Penetration effect decreases with increasing n and l quantum numbers, meaning electrons are closer to the nucleus in ns orbitals than np orbitals, and closer in np orbitals than nd orbitals. Effective nuclear charge experienced by outer electrons increases across a period as it is partially shielded by inner electrons. Valency generally increases from left to right across a period, remaining constant within a group, and p-block, d-block, and f-block elements can have variable valencies. The inert pair effect causes decreased stability of the highest valency and increased stability of the next lowest valency for elements in groups 13, 14, and 15.
Penetration effect decreases with increasing n and l quantum numbers, meaning electrons are closer to the nucleus in ns orbitals than np orbitals, and closer in np orbitals than nd orbitals. Effective nuclear charge experienced by outer electrons increases across a period as it is partially shielded by inner electrons. Valency generally increases from left to right across a period, remaining constant within a group, and p-block, d-block, and f-block elements can have variable valencies. The inert pair effect causes decreased stability of the highest valency and increased stability of the next lowest valency for elements in groups 13, 14, and 15.
Penetration effect decreases with increasing n and l quantum numbers, meaning electrons are closer to the nucleus in ns orbitals than np orbitals, and closer in np orbitals than nd orbitals. Effective nuclear charge experienced by outer electrons increases across a period as it is partially shielded by inner electrons. Valency generally increases from left to right across a period, remaining constant within a group, and p-block, d-block, and f-block elements can have variable valencies. The inert pair effect causes decreased stability of the highest valency and increased stability of the next lowest valency for elements in groups 13, 14, and 15.
Classification of Elements and Periodicity in Properties -Class-3
• Penetration effect- Measure of closeness of electron or orbital to the nucleus ,
• Penetration effect is inversely proportional to ( n + l ) • Order of penetration effect is ns > np > nd > nf
• Effective Nuclear charge- Nuclear charge experienced by outer most electron
• Zeff is less than the nuclear charge due to repulsive force of inner electron • Zeff increases in a period while remain almost constant in a group
• Valency increases from 1 to 4 and then decreases from 4 to 0 in second period
• Valency increases from 1 to 4 and then decreases wrt H and Metal in a period • Valency increases from 1 to 7 wrt F and O in a period • Valency remain constant in a group • p-Block, d-Block & f-Block elements exhibit variable valencies • Inert pair effect- stability of Nth valency decrease and (N-2)th valency increases in a group of 13,14 and 15 group elements
Periodic Properties-Gen 1 and Gen 2 Page 1
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