagnetic radiation, which of the following has greater wavelength than visible light? 1) U.V-rays 2) LR-tays 3) Gamma rays 4) X-rays 6. Which of the following radiation following has highest wave number? 1) Microwaves 2) Xerays 3) LR. = rays 4) Radiowaves 7. Taree energy levels P, Q, R of a certain atom are such that Ey < Bg < Fp If Ay. Ap and Ay are the wave length of radiation corresponding to transition R > Q:Q — P ‘and R—> P respectively. The correct relationship between ,, %> and A; is Vet 2b 1) hy+ha =o Det Dandie Dy ria wae w Bohar's atomic model : ; 8, The total energy of electron in an atom js a combination of potential encrey (PE) and kinetic energy (KE) If total energy is -E for an electron in an atom, then its (KE) and (PE) respectively are 1) 28, -B 2) 2B, B 3) B,-2B 4)B,-B Hydrogen Spectrum, E of ¢, velocity of eradius of nth orbit 9. Which of the following transistions in hydrogen atom will require the highest amount of energy : Inelwne2 2)nelton=3 3)n=2tonel 4)n=3tone4 10. In Bohr series of lines of hydrogen spectrum, the third line from the:ted end corresponds to which | oe of the following inter - orbit jumps of the electron for Bohr orbits in an atom of hydrogen ? )392 nS42 41 4245 Debroglie theory . : d 11. The de Broglie wavelength associated with a moving particle of fixed mass is inversely proportional ‘0 F 1) Its kinetic energy 2) Square root of its kinetic energy 3) Square of its kinetic energy 4) Cube of its kinetic energy [TARGET SERIES for Jr. ICON IC Students s c 3} [OBJECTIVE CHEMISTRY IA & 18] 12. The de Broglie wavelength of a Particle with mass I g and velocity 100 m/s is 1) 6.63 x 10° m 2) 6.63 x 104 m 3) 6.63 x 10°5 m 4) 6.63 x 10° m ~ The graph between momentum p and de-Broglie wavelength A of photon is Ko’ 14. If the wavelength of the electron is numerically equal to the distance travelled by it in one second, then » aa fe Dred aaah » aft 15. An electron of velocity “x’ is found to associate with a wave. The velocity to be possessed by the neutron to have half the de-Broglie wavelength possessed by electron is » iw 2 ag 5 4) 1840 x Quantum numbers 16. The impossible set of quantum numbers is C) 1yn=2,1=0,m=0,s=+1/2 ‘2)n22,l21, m=0,s=+1/2 Ajn=2,/20,m=1,s=-12 4)n=3,/=1, m=-1,s=-12 7. The two electrons occupying an orbital are distinguished by 1) quantum number 2) Azimuthal quantum number 3) Magnetic quantum number AS Spin quantum number The number of sub levies in the quantum level n = 3 is n1 22 wa 44 ¥, The number of different spatial arrangements for the orbital with / = 2 is 1 23. 35 4)7 Orbitals 20. Which one of the following expressions represent the glectron probability function (D) 1) ame de y* 2) ane dry ‘4c? dry? 4) 4ne dry 21. The density of electron cloud of the orbital d,, in yz plane is Ay Leto 2) Maximum 3) Not determined 4) Infinite 22. The number of nodes and nodal planes in 4p orbital are respectively phi 21,2 32,3 4) 3,2 23. There is no difference between a 2p and a 3p orbital regarding WA 1) Value of 2) Size 3) Bnergy ‘Shape 33}¢$—___ ‘TARGET SERIES for Jr. ICON IC (OBJECTIVE CHEMISTRY TA H 183} {ATOMIC STRUCTURE] Electronic configuration 24, Electrons never pair, if there are emply orbitals in a given sub-shell. This is 1) Aufbau principle 2) Pauli’s exclusion principle jund’s rule of maximum multiplicity 4) Heisenberg's uncertainity principle 25. Nitrogen atom has 3 unpaired electrons in its ground state, It can be explained by 1) Auf bau principle 2) Pauli’s principle 4) Hund’s rule 4) All of these 26. In which of the following Aufbau principle is violated » Eth x fy 3) mel 2s 2p : 2p 27. Which of the following has maximum unpaired d-clectrons?, 1) Zn* re ©) 3) Ni* 28. Which one of the following pairs of ions have the same electronic configuration 2p 1) Cr, Fe 2 © A) Fe, Mn? n 3) Fe**, Co* . 4) Sc¥#, Coe } 29. Consider the following pairs of ions i) Se*® and Tit* ii) Mn*? and Fe*? iii) Fe*? and Co** iv) Cut and Zn*? ‘Among these pairs of ions, isoelectronic pairs would include 1) ii, iif and iv 2) ji, ii and iv 3) i, ii and iv 4) i, ii and iii 30. The incorrect electronic arrangement is 1) 2,8, 13,1 2) 2, 8, 12,2 3) 2, 8, 8,1 4) 2, 8, 82 (Lectrure Sheet/Class work) — Straight Objective Type Question: Nature of light, POT, PEE 1. The ratio of energies of two photons of wavelengths 2000 and 4000 A’. Dis4 24s1 31:2 a2 2. The wave length of light having wave number 4000 cm’ is 1) 25hm 2) 250m 3) 25hm_ 4) 25am 3. The work function of a metal is 4.2 eV. If radiations of 2000A° fall on the metal, then the kinetic ‘energy of the fastest photoelectron is 1) 1.6 x 10°95 2) 1.6 « 105 3) 64x10 4) 32x 10°F Bohar’s atomic model 4. The ratio of the radii of the first three orbits in an atom of hydrogen is 11:4:9 292421 31:2:3 4)3:2:1 [ATOMIC 6TRUCTURE 74 ~{EIOBJECTIVE CHEMISTRY 1A tg Hydrogen Spectrum, K of @, velacty of @ radius of nth orblt 5. ‘The equation corresponding to the wave number of spectral lines in Pfund series is to * eu 1a eft. 7 1 11 » (e 3] 2 Es 4] Py af 3] oR 4-4] ‘Total number of spectral lines when electron jumps from 8" orbit to 2% orbit 6 2) 36 3) 21 4) 38 An excited hydrogen atom emits a photon of wavelength 2. while Teturning to the ground state. jf R is the Rydberg’s constant, then the quantum number n of the excited state is 1) ik 2) R= ee 4) SiROR-D & The wavelength of the first member of the Balmer series in hydrogen spectrum is x A®.Then the wave length (in A°) of the first member of Lyman series in the same spectrum is 5 4 27 DB 25% 3) rad 4) ae 9. The minimum and maximum values of wavelength in the Lyman series of a H atom are, respectively 1) 364.3 nm and 653.4 nm 2) 91.2 nm and 121.5 nm 3) 41.2 nm and 102.6 nm 4) 9.12 nm and 121.5 nm Debroglie theory 19, A proton and an o.-particle are accelerated through the same potential difference. The ratio of the de-Broglie wave length of proton and o.- particle is 1 ne DE 322 42 Be*? and a proton are accelerated by the same potenatial, their de-Broglie wavelengths have the ratio (assume mass of proton = mass of neutron) 112 Dis 31a 4) 2:1 12. A particle X moving with a certain velocity has a debroglie wave length of 1A, If particle Y has a mass of 25% that of X and velocity 75% that of X, debroglies wave length of Y will be 13h 25.33 A 3) 6.88 A 448A iW 13. A cricket ball of mass 0.5kg is moving with a velocity of 100 ms“, the wavelength associated with its motion is 1) 13.25 « 10m 2) 13.25 x 104m 3) 13.25 x 10-%m_ 4) 6.6 x 10m 14, If the Planck's constant h = 6.6 x'J0™ Js, the de-Broglie’s wave length of a particle having momentum of 3.3. 10% kg.ms will be 1) 2 10m 21% 10% m 3) 105m 4)4x 10 m 15. An electron of velocity ‘x’ is found to associate with a wave. The velocity to be possessed by the neutron to have half the de-Broglie wavelength possessed by electron is x x x ) Teo 2 7480 3 0 4) 1840 x ae 4€@ TARGET SERIES for Jr. ICON IC Students Heisenberg uncertainity principle 16 An electron is allowed to move freely in a closed cubic box of length of side 10 em. The uncertainty in its velocity will be 1) 3.38 x 104m sec! 2) $.8 x 104 msec"! 3) 4 x 105m sec"! 4) 4x 10° m sec"! 17, A particle of mass one microgram is confined to move along one direction (x-axis) within a region 1 mm in extension. What is the uncertainity in its velocity? 1) 3.313 x 10 cm! — 2) 5.012 x 10% em! 3) 8.325 x 10% cm! 4) 5.27 x 107! emt 18. ‘The uncertainities in the velocities of two particles A and B are 0.05 and 0.02m.sec"' respectively. The mass of B is five times to that of mass A. What is the ratio of uncertainities (4) in their positions n2 2) 0.25 3)4 41 19. The mass of a praticle is 10-!g and its radius is 2 x 10+ cm. If its velocity is 10°6 cm sec"! with 0.0001% uncetrainty in measurement, the uncertainty in its position is: 1) 52x 10m 2) 5.2 x 107m 3) 5.2 x 10m 4) 5.2 x 10%m 20. Uncertainity in position of a minute particle of mass 25g in space is 10-5 m, What is the uncertainity in its velocity (in ms“) ? (h = 6.6 x 10° Js) 1) 21 x 10 2) 0.5 x 19° 3) 241 x 108 4) 05 x 103 21. The uncertainity in momentum of an electron is 1 x 10-$ kgam/s. The uncertainity in its position will be (h = 6.62 x 10™ kg.m/s) . ‘ 1) 1.05 x 10° m 2) 1.05 x 10° m 3) 5.27 x 10° m 4) 5.27 x 107m Quantum numbers L . 22. Correct set of four quantum numbers for the valence electron of Rubidium (Z =,37) is AV5,0, 0, +12 ° 2) 5, 1,0, #12 3) 5, 1,1, +12 4) 6, 0, 0, #172 23. For a particular value of azimuthal quantum number (J), the total number of magnetic quantum number values (m) is given by m+1 -1 2m+1 +1 Die Ales l= ane 24. Ifn and / are principle and azimubtal quantum numbers respectively, then the expression for calcu- lating the total number of electrons in any energy level is fen fen ee feact 1) D221+1) 2) ¥221+1) 3) D@l+) AY, 221+) i=) iat i=} =} 25. Which of the following sets of quantum ‘numbers describes the electron which is removed most TARGET SERIES for Jr. ICON IC Students [53} @h13 easily fom a potassium atom in its ground state ? 1 Daw3telmelm=-5 2)n=2,1=1,m,=0,m,= + 1 3)n=4,1=0,m,=1,m= +5 Aj n= 4,120,m,=0,m,= +5 Orbitals . 26. The electrons, identified by n & 1; (i) n=4,/ = M(ii)n=4, 1 =0 (ili) n=3,/ =2 (iv) n=3, 1s can be placed in order. of increasing energy, from the lowest to highest as: 1) Gv) < Gi) < dil) <1@) 2) ii) < (iv) < (i) < (iii) 3) (i) < (ii) < Gi) < iv) 4) iii) < (i) < (iv) < (ii) ‘Numerical/ Integer Type Questions 27. ‘The radius of first Bohr’s orbit for hydrogen is 0.53 A°, The radius of third Bohr’s orbit would be 28. If each hydrogen atom in the ground state, 1.0 mole of H atoms are excited by absrobing photons of energy 8.4 eV, 12.09 eV and 15.0 eV of energy, then the number of spectral lines emitted is equal to 29. ‘The engergy of separation of an electron in a Hydrogen like atom in excited state is 3.4 eV. The de-Broglie wave length (in A°) associated with the electron is __ 30. At 200°C the velocity of hydrogen molecule is 2.0 x 10cm/sec. In this case, the de-Broglie wavelength is about A. 31. The de Broglie wavelength of neutron at 27°C is 4, The wavelength at 927°C will be Ej the value of xis__ x 7 emg its . 2p 48 P= Wow many electrons maximumcan have n+! = 4 inan atom, 2B SS _ og 33. If magnetic quantum number of a given electron is represented -3, then what will be its principal quantum number ? +4. The atomic number of an element ‘M’ is 26, How many electrons are present in the M-shell of the element in its M* state ? 35. For how many orbitals, the quantum numbers n = 3, | = 2, m = +2 are possible ? 36. The number of waves make by a Bohr electron in an orbit of maximum magnetic quantum number +2is: 37. How many electrons in an atom with atomic number 105 can have (n + 1) = 8? 38. ‘The maximum number of electrons with s = +1/2 in an orbital for which I = 2 is _ 39. If the value of principal quantum number is 3, the total possible values for magnetic quantum number will be 40. Principal quantum number of the shell to which the g-subshell first arise is 41. Number of photons of light with a wave length of 4000 pm necessary to provide one joule of energy approximately x x 10!6 Then x is 42. The frequency of a radiation having a wave number of 2 x 10" cmr! will be x x 10% s-!. Then the value of x is 43. Photon having energy equivalent to the binding energy of 4th state of He* atom is used to eject an electron from the metal surface of work function 1.4 eV. If electrons are further accelerated through the potential difference of 4V then the minimum value of de-Broglie wavelength as- ated with the electron is : 44, uncertainty in position is Bi. Find uncertainty in measurement of de-Broglie wavelength (in A ) is x. The value of x/S = 45. Number of possible spectral lines which may be emitted’ in Brackett series in H atom, if electrons present in 9" excited level returns to ground level, are 46. In hydrogen atom the kinetic energy of electron is 3.4 eV, The distance of that electron from the nucleus in A° 47. The wavelength of a certain line in Balmer Series is observed to be 4329 A°, ‘To what value of ‘n’ does this correspond ? (R, = 109678 om!) (Z = 1) 48. The wavelength of m" line Balmer series for an orbital is 4103A°, What is the value of m ? 49, Heatoms in ground state (13,6 eV) are excited by monochromatic radiations of photon of energy 12.1 eV. Find the number of spectral lines emitted in H-atom. 50, The ratio of wave number of the’limiting line of Lyman series to the limiting line of Balmar series in Hydrogen spectrums is __ Sriesa (Practice Sheet / Homework) Straight Objective Type Questions Fundamental particles 1. The number of protons, electrons and neutrons in ,sBr*” are respectively 1) 35, 35, 80 2) 35, 35, 45 3) 80, 80, 35 4) 45, 45, 35 Nature of light, PQT, PEE 2. Which of the following properties of a wave is independent of the other? 1) Wave number 2) Wave length 3) Frequency 4) Amplitude 3. The energy of a photon is 3x10~? ergs. What is its wavelength in nm 1 (h = 6.62 x 1077 erg. sec; c = 3x10"cms) : 1) 662 2) 1324 3) 66,2 7 4) 6.62 4. The wave length of light having wave number 4000 em is 1) 25pm 2) 250m 3) 25h 4) 25m 5. Light of A = 310 nm is used in an experiment'of photo electric effect with Li (W = 2.5eV). What is its stoping potential OSV 210V 3)20V 4H1SV 6. The ratio of slopes of K,.,, ¥s. v and V, vs. v curves in the photoelectric effect gives (v = frequency, K,a, = maximum kinetic energy, Vy = stopping potential) 1) charge of electron * 2) planck’s constant 3) work function 4) the ratio of Plank’s constant to charge on ¢~ Bohar’s atomic model 1. Acconling to Bohr’s theory, the Ro momentum of ae in 5 orbit is yn ast 225 a 3) 10% 4) ww? = [TARGET SERIES for Jr. ICON IC Students i CPs OBJECTIVE CHEMISTRY iA ip No of revolutions mate hy the electron in one sec in 2” orbit of Be™ 1) 1.31 10% 2) 213 « 10 _ 9) 1.23 « 108 4) 2.68 x 104 An electron is revolving in the 2% orbit of He* ion. To this if 12.1 eV of energy supplied. Then which orbit it will be excited. D6 ne 34 42 In hydrogen atom the kinetic energy of electron is 3.4 eV. The distance of that electron from ti nucleus Danae 2) O.S29A° 3) 1.587A° 4) 21.16A° The energy of second Bobr orbit of hydrogen atom is -328 KJ. mol-!, hence energy of fourth Bohy ortet would be 2-41 mot 2) -82 J mot! 3) -166 J mor! 4) -1312 J mor! Hrdrogen Spectrum. E of <, velocity of = radius of nth orbit v the electron in the 1* Bohr orbit of H-atom is 218 x WW emvsec 2) 2.18 x 10% msec 3) 2.18 x 10 cm/se 4) 36559 x 10° cm/sec A spectral line of hydrogen with 7, = 4938AY belongs to the series Dime 2) Balmer 3) Paschen 4) Pfund Tota! mamnber of spectral lines when electron jumps from 8 orbit to 2™ orbit D6 Dx Ha 4) 38 4 % present in the 4* energy level of H- atom. When the electron returns to E transitions would be D4 2) 492,231 4) All the above energy level diagram of an atom and the origin of six spectral lines in 5 arises from the transition from level B to A). Which of the following *ill also occur im the absorption spectrum ? c 7s A : “5 : rat E 045.6 D12345.6 31.4.6 41,23 22, for the transition n = 2 to m = | im the hydrogen emission x yeing vpecal line also has 2 wavelength of X Da” ne i the Balmer series of spectrum of “H" 2) "Hy” line im the Balmer series of spectrum of “H" 3) ‘H," line in the Balmer series of spectram of “He~ 4) "Hy" line in the Balmer series of spectrum of “He” OBJE! E CHEMISTRY IA ATOMIC STRUCTURE |- 18. 19, 20. 2 22 23. 24, ‘The ratio of the wave lengths of the first line in the Lyman series of the spectrum of Hydorgen atom and the first line in the Balmer series of the spectrum of He* is 1) 20227 2) 2720 3) 275 4) 527 In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds to which ‘one of the following inter - orbit jumps of the electron for Bohr orbits in an atom of hydrogen ? 1342 542 N41 M295 In a certain electronic transition from the quantum level, ‘n’ to the ground state in atomic hydrogen in one or more steps, no line belonging to the Bracket series is observed. What wave numbers may be observed in the Balmer series? (R = Rydberg Constant) yp BR 2) 28 BR 9 BR oo RR 9°36 16°9 36°16 4°16 ‘The minimum and maximum values of wavelength in the Lyman series of a H atom are, respectively 1) 364.3 nm and 653.4 nm 2) 91.2 nm and 121.5 nm 3) 41.2 nm and 102.6 nm 4) 9.12 nm and 121.5 nm The ratio of wavelength values of series limit lines (n, = o>) of Balmer series and Paschen serie are 14:9 29:4 3)2:3 4)3:2 ‘The wavelength of the first member of the Balmer series in hydrogen spectrum is x A°.Then the wave length (in A°) of the first member of Lyman series in the same spectrum is 2 ax a3 os cues '; s A hydrogen sample is prepared in a particular excited state A. Photons of energy 2.55 eV/atom get absorbed into the sample to take some of the electrons to a further excited state B, Determine the number of photons when an electron in the higher excited state B returns to the ground state. 11s 2)10 36 43 Debroglie theory 25. 26. 21. 28. If A, Iyand dy are the wave lengths of electron in L, M, N energy levels of H-atom respectively. What is their decreasing order: 1) Ay > Ay > Ay 2) Dey > Pag > Io, 3) hy = Py = Ory 4) Day > oy >I, ‘The de Broglie wavelength associated with a moving particle of fixed mass is inversely proportional to 1) Its kinetic energy 2) Square root of its kinetic energy 3) Square of its kinetic energy 4) Cube of its kinetic energy ‘The de Broglie wavelength of a particle with mass 1 g and velocity 100 mis is 1) 6.63 x 103 m 2)663x10%m 3) 6.63 x 105 m4) 6.63 x 10 m A cticket ball of mass 0.5kg is moving with a velocity of 100 m.~!, the wavelength associated with its motion is 1) 13.25 x 10-%m 2) 1325 104m 3) 13.25 10m 4) 646 x 104m. [TARGET SERIES for Jr. ICON IC Students [73- § 7 [ATOMIC STRUCTURE | 5} ________(@¢[ OBJECTIVE CHEMISTRY IA aip [OBJECTIVE CHEMISTRY 1A & i 29. For an electron to have the same de broglie wave length as that of a Deutron, its velocity should j, times that of Deutron 1) 1836 2) 171836 3) 3672 4) 113672 Electronic configuration 30. No (wo electrons in an orbital can have parallel spin, This statement emerges from 1) Hund's rule 2) Aufbau principle 3) Pauli’s exclusion principle 4) (n + J) rule Numerical /integer Type Questions 31, Find the ratio of energy of a photon of 2000A° wavelength radiation to that of 4000A° radiation, 32. A light source of wavelength }, illuminates a metal and ejects photo-eleotrons with (K. Jax = leV, Another light source of wave length ro ejects photo-electrons from same metal with (K-B) pax = 4€¥, the value of work function is 0.1x. Then the value of x is__ 33, Assume that 2 x 107!” J of light energy is needed by the interior of the human eye to see an object. The number of photons of yellow light with 2,= 595.2nm are needed to generate this minimum energy is 12x, Then the value of x is__, 34, Number of photons of light with a wave length of 4000 pm necessary to provide one joule of ‘energy approximately x x 10' Then x is 35. The number of electrons with m = Q in an atom with atomic number 33 is 5x. Then the value of x is_ 36. Find out the number of angular nodes in the orbital to which the last electron of Cr enter 37. The orbital angular momentum of 3p electron is Va. Then the value of x is. 38. An ion Mn* has the magnetic moment equal to 4.9 BM. What is the value of a ? 39. A compound of vanadium has magnetic moment of 1.73 BM. It suggests the vanadium oxidation state in the compound is +x. Then the value of x is __. 40. The electron in the ground state for a single H — atom absorbs a photon of wavelength 97.28nm and it reaches to maximum level ‘n’ then when it returns from this level to ground state. Maximum numbers of lines can be obtained in its spectrum? 41. A transition for H-atom from II to I orbit has same wavelength as from n" orbit to 2 orbit for He* ‘ion. The value of ‘n’ is __ 42. The wavelength of m™ line Balmer series for an orbital is 4103A°. What is the value of m ? 43. The electron in Li?* ions are excited from ground state by absorbing 8.4375 R,, energy/electron. How many emission lines are expected during de-excitation of electrons to ground state ? i 1 24 33 41 5)2 62 72 83 92 10)2 Wy2 12)1 13)3 141 15)3 163 17)4 +=18)3 19)3 20)3 | 211 _22)1 234 24) 25)B_—-26)Z_27)2_—28)2_ 2/2 3)2_— ‘TARGET SERIES for Jr. ICON IC Students OBJECTIVE CHEMISTRY IA & 18/5) ERTOMIC STRUCTURE — — ——s 7 | eee) ; ve a 34 41 8/4 «©6973 8) -9)2_10)3 | WZ 12)2 13/3 14)115)3_—16)1—17)4 18)1 19) 1 20)3 21)$ 22)1 —-23)2 aaj 25)4 © -26)1 27) 283 -29)7 30) | $1)2 82)8 —33)4 34) 19 95)1 36) «9717 3B)1 99)9 40) 412 42)6 = 43)5 —44)545)6 = 46)2— 47) 48)4 «49)9 50)4 N24 = 3)1 41 5)4 BT 7) 8)T QT 10)9 11)2 12) 13)2 143 15)4—'16)2_—s17)4 18)1— 19)2 20)3 21)2 22)1 231 24)3 25/2 -28)2_ 27/1 28)S_-29)3_30)3 | 312 825 = 33)5—-34)2_ 95) -6)2_— 37/2 38)9_ 39)4 40/4 41)2 4294 433 7 LEVEL-I| (ADVANCED) |2> ‘Straight Objective Type Questions 1. An or. particle having kinetic energy 5 MeV falls on a Cu-foil. The shortest distance from the nucleus of Cu to which c— particle reaches is (Atomic no. of Cu = 29, K = 9 x 10? Nm?/C?) a) 2.35 x 103 m b) 1.67 x 104m ¢) 5.98 x 10-'m, 4) 1.67 x 10m 2. If the energy of H-atom in the ground state is -E, the velocity of photo-electron emitted when a photon having energy E, strikes a stationary Li** ion in ground state, is given by: 7 = Pe, -31 5 vee B) . ve PE $ v= 2 y -( iE) ™ “Vm 3 m m 3. As an electron is brought from an infinite distance close to nucleus of atom, the energy of electron a) Increases to a greater +ve value b) Decreases to a smaller +ve value ©) Increases to a smaller —ve value 4) Decreases to a greater —ve value 4. In electromagnetic radiation, which of the following has greater wavelength than visible light? a) UV-rays b) LR-rays ©) Gamma rays 4) X-rays 5. The increasing order of e/m values for electron, proton, neutron and alpha particle is, a) ©, p,m. bape, a np, ae d)n, a, pe 6. The e/m of proton is a) 1.78 x 10 cig b) 9.57 x 10* lg ©) 19.14 x 10% e/g d) 0.478 x 104 e/g 7. The maximum number of electrons accommodated in Sf orbitals as b) 10 o4 4) 18 Electrons never pair, if there are empty orbitals in a given sub-shell. This is rc ) Aufbau principle b) Pauli’s exclusion principle ©) Hund’s rule of maximum multiplicity 4) Heisenberg’s uncertainity principle ‘TARGET SERIES for Jr. ICON IC Students: y 19 (arom STRUCTURE |\\)) Sel ct the incorrect statement 8) KE, of photo-electron does not depend upon the wavelength of incident radiation 'b) Photoslectrie current depends on intensity of incident ratiation and on frequency ¢) Stopping Potential depends on frequency of radiation and not on intensity d) photoelectric current increases when we use photons of high frequency. The number of photons of light wave number ‘x’ in 10 J of energy source is: 10 ) 10 her ot on o 11. If radius of second stationary orbit (in Bohr’s atom) is R, ‘Then radius of third orbit will be a) RS b) OR o) RO 4) 2.25R 12. The radius of which of the following orbit is same as that of the first Bohr’s orbit of hydrogen atom? a) He* (n= 2) b) Li* (n= 2) o) L* (n= 3) 4) Bo (n = 2) 18. ‘The energy of an electron in the first Bohr orbit of H atom is ~13.6 eV , The possible energy value of the excited state for electrons in Bohr orbits of hydrogen is: a) 3.4 eV b) 4.2 eV ©) 6.8 eV 4) + 6.8 eV 14, onisation energy of He* is 19.6 x 10-''Y atom, The energy of the first stationary state of Li? is a) - 4.41 x 10° Jatom=! b) = 4.41 x 10-17 Jatom”! ©) = 44.1 x 10° Jatom-! 4) - 8.72 x 10° J.atom-! 15. In an atom, two electrons move round the nucleus in circular orbits of radii R and 4R. The ratio of the time taken by them to complete one revolution is al: bart 1:8 8:1 More than One correct answer Type Questions 16. Whenever a hydrogen atom emits a quantum in the visible region of Balmer series : 4) it may emit another quantum in Balmer series again ») it must emit another quantum in ultraviolet region of Lyman series +c) second quatum of wavelength 122nm will be emitted 4) second quantum will be emitted in Paschen series i.c., near infrared region 17. False statement about the de-Broglie’s wavelength of an electron in the first Bohr's orbit is 4) equal to the circumference of the first orbit ») equal to twice the circumference of the first orbit ©) equal to half the circumference of the first orbit 4) equal to one fourth of the circumference of the first orbit 18, . Which is correct in case of p-orbitals ? 4) They are spherically symmetrical b) They have strong directional character ©) They are three fold degenerate orbitals 49 Tit res nat shag x, ¥ ond su ae mo, [20 Ps TARGET S| for Jr. ICON IC Students 19. Choose the correct statement 4) Splitting of spectral lines in magnetic field is due to presence of degenerate orbitals ») In the presence of electricfield, energy value of P,, P, & P, of same orbit are different c) Degenerate orbitals differs only in their orientation 4) degenerate orbitals have same shape, but different energy 20. Which of the following statements are not correct 2) The ionization energy of a hydrogen-like species in its ground state is equal to the magnitude of energy of the orbit having a = 1 ) The ionization energy of a hydrogen-like species in its ground state increases in proportion to the Positive charge in its nucleus c) According to the uncertainty principle, ApAx 2p d) Sd —» 2s 26. Which of the following are wrong ? a) de Broglie relation is applicable only to microscopic particles ) The uncertainities in measurements are due to the imperfections of the techniques used to mea- sure them. c) The wave function y always has positive values. d) There is some probability of finding the electron even outside the boundary of the orbital. 27. According to deBroglie a) @ moving electron possess wave character _b) light posses particle character ¢) a moving proton posess wave character 4) all moving particles possess wave character ‘ATOMIC STRUCTURE [335 [OBI 28. In which of the following conditions the de Broglie wavelength of parti particle B (m, > my) ? a) Linear momentum of these particles are same b) Move with same speed ) Move with same kinetic energy d) Have fallen through same height 29. Select the correct statements about the wave function y a) W must be real b) W must be single values, continuous c) Whas no physical significance 4) y' gives the probability of finding the electrons 30. The probability of finding an electron in the p, orbital is a) zero at nucleus ») the same on all the sides around nucleus ©) zero on the z-axis 4) maximum on the two opposite sides of the nucleus along the x-axis Linked Comprehension Type Questions Hinked Comprehension Type Questions Passage-I : Excited atoms emit radiations consisting of only certain discrete frequencies or wavelengths. In spectroscopy it is often more convenient to use frequencies ot wave numbers than wavelength because frequencies and wave numbers are proportional to energy and spectroscopy involves transitions between different enetgy levels. The line spectrum shown by a mono electronic excited 1st 2R|—-— E al 31. The ratio of wavelength for II line of Balmer series and I line of Lyman series is at 2 3 a4 2. The given diagram indicates the energy levels of certain atom. When an electron moves from 2E level to E level. a photon of wavelength 2, is emitted. The wavelength of photon emitted during its transition from 4E jevel to E level is stom (a fnge print of an atom) is called atomic spectrum. a 3 3A [-« cA oF a ; 4B 3 °) & 4) 3A E 3 Passage-II : : The only e- in the H-atom resides under ordinary conditions on the first orbit when energy is supplied, the e-moves to higher energy shells depending upon the amount of energy absorbed. When an e~ emits energy i.e. the e~ returns to the lowest energy state, from this Lyman, Balmer, Paschen, Bracket, Pfund series are there; so different spectral lines in the spectra of atoms correspond to different transitions of e~ s ftom higher to lower energy levels: 33. If the shortest wavelength of H atom in Lyman series x, then longest wavelength in Balmer series of He* is Box x 9x Sx as 4 os 9 (2)

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