Safety Data Sheet in Accordance With Regulation (EU) No.453/2010

Safety Data Sheet in accordance with
Regulation (EU) No.453/2010

Kieralon MW liq Page 1(13)
Substance key: KS13158 Revision Date: 29.05.2015

Version : 2 - 0 / GB Date of printing : 11.10.2016
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Trade name
Kieralon MW liq
Material number: 102000
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Textile processing industry
Type of use : Textile auxiliary
1.3. Details of the supplier of the safety data sheet

Identification of the company
Archroma Management GmbH
Neuhofstrasse 11
4153 Reinach, Switzerland
Telephone no. : +41 61 716 3401
Information about the substance/mixture
Product Stewardship +41 61 716 3401
e-mail: PS.MSDS-Europe@archroma.com
1.4. Emergency telephone number

+49 69 2222 5285, +33 1 7211 0003, +39 0236 042 884 (24 h)
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
Hazard class Hazard category H-phrase
Corrosive to metals Category 1 May be corrosive to metals.
Skin irritation Category 2 Causes skin irritation.
Serious eye Category 1 Causes serious eye damage.
damage/eye
irritation
Classification according EC Directive (67/548/EEC or 1999/45/EC, as amended)
Category of Hazard symbol R - phrases
danger/Category
Irritant Risk of serious damage to eyes.
2.2. Label elements

Labelling according CLP regulation (Regulation (EC) No. 1272/2008, as amended)

Hazard pictograms
Signal word
Danger
Hazard statements
H290 May be corrosive to metals.
H315 Causes skin irritation.
H318 Causes serious eye damage.
Precautionary statements
P234 Keep only in original container.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 + P312 IF ON SKIN: Wash with plenty of soap and water. Call a
POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 + IF IN EYES: Rinse cautiously with water for several minutes.
P310 Remove contact lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON CENTER or doctor/
physician.
P390 Absorb spillage to prevent material damage.
2.3. Other hazards

No additional hazards are known except those derived from the labelling.
SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
polyglycolether
anionic
Hazardous ingredients
Alcohols, C13-15-branched and linear, ethoxylated (7 EO)
Concentration : 10 - 15 %
CAS number : 157627-86-6
EC number: 500-337-8
Classification hazard substance EC
Xn Harmful R22
Xi Irritant R41
GHS classification EC
Acute toxicity Category 4 H302

Serious eye damage Category 1 H318

Chronic aquatic toxicity Category 3 H412
Trisodiumnitrilo triacetate
Concentration : <5 %
CAS number : 5064-31-3
Index Number 607-620-00-6
Carc.Cat.3 Carcinogenic Category 3 R40
Xn Harmful R22
Xi Irritant R36
Eye irritation Category 2 H319
Carcinogenicity Category 2 H351
Diethanolamine
Concentration : 1-2%
CAS number : 111-42-2
Index Number 603-071-00-1
REACH - Registration 01-2119488930-28-XXXX
number according to
article 20(3):
Xn Harmful R22
R48/22
Xi Irritant R38
R41
Skin irritation Category 2 H315
Specific target organ Category 2 H373
toxicity - repeated
exposure
Sodium p-cumenesulphonate
Concentration : 1-2%
CAS number : 15763-76-5
Xi Irritant R36
Eye irritation Category 2 H319

Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.

Concentration : 0.5 - 2 %
CAS number : 85536-14-7
Xn Harmful R22
C Corrosive R34
Skin corrosion Category 1C H314
The text of the R-phrases is shown in section 16.
The text of the H-phrases is shown in section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures

General information
Get medical advice/ attention if you feel unwell.
After inhalation
If inhaled, remove to fresh air.
After contact with skin
In case of contact, immediately flush skin with plenty of water.
After contact with eyes
Rinse immediately with plenty of water and seek medical advice.
After ingestion
If swallowed, call a poison control centre or doctor immediately.
Treat symptomatically.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms
No symptoms known currently.
Hazards
No hazards known at this time.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media


Suitable extinguishing media

all
Extinguishing media that must not be used for safety reasons
No restrictions
5.2. Special hazards arising from the substance or mixture

Carbon oxides
Nitrogen oxides (NOx)
Sulphur oxides
5.3. Advice for firefighters

Special protective equipment for firefighting
Self-contained breathing apparatus
Further information
Not combustible.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Wear suitable protective equipment.
6.2. Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.
6.3. Methods and material for containment and cleaning up

Pick up with absorbent material (eg sand, sawdust). Rinse away rest with water
6.4. Reference to other sections

Additional information
Do not let the liquid drain into rivers, ponds or sewer systems.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Hygiene measures
Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it before reuse.
Advice on protection against fire and explosion
No special measures necessary.
7.2. Conditions for safe storage, including any incompatibilities


Further information on storage conditions

Keep containers tightly closed in a cool, well-ventilated place.
Handle and open container with care.
Keep away sources of ignition.
7.3. Specific end use(s)

No further recommendations.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters

Exposure limit values
Exposure limit values are not available.
DNEL/DMEL values
DNEL/DMEL values are not available.
PNEC values
PNEC values are not available.
8.2. Exposure controls

General protective measures
Do not breathe vapours, aerosols.
Do not breathe gas.
Respiratory protection : In case of inadequate ventilation wear respiratory protection.
Hand protection : Use impermeable, CE-approved gloves for the manipulation of
chemical products.
Take note of the information given by the producer concerning
permeability and break through times, and of special
workplace conditions (mechanical strain, duration of contact).
Eye protection : Face-shield
Body protection : working clothes
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : liquid
Form : aqueous-organic solution
Particle size : not applicable
Colour : pale yellow
Odour : yes
Odour threshold : not tested.
pH value : 10 - 11 (20 °C)
Melting point : not applicable

Boiling point : approximately 100 °C

Sublimation point : not applicable
Flash point : no flash point up to the boiling point
Evaporation rate : not tested.
Combustion number : not applicable
Minimum ignition energy : not tested.
Vapour pressure : not tested.
Solubility in water : (20 °C)
miscible
Octanol/water partition not tested.
coefficient (log Pow) :
Ignition temperature : not tested.
Thermal decomposition : not tested.
Viscosity (dynamic) : not tested.
Oxidizing properties : not tested.
9.2. Other information

Density : 1.05 g/cm3 (20 °C, 1,013 hPa)
SECTION 10: Stability and reactivity
10.1. Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2. Chemical stability

Stable under normal conditions.
10.3. Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.
10.4. Conditions to avoid

None known.
10.5. Incompatible materials

Corrosive effect on aluminium.
10.6. Hazardous decomposition products

When used and handled as intended, none.
SECTION 11: Toxicological information


11.1. Information on toxicological effects

Information related to the product itself:
Acute oral toxicity : LD50 > 5,000 mg/kg (rat)
Method : OECD Test Guideline 401
Acute dermal toxicity : not tested.
Acute inhalation toxicity : not tested.
Irritant effect on skin : No skin irritation (rabbit)
Method : 1999/45/EC
irritating (rabbit)
Method : Evaluated according to GHS (Globally Harmonized
System) criteria
Irritant effect on eyes : Risk of serious damage to eyes. (rabbit eye)
System) criteria
Sensitization : not tested.
Repeated dose toxicity: not tested.
Genetic toxicity in vitro : not tested.

Assessment of mutagenicity : No information available.
Assessment of No information available.
carcinogenicity :
Assessment of toxicity to No information available.
reproduction :
Information related to the component: Trisodiumnitrilo triacetate

Acute oral toxicity : LD50 1,100 mg/kg (rat)
Acute toxicity estimate 500 mg/kg
Method : Converted acute toxicity point estimate
Information related to the component: Diethanolamine

Acute oral toxicity : LD50 710 mg/kg (rat)
Acute toxicity estimate 500 mg/kg
Method : Converted acute toxicity point estimate
SECTION 12: Ecological information
12.1. Toxicity
Fish toxicity : LC50 > 100 mg/l (96 h)
System) criteria
Daphnia toxicity : EC0 > 1 mg/l (24 h, Daphnia magna (Water flea))

EC50 6 mg/l (24 h, Daphnia magna (Water flea))

Algae toxicity : not tested.
Bacteria toxicity : IC50 > 100 mg/l (activated sludge)
Method : ETAD method 103
12.2. Persistence and degradability

Biodegradability : All ingredients showing toxic effects in the aquatic
environment (1 < LC50 < 100 mg/l for one of the aquatic
species) are readily biodegradable in tests performed
according to the OECD 301 series test guidelines.
90 % (28 d, Dissolved organic carbon (DOC))
Method : OECD Test Guideline 302B
Chemical oxygen demand 405 mg/g
(COD) : Method : SANDOZ internal test
12.3. Bioaccumulative potential

Bioaccumulation: not tested.
12.4. Mobility in soil

Behaviour in environmental compartments
no data available
12.5. Results of PBT and vPvB assessment

no data available
12.6. Other adverse effects

Additional ecotoxicological remarks
no data available
SECTION 13: Disposal considerations
13.1. Waste treatment methods

Product
Dispose of in accordance with local regulations.
Uncleaned packaging
Consider recycling.

Composition
C; H; N; Na; S
SECTION 14: Transport information
Section 14.1. to 14.5.
ADR
UN no. UN 2735
Proper shipping name: Amines, liquid, corrosive, n.o.s.
Hazard inducer(s): Nitrilotriacetic acid sodium salt
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80
Remarks Shipment permitted
ADN
UN no. UN 2735
Class: 8
Primary risk: 8
Packing group: III
RID
UN no. UN 2735
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80
IATA
UN no. UN 2735
Class: 8
Primary risk: 8
Packing group: III
IMDG
UN no. UN 2735
Class: 8
Primary risk: 8
Packing group: III
EmS : F-A S-B

14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
No transport as bulk according IBC - Code.
Further information
corrosive on steel and / or aluminium
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Other regulations
The surfactant(s) contained in this mixture complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion
are held at the disposal of the competent authorities of the Member States and will be made
available to them, at their direct request or at the request of a detergent manufacturer.
15.2. Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.
SECTION 16: Other information

Product should be stored, handled and used in accordance with good industrial hygiene practices
and in conformity with legal regulations. The information contained herein is based on the present
state of our knowledge and is intended to describe our products from the point of view of safety
requirements. It should therefor not be construed as garanteeing specific properties.

Text of the R-phrases assigned to the ingredients/components mentioned in section 3 :

R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R38 Irritating to skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
List of the text of the hazard statements mentioned section 3 (H-phrases) :
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Legend
ADN European Agreement concerning the International Carriage of Dangerous
Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous
Goods by Road
AOX Adsorbable organic bound halogens
CAS Chemical Abstracts Service
DMEL Derived Minimal Effect Level (genotoxic substances)
DNEL Derived No Effect Level
EC50 Half maximal effective concentration
GHS Globally Harmonized System
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Lethal Concentration 50%
LD50 Lethal Dose 50%
MARPOL International Convention for the Prevention of Pollution From Ships
NOAEC No Observed Adverse Effect Concentration
NOAEL No Observed Adverse Effect Level
NOEC Non Observed Effect Concentration
OEL Occupational Exposure Limit
PBT Persistent, Bioaccumulative, Toxic
PEC Predicted Environmental Concentration
PNEC Predicted No Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID International Rule for Transport of Dangerous Substances by Railway
SVHC Substances of Very High Concern
vPvB very Persistent and very Bioaccumulative
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Archroma makes no warranties, express or

implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and assumes
no liability in connection with any use of this information. Any user of this product is responsible for
determining the suitability of Archroma's products for its particular application. Nothing included in this
information waives any of Archroma's General Terms and Conditions of Sale, which control unless it
agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due
to possible changes in our products and applicable national and international regulations and laws, the
status of our products could change. Material Safety Data Sheets providing safety precautions, that
should be observed when handling or storing Archroma products, are available upon request and are
provided in compliance with applicable law. You should obtain and review the applicable Material
Safety Data Sheet information before handling any of these products. For additional information,
please contact Archroma.

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Safety Data Sheet in Accordance With Regulation (EU) No.453/2010

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Safety Data Sheet in accordance with

Regulation (EU) No.453/2010

Substance key: KS13158 Revision Date: 29.05.2015

SECTION 1: Identification of the substance/mixture and of the

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.2. Label elements

Substance key: KS13158 Revision Date: 29.05.2015

2.3. Other hazards

SECTION 3: Composition/information on ingredients

Substance key: KS13158 Revision Date: 29.05.2015

Serious eye damage Category 1 H318

Substance key: KS13158 Revision Date: 29.05.2015

Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.

SECTION 4: First aid measures

4.1. Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

Substance key: KS13158 Revision Date: 29.05.2015

Suitable extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

Substance key: KS13158 Revision Date: 29.05.2015

Further information on storage conditions

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.2. Exposure controls

SECTION 9: Physical and chemical properties

Substance key: KS13158 Revision Date: 29.05.2015

Boiling point : approximately 100 °C

9.2. Other information

SECTION 10: Stability and reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

Substance key: KS13158 Revision Date: 29.05.2015

11.1. Information on toxicological effects

Genetic toxicity in vitro : not tested.

Information related to the component: Trisodiumnitrilo triacetate

Information related to the component: Diethanolamine

SECTION 12: Ecological information

Substance key: KS13158 Revision Date: 29.05.2015

EC50 6 mg/l (24 h, Daphnia magna (Water flea))

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

SECTION 13: Disposal considerations