10/1/23, 3:37 PM CN102260451A - Solvent-free epoxy glass flake coating and preparation method - Google Patents

Patents

Solvent-free epoxy glass flake coating and preparation method

Abstract
CN102260451A
The invention discloses a solvent-free epoxy glass flake coating and a preparation method. The
China
coating is used for splash zones of offshore platform jackets to improve the anticorrosion capacity
of steel pipes and prolong the service life of the steel pipes. The preparation method comprises the
following steps of: adding a reactive diluent 660A into an epoxy resin, adding an organic bentonite Download PDF Find Prior Art Similar
rheological aid 881-B, an EP 2440 adhesion promotion resin, silicone oil, carbon black, titanium
white and aluminum trippolyhosphate, mixing uniformly, grinding, adding glass flakes, and stirring Other languages: Chinese
uniformly to form solution A; forming solution B by using an epoxy curing agent H633; and mixing
Inventor: 范云鹏, 林竹, 王志涛, 韩文礼
the solution A and the solution B to obtain the solvent-free epoxy glass flake coating during use.
Solvents are not volatilized in the curing process, the coating is slightly shrunk, and the solvent-free Current Assignee : China National Petroleum Corp , CNPC
epoxy glass flake coating has a compact structure and high permeability resistance; moreover, the Offshore Engineering Co Ltd , CNPC Engineering Technology
solvent-free epoxy glass flake coating has extremely strong cohesive force and good anticorrosion Research Institute Co Ltd
performance.

Worldwide applications

2011 CN

Application CN 201110191623 events

2011-07-08 Application filed by China National Petroleum

Corp, CNPC Offshore Engineering Co Ltd, CNPC
Engineering Technology Research Institute Co
Ltd

2011-07-08 Priority to CN 201110191623

2011-11-30 Publication of CN102260451A

2013-05-01 Application granted

2013-05-01 Publication of CN102260451B

Status Active

2031-07-08 Anticipated expiration

Info: Patent citations (2), Cited by (7), Legal events, Similar

documents, Priority and Related Applications

External links: Espacenet, Global Dossier, Discuss

Claims (4) Hide Dependent

1. non-solvent epoxy glass-flake coating, it is characterized in that being made up of A liquid and B liquid, wherein A liquid promotes resin, 0.001～0.005 weight part carbon
black, 0.05～0.1 weight part titanium dioxide, 0.1～0.2 weight part aluminium triphosphate, 0.01～0.05 weight part organobentonite auxiliary rheological agents 881-B, 0.1～0.5
weight part, 80 order glass flakes to form by 1 weight part bisphenol A type epoxy resin E51,0.1～0.15 weight part reactive thinner 660A, 0.0005～0.001 weight part silicone oil,
0.001～0.005 weight part EP, 2440 sticking power; B liquid is epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2～0.25 weight part B liquid during use.

2. non-solvent epoxy glass-flake coating according to claim 1, it is characterized in that being made up of A liquid and B liquid, wherein A liquid promotes resin, 0.002
weight part carbon black, 0.09 weight part titanium dioxide, 0.15 weight part aluminium triphosphate, 0.05 weight part organobentonite auxiliary rheological agents 881-
B, 0.4 weight part, 80 order glass flakes to form by 1 weight part bisphenol A type epoxy resin E51,0.13 weight part reactive thinner 660A, 0.0008 weight part silicone oil,
0.002 weight part EP, 2440 sticking power; B liquid is epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2 weight part B liquid during use.

3. the manufacture method of a non-solvent epoxy glass-flake coating as claimed in claim 1, it is characterized in that forming by A liquid and B liquid, wherein A liquid
adds 0.1～0.15 weight part reactive thinner 660A dispersing and dissolving in addition in 1 weight part bisphenol A type epoxy resin E51, add 0.0005～0.001 weight part
silicone oil again, 0.001～0.005 weight part EP 2440 sticking power promote resin, high-speed stirring, under condition of stirring, add 0.001～0.005 weight part carbon
black, 0.05～0.1 weight part titanium dioxide, 0.1～0.2 weight part aluminium triphosphate, 0.01～0.05 weight part organobentonite auxiliary rheological agents 881-B,
grind 0.5～1h with sand mill then, add 0.1～0.5 weight part, 80 order glass flakes afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by
1 weight part A liquid and 0.2～0.25 weight part B liquid during use.

4. the manufacture method of non-solvent epoxy glass-flake coating according to claim 3, it is characterized in that forming by A liquid and B liquid, wherein A liquid adds
0.13 weight part reactive thinner 660A dispersing and dissolving in addition in 1 weight part bisphenol A type epoxy resin E51, add 0.0008 weight part silicone oil again,
0.002 weight part EP 2440 sticking power promote resin, high-speed stirring, under condition of stirring, add 0.002 weight part carbon black, 0.09 weight part titanium
dioxide, 0.15 weight part aluminium triphosphate, 0.05 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand mill then, add 0.4 weight
part, 80 order glass flakes afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2 weight part B liquid
during use.

Description

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10/1/23, 3:37 PM CN102260451A - Solvent-free epoxy glass flake coating and preparation method - Google Patents
Non-solvent epoxy glass-flake coating and manufacture method

Technical field

The present invention relates to the steel structure anti-corrosion paint technical field, particularly a kind of non-solvent epoxy glass-flake coating and manufacture
method.

Background technology

Development along with the offshore oil exploration exploitation, platform construction enters the fast-growing period, the steel structure anti-corrosion paint
consumption significantly increases thereupon, existing epoxy glass flake coating mostly is solvent-borne type greatly, solvent evaporates causes coating voidage and
shrinking percentage to increase, easily form stress raisers, make coating fragility big, sticking power, permeability resistance and shock resistance reduce; When coating
was thicker, solvent easily was trapped in coating inside, influences coating compactness; The solvent height, environmental pollution.

Summary of the invention

The objective of the invention is: a kind of non-solvent epoxy glass-flake coating is provided, avoids above-mentioned weak point of the prior art and a kind of
environmental protection, corrosion-resistant, non-solvent epoxy glass-flake coating that mechanical property is strong are provided.

The technical solution used in the present invention: the non-solvent epoxy glass-flake coating, form by ten kinds of components, wherein:

1, bisphenol A type epoxy resin E51: domestic have how tame factory to produce and sell goods.

2, reactive thinner 660A: chemical name: butylglycidyl ether, claim epoxy propane butyl ether again, be called for short BGE, as the reactive thinner of Resins, epoxy.The
production of the magnificent chemical industry of Wuxi City product company limited also has production marketing.

3, silicone oil: chemical name: polydimethylsiloxane, make paint antifoaming agent, precious chemical industry company limited produces and production marketing is
arranged in the Qingdao.

4, EP 2440 sticking power promote resin:

Qian Fenglin edits domestic and international coatings additive(s) kind handbook Chemical Industry Press, in August, the 1999 first version first impression, the 15th
page.Manufacturer: Huels AG

5, carbon black: particle diameter is between 10～500 μ m.

6, titanium dioxide: claim anatase titanium dioxide GR composite titanium dioxide again, median size≤2 μ m, manufacturer: Chuzhou Grea Minerals Co., Ltd..

7, aluminium triphosphate: molecular formula: AlH 2P 3O 10325 screen residues≤0.5%, manufacturer: the sincere fine powder of promise Industrial Co., Ltd.

8, organobentonite auxiliary rheological agents 881-B:(manufacturer: the blue or green Hong Huagongzhujichang in Linan City)

9, glass flake: 80 orders, glass flake are overlapping arrangement in coating, therefore the permeability resistance of filming have been played great role.Five Yang
Fangfucailiaochang of Wenan County, Hebei province have production marketing.

10, epoxy hardener H633: technical indicator:

Manufacturer: Changzhou Han Ke Chemical Industry Science Co., Ltd.

The non-solvent epoxy glass-flake coating: be made up of A liquid and B liquid, wherein A liquid promotes resin, 0.001～0.005 weight part carbon black, 0.05～0.1 weight
part titanium dioxide, 0.1～0.2 weight part aluminium triphosphate, 0.01～0.05 weight part organobentonite auxiliary rheological agents 881-B, 0.1～0.5 weight part, 80
order glass flakes to form by 1 weight part bisphenol A type epoxy resin E51,0.1～0.15 weight part reactive thinner 660A, 0.0005～0.001 weight part silicone oil, 0.001～
0.005 weight part EP, 2440 sticking power; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2～0.25 weight part B liquid during use.

The non-solvent epoxy glass-flake coating, it is characterized in that being made up of A liquid and B liquid, wherein A liquid promotes resin, 0.002 weight part carbon
black, 0.09 weight part titanium dioxide, 0.15 weight part aluminium triphosphate, 0.05 weight part organobentonite auxiliary rheological agents 881-B, 0.4 weight part, 80
order glass flakes to form by 1 weight part bisphenol A type epoxy resin E51,0.13 weight part reactive thinner 660A, 0.0008 weight part silicone oil, 0.002 weight part EP,
2440 sticking power; B liquid is epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2 weight part B liquid during use.

The manufacture method of non-solvent epoxy glass-flake coating, it is characterized in that forming by A liquid and B liquid, wherein A liquid adds 0.1～0.15 weight part
reactive thinner 660A dispersing and dissolving in addition in 1 weight part bisphenol A type epoxy resin E51, add 0.0005～0.001 weight part silicone oil again, 0.001～
0.005 weight part EP 2440 sticking power promote resin, high-speed stirring, under condition of stirring, add 0.001～0.005 weight part carbon black, 0.05～0.1 weight
part titanium dioxide, 0.1～0.2 weight part aluminium triphosphate, 0.01～0.05 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand
mill then, add 0.1～0.5 weight part, 80 order glass flakes afterwards, mix, make A liquid; B liquid is epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2～0.25
weight part B liquid during use.

The manufacture method of non-solvent epoxy glass-flake coating, it is characterized in that forming by A liquid and B liquid, wherein A liquid adds 0.13 weight part
reactive thinner 660A dispersing and dissolving in addition in 1 weight part bisphenol A type epoxy resin E51, add 0.0008 weight part silicone oil again, 0.002 weight part
EP2440 sticking power promotes resin, high-speed stirring, under condition of stirring, add 0.002 weight part carbon black, 0.09 weight part titanium dioxide, 0.15 weight
part aluminium triphosphate, 0.05 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand mill then, add 0.4 weight part, 80 order glass
flakes afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2 weight part B liquid during use.

Non-solvent epoxy glass-flake coating of the present invention, use reactive thinner 660A to reduce system viscosity and satisfy construction requirement, reactive
thinner 660A contains epoxy group(ing), itself participates in reaction during curing, become the integral part that solidifies the back coating, therefore can eliminate
problems such as coating disadvantage that solvent based coating causes because of solvent evaporates and environmental pollution.Contain a large amount of
hydroxyls and ether isopolarity group in the bisphenol A type epoxy resin E51 molecular structure that uses, active epoxy group(ing) can form very firm chemical bond
with the interface metal atomic reaction in solidification process, has strengthened the sticking power of coating and base material.The glass flake that uses can
laminate the infiltration of effective obstruct corrosive medium mutually, improves the anti-permeability performance of coating, realizes long-effective corrosion.The
aluminium triphosphate depolymerization reaction that uses forms tripolyphosphate radical ion, the PO that it is used than bonderizing 4 + 3Ion is to FO + 3Ion and each
metal ion species have stronger chelating ability, form remarkable passive film on coated article surface, and the corrosion of metal objects such as iron and steel is had

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extremely strong restraining effect.The organobentonite auxiliary rheological agents 881-B that uses has good anti-heavy property and puts flow, has not only
strengthened the stability and the anti-heavy property of coating, and has overcome the trickling problem that usually faces in the thick coating construction.

The present invention's beneficial effect compared with prior art: solvent-free volatilization in the non-solvent epoxy glass-flake coating solidification process, coating is
shunk little, the compact structure anti-permeability performance is good, and has an extremely strong cohesive force, Corrosion Protection is strong, can be used for the
guide pipe on offshore platform splash zone, improve the anti-corrosion capability of steel pipe, prolong the working life of steel pipe.

1, non-solvent epoxy glass-flake coating of the present invention does not contain volatile solvent, and the feature of environmental protection is outstanding; Paint film
shrinks for a short time in the coating curing process, and alleviated internal stress and concentrated, so the coating structure densification, anti-permeability
performance is good, and has extremely strong cohesive force, and sticking power surpasses 12MPa, and the Corrosion Protection of coating significantly strengthens.

2, non-solvent epoxy glass-flake coating of the present invention, the aluminium triphosphate of interpolation makes the Corrosion Protection of coating stronger; The
881-B that adds makes coating have good sag prevention, and the wet-film thickness of once constructing can reach 500 microns, convenient construction.

Embodiment

Embodiment 1: the manufacture method of non-solvent epoxy glass-flake coating, in stainless charging basket, add 1 weight part bisphenol A type epoxy resin E51, add
0.13 weight part reactive thinner 660A dispersing and dissolving in addition again, add 0.0008 weight part silicone oil again, 0.002 weight part EP 2440 sticking power
promote resin, high-speed stirring, under condition of stirring, add 0.002 weight part carbon black, 0.09 weight part titanium dioxide, 0.15 weight part aluminium
triphosphate, 0.05 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand mill then, add 0.4 weight part, 80 order glass flakes
afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2 weight part B liquid during use.The raw materials
used commercially available product that is.

The application property of non-solvent epoxy glass-flake coating and coating performance test-results see Table 1.

Table 1 coating performance experimental result

Embodiment 2: the manufacture method of non-solvent epoxy glass-flake coating, in stainless charging basket, add 1 weight part bisphenol A type epoxy resin E51, add
0.1 weight part reactive thinner 660A dispersing and dissolving in addition again, add 0.0005 weight part silicone oil again, 0.001 weight part EP 2440 sticking power
promote resin, high-speed stirring, under condition of stirring, add 0.001 weight part carbon black, 0.05 weight part titanium dioxide, 0.1 weight part aluminium
triphosphate, 0.01 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand mill then, add 0.1 weight part, 80 order glass flakes
afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.2 weight part B liquid during use.The raw materials
used commercially available product that is.

Embodiment 3: the manufacture method of non-solvent epoxy glass-flake coating, in stainless charging basket, add 1 weight part bisphenol A type epoxy resin E51, add
0.15 weight part reactive thinner 660A dispersing and dissolving in addition again, add 0.001 weight part silicone oil again, 0.005 weight part EP 2440 sticking power
promote resin, high-speed stirring, under condition of stirring, add 0.005 weight part carbon black, 0.1 weight part titanium dioxide, 0.2 weight part aluminium
triphosphate, 0.05 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand mill then, add 0.5 weight part, 80 order glass flakes
afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.25 weight part B liquid during use.The raw materials
used commercially available product that is.

Embodiment 4: the manufacture method of non-solvent epoxy glass-flake coating, in stainless charging basket, add 1 weight part bisphenol A type epoxy resin E51, add
0.15 weight part reactive thinner 660A dispersing and dissolving in addition again, add 0.0006 weight part silicone oil again, 0.004 weight part EP 2440 sticking power
promote resin, high-speed stirring, under condition of stirring, add 0.003 weight part carbon black, 0.08 weight part titanium dioxide, 0.18 weight part aluminium
triphosphate, 0.03 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand mill then, add 0.3 weight part, 80 order glass flakes
afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.25 weight part B liquid during use.The raw materials
used commercially available product that is.

Embodiment 5: the manufacture method of non-solvent epoxy glass-flake coating, in stainless charging basket, add 1 weight part bisphenol A type epoxy resin E51, add
0.15 weight part reactive thinner 660A dispersing and dissolving in addition again, add 0.0007 weight part silicone oil again, 0.001 weight part EP 2440 sticking power
promote resin, high-speed stirring, under condition of stirring, add 0.003 weight part carbon black, 0.08 weight part titanium dioxide, 0.2 weight part aluminium

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10/1/23, 3:37 PM CN102260451A - Solvent-free epoxy glass flake coating and preparation method - Google Patents
triphosphate, 0.05 weight part organobentonite auxiliary rheological agents 881-B, grind 0.5～1h with sand mill then, add 0.5 weight part, 80 purpose glass flakes
afterwards, mix, make A liquid; B liquid is made up of epoxy hardener H633, is mixed by 1 weight part A liquid and 0.25 weight part B liquid during use.The raw materials
used commercially available product that is.

Patent Citations (2)

Publication number Priority date Publication date Assignee Title

CN101012361A * 2007-02-16 2007-08-08 天津市津博发金属制品有限公司 Adhesive for prestress steel strand anticorrosive coating

CN101531858A * 2009-04-17 2009-09-16 洛阳七维防腐工程材料有限公司 Ocean engineering concrete anti-corrosive paint

Family To Family Citations

* Cited by examiner, † Cited by third party

Cited By (7)

Publication number Priority date Publication date Assignee Title

CN102660107A * 2012-05-31 2012-09-12 东北林业大学 Post-treatment agent and method for using same to treat eucalyptus/PES
(polyether sulfone) composite powder formed part formed by selective laser
sintering

CN103788735A * 2012-10-29 2014-05-14 中冶建筑研究总院有限 Solvent-free flexible anticorrosion epoxy coating material, preparation method
公司 thereof and using method thereof

CN103980793A * 2013-02-07 2014-08-13 李清 New solventless epoxy coating

CN105925128A * 2016-05-12 2016-09-07 江苏永阳新材料科技有 Solvent-free epoxy glass flake paint

限公司

CN106047065A * 2016-07-01 2016-10-26 洛阳双瑞防腐工程技术 Solvent-free epoxy glass flake coating for sea splash zone steel structures and
有限公司 preparation method thereof

CN106243922A * 2016-08-23 2016-12-21 西北永新涂料有限公司 A kind of low-viscosity solvent-free graphite-epoxy alkene glass-flake coating and
preparation method thereof

CN109836963A * 2018-04-18 2019-06-04 上海振华重工（集团） A kind of preparation method of solvent-free epoxy glass flake coating
常州油漆有限公司

Family To Family Citations

* Cited by examiner, † Cited by third party, ‡ Family to family citation

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Priority And Related Applications

Priority Applications (1)

Application Priority date Filing date Title

CN 201110191623 2011-07-08 2011-07-08 Solvent-free epoxy glass flake coating and preparation method

Applications Claiming Priority (1)

Application Filing date Title

CN 201110191623 2011-07-08 Solvent-free epoxy glass flake coating and preparation method

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2011-11-30 C06 Publication

2011-11-30 PB01 Publication

2012-01-11 C10 Entry into substantive examination

2012-01-11 SE01 Entry into force of request for substantive examination

2013-05-01 C14 Grant of patent or utility model

2013-05-01 GR01 Patent grant

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