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*
\\
\
i+'
r+"
-
:tr
fr el
d,
}
i-,
- COMPTON EFFEcT
f.l'
- X.rays,y_rayselc.,ofhigtlfrequettcyisallowedtofallonafinescalte,rlr,the
viz'
+t
',-'-
beam is scattered. into two cornponents
+\ (i)
One component ltaving the same frequency
the urcidettt radiation, so called unmodified
(or) wavei'length as that of
radiation' and
{ (ii) The orher componeni having lower frequen"l @r) higher wavelength
*-;;i conryared to irrcident radiation' so called
modified radiatian'
t-;j 'hv'
**t
:. -.i
o7 ,
Compton shift: When a photon of energy ,coll,idl.: Y"\::.::::.::
the photon gives ir-s en?rg! t.o the
Jrir"'lri"ot-rrrt,
scattered photon will have lesser energy bil
the
erectron. Therefore
lower frequency (or) higher
gains
of"icident photon' Since the electron
t+'1
F"!
wavelengtlt compared to the wavelength
energy, it recoils with the velocity
'v',"This-
1{eit
is called Compton effect and
n, iniSt in wavelength is callecl Compton shift'
h" we get (i) Unmodified radiations
Thus as a result of compton scattering,
I\.I (ii) Modified radiations and (iii) a recoil electron'
t{-.,
F...5 ., THEORY OF COMPTON EFFECT
+.r and an electron rs
In Cam-nton scaltering lhe collision between a photon
-+ of
,i;;;r;."';";n'uy" opptvrig ilrc taws of 'ont'*!tio' 'n"8t
tlrc expression for clmpton wavelength
is
*d *o*'
-:
{-b
Assumptions
l. The collision occurs between the photon and an electron in the scattering
material.
2. The electron is free and is at rest before collision with the incident photon.
With these assunlptions let us consider a photon of energy 'ftv' colliding
Y
with an electron at rest.
During the collision process, a part
of energy is given to the electron, which
'intum increases the kinetic energy of the
electron and hence it recoils at an angle E -hr, ,p -h v/c
+"r
q*, Let us find the energy and
.o-qct
J
momentum components before and
;o_ U after collision process.
*:=
Energy betore collision
=. ta (i) Energy of the incident photon = lzv.
si\
f -, J
(ii) EnergY of the electron at rest - ffioc
)
?h,
C-^
(ii) of the recoil electron = nrc"
Energy
2
... (3)
F
ft
;-.
-
-ir
Before Collision :
X-Component of Momentum
(i) X-component momentum
of the incident photon:C=li.V
-
at rest = 0 -h
I E -hv P -hv/c
L
o ,{
l.')' A
the scattered Photon =; cos u iL,
fl
-My
of
(ii) X-component momentum D
-{
the recoil electron can be calculated .h
*-
r{
;, i.
Weknowaccorrlingtothelawofconservationofmomentum
Totalmomentumbeforecollision=Totalmomentumaftercollision
(5)
.'. Equation (4; = Equation
...(6)
Y-component of Momentum
Before Collision
(i) Y- component momentum of the incident photon = 00
(ii) Y- component momentum of the electron at rest'=
' ;. Total Y'Component'of n:tomentwn before
collisiort =0 ... (7)
Y-Component of momentum After collision
_M
s
(ii) From fig 4'5, ln L OCD. sin Q =;i
*
... Y-Component rnomentum of the recoil electron = nv sin 0
:..(9)
*}'r
-
il
CC
(or) nzcv cos Q - /r (v - v 'cos 0) .,. (i0)
*2 r2r'1.or'q + sin2q; =lt2 lv2 -2v v'cos 0 + (v') 01 + tt2 1v ')2 sin2 o
"o'2
Since .or2 q + sin2q =,1 and h'(u')' 1cos20 + sin201 = 42 (v')2 we get
-2v v'coso+(v)21
:
... (t2)
(or) n2 12 u2 =t 1v2
'
From equation (3), we can ivrite
,nr'=rnol'+h(v-v')
Squaring on both sidcs we $et
*'14 =nriro +2ltntscz (v -v') + h2lvT -2v v '+ (v')'I .'. (13)
'i
l
!
J
,l
I
J)
r.
fr
F
c_
c-r
formula for the variation of
From the theory of relativitY, the relativistic :
is given by
-^^^ ..,irh
llldJJ wlLll
thp
!!rv rrplncitv of the electron
ttlg
e+
2 .2^2
can write
Equating equations (16) and (14), we
-L
*f;ra =o,?sro +2hmn/ (u -v')-2lr2v v'(1 -cos
I
0)
t.,,,,
-r
(or) Ztt*0 c|(v - v ') =2 hzv v ' (1 - cos 0)
bR
Yi!.!.,n
-r
&tri
E\Y!4
g{#,
(n') d'=+(l-cos0) :rir
vv' moc-
:*-
W
t"rr; *
1
("')
t=ft,,t':::'
-cos0) -r
i-i=;J(1 ir
Since X=9andl,i
V
=fV, *. can write equation (17) as
r:--
I
'.:..
1.,- )" =+(l
froc
- cos 0)
='l
I
t
....(18)
€;-.
t @r) Change in wwelength
€:
€i\r
* g-\r
. _:'
+,
\_
*r
-+,
Equation (18) represents the shift in wavelength, i.e., Compton Shifi which is
independent of the incident radiation as well as the nature of the icatte.lng ,rbrt.n.e.
-t I
:' Thus the slift in wavelength (or) Compton Shift purely depends on the angle
+
-h of scattering.
SPECIAL CA5E5
(i) lVhen 0 = 0;
1 Pro b9o^^s)
#
* Case cos 0 = 1
#\
6(t LILc vuLPuL u,) Pi.UN, ii\eJei
F\ h
.', Equation (18) becomes A)" =moc
t*\
E{...
Substituting the values of h, mo and c we gir
+
-
H
F\L
Thusfor0=180o the shift in wavelength is found to be maxitnum.fRefer
fi1. 4.7)
i1. . .'. When the angle of scattering (0) varies from 0 to 180", the wavelength
shifts from )" to ).+s
^-5
H
ffioc
).i-I.
F
s
-r
\i
:-
The shift in wavelength (or) difference in wavelength (A)") of the two scattered
beams is found to increase with respect to the increase in scattering angle.
l' i.
:.P DUAL NATURS OF RADIATION (LI6HT) AND
,, MAfiER (PARTTCLES) - MATTER WAVE5
,,de-Broglie concePt ol Duol Noture
i:
The universe is made of Radiation (light) and matter (particles). The light
,,exhibits the dual nature (i.e.,) it can behaves both as a wave (Interference, diffraction
l,phenomenon) and as a
particle (Compton effect, photo-electric effect etc).
the nature loves symmetr), in 1924 Louis de-Broglie suggested that
' Since (or) any other maierial particle must exhibit wave like properties in
an electron
:,addition to particle nature. 'CnDV;h I
The waves associated with annruteiial particle are called as Matter waYes
,
'de-Broglie Wovelength
Frorh the theory of light, considering a photon as a paflicle the total energy of
the photon is given bY E = ntcz. ... ( 1)
.-
where m -) Mass of the Pariicle
3$
c + VelocitY of light
:.d-,-
Considering the photon as a wave, the total energy is given by E=hv... (2)
+
#-L
rc-
, __l
h\
!*1"
)_{r
H
I_aI
q
Hr
+\
h
fl-...
S*
#It
l\rr
e\
+i
ffi
ffi
trr
ffi
"}b
t'b
":t
.
--
J
-[
=r
_.1
J I
J-f
JJ
J
SCHRODINGER WAVtr EQUATION *t
basic pnnntion
"p lrqcin
Schrodinger equation is'one of the equations in quantu- 1:,chani-cs like =J
Newton's law of motion. Newton's law of motion is applied -or.tl1
to
:r,.l
*^;-r"api. particles, whereas Schrodinger_ equation is used -for
both
3l
macroscoii. unO microscopic particles. Schrodinger derived a mathematical
equation to describe the dual nature of matter waves. There are two ,+
foims of
+*
Schrodirr..ger wave equation: i r'''
(i) Time clependent wave equation, and
(ii) irfime independent w'ave equation' ': L
He derived rh;';;*flons by incu.poruti,n^s th3 following two assumotions:
(i) de Broglie wavelength can be applied for the matte, ior.. forluny fleld of
forie, BaseJon this, the total energy of a particle can be written ais' ri -!
TE=P.E.+K,E. i fi
i,: hrr
n=:;m:iw
i-
tz*@:iffz i
qo'26)
(D The wave function associated with the material particles, with function
rtifie'I can be written as, Ii
-
YO'r-i*
,,r^ (10.27)
'1
- ZtT v, where
Lro is the amplitude of the wave at the point (x, y, z) and @
il;'ir*r.n.y or radiation' l
#
The diiferential wave
canbewgitten.intermsofCartesiancoordinatesas,
'l (10.28)
. dx" dy'
+5
e-J I
The solqlion fpr Eq. (10'28) is Eq' (10'2'l)
Differentiating Eq. (10'27) w'r't' / twice' we
get'
$
JL'
/t,
'.)
Y =-
d-v _
iaryoe-irt =
*'ry
- i(D\y
(10.2e)
#
.i+-.*-: : '
&2
Substituting the value of d2 tyld? in Eq'
(10'28)' we get'
d'rlt,d'rlr,d'V---a?%v
++.*n{4=- 2
(10.30)
*+'
*1.5
dn dz u
(2nvY
"ut 2T
s
q'\
where
.-\
a = Znv.
,
tY-*tY*t+--on':'
d*T ' dy, dzz
, u"
u
F"-r*5 i d'ry ty
-dF - 7'v' *' dz2= -4t
ty- x zm(E - n\y (10.32)
ffi
Ett
| lr'
Y : a2 * 0'. * i:-
772-
But av-iy' oz'
ffi-r 2
where V it the Laplacian operator'
ffi'a Equation (10.32) can be written as'
ffi
k\ts
^ 8It2
V'rlr=*:f m@- nV ( 10.33)
2m
ffite
ffi
h2
h
where h----)r
ffi
ffif -The . : nr /1O 14)
Equation (10.33) or (10'34) is known
2m
H-F :
ffiF
m. I.
r
ffi'
t*' ,
;.
ti eI.
er
t
i
.:
r.
i
(ii) Schrddinger time dependent wave equation F
For a free particle, the potential energy V = A. J
F.
Therefore, Eq, (10.34) becomes ;
.,.}
";.
t'r
(ru.35) ft
(-
Fro m the
we get,
s chro crin ger,.. o nl':r:^{r:.:r,;:,ti ari ng Eq. ( 1 0. 27 ) w.r.t. /, c-
g_!1
iav-_ iLrvy
;
fl
dt
=_ ).
.l
t\
l
L.{
i
Substituting E = hv, we get,
9v = "-t24 V__,iV
.E
,--i
,.J
drh
fl *J
J
drY
Ev= il
idt i,:
EW = ih-=f
dr4r
(10.36) .J
From Schrodinger time independent F.q. (10.34)
2m- _ 2m-
J
,,
Y',y* *,or+-+vv=o
'h'drh2 (10:37)
$
Multiplying Eq. (10.37) by t'lZ*, we ger,
lt y:v+ihdv -ttv=O
2m ' d[ '
iri
:
- i'l
i.
'l
.L
:I
..{
or
+')
- :-Y'ry
/"tn
+ vv = rn
4v
dt
(10:,38)
lj
ii J
-li. V2 + v- H (10)39)
'.:I
i:l
2m
where f/ is an operator known as Hamiltonian operator. Therefore,
where EV - in x
HV
- Ertr
dY is an energy operaror.
dr
(10.40)
il
Equations (10.38) or (10.40) is called as Schrodinger tinte dependent wave
{
ecluatiott. i.
Physicat significance of y
(i) lt relates the particles and wave nature of matter statistically.
(ii) It is a eomplex quantity and hence we cannot measure it.
i$
(iii) Its square is a measure of the probability of finding the particle at a
partiCular position. rt cannor prEdlct-the eract locatlon of the p4fi.9@
.iv) The wave function is a complex quantity, whereas the probability is a
{ Ieal and posirive quantity. Therefore, a term callcd position probability
density P(r, r) is introduced. It is defined as the product of the wave
;, functjon ty and its comp.lex conju gate as,
.\:
) P (r, /) = | ry (r, t)12
:
t'(v) [he probability of finding the particle within a volume dr is
l-, i
j
P = ! tyt2dr
where dT - dx dy dz.
,(vi) ff a particle is definitely present, then its probability value is one,
ii' +6
' i.e. F = ltyfar= 1
;(
oLx
Fig. Particle in a box
Assume that the particle is freely moving inside the box. The motion of the
particle is restricted by the wails of the box. The particle is bouncing back and
forth between the walls of the box at x = 0 and x = L.For a particle moving
freely at the bottom of the potential well. the potential energy is very lo',v. Since
the potential energy is very low, it is assumed to be zero between .x = 0 and
,-_ f
-L - t),
The potential energy of the particle at the walls is infinite. Due to the infinite
la- Ie escape-fiom-r
box, i.e. -cannor
V= 0, for 0<x<L
:'.
,l
r
=t
+
J
.:j
_J
V=*, for 0>x2L
o+
i
since the particle cannot be present outside the box, its wave functiori i S ZEIO, ,l
i.e.
hylz = O, for 0> x> L
i
I
,
,.
)J
- .,{
i.e. V=0 at x=0and,x-L
Inside the potential well, since the electron is present, the wave function is
hylz* 0, for 0<xcL I:J
i
The Schrodinger one-dimensional time-independent equation is , .t'1
d2ttt 'it
2nt -
*a +;;(E - .
v)ty - 0 i (i0.4j1)
:
l:,. *f^l
For a freely moving particle, v = 0. Therefore, Eq, (10.41) can be written as,
".''q'
$[
{Y- +!rv = s (t0.4)
. (Lr- h- :
Taking - .-d
!s- f
:_.
tf (10.4,3)
n,,
i,.3
Equation (JA.42) can be
'l;.
i
d
{Y * Fw= o
w1i:ttoo,OS.,.
.:
:-il tt*
(r0.44) I
dYt '
-il
Equation (10.44) is similar to the equation of harmonic motion and the "'i,. d
solution of the above equation is written as,
V=Asin kx+Bcos lcx (10.4s)
''
,'d
',,.,.Il,,l
where A is the amplitude of the electron's wave function. ,1. . . t::'.-1,
^r
Since the electron is present inside the, box, A * A. -
;.'-:.: -.
L* =.
,r'ft' v--'r12
"tt t - "2m ='llj{
.:.r: .t t::.:j;:'.\
n' jT' h2 n'h' 10.47)
or ttn-
D Y--=*"-'__-- (
.,
t "Brr'rn 8mt
The wlve equation
nfix (10'48)
V, =A stn
L
present inside the box, then
Letuspnd4.valueofA.Ifanelectronisdefinitely
i:
,i:
.J' -
Lr\
(10'4e)
i.e. ri
I
iIo\u/ i,+',in'(9dir=I
\-rl, {l
L
i
J - \ 'q-1*
L) =
*,i,-,2( a
A'
:r.
0
L
- cos( 2nnx I 1
i
J
d,r - A'
a
OI ;t
( 1 0.s0)
Thereiore,
i(Eh5
E L" tt o"' \'ttc _s *rq
*l-BH
----
C'Orponrnts of Transmission Etectron microscope (TEM)
The essential components of a Transmission Electron microscope are
(i) Electron Gun
(ii) $pecimen holder
t
(iii) Electron !enses
(condenser lens, objective lens, intermediate lens, projector lens)
(iv) Vacuum pumps and
(v) Viewing screen or photographic plate
(i)Electron Gun
,Hair pin' filarnent. which when heated emit5 elections due.rtCI
Electron Gun consists of a Tungsten 'Hair Pin' filarnent, : c. ::i;j
,specimen holder
The specimen is held in a special holder'
Cplics
.,: i
Electron lenrs I
-*:::ing
g the intensity of the magnetic fields produced by
a::
r-J
IEE
+5
f4
.-
J
ETL
D
SqxtN,N,l'NG ELEC RON MICtr{OSCOPE (SEM) t-
>
.KngU', inyentgd s-qannug eiectrro-O..nicr.osa,op.e,.in."t935. ,The '.diagr'ammat'ic
representation of a scanning electron m-icroscope is shown in Fig. 4'9- It isr >
-r
uB.ed to prgduce. a three dirnensional image of a spQeimen of any size and a
thic,kness. The olectrons produced by the, hot filaialent are accelerated b1i >
eieotrie, an(i:,magetrc fields. The emerging ele,ctrons witlt a spot size of nearlr' i
!
I0 nrn is made, to incident on a cond.ucting sample undet study. If 'the sEpple.:
is non cong.u.qting a thin layer of 5-50 thick g$d or 4qy other, metal rrf i
coatin-g is made and then the sampJe is,used, for,,study. A scanning coil deflegts'
the eleclron beam, so that the sample is scanned by point by point. The t-a
electroqs striking on the,g-appleproduces second4ry electrons. The number'orf' Q.
>
seeondalyrieieetrons, produ0ed:'d,gpe upon the.:geornetr.y and other'propertigsr
of the samples. The seconclary elecrron$ are collected by a positively chargecl !-r
elccti:qn del6.etor, which,'aceeleratcs thc elccfibn's to'very rhigh energyi in thc .J
or'(tref of, ?*,
6
t -
, 1 +a
t !
,"\
i
:
<
( .rz
i
( v
i
-l
ffi -i
\,
l
ffi