You are on page 1of 18

Diresul Navy RDT-GF liq 150 Page 1(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

SECTION 1: Identification of the substance/mixture and of the


company/undertaking
1.1. Product identifier
Trade name
Diresul Navy RDT-GF liq 150
Material number: 172074

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Textile processing industry
Type of use : textile dye

1.3. Details of the supplier of the safety data sheet


Identification of the company
Archroma Ibérica S.L.U.

ZAL - Prat, c/ Cal Coracero, 46-56


8820 El Prat de Llobregat (Barcelona)
Telephone no. : +34 93 479 83 00
Information about the substance/mixture
Product Stewardship +34 93 479 8300
e-mail: PS.MSDS-Iberica@archroma.com

1.4. Emergency telephone number


+44 (0) 1235 239 670 (24 h)

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
Hazard class Hazard category H-phrase
Skin corrosion Category 1 Causes severe skin burns and eye damage.
Serious eye Category 1 Causes serious eye damage.
damage
Contact with acids liberates toxic gas.
Classification according EC Directive (67/548/EEC or 1999/45/EC, as amended)
Category of Hazard symbol R - phrases
danger/Category
Contact with acids liberates toxic gas.
Corrosive Causes burns.

2.2. Label elements


Labelling according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
Diresul Navy RDT-GF liq 150 Page 2(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Hazard pictograms

Signal word
Danger
Hazard statements
H314 Causes severe skin burns and eye damage.
EUH031 Contact with acids liberates toxic gas.
Precautionary statements
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.

2.3. Other hazards


No additional hazards are known except those derived from the labelling.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
sulfur dyestuff
anionic

Hazardous ingredients
Sodium sulphide
Concentration : 2-4%
CAS number : 1313-82-2
EC number: 215-211-5
Index Number 016-009-00-8
REACH - Registration 01-2119513694-38-0005
number according to
article 20(3):
Diresul Navy RDT-GF liq 150 Page 3(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Classification hazard substance EC


C Corrosive R34
Xn Harmful R22
R31
N Dangerous for the environment R50
GHS classification EC
Corrosive to metals Category 1 H290
Acute toxicity Category 3 H301
Skin corrosion Category 1B H314
Acute aquatic toxicity Category 1 H400
Serious eye damage Category 1 H318
EUH031
EUH071

Sodium xylenesulphonate
Concentration : 7 - 10 %
CAS number : 1300-72-7
EC number: 215-090-9
Classification hazard substance EC
Xi Irritant R36
GHS classification EC
Eye irritation Category 2 H319

2-(2-Ethoxyethoxy)ethanol
Concentration : >= 7 - <= 10 %
CAS number : 111-90-0
EC number: 203-919-7
Classification hazard substance EC
Xi Irritant R36
GHS classification EC
Eye irritation Category 2 H319
The text of the R-phrases is shown in section 16.
The text of the H-phrases is shown in section 16.

SECTION 4: First aid measures


4.1. Description of first aid measures
General information
In the case of accident or if you feel unwell, seek medical advice immediately.
After inhalation
Move the victim to fresh air.
Keep patient warm and at rest.
In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
Diresul Navy RDT-GF liq 150 Page 4(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

After contact with skin


Take off contaminated clothing and shoes immediately.
In case of contact, immediately flush skin with soap and plenty of water.
Call a physician if irritation persists.
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion
IF SWALLOWED:
Rinse mouth with water.
Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed
Hazards
The possible risks known are those derived from the labelling (see section 2).

4.3. Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media
all
Extinguishing media that must not be used for safety reasons
No restrictions

5.2. Special hazards arising from the substance or mixture


Carbon oxides
Nitrogen oxides (NOx)
Sulphur oxides

5.3. Advice for firefighters


Special protective equipment for firefighting
Self-contained breathing apparatus
Further information
Not combustible.
Cool closed containers exposed to fire with water spray.
Remove from danger zone

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Wear personal protective equipment. Unprotected persons must be kept away.
Stay upwind/ keep distance from source.
Diresul Navy RDT-GF liq 150 Page 5(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

6.2. Environmental precautions


The product should not be allowed to enter drains, water courses or the soil.

6.3. Methods and material for containment and cleaning up


Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust).
Dispose of absorbed material in accordance with the regulations.

6.4. Reference to other sections


Additional information
Information regarding Safe handling, see chapter 7.
For personal protection see section 8.
Information regarding Waste Disposal, see chapter 13.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed.
If any hydrogen sulfide (H2S) is detected during use of the product, evacuate the workplace
to a very well-ventilated area and call the Emergency Response Team.
Hygiene measures
Avoid contact with skin and eyes.
Contact with acids liberates very toxic gas.
Always work in a well-ventilated area; ensure that all packages and equipment where the
dyes will be used are clean and free of contamination with undesired substances, particularly
acids.

Advice on protection against fire and explosion


Keep away sources of ignition.

7.2. Conditions for safe storage, including any incompatibilities


Advice on storage compatibility
Store separately from acids and oxidizing products in order to minimize the risk of reaction in
a possible leak.
Further information on storage conditions
Keep container tightly closed.
Keep only in the original container in a cool, well-ventilated place.

7.3. Specific end use(s)


No further recommendations.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
Exposure limit values
Diresul Navy RDT-GF liq 150 Page 6(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Exposure limit values are not available.

DNEL/DMEL values
DNEL/DMEL values are not available.

PNEC values
PNEC values are not available.

8.2. Exposure controls


General protective measures
Observe the usual precautions for handling chemicals.
Hand protection : Gloves (alkali-resistant)
Take note of the information given by the producer concerning
permeability and break through times, and of special
workplace conditions (mechanical strain, duration of contact).
Eye protection : Tightly fitting safety goggles
Body protection : Alkali-resistant protective clothing

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Physical state : liquid
Form : Aqueous solution
Colour : dark blue
Odour : yes
pH value : 12 - 14 (20 °C)
Melting point : not applicable
Boiling point : approximately 100 °C
Flash point : no flash point up to the boiling point
Lower explosion limit : not applicable
Upper explosive limit : not applicable
Vapour pressure : not tested.
Solubility in water : (20 °C)
miscible
Octanol/water partition This property is not applicable for mixtures.
coefficient (log Pow) :
Self-ignition temperature : The substance or mixture is not classified as pyrophoric.
Thermal decomposition : not tested.
Viscosity (dynamic) : < 100 mPa.s (20 °C)

9.2. Other information


Diresul Navy RDT-GF liq 150 Page 7(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Density : 1,2 g/cm3 (20 °C)


Further information
Incompatible with acids.

SECTION 10: Stability and reactivity

10.1. Reactivity
See section 10.3. "Possibility of hazardous reactions"

10.2. Chemical stability


Stable under normal conditions.

10.3. Possibility of hazardous reactions


With acids hydrogen sulphide is produced.

10.4. Conditions to avoid


Incompatible with strong acids and oxidizing agents.

10.5. Incompatible materials


See under section "Conditions to avoid"

10.6. Hazardous decomposition products


When used and handled as intended, none.

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Information related to the product itself:
Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Method : test result of a related preparation.
Irritant effect on skin : Corrosive (rabbit)
Method : evaluation based on the high pH-value
Irritant effect on eyes : Risk of serious damage to eyes. (rabbit)
Method : evaluation based on the high pH-value
Sensitization : not tested.
Assessment of mutagenicity : No information available.
Carcinogenicity : not tested.
Developmental not tested.
toxicity/teratogenicity :
Assessment of teratogenicity : No information available.
Specific target organ toxicity not tested.
(STOT) - single exposure :
Diresul Navy RDT-GF liq 150 Page 8(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Specific target organ toxicity not tested.


(STOT) - repeated exposure :

Information related to the component: Sodium sulphide


Acute oral toxicity : Acute toxicity estimate 100 mg/kg
Method : Converted acute toxicity point estimate
LD50 254 mg/kg (rat)
Method : OECD Test Guideline 401
Acute dermal toxicity : Study not performed as the substance is corrosive.
Acute inhalation toxicity : not applicable
Irritant effect on skin : Corrosive
Based on pH
Irritant effect on eyes : Corrosive
Based on pH
Sensitization : Study not performed as the substance is corrosive.
Repeated dose toxicity: Repeated Dose Toxicity (subchronic study)
Route of application: Oral
The study is not necessary from a scientific perspective.
Repeated Dose Toxicity (subchronic study)
Route of application: Inhalation
NOAEL: 14 mg/m3 (Exposure time : 90 d, Frequency of
treatment: 6 h/day, 5 days/week, Dose: 10 - 30 - 80 ppm, rat,
male and female)
Method : Other
Source : literature
Information relate to hydrogen sulfide.
Repeated Dose Toxicity (subchronic study)
Route of application: Dermal
The study is not necessary from a scientific perspective.
Genetic toxicity in vivo : Micronucleus test
mouse ( NMRI, male and female)
intraperitoneal 30 h 24 - 48 - 96,1 mg/kg Bone marrow cells
Method : OECD Test Guideline 474
Source : literature
negative
Genetic toxicity in vitro : Test type : Ames test
Test system : Salmonella typhimurium
Concentration : 4 - 5000 µg/plate
Metabolic activation : with and without
Result : negative
Method : OECD Test Guideline 471
Source : European Chemicals Agency (ECHA)
Diresul Navy RDT-GF liq 150 Page 9(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Test type : Mouse lymphoma assay


Test system : Mouse cells
Concentration : 50 - 781 µg/ml
Metabolic activation : with and without
Result : negative
Method : OECD Test Guideline 476
Source : European Chemicals Agency (ECHA)
Assessment of mutagenicity : It is concluded that the product is not mutagenic based on
evaluation of several mutagenicity tests.
Carcinogenicity : From scientific point of view the study is not necessary.
Assessment of Carcinogenicity classification not possible from current data.
carcinogenicity :
Developmental Route of application: Inhalation
toxicity/teratogenicity : NOAEL: 80 ppm (Frequency of treatment: 6 h/day, 7
days/week, Dose: 10 - 30 - 80 ppm, rat, male and female)
NOAEL (maternal): 80 ppm (Frequency of treatment: 6 h/day,
7 days/week, Dose: 10 - 30 - 80 ppm, rat, male and female)
Method : Other
Source : literature
Hydrogen sulfide (H2S)
Toxicity to One generation study
reproduction/fertility : NOAEL parent: 80 ppm (Frequency of treatment: 6 h/day, 7
days/week, Pre-mating exposure period, male: 14 d, Pre-
mating exposure period, female: 14 d, Dose: 10 - 30 - 80 ppm,
rat, male and female)
NOAEL F1: 80 ppm (Frequency of treatment: 6 h/day, 7
days/week, Pre-mating exposure period, male: 14 d, Pre-
mating exposure period, female: 14 d, Dose: 10 - 30 - 80 ppm,
rat, male and female)
Method : OECD 421
Source : literature
Hydrogen sulfide (H2S)
Assessment of toxicity to No reproductive toxicity to be expected.
reproduction :
Assessment of teratogenicity : No teratogenic effects to be expected.
Specific target organ toxicity Based on available data, the classification criteria are not met.
(STOT) - single exposure :
Specific target organ toxicity Based on available data, the classification criteria are not met.
(STOT) - repeated exposure :
Aspiration hazard :
no data available
Remarks
Poisoning affects the central nervous system

Information related to the component: Sodium xylenesulphonate


Acute oral toxicity : LD50 > 7.000 mg/kg (rat)
Diresul Navy RDT-GF liq 150 Page 10(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Acute dermal toxicity : LD50 > 2.000 mg/kg (rabbit)


Acute inhalation toxicity : not tested.
Irritant effect on skin : Mild skin irritation (rabbit)
Method : OECD Test Guideline 404
Source : Supplier
Irritant effect on eyes : Moderate eye irritation (rabbit eye)
Method : OECD Test Guideline 405
Source : Supplier
Sensitization : non-sensitizing (guinea pig)
Method : OECD Test Guideline 406
Source : Supplier
Repeated dose toxicity: Repeated Dose Toxicity (subchronic study)
Route of application: Dermal
NOAEL: > 440 mg/kg (mouse)
Method : OECD Test Guideline 411
Source : Supplier
Repeated Dose Toxicity (subchronic study)
Route of application: Oral
NOAEL: 763 - 3.534 mg/kg (rat)
Method : OECD Test Guideline 408
Source : Supplier
Genetic toxicity in vivo : Micronucleus test
Method : OECD Test Guideline 474
Source : Supplier
negative
Micronucleus test
Method : EPA OPPTS
Source : Supplier
negative
Genetic toxicity in vitro : Test type : Sister chromatid exchange assay
Result : ambiguous
Method : EPA OPPTS
Source : Supplier
Assessment of mutagenicity : It is concluded that the product is not mutagenic based on
evaluation of several mutagenicity tests.
Source : Supplier
Carcinogenicity : Based on available data, the classification criteria are not met.
Source : Supplier
Assessment of No evidence of carcinogenicity in animal studies.
carcinogenicity : Source : Supplier
Developmental Route of application: Oral
toxicity/teratogenicity : NOAEL: > 936 mg/kg (rat)
Source : Supplier
Toxicity to NOAEL F1: > 936 mg/kg (rat)
reproduction/fertility : Method : Other
Source : Supplier
Diresul Navy RDT-GF liq 150 Page 11(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Assessment of toxicity to No reproductive toxicity to be expected.


reproduction : Source : Supplier
Assessment of teratogenicity : No teratogenic effects to be expected.
Source : Supplier
Specific target organ toxicity Based on available data, the classification criteria are not met.
(STOT) - single exposure :
Specific target organ toxicity Based on available data, the classification criteria are not met.
(STOT) - repeated exposure :
Aspiration hazard :
No aspiration toxicity classification

Information related to the component: 2-(2-Ethoxyethoxy)ethanol


Acute oral toxicity : LD50 6.500 mg/kg (rat)

SECTION 12: Ecological information

12.1. Toxicity
Information related to the product itself:
Fish toxicity (chronic) : not available
Daphnia toxicity : EC50 > 100 mg/l (48 h, Daphnia magna (Water flea))
Method : test result of a related preparation.
Daphnia toxicity (chronic) : not available
Bacteria toxicity : IC50 > 100 mg/l (activated sludge)
Method : test result of a related preparation.
Sediment toxicity : not available

Information related to the component: Sodium sulphide


Fish toxicity : LC50 0,0027 mg/l (96 h)
Method : OECD Test Guideline 203
Source : literature
Fish toxicity (chronic) : NOEC >= 0,0092 mg/l (28 d, Lepomis macrochirus (Bluegill
sunfish))
Analytical monitoring : yes
Method : Other
Source : literature
LOEC > 0,0092 mg/l (28 d, Lepomis macrochirus (Bluegill
sunfish))
Analytical monitoring : yes
Method : Other
Source : literature
Daphnia toxicity : LC50 0,032 - 0,085 mg/l (96 h, Penaeus indicus)
Method : EPA
Source : literature
Diresul Navy RDT-GF liq 150 Page 12(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Daphnia toxicity (chronic) : LOEC 32 mg/l (28 d, Scapharca inaequivalvis)


Analytical monitoring : no data available
Method : Other
Source : literature
Algae toxicity : NOEC (Growth rate) 0,77 mg/l (4 h, Skeletonema costatum)
Method : OECD Test Guideline 201
Source : literature
LOEC (Growth rate) 1,6 mg/l (4 h, Skeletonema costatum)
Method : OECD Test Guideline 201
Source : literature
EC50 (Growth rate) 1,5 mg/l (4 h, Skeletonema costatum)
Method : OECD Test Guideline 201
Source : literature
Bacteria toxicity : EC50 14 mg/l (72 h, Entosiphon sulcatum)
Method : Other
Source : literature
Toxicity to soil-dwelling not applicable
organisms :
Toxicity to terrestrial plants : not applicable
Toxicity to other (other avian)
environmentally relevant not applicable
organisms :
Sediment toxicity : Lytechinus pictus
Type of sediment : Natural sediment
Total exposure duration : 49 d
NOEC
1,1 mg/l
Basis of effect : mortality
Method : Other
Source : literature
Lytechinus pictus
Type of sediment : Natural sediment
Total exposure duration : 49 d
LOEC
3,1 mg/l
Basis of effect : mortality
Method : Other
Source : literature

Information related to the component: Sodium xylenesulphonate


Fish toxicity : > 1.000 mg/l (96 h, Fish)
Method : US-EPA OPPTS 850.1085
Source : Supplier
Fish toxicity (chronic) : not available
Diresul Navy RDT-GF liq 150 Page 13(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Daphnia toxicity : EC50 > 40,3 mg/l (Daphnia magna (Water flea))
Method : OECD Test Guideline 202
Source : Supplier
static test
EC50 > 1.000 mg/l (Daphnia magna (Water flea))
Method : OPPTS 850.1010
Source : Supplier
static test
Daphnia toxicity (chronic) : not available
Algae toxicity : EC50 > 230 mg/l (96 h, Algae general)
Method : EPA
Source : Supplier
EC50 (Growth rate) 310 mg/l (72 h, Algae general)
Method : Directive 67/548/EEC, Annex V, C.3.
Source : Supplier
Bacteria toxicity : EC50 > 1.000 mg/l (3 h, activated sludge)
Method : OECD Test Guideline 209
Source : Supplier

12.2. Persistence and degradability


Information related to the product itself:
Biodegradability : 45 % (28 d)
Method : OECD Test Guideline 302B
By analogy with a product of similar composition
Chemical oxygen demand 851 mg/g
(COD) :
Biochemical oxygen demand 20 mg/g
(BOD5) : 5d

Information related to the component: Sodium sulphide


Physico-chemical not applicable
eliminability :
Photodegradation : air
not applicable
water
not applicable
Soil
not applicable
Biodegradability : Inorganic product, cannot be eliminated from the water by
biological purification processes.
Chemical oxygen demand not available
(COD) :
Biochemical oxygen demand not available
(BOD5) :
Diresul Navy RDT-GF liq 150 Page 14(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Information related to the component: Sodium xylenesulphonate


Physico-chemical Source : Supplier
eliminability : Readily biodegradable, according to appropriate OECD test.
Photodegradation : Source : Supplier
not available
Biodegradability : 100 % (28 d, CO2 formation in % of theoretical value)
Readily biodegradable.
Method : OECD Test Guideline 301B
Source : Supplier

12.3. Bioaccumulative potential


Information related to the product itself:
Bioaccumulation: not tested.

Information related to the component: Sodium sulphide


Bioaccumulation: Accumulation in aquatic organisms is unlikely.

Information related to the component: Sodium xylenesulphonate


Bioaccumulation: Source : Supplier
Low potential for bioaccumulation (log Pow < 3).

12.4. Mobility in soil


Information related to the product itself:
Behaviour in environmental compartments
no data available

Information related to the component: Sodium sulphide


Transport and distribution adsorption
between environmental not applicable
compartments :
Behaviour in environmental compartments
not available

Information related to the component: Sodium xylenesulphonate


Transport and distribution adsorption (water - soil)
between environmental Source : Supplier
compartments : not available
Behaviour in environmental compartments
not available

12.5. Results of PBT and vPvB assessment


Information related to the product itself:
no data available

Information related to the component: Sodium sulphide


Diresul Navy RDT-GF liq 150 Page 15(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

Not relevant for inorganic substances

Information related to the component: Sodium xylenesulphonate


The substance does not meet the criteria for PBT or vPvB substance.

12.6. Other adverse effects


Information related to the product itself:
Additional ecotoxicological remarks
Product does not contain any organic bound Halogens which could lead to AOX-values.

Information related to the component: Sodium sulphide


Additional ecotoxicological remarks
The product should not be allowed to enter drains, water courses or the soil.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Product
Reuse according to instructions of the plant manager or ask supplier.
Residual chemical should be subjected to waste management, using an approved
waste disposal contractor, in compliance with EC regulations 91/156/EEC;
91/689/EEC; 94/62/EC and subsequent amendments
Uncleaned packaging
Consider recycling.
Packaging that cannot be cleaned should be disposed of as product waste
In case of disposal, the chemical elements contained in the preparation have to be
considered.
Dispose of in accordance with local regulations.
Composition
C; H; N; O; S

SECTION 14: Transport information


Section 14.1. to 14.5.
Diresul Navy RDT-GF liq 150 Page 16(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

ADR
UN no. UN 2801
Proper shipping name: Dye, liquid, corrosive, n.o.s.
Hazard inducer(s): Sodium Sulphide
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80
Remarks Shipment permitted
ADN
UN no. UN 2801
Proper shipping name: Dye, liquid, corrosive, n.o.s.
Hazard inducer(s): Sodium Sulphide
Class: 8
Primary risk: 8
Packing group: III
Remarks Shipment permitted
RID
UN no. UN 2801
Proper shipping name: Dye, liquid, corrosive, n.o.s.
Hazard inducer(s): Sodium Sulphide
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80
Remarks Shipment permitted
IATA
UN no. UN 2801
Proper shipping name: Dye, liquid, corrosive, n.o.s.
Hazard inducer(s): Sodium Sulphide
Class: 8
Primary risk: 8
Packing group: III
Remarks Shipment permitted
IMDG
UN no. UN 2801
Proper shipping name: Dye, liquid, corrosive, n.o.s.
Hazard inducer(s): Sodium Sulphide
Class: 8
Primary risk: 8
Packing group: III
Remarks Shipment permitted
EmS : F-A S-B

14.6. Special precautions for user


See sections 6 to 8 of this Safety Data Sheet.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
Diresul Navy RDT-GF liq 150 Page 17(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

No transport as bulk according IBC - Code.

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Other regulations
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.

15.2. Chemical safety assessment


No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.

SECTION 16: Other information

Text of the R-phrases assigned to the ingredients/components mentioned in section 3 :


R22 Harmful if swallowed.
R31 Contact with acids liberates toxic gas.
R34 Causes burns.
R36 Irritating to eyes.
R50 Very toxic to aquatic organisms.
List of the text of the hazard statements mentioned section 3 (H-phrases) :
EUH031 Contact with acids liberates toxic gas.
EUH071 Corrosive to the respiratory tract.
H290 May be corrosive to metals.
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.

Legend
ADN European Agreement concerning the International Carriage of Dangerous
Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous
Goods by Road
AOX Adsorbable organic bound halogens
CAS Chemical Abstracts Service
DMEL Derived Minimal Effect Level (genotoxic substances)
DNEL Derived No Effect Level
EC50 Half maximal effective concentration
GHS Globally Harmonized System
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Lethal Concentration 50%
LD50 Lethal Dose 50%
Diresul Navy RDT-GF liq 150 Page 18(18)

Substance key: 000000051812 Revision Date: 22.05.2015


Version : 2 - 0 / EU Date of printing : 29.03.2016

MARPOL International Convention for the Prevention of Pollution From Ships


NOAEC No Observed Adverse Effect Concentration
NOAEL No Observed Adverse Effect Level
NOEC Non Observed Effect Concentration
OEL Occupational Exposure Limit
PBT Persistent, Bioaccumulative, Toxic
PEC Predicted Environmental Concentration
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID International Rule for Transport of Dangerous Substances by Railway
SVHC Substances of Very High Concern
vPvB very Persistent and very Bioaccumulative

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Archroma makes no warranties, express or
implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and assumes
no liability in connection with any use of this information. Any user of this product is responsible for
determining the suitability of Archroma's products for its particular application. Nothing included in this
information waives any of Archroma's General Terms and Conditions of Sale, which control unless it
agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due
to possible changes in our products and applicable national and international regulations and laws, the
status of our products could change. Material Safety Data Sheets providing safety precautions, that
should be observed when handling or storing Archroma products, are available upon request and are
provided in compliance with applicable law. You should obtain and review the applicable Material
Safety Data Sheet information before handling any of these products. For additional information,
please contact Archroma.

You might also like