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Revision Description Date Whom

Add ton/year column in the HAP output and determine if the


35 source is a major source, or area source in terms of 40 CFR Part 12 Jun 2013 GMLS
63.
36 Extend the glossary 12 Jun 2013 GMLS
37 Add list of legislation to the CEMS tab 12 Jun 2013 GMLS
38 Area Source or Major Source is output in the Emissions Tab 12 Jun 2013 GMLS
39 EPA limits on PM2.5 added to the Criteria Tab 12 Jun 2013 GMLS
40 Electric boiler, Emissions tab revised 16 Dec 2013 GMLS
41 Revise the Criteria Layout 27 Dec 2013 GMLS
42 Revise Company Name 02 Jan 2014 GMLS
43 Water added to the operating details 02 Jan 2014 GMLS
44 Add ancilliary power costs 02 Jan 2014 GMLS
45 Raw water temperature added 03 Jan 2014 GMLS
46 Chemicals cost added 03 Jan 2014 GMLS
47 Formating of Emissions Inventory 03 Jan 2014 GMLS
48 Add NPI mercury abatement rates 04 Jan 2014 GMLS
Abatement for PM2.5 using a multicyclone - use EMEP values as
49 04 Jan 2014 GMLS
NPI does not provide.
50 Added several items to the glossary 27 Sep 2014 GMLS
Add some definitions to the list, added revision information on all
51 08 Dec 2014 GMLS
the sheets
52 Added Chinese air pollution standards to CEMS page 01 Jan 2016 GMLS
Added CO2 tab concerning the EPA CO2 limit on coal fired
53 11 Feb 2016 GMLS
boilers. Dated Aug 3, 2015
54 Added EPA CO limits to criteria tab 13 Feb 2016 GMLS
Added EPA Pb limits to the criteria tab
Added EPA Ozone limits to the criterial tab
Added the EPA NO2 limits to the criteria tab
Added the EPA PM limits to the criteria tab
Added note of the latest CFG for each critera pollutant
55 Added the CO2 limit to the Greenhouse tab 13 Feb 2016 GMLS
56 Definitions tab updated 13 Feb 2016 GMLS
57 Corrected the CEMS requirement 13 Feb 2016 GMLS
58 Added to the definitions tab 12 Jan 2019 GMLS
59 Added further definitions 13 Jan 2019 GMLS
60 Add note about BLIER 22 Jan 2019 GMLS

60 22 Jan 2019
Job Number
Date

Acronym Definition

ATH Alternate Threshold Canada


BLIER Base-Line Industrial Emission Requirement Canada
CACs Criteria Air Contaminants
CAS Chemical Abstracts Service
CEPA 1999 Canadian Environmental Protection Act 1999 Canada
CCME Canadian Council of Ministers of the Environment Canada
CCS Carbon Capture and Sequestration
CHP Combined Heat and Power
CPM Condensable Particulate Matter (assumed to be less than 1 micron in diameter)
Criteria pollutant The six criteria pollutants are sulphur dioxide, nitrogen oxides, carbon monoxide, lead, particulate matter less than 10 micron and ozone.
DET Domestic Emissions Trading Canada
ECA Environmental Compliance Approval Canada
ESDM Emissions Summary and Dispersion Modelling Canada
EPA Environmental Protection Agency USA
EPER European Pollutant Emission Register Europe
EPRI Electric Power Research Institute USA
GHG GreenHouse Gas
GLC Ground Level Concentration Canada
GWP Global Warming Potential
HAP Hazardous Air Pollutants
IGCC Integrated Gasification Combined Cycle
IGFC Integrated Gasification Fuel Cell
JSL Jurisdictional Screening Level Canada
MMBTU Million BTU per hour, or MMBH
MOE Ministry of Environment (prior to 2016) Canada
MOECC Ministry of Environment and Climate Change Canada
NAICS North American Industrial Classification System
NERM National Emissions Reduction Masterplan Canada
NOx Oxides of nitrogen based on nitrogen dioxide
NPRI National Pollutant Release Inventory Canada
PAH Polynuclear Aromatic Hydrocarbons
PM Particulate Matter
PM2.5 Particulate matter less than or equal to 2.5 microns in aerodynamic diameter
PM10 Particulate matter less than or equal to 10 microns in aerodynamic diameter
PIBS Public Information Banking System Canada
POI Point of Impingement Canada
Poly Organic Matter - includes organic compounds with more than one benzene ring and which have a boiling point greater than or equal to
POM
100 oC
RAQM Regional Air Quality Model Canada

Definitions Prepared By
Page 2 of 36
701631373.xlsx Leonine International Inc
Job Number
Date

RDIS Residual Discharge Information System Canada


RFS Renewable Fuel Standard USA
RIN Renewable Identification Numbers USA
RSH methyl mercaptan
RSR methyl sulfide
RSSR methyl disulfide
RVO Renewable Volume Obligation USA
SCC Standard Classification Code
SOFC Solid Oxide Fuel Cell
SOx oxides of sulfur based on sulfur dioxide
TOC total organic compound - all organics including non-photoreactive compounds
TPM Total Particulate Matter
TRI Toxics Release Inventory USA
UNFCCC United Nations Framework Convention on Climate Change Global
URT Upper Risk Threshold Canada
USC Ultra super critical
VCR Voluntary Challenge and Registry Canada
volatile organic compound - any compound of carbon excluding carbon monoxide, carbon dioxide, metallic oxides and carbonates,
VOC
amonnium carbonate which participate in atmospheric chemical reactions

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Definitions Prepared By
Page 3 of 36
701631373.xlsx Leonine International Inc
Wood - ECBiomass Pellet
Gross calorific value 18.77 MJ/kg

Constituent % mass
Carbon 47.08
Chlorine 0.02
Hydrogen 5.36
Sulphur 0.04
Oxygen 39.12
Nitrogen 0.09
Moisture 7.46
Ash 0.83

Prepared by
Leonine International Inc
Industrial Bake Company Emissions Inventory Job number 0432_x000D_18 Mar 2019

EPA AP-42 - Section 1.6, Sept 2003; IPCC Table 2.2 (2006); NPI Table 33Ver. 3.6, Dec 2011
Fuel details Boiler heating classification Heat In Furnace Configuration 40 CFR Part 63
MMBtu
Wood Industrial 29.0 gross Duth-oven Normal Area Source
Wood - ECBiomass Pellet 8.5 MWth

Operation
Fuel 1,612.1 kg/hour 130.78 USD/hour 1,145,622 USD/year
Steam 8,902 kg/hour 5.52 ton steam/ton fuel 77,982 ton/year
Air 18,185 kg/hour 100.00 % excess air
Feed 12,273 kg/hour 100.00 °C Makeup 7,599 kg/hour 30 °C 7.60 USD/hour 66,569 USD/year
Chemicals 2.28 USD/hour 19,971 USD/year
Operating 8,760 Hours/year 0 hours/day
Emissions for World Wide Woods

Products of
Fuel Air Steam Ash Fly ash Argon Oxygen Nitrogen Water
Boiler Abatement combustion [229°C]
ton/year ton/year ton/year ton/year ton/year ton/year ton/year ton/year ton/year ton/year
SHOD 10000/2400 Multicyclone 14122 159,304 77,981 105.5 13.3 2017.427 18203.2 118,802.9 9,839.1 173,309
Particulate Matter (Multicyclone) VOC
CO2 CO NOx N2O SO2 SO3 TOC Non CH4 Total Carbon
Cond' Filterable Stack SO4
Methane
ton/year ton/year ton/year ton/year ton/year NA ton/year ton/year ton/year NA ton/year ton/year ton/year µg/year ton/year
22,223 8751.2 1.9 45.6 34.2 ND 8,751.2 1.5 2.8 ND 4.4 1.5 2.4 0.0 6,069
24,429
IPCC Fuel Category - Wood: Range - Default followed by Min/Max
CO₂ Global Warming Potential (100 year) N₂O CH₄
ton/year ton CO2e/year kg/year ton/year
27,554 52,147 984.1 7.4
23372 / 32474 50/500 369 / 3690 2.5 / 24.6
Emissions at power plant

CO2 PM Ash NOx SO2 CH₄ Carbon


Used
µg/year µg/year µg/year µg/year µg/year µg/year µg/year
Generating Steam 0 0.0 0.0 0.0 0.0 0.0 0
ton/year kg/year ton/year kg/year ton/year kg/year ton/year
Ancilliary Power 322.7 59.4 53.0 465.4 1.3 6.7 88.1 451.89 USD/hour 3,958,597 USD/year

Form Revision 60 Boiler file - SHOD10-24 columbus.bd10


22 Jan 2019 Customer file - Creative-600HP.bc10
EPA version 1595.03.05.13 Fuel file - Wood - ECBiomass Pellet.ful
BPVM version 1599.07.71.05 Site file - Vancouver Canada.bs10

Emissions
701631373.xlsx
Prepared by_x000D_Leonine International Inc Page 5 of 36
Acid rain

Hydrochloric acid HCl 2.2 ton/year 12.5 ppm


Hydrogen fluoride HF ND NA ND NA
Hydrogen sulfide H2S ND NA ND NA
Nitrogen dioxide NO2 8749.8 ton/year 50486.6 ppm
Nitrogen oxide NO ND NA ND NA
Nitrous oxide N2O 1.5 ton/year 8.5 ppm
NOx based on NO2 8751.2 ton/year 50495.1 ppm
Sulphur dioxide SO2 2.8 ton/year 16.4 ppm
Sulphur trioxide SO3 ND NA ND NA
SOx as SO2 2.8 ton/year 16.4 ppm

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc
Averaging period
Criteria Pollutants - Duth-oven furnace configuration - at 7.80
Year 24-hour 8-hour 1-hour 10-min 1-hour Control Method 4.24 Nm³/s
am³/s

Carbon monoxide CO 8751.2 ton/year 50495.1 ppm 277,500,000.0 0.0 ### ### µg/s 65,448.1 mg/Nm³
Lead Pb 5.5 kg/year 0.0 ppm 173.5 0.0 173.5 173.5 µg/s 0.0 mg/Nm³
Nitrogen dioxide NO2 8749.8 ton/year 50486.6 ppm 277,453,024.0 0.0 ### ### µg/s 65,437.0 mg/Nm³
Nitrogen oxide NO ND NA ND NA -277,777.8 0.0 -277,777.8 -277,777.8 µg/s -65.5 mg/Nm³
Nitrous oxide N2O 1.5 ton/year 8.5 ppm 46,978.8 0.0 46,978.8 46,978.8 µg/s 11.1 mg/Nm³
NOx based on NO2 8751.2 ton/year 50495.1 ppm 277,500,000.0 0.0 ### ### µg/s 65,448.1 mg/Nm³
Ozone 0.0 µg/year 0.0 ppm 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
PM2.5 34.6 ton/year 199.9 ppm 1,098,582.0 0.0 1,098,582.0 1,098,582.0 µg/s 578,201.0 Multicyclone 259.1 136.4 mg/Nm³
PM5 39.2 ton/year 226.2 ppm 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
PM10 41.0 ton/year 236.7 ppm 1,300,952.4 0.0 1,300,952.4 1,300,952.4 µg/s 975,714.3 Multicyclone 306.8 230.1 mg/Nm³
PM condensable 1.9 ton/year 11.2 ppm 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
PM filterable 45.6 ton/year 263.0 ppm 1,445,502.6 0.0 1,445,502.6 1,445,502.6 µg/s 1,084,126.9 Multicyclone 340.9 255.7 mg/Nm³
PM total 47.5 ton/year 274.2 ppm 1,506,936.5 0.0 1,506,936.5 1,506,936.5 µg/s 355.4 0.0 mg/Nm³
Sulphur dioxide SO2 2.8 ton/year 16.4 ppm 90,343.9 0.0 90,343.9 90,343.9 µg/s 21.3 mg/Nm³
Sulphur trioxide SO3 ND NA ND NA 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
Sulphate particulate ND NA ND NA 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
SOX as SO2 2.8 ton/year 16.4 ppm 90,343.9 0.0 90,343.9 90,343.9 µg/s 21.3 mg/Nm³

Uncontrolled values Bold results are the values required for reporting in the South African regulations Uncontrolled Controlled
Results Results

Rolling
EPA Limits Valid Year
3-month
24-hour 8-hour 3 hourly 1-hour 10-min Notes

Carbon monoxide CO 76 FR 54294 - 31 Aug 2011 9 35 ppm Not to be exceeded more than once per year
Lead Pb 73 FR 66964 - 12 Nov 2008 0.15 µg/m³ 0.15 µg/m³, averaging period= rolling 3-month, not to be exceeded.

Nitrogen dioxide NO2 77 FR 20218 - 3 Apr 2012 100 ppb 98th percentile of 1-hour daily maximum concentrations, averaged over 3 years

Nitrogen dioxide NO2 53 ppb Annual Mean

Ozone 80 FR 65292 - 26 Oct 2015 0.070 ppm Annual fourth-highest daily maximum 8-hour concentration, averaged over 3 years

PM2.5 78 FR 3086 - 15 Jan 2013 35 µg/m³ 98th percentile, averaged over 3 years
PM2.5 78 FR 3086 - 15 Jan 2013 12 µg/m³ Annual mean, averaged over 3 years
PM10 78 FR 3086 - 15 Jan 2013 150 µg/m³ Not to be exceeded more than once per year on average over 3 years

Sulphur dioxide SO₂ 75 FR 35520 - 22 Jun 2010 75 ppb 99th percentile of 1-hour daily maximum concentrations, averaged over 3 years

Primary - provide public health protection, including protecting the health of "sensitive" populations such as asthmatics, children, and the elderly.

Lead Pb 73 FR 66964 - 12 Nov 2008 0.15 µg/m³ 0.15 µg/m³, averaging period= rolling 3-month, not to be exceeded.
Nitrogen dioxide NO2 53 ppb Annual Mean

Ozone 0.070 ppm Annual fourth-highest daily maximum 8-hour concentration, averaged over 3 years
80 FR 65292 - 26 Oct 2015
PM2.5 78 FR 3086 - 15 Jan 2013 35 µg/m³ 98th percentile, averaged over 3 years
PM2.5 78 FR 3086 - 15 Jan 2013 15 µg/m³ Annual mean, averaged over 3 years
PM10 78 FR 3086 - 15 Jan 2013 150 µg/m³ Not to be exceeded more than once per year on average over 3 years
Sulphur dioxide SO₂
77 FR 20218 - 3 Apr 2012 0.5 ppm Not to be exceeded more than once per year
(Secondary)
Secondary - provide public welfare protection, including protection against decreased visibility and damage to animals, crops, vegetation, and buildings.

Form Revision 60
22 Jan 2019

Prepared by
Leonine International Inc.
EPA version 1595.03.05.13
BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
to be exceeded.

ons, averaged over 3 years

tration, averaged over 3 years

rage over 3 years

ons, averaged over 3 years

to be exceeded.

tration, averaged over 3 years

rage over 3 years

Prepared by
Leonine International Inc.
Polychlorinated dibenzo-p-dioxins

2, 3, 7, 8 - TCDD 980.1 µg/year


TCDD Tetrachlorodibenzo-p-dioxin 53.6 mg/year
PeCDD Pentachlorodibenzo-p-dioxin 170.9 mg/year
HxCDD Hexachlorodibenzo-p-dioxin 182.3 g/year
HpCDD Heptachlorodibenzo-p-dioxin 227.9 mg/year
OCDD Octachlorodibenzo-p-dioxin 7.5 g/year
Total PCDD 190.3 g/year

Polychlorinated dibenzo-p-furans

2, 3, 7, 8 - TCDF 10.3 mg/year


TCDF Tetrachlorodibenzo-p-furan 85.5 mg/year
PeCDF Pentachlorodibenzo-p-furan 47.9 mg/year
HxCDF Hexachlorodibenzo-p-furan 31.9 mg/year
HpCDF Heptachlorodibenzo-furan 27.4 mg/year
OCDF Octachlorodibenzo-p-furan 10.0 mg/year
Total PCDF 202.6 mg/year

Polychlorinated dioxins and furans (TEQ)

Total PDF 190.519 kg/year

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc
Greenhouse EPA Limit

Carbon monoxide CO 8751.2 ton/year 50495.1 ppm


Carbon dioxide CO2 22222.9 ton/year 128227.1 ppm 636 kg/MWh produced
Methane CH4 2.4 ton/year 13.8 ppm
Nitrogen dioxide NO2 8749.8 ton/year 50486.6 ppm
Nitrogen oxide NO ND NA ND NA
Nitrous oxide N2O 1.5 ton/year 8.5 ppm
NOx based on NO2 8751.2 ton/year 50495.1 ppm
VOC - non methane 1.5 ton/year 8.5 ppm
VOC 0.0 µg/year 0.0 ppm

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
Actual

MWh produced 3-Aug-15 410.464

Prepared by
Leonine International Inc.
Hazardous air pollutants

Acetaldehyde 94.6 kg/year 0.5 ppm


Acetophenone 364.7 mg/year 0.0 ppm
Acrolein 455.9 kg/year 2.6 ppm
Antimony 900.3 g/year 0.0 ppm
Arsenic 2.5 kg/year 0.0 ppm
Benzene 478.6 kg/year 2.8 ppm
Benzyl chloride ND NA ND NA
Beryllium 125.4 g/year 0.0 ppm
Bromoform ND NA ND NA
Cadmium 467.3 g/year 0.0 ppm
Carbon disulfide ND NA ND NA
Carbon tetrachloride 5.1 kg/year 0.0 ppm
Chlorine 90.0 kg/year 0.5 ppm
Chloroacetophenone ND NA ND NA
Chlorobenzene 3.8 kg/year 0.0 ppm
Chloroform 4.3 kg/year 0.0 ppm
Chromium 2.4 kg/year 0.0 ppm
Cobalt 740.8 g/year 0.0 ppm
Cumene ND NA ND NA
Dibenzofuran 202.6 mg/year 0.0 ppm
1,4-Dichlorobenzene ND NA ND NA
2,4-Dinitrophenol 20.5 g/year 0.0 ppm
2,4-Dinitrotoluene ND NA ND NA
Ethyl benzene 3.5 kg/year 0.0 ppm
Ethyl chloride ND NA ND NA also known as Chloroethane
Ethylene dibromide ND NA ND NA also known as 1,2-Dibromoethane
Ethylene dichloride ND NA ND NA also known as 1,2-Dichloroethane
Ethylidene dichloride ND NA ND NA also known as 1,1-Dichloroethane
Formaldehyde 501.4 kg/year 2.9 ppm
Hexane ND NA ND NA
Hydrochloric acid 2.2 ton/year 12.5 ppm
Hydrogen fluoride ND NA ND NA
Isophorone ND NA ND NA
Lead 5.5 kg/year 0.0 ppm
Manganese 182.3 kg/year 1.1 ppm
Mercury 398.9 g/year 0.0 ppm
Methyl bromide ND NA ND NA also known as Bromomethane
Methyl chloride ND NA ND NA
Methyl ethyl ketone ND NA ND NA
Methyl hydrazine ND NA ND NA
Methyl methacrylate ND NA ND NA
Methyl tert butyl ether ND NA ND NA
Methylene chloride ND NA ND NA also known as Dichloromethane
Naphthalene 11.1 kg/year 0.1 ppm
Nickel 3.8 kg/year 0.0 ppm
4-Nitrophenol 12.5 g/year 0.0 ppm
Pentachlorophenol 5.8 g/year 0.0 ppm

Prepared by
Leonine International Inc.
Phenol 5.8 kg/year 0.0 ppm
Phosphorous 3.1 kg/year 0.0 ppm
POM ND NA ND NA
Propionaldehyde 7.0 kg/year 0.0 ppm
Selenium 319.1 g/year 0.0 ppm
Styrene 216.5 kg/year 1.2 ppm
2,3,7,8-Tetrachlorodibenzo-p-
980.1 µg/year 0.0 ppm
dioxin
Tetrachloroethylene ND NA ND NA also known as Perchloroethylene
Toluene 104.8 kg/year 0.6 ppm
1,1,2-Trichloroethane 3.5 kg/year 0.0 ppm
2,4,6-Trichlorophenol 2.5 g/year 0.0 ppm
Vinyl chloride 2.1 kg/year 0.0 ppm
Xylenes ND NA ND NA
m-Xylene ND NA ND NA
o-Xylene 2.8 kg/year 0.0 ppm
p-Xylene ND NA ND NA
TOTAL

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
40 CFR Part 63
[ton/year]
0.1042855
0.0004021
0.5025790
0.0009926
0.0027640
0.5277072
0.0000000
0.0001382
0.0000000
0.0005151
0.0000000
0.0056536
0.0992592
0.0000000
0.0041465
0.0047749
0.0026383
0.0008167
0.0000000
0.0002234
0.0000000
0.0000226
0.0000000
0.0038951
0.0000000
0.0000000
0.0000000
0.0000000
0.5528365
0.0000000
0.0000024
0.0000000
0.0000000
0.0060307
0.2010310
0.0004398
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0121870
0.0041465
0.0000138
0.0000064

Prepared by
Leonine International Inc.
0.0064077
0.0033924
0.0000000
0.0076646
0.0003518
0.2387254
0.0010805
0.0000000
0.1155927
0.0038951
0.0000028
0.0022612
0.0000000
0.0000000
0.0031410
0.0000000
2.4200234 Area Source

Prepared by
Leonine International Inc.
Trace elements

Antimony 900.3 g/year 0.0 ppm


Arsenic 2.5 kg/year 0.0 ppm
Barium 19.4 kg/year 0.1 ppm
Cadmium 467.3 g/year 0.0 ppm
Chloride ND NA ND NA
Chromium total 2.4 kg/year 0.0 ppm
Chromium hexavalent 398.9 g/year 0.0 ppm
Cobalt 740.8 g/year 0.0 ppm
Copper 5.6 kg/year 0.0 ppm
Iron 112.8 kg/year 0.7 ppm
Lead 5.5 kg/year 0.0 ppm
Manganese 182.3 kg/year 1.1 ppm
Mercury 398.9 g/year 0.0 ppm
Molybdenum 239.3 g/year 0.0 ppm
Nickel 3.8 kg/year 0.0 ppm
Phosphorous 3.1 kg/year 0.0 ppm
Potassium 4.4 ton/year 25.6 ppm
Selenium 319.1 g/year 0.0 ppm
Silver 193.7 kg/year 1.1 ppm
Sodium 41.0 kg/year 0.2 ppm
Strontium 1.1 kg/year 0.0 ppm
Tin 2.6 kg/year 0.0 ppm
Vanadium 111.7 g/year 0.0 ppm
Yttrium 34.2 g/year 0.0 ppm
Zinc 47.9 kg/year 0.3 ppm

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
Various organic compounds

Acetaldehyde 94.6 kg/year 0.5 ppm


Acetone 21.7 kg/year 0.1 ppm
Acetophenone 364.7 mg/year 0.0 ppm
Acrolein 455.9 kg/year 2.6 ppm
Benzaldehyde 96.9 g/year 0.0 ppm
Benzene 478.6 kg/year 2.8 ppm
Benzoic acid 5.4 g/year 0.0 ppm
Benzyl chloride ND NA ND NA
Bis(2-ethylexyl)phthalate (DEHP) 5.4 g/year 0.0 ppm
Bromoform ND NA ND NA
Bromomethane 1.7 kg/year 0.0 ppm
Butane ND NA ND NA
2-Butanone (MEK) 615.4 g/year 0.0 ppm
Carbazole 205.1 g/year 0.0 ppm
Carbon disulfide ND NA ND NA
Carbon tetrachloride 5.1 kg/year 0.0 ppm
Chlorine 90.0 kg/year 0.5 ppm
2-Chloroacetophenone ND NA ND NA
Chlorobenzene 3.8 kg/year 0.0 ppm
Chloroform 4.3 kg/year 0.0 ppm
Chloromethane 2.6 kg/year 0.0 ppm
2-Chloronaphthalene 273.5 mg/year 0.0 ppm
2-Chlorophenol 2.7 g/year 0.0 ppm
Crotonaldehyde 1.1 kg/year 0.0 ppm
Cumene ND NA ND NA
Cyanide ND NA ND NA
Decachlorobiphenyl 30.8 mg/year 0.0 ppm
Dibenzo(a,h)anthracene 1.0 g/year 0.0 ppm
1,2-Dibromoethene ND NA ND NA
Dichlorobenzene ND NA ND NA
Dichlorobiphenyl ND NA ND NA
1,2-Dichloroethane ND NA ND NA
Dichloromethane ND NA ND NA
1,2-Dichloropropane ND NA ND NA
7,12-Dimethylbenz(a)anthracene ND NA ND NA
Dimethyl sulfate ND NA ND NA
2,4-Dinitrophenol 20.5 g/year 0.0 ppm
2,4-Dinitrotoluene ND NA ND NA
Ethane ND NA ND NA
Ethyl benzene 3.5 kg/year 0.0 ppm
Ethyl chloride ND NA ND NA
Ethylene dichloride ND NA ND NA
Ethylene dibromide ND NA ND NA
Formaldehyde 501.4 kg/year 2.9 ppm
Heptchlorobiphenyl 7.5 mg/year 0.0 ppm
Hexachlorobiphenyl 62.7 mg/year 0.0 ppm
Hexanal 797.7 g/year 0.0 ppm

Prepared by
Leonine International Inc.
Hexane ND NA ND NA
Isobutyraldehyde 1.4 kg/year 0.0 ppm
Isophorone ND NA ND NA
Methyl bromide ND NA ND NA
3-Methylchloranthrene ND NA ND NA
Methyl chloride ND NA ND NA
Methyl ethyl ketone ND NA ND NA
Methyl hydrazine ND NA ND NA
Methyl methacrylate ND NA ND NA
2-Methylnaphthalene 18.2 g/year 0.0 ppm
Methyl tert butyl ether ND NA ND NA
Methylene chloride ND NA ND NA
Monochlorobiphenyl 25.1 mg/year 0.0 ppm
2-Nitrophenol 27.4 g/year 0.0 ppm
4-Nitrophenol 12.5 g/year 0.0 ppm
Pentachlorobiphenyl 136.8 mg/year 0.0 ppm
Pentachlorophenol 5.8 g/year 0.0 ppm
Pentane ND NA ND NA
Perylene 59.3 mg/year 0.0 ppm
Phenol 5.8 kg/year 0.0 ppm
Polycyclic Organic Matter (POM) ND NA ND NA
Propanal 364.7 g/year 0.0 ppm
Propane ND NA ND NA
Propionaldehyde 7.0 kg/year 0.0 ppm
RSH, RSR and RSSR ND NA ND NA
Styrene 216.5 kg/year 1.2 ppm
Tetrachlorbiphenyl 284.9 mg/year 0.0 ppm
Tetrachloroethene 4.3 kg/year 0.0 ppm
Tetrachloroethylene ND NA ND NA
o-Tolualdehyde 820.5 g/year 0.0 ppm
p-Tolualdehyde 1.3 kg/year 0.0 ppm
Toluene 104.8 kg/year 0.6 ppm
Trichlorobiphenyl 296.3 mg/year 0.0 ppm
1,1,1-Trichloroethane 3.5 kg/year 0.0 ppm
Trichloroethene 3.4 kg/year 0.0 ppm
Trichlorofluoromethane 4.7 kg/year 0.0 ppm
2,4,6-Trichlorophenol 2.5 g/year 0.0 ppm
Xylenes ND NA ND NA
m-Xylene ND NA ND NA
o-Xylene 2.8 kg/year 0.0 ppm
p-Xylene ND NA ND NA
Vinyl acetate ND NA ND NA
Vinyl chloride 2.1 kg/year 0.0 ppm

Form Revision 60
22 Jan 2019

Prepared by
Leonine International Inc.
EPA version 1595.03.05.13
BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
Polynuclear aromatic hydrocarbons

Biphenyl ND NA ND NA
Acenaphthene 103.7 g/year 0.0 ppm
Acenaphthylene 569.8 g/year 0.0 ppm
Anthracene 341.9 g/year 0.0 ppm
Benzo(a)anthracene 7.4 g/year 0.0 ppm
Benzo(a)pyrene 296.3 mg/year 0.0 ppm
Benzo(b)fluoranthene 11.4 g/year 0.0 ppm
Benzo(b,j,k)fluoranthene ND NA ND NA
Benzo(b,k)fluoranthene ND NA ND NA
Benzo(j,k)fluoranthene 11.4 g/year 0.0 ppm
Benzo(k)fluoranthene 4.1 g/year 0.0 ppm
Benzo(g,h,i)perylene 10.6 g/year 0.0 ppm
Chrysene 4.3 g/year 0.0 ppm
Fluorathene 182.3 g/year 0.0 ppm
Fluorene 387.5 g/year 0.0 ppm
Indeno(1,2,3-cd)pyrene 9.9 g/year 0.0 ppm
Naphthalene 11.1 kg/year 0.1 ppm
Phenanthrene 797.7 g/year 0.0 ppm
Pyrene 421.7 g/year 0.0 ppm
5-Methyl chrysene ND NA ND NA
Total PAH 13.9 kg/year 0.0 kg/year

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
Industrial Bake Company World Wide Woods

Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Flue gas temperature NA 229.3 °C NA NA
Hot gas stack flow NA 7.8 am³/s

Principal mass flows [TPA]

Air for combustion NA 159,304 TPA 0.000 159,304.112


Fuel NA 14,122 TPA 0.000 14,121.725
Steam NA 77,981 TPA 0.000 77,981.096
Boiler ash NA 105.5 TPA 0.000 105.489
PM - at chimney stack NA 34.2 TPA 0.000 34.189
PM - collected as grit NA 13.3 TPA 0.000 13.334 87,591,240
Combustion Products (XA= 100%) NA 173,309 TPA 0.000 173,308.625
Carbon dioxide 124-38-9 22,223 TPA 322.7 0.000 0.000 22,545.592 23,372 27,554 32,474 100000000
Carbon footprint NA 6,069 TPA 88.1 0.000 0.000 6,156.879
Global Warming Potential [CO2e] NA 52.1 TPA 0.000 52.147
Argon NA 2,017 TPA 0.000 2,017.427
Nitrogen NA 118,803 TPA 0.000 118,803
Oxygen NA 18,203 TPA 0.000 18,203.202
Water vapour NA 9,839 TPA 0.000 9,839.109

Acid rain [kg/year]

Hydrochloric acid HCl 7647-01-0 2,165 kg/year 0.000 2,165.305 ND 10,000.000 87,591,240
Hydrogen fluoride HF 7664-39-3 ND kg/year 0.000 0.000 ND 10,000.0
Hydrogen sulfide H2S 7783-06-4 ND kg/year 0.000 0.000 10000
Nitrogen dioxide NO2 10102-44-0 8,749,759 kg/year 460.4 0.000 460.373 8,750,219.288
Nitrogen oxide NO 10102-43-9 ND kg/year 0.000 0.000
Nitrous oxide N2O 10024-97-2 1,482 kg/year 5.039 0.000 5.0 1,486.6 369.0 984.1 3,690 2,700.000
NOx based on NO2 10102-44-0 8,751,240 kg/year 465.4 0.000 465 8,751,706 21,041 21,467.000
Sulphur dioxide SO2 7446-09-5 2,849 kg/year 1,282 0.000 1,282 4,131 2,401 20,000.000
Sulphur trioxide SO3 - ND kg/year 32.1 0.000 32.052 32.052
SOx as SO2 7446-09-5 2,849 kg/year 1,314 0.000 1,314 4,163

Criteria pollutants [kg/year] - Duth-oven

PM2.5 - Uncontrolled N/A - M10 34,645 kg/year 0.0 29,258.8 38,694 300.000
PM5 - Uncontrolled - 39,203 kg/year 0.0 0.0
PM10 - Uncontrolled N/A - M09 41,027 kg/year 0.0 44,922.0 45,754 500.000
PM Condensable - Uncontrolled - 1,937 kg/year 0.0 2,680.5
PM Filterable - Uncontrolled - 45,585 kg/year 0.0 52,252.4 20,000 87,591,240
PM Total - Uncontrolled - 47,523 kg/year 59.4 0.000 204.4 55,137.3 20,000.000
Carbon monoxide CO 603-08-0 8,751,240 kg/year 0.0 8,935.1 57,617 20,000.000 1,732,913
Lead Pb NA - 08 5.470 kg/year 0.000 5.470 3.149 10,000.000
Nitrogen dioxide NO2 10102-44-0 8,749,759 kg/year 460.4 0.000 460 8,750,219
Nitrogen oxide NO 10102-43-9 ND kg/year 0 0
Nitrous oxide N2O 10024-97-2 1,482 kg/year 5.039 0.000 5.0 1,486.6 2700
NOx based on NO 10102-43-9 0.000 465.4 0.000 465.4 465.4 14000
NOx based on NO2 10102-44-0 8,751,240 kg/year 1,602 0.000 1,602 8,752,842 21,467.000
Ozone - 0.000 kg/year 0.000 0.000 21,041 21467
PM2.5 - Controlled Multicyclone N/A - M10 18,234 kg/year 0 18,234 300
PM10 - Controlled Multicyclone N/A - M09 30,770 kg/year 0 30,770 500
PM Total - Controlled Multicyclone - 34,189 kg/year 204.4 0.000 204 34,393
Sulphur dioxide SO2 7446-09-5 2,849 kg/year 1,282 0.000 1,282 4,131 2,401 20,000.000
Sulphur trioxide SO3 - ND kg/year 32.1 0.000 32.052 32.052
Sulphate particulate - ND kg/year 0.000 0.000
SOX as SO2 7446-09-5 2,849 kg/year 1,314 0.000 1,314 4,163

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Complete Leonine International
Industrial Bake Company World Wide Woods

Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year

Polychlorinated dibenzo-p-dioxins [mg/year]

2, 3, 7, 8 - TCDD 1746-01-6 0.980 mg/year 0.000 0.980 0


TCDD Tetrachlorodibenzo-p-dioxin - 53.6 mg/year 0.0 53.6
PeCDD Pentachlorodibenzo-p-dioxin - 170.9 mg/year 0.0 170.9
HxCDD Hexachlorodibenzo-p-dioxin - 182,341 mg/year 0 182,341
HpCDD Heptachlorodibenzo-p-dioxin - 227.9 mg/year 0 228
OCDD Octachlorodibenzo-p-dioxin - 7,522 mg/year 0 7,522
Total PCDD - 190,315 mg/year 0 190,315

Polychlorinated dibenzo-p-furans [mg/year]

2, 3, 7, 8 - TCDF 51207-31-9 10.3 mg/year 0.0 10.3 0


TCDF Tetrachlorodibenzo-p-furan - 85.5 mg/year 0.0 85.5
PeCDF Pentachlorodibenzo-p-furan - 47.9 mg/year 0.0 47.9
HxCDF Hexachlorodibenzo-p-furan - 31.9 mg/year 0.0 31.9
HpCDF Heptachlorodibenzo-furan - 27.4 mg/year 0.0 27.4
OCDF Octachlorodibenzo-p-furan - 10.0 mg/year 0.0 10.0
Total PCDF - 202.6 mg/year 0 203

Polychlorinated dioxins and furans (TEQ)

Total PDF - 190732.006 mg/year 0 190,732 7.470

Greenhouse [kg/year]

Carbon monoxide CO 603-08-0 8,751,240 kg/year 0.0 8,751,240.1 57,617 20,000.000


Carbon dioxide CO2 124-38-9 22,222,867 kg/year 322,725 0.000 322,725 22,545,592 100000000
Methane CH4 74-82-8 2,393 kg/year 6.667 0.000 7 2,400 2,460 7,381 24,602 5000000
Nitrogen dioxide NO2 10102-44-0 8,749,759 kg/year 460.4 0.000 460.373 8,750,219.288
Nitrogen oxide NO 10102-43-9 ND kg/year 0.000 0.000
Nitrous oxide N2O 10024-97-2 1,482 kg/year 5.039 0.000 5 1,487 2700
NOx based on NO2 10102-44-0 8,751,240 kg/year 465.4 0.000 465 8,751,706 21,041 21,467.000
VOC - non methane - 1,482 kg/year 0.000 1481.525 0.000
VOC N/A - M16 0.000 kg/year 0 0 1,695 10,000.0

Hazardous air pollutants [g/year]

Acetaldehyde 75-07-0 94,590 g/year 0 94,590 10000


Acetophenone 98-86-2 0.365 g/year 0.000 0.365 10000
Acrolein 107-02-8 455,854 g/year 0 455,854 10000
Antimony NA - 01 900.3 g/year 0.0 900.3 ND 10,000
Arsenic NA - 02 2,507 g/year 0.0 2,507.2 603.0 10,000.000
Benzene 71-43-2 478,646 g/year 0 478,646 10000
Benzyl chloride 100-44-7 ND g/year 0.000 0.000
Beryllium 7440-41-7 125.4 g/year 0.000 125.360 2.316 500.0
Bromoform ND g/year 0.000 0.000
Cadmium NA - 03 467.2 g/year 0 467 149.7 10,000.000
Carbon disulfide 75-15-0 ND g/year 0.000 0.000 10000
Carbon tetrachloride 56-23-5 5,128 g/year 0 5,128 10000
Chlorine 7782-50-5 90,031 g/year 0 90,031 10000
Chloroacetophenone ND g/year 0.000 0.000
Chlorobenzene 108-90-7 3,761 g/year 0 3,761 10000
Chloroform 67-66-3 4,331 g/year 0 4,331 10000
Chromium NA - 04 2,393 g/year 0.0 2,393.2 10,000.000
Cobalt NA - 05 740.8 g/year 0.000 740.762 ND 10,000
Cumene 98-82-8 ND g/year 0.000 0.000 10000

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Complete Leonine International
Industrial Bake Company World Wide Woods

Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Dibenzofuran 0.203 g/year 0.000 0.203
1,4-Dichlorobenzene ND g/year 0.000 0.000
2,4-Dinitrophenol 20.5 g/year 0.000 20.513
2,4-Dinitrotoluene 121-14-2 ND g/year 0.000 0.000 10000
Ethyl benzene 100-41-4 3,533 g/year 0 3,533 10000
Ethyl chloride ND g/year 0.000 0.000
Ethylene dibromide ND g/year 0.000 0.000
Ethylene dichloride ND g/year 0.000 0.000
Ethylidene dichloride ND g/year 0.000 0.000
Formaldehyde 50-00-0 501,439 g/year 0 501,439 10000
Hexane 100-54-3 ND g/year 0.000 0.000 10000
Hydrochloric acid 7647-01-0 2,165,305 g/year 0 2,165,305 ND 10,000.000
Hydrogen fluoride 7664-39-3 ND g/year 0.000 0.000 ND 10,000
Isophorone ND g/year 0.000 0.000
Lead NA - 08 5,470 g/year 0.0 5,470.2 3,149 10,000.000
Manganese NA - 09 182,341 g/year 0 182,341 ND 10,000
Mercury NA - 10 398.9 g/year 0 399 36.4 5.000 ###
Methyl bromide ND g/year 0.000 0.000
Methyl chloride ND g/year 0.000 0.000
Methyl ethyl ketone 78-93-3 ND g/year 0.000 0.000 10000
Methyl hydrazine ND g/year 0.000 0.000
Methyl methacrylate 80-62-6 ND g/year 0.000 0.000 10000
Methyl tert butyl ether 1634-04-4 ND g/year 0.000 0.000 10000
Methylene chloride ND g/year 0.000 0.000
Naphthalene 91-20-3 11,054 g/year 0 11,054 10000
Nickel NA - 11 3,761 g/year 0 3,761 487.2 10,000.000
4-Nitrophenol 12.5 g/year 0.000 12.536
Pentachlorophenol (PCP) 87-86-5 5.812 g/year 0.000 5.812 500
Phenol 108-95-2 5,812 g/year 0 5,812 10000
Phosphorous 7723-14-0 3,077 g/year 0 3,077
Polycyclic Organic Matter (POM) ND g/year 0.0 0.0
Propionaldehyde 123-38-6 6,952 g/year 0 6,952 10000
Selenium NA - 12 319.1 g/year 0 319 ND 10,000.000
Styrene 100-42-5 216,530 g/year 0 216,530 10000
2,3,7,8-Tetrachlorodibenzo-p-dioxin 1746-01-6 0.001 g/year 0.000 0.001 0
Tetrachloroethylene 127-18-4 ND g/year 0.000 0.000 10000
Toluene 108-88-3 104,846 g/year 0 104,846 10000
1,1,2-Trichloroethane 79-00-5 3,533 g/year 0 3,533
2,4,6-Trichlorophenol 88-06-2 2.507 g/year 0.000 2.507
Vinyl chloride 75-01-4 2,051 g/year 0 2,051 10000
Xylenes 1330-20-7 ND g/year 0.0 0.0 10000
m-Xylene 108-38-3 ND g/year 0.000 0.000
o-Xylene 95-47-6 2,849 g/year 0 2,849
p-Xylene 106-42-3 ND g/year 0.000 0.000

Trace elements [g/year]

Antimony NA - 01 900.3 g/year 0 900 ND 10,000


Arsenic NA - 02 2,507 g/year 0 2,507 603.0 10,000.000
Barium - 19,374 g/year 0 19,374
Cadmium NA - 03 467.2 g/year 0.0 467.2 149.7 10,000.000
Chloride - ND g/year 0 0
Chromium total NA - 04 2,393 g/year 0 2,393 10,000.000
Chromium trivalent - ND g/year 0.000 0.000 1,101
Chromium hexavalent 18540-29-9 398.9 g/year 0.0 398.9 324.8 500.0
Cobalt NA - 05 740.8 g/year 0.000 740.762 ND 10,000
Copper NA - 06 5,584 g/year 0 5,584 2,641 10,000.000
Iron 7439-89-6 112,824 g/year 0.000 112,823.808 3000
Lead NA - 08 5,470 g/year 0 5,470 3,149 10,000.000

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Complete Leonine International
Industrial Bake Company World Wide Woods

Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Manganese NA - 09 182,341 g/year 0 182,341 10,000
Mercury NA - 10 398.9 g/year 0.000 398.872 36.4 5.0
Molybdenum 239.3 g/year 0.000 239.323 5.000
Nickel NA - 11 3,761 g/year 0.0 3,760.8 10000
Phosphorous 7723-14-0 3,077 g/year 0.000 3,077.012
Potassium - 4,444,574 g/year 0.000 4,444,573.623
Selenium NA - 12 319.1 g/year 0 319 ND 10,000.000
Silver NA - 13 193,738 g/year 0.000 193,737.821 10000
Sodium - 41,027 g/year 0.000 41,026.828
Strontium - 1,140 g/year 0.000 1,139.634
Tin 7440-31-5 2,621 g/year 0.000 2,621.158 3000
Vanadium 7440-62-2 111.7 g/year 0.000 111.684 10000
Yttrium 34.2 g/year 0.000 34.189
Zinc NA - 14 47,865 g/year 0.0 47,864.6 0.000 10,000.000

Various organic compounds [g/year]

Acetaldehyde 75-07-0 94,590 g/year 0 94,590 10000


Acetone 67-64-1 21,653 g/year 0 21,653 3000
Acetophenone 98-86-2 0.365 g/year 0.000 0.365 10000
Acrolein 107-02-8 455,854 g/year 0 455,854 10000
Benzaldehyde 96.9 g/year 0.0 96.9
Benzene 71-43-2 478,646 g/year 0 478,646 10000
Benzoic acid 5.356 g/year 0.0 5.4 10000
Benzyl chloride 100-44-7 ND g/year 0.000 0.000
Bis(2-ethylexyl)phthalate (DEHP) 117-81-7 5.356 g/year 0.0 5.4
Bromoform ND g/year 0.000 0.000
Bromomethane 74-83-9 1,709 g/year 0 1,709 10000
Butane ND g/year 0.000 0.000
2-Butanone (MEK) 615.4 g/year 0 615
Carbazole 205.1 g/year 0 205
Carbon disulfide 75-15-0 ND g/year 0.000 0.000 10000
Carbon tetrachloride 56-23-5 5,128 g/year 0 5,128 10000
Chlorine 7782-50-5 90,031 g/year 0 90,031 10000
2-Chloroacetophenone ND g/year 0.000 0.000
Chlorobenzene 108-90-7 3,761 g/year 0 3,761 10000
Chloroform 67-66-3 4,331 g/year 0 4,331 10000
Chloromethane 74-87-3 2,621 g/year 0 2,621 10000
2-Chloronaphthalene 0.274 g/year 0.000 0.274
2-Chlorophenol 2.735 g/year 0.0 2.7
Crotonaldehyde 4170-30-3 1,128 g/year 0 1,128 10000
Cumene 98-82-8 ND g/year 0.000 0.000 10000
Cyanide NA - 07 ND g/year 0.000 0.000
Decachlorobiphenyl 0.031 g/year 0.000 0.031
Dibenzo(a,h)anthracene 53-70-3 1.037 g/year 0.000 1.037
1,2-Dibromoethene 106-93-4 ND g/year 0.000 0.000
Dichlorobenzene ND g/year 0.000 0.000
Dichlorobiphenyl ND g/year 0.000 0.000
1,2-Dichloroethane 107-06-2 ND g/year 0.000 0.000
Dichloromethane 75-09-2 ND g/year 0.000 0.000 10000
1,2-Dichloropropane 78-87-5 ND g/year 0.000 0.000
7,12-Dimethylbenz(a)anthracene ND g/year 0.000 0.000
Dimethyl sulfate 77-78-1 ND g/year 0.000 0.000
2,4-Dinitrophenol 20.5 g/year 0.0 20.5
2,4-Dinitrotoluene 121-14-2 ND g/year 0.000 0.000 10000
Ethane ND g/year 0.000 0.000
Ethyl benzene 100-41-4 3,533 g/year 0 3,533 10000
Ethyl chloride ND g/year 0.000 0.000
Ethylene dichloride ND g/year 0.000 0.000

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Complete Leonine International
Industrial Bake Company World Wide Woods

Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Ethylene dibromide ND g/year 0.000 0.000
Formaldehyde 50-00-0 501,439 g/year 0 501,439 10000
Heptchlorobiphenyl 0.008 g/year 0.000 0.008
Hexachlorobiphenyl 0.063 g/year 0.000 0.063
Hexanal 797.7 g/year 0 798
Hexane 110-54-3 ND g/year 0.000 0.000 10000
Isobutyraldehyde 78-84-2 1,368 g/year 0 1,368 10000
Isophorone ND g/year 0.000 0.000
Methyl bromide ND g/year 0.000 0.000
3-Methylchloranthrene ND g/year 0.000 0.000
Methyl chloride ND g/year 0.000 0.000
Methyl ethyl ketone 78-93-3 ND g/year 0.000 0.000 10000
Methyl hydrazine ND g/year 0.000 0.000
Methyl methacrylate 80-62-6 ND g/year 0.000 0.000 10000
2-Methylnaphthalene 18.2 g/year 0.0 18.2
Methyl tert butyl ether 1634-04-4 ND g/year 0.000 0.000 10000
Methylene chloride ND g/year 0.000 0.000
Monochlorobiphenyl 0.025 g/year 0.000 0.025
2-Nitrophenol 27.4 g/year 0.0 27.4
4-Nitrophenol 12.5 g/year 0.0 12.5
Pentachlorobiphenyl 0.137 g/year 0.000 0.137
Pentachlorophenol (PCP) 87-86-5 5.812 g/year 0.0 5.8 500
Pentane ND g/year 0.000 0.000
Perylene 0.059 g/year 0.000 0.059 50
Phenol 108-95-2 5,812 g/year 0 5,812 10000
POM ND g/year 0.000 0.000
Propanal 364.7 g/year 0 365
Propane ND g/year 0.000 0.000
Propionaldehyde 123-83-6 6,952 g/year 0 6,952 10000
RSH, RSR and RSSR ND g/year 0.000 0.000
Styrene 100-42-5 216,530 g/year 0 216,530 10000
Tetrachlorbiphenyl 0.285 g/year 0.000 0.285
Tetrachloroethene 4,331 g/year 0 4,331
Tetrachloroethylene 127-18-4 ND g/year 0.000 0.000 10000
o-Tolualdehyde 820.5 g/year 0 821
p-Tolualdehyde 1,254 g/year 0 1,254
Toluene 108-88-3 104,846 g/year 0 104,846 10000
Trichlorobiphenyl 0.296 g/year 0.000 0.296
1,1,1-Trichloroethane 71-55-6 3,533 g/year 0 3,533
Trichloroethene 3,419 g/year 0 3,419
Trichlorofluoromethane 4,672 g/year 0 4,672
2,4,6-Trichlorophenol 88-06-2 2.507 g/year 0.0 2.5
Xylenes 1330-20-7 ND g/year 0.000 0.000 10000
m-Xylene 108-38-3 ND g/year 0.000 0.000
o-Xylene 95-47-6 2,849 g/year 0 2,849
p-Xylene 106-42-3 ND g/year 0.000 0.000
Vinyl acetate 108-05-4 ND g/year 0.000 0.000 10000
Vinyl chloride 75-01-4 2,051 g/year 0 2,051 10000

Polynuclear aromatic hydrocarbon [g/year]

Biphenyl 95-52-4 ND g/year 0.000 0.000 10000


Acenaphthene 83-32-9 103.7 g/year 0.0 103.7 5
Acenaphthylene 208-96-8 569.8 g/year 0 570 5
Anthracene 120-12-7 341.9 g/year 0 342 10000
Benzo(a)anthracene 7.408 g/year 0.0 7.4 50
Benzo(a)pyrene 50-32-8 0.296 g/year 0.000 0.296 50
Benzo(b)fluoranthene 205-99-2 11.4 g/year 0.0 11.4 50
Benzo(b,j,k)fluoranthene ND g/year 0.000 0.000

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Complete Leonine International
Industrial Bake Company World Wide Woods

Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Benzo(b,k)fluoranthene ND g/year 0.000 0.000
Benzo(j,k)fluoranthene 11.4 g/year 0.0 11.4
Benzo(k)fluoranthene 207-08-9 4.103 g/year 0.0 4.1 50
Benzo(g,h,i)perylene 10.6 g/year 0.0 10.6 50
Chrysene 218-01-9 4.331 g/year 0.0 4.3 50
Fluorathene 206-44-0 182.3 g/year 0 182 50
Fluorene 86-73-7 387.5 g/year 0 387 5
Indeno(1,2,3-cd)pyrene 193-39-5 9.915 g/year 0.0 9.9
Naphthalene 91-20-3 11,054 g/year 0 11,054 10000
Phenanthrene 85-01-8 797.7 g/year 0 798 50
Pyrene 129-00-0 421.7 g/year 0 422 50
5-Methyl chrysene ND g/year 0.000 0.000
Total 13,919 g/year 0 13,919 25,137

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

701631373.xlsx Prepared By
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Complete Leonine International
Canadian
National Pollution Inventory - Table 34 Threshold
kg/year

Oxides of Nitrogen

NOx Uncontrolled 21,041 kg/year 21,467


SCR 2,104 kg/year 6,312 21,467
SNCR 10,521 kg/year 14,729 21,467
SNCR with LNB 5,260 kg/year 7,364 21,467
LEA 11,783 kg/year 18,937 21,467
LNB - Air Staged 13,677 kg/year 15,781 21,467
LNB - Flue Gas Recirculation 16,833 kg/year 21,041 21,467
LNB - Fuel Staged 8,417 kg/year 10,521 21,467

Sulphur Dioxide

SO2 Uncontrolled 2,401 kg/year 20,000


Wet Scrubber 48.0 kg/year 240.1 20,000
Semi-Dry Scrubber 240.1 kg/year 480.1 20,000
Dry Scrubber 480.1 kg/year 1,200 20,000

PM (particulate less than 10µm)

PM10 Uncontrolled 45,754 kg/year 500


ESP 45.8 kg/year 4,575 500 new ESP ≥ 99% efficient
Bag Filter 45.8 kg/year 2,288 500
Single high throughput Cyclone 27,453 kg/year 41,179 500
Single Conventional Cyclone 4,575 kg/year 32,028 500
Single High Efficiency Cyclone 2,288 kg/year 18,302 500
Multicyclone 3,432 kg/year 9,151 500
Venturi Scrubber 457.5 kg/year 13,726 500
Condensation Scrubber 45.8 kg/year 457.5 500
Impingement Scrubber 457.5 kg/year 22,877 500
Orifice Scrubber 457.5 kg/year 9,151 500

PM (particulate less than 2.5µm)

PM2.5 Uncontrolled 38,694 kg/year 300


ESP 38.7 kg/year 3,869 300 new ESP ≥ 99% efficient
Bag Filter 38.7 kg/year 1,935 300
Single high throughput Cyclone 34,824 kg/year 38,694 300
Single Conventional Cyclone 23,216 kg/year 38,694 300
Single High Efficiency Cyclone 1,935 kg/year 15,477 300
Multicyclone 25,151 kg/year 25,151 300 refer EMEP Table 8.2
Venturi Scrubber 11,608 kg/year 30,955 300
Condensation Scrubber 386.9 kg/year 11,608 300
Impingement Scrubber 386.9 kg/year 19,347 300
Orifice Scrubber 386.9 kg/year 7,739 300

Mercury (Hg)

Mercury Uncontrolled 0.036 kg/year 5


Wet Scrubber 0.013 kg/year 0.016 5
Wet Scrubber with conditioning agent 0.007 kg/year 0.009 5
Spray Absorber & Fabric Filter (limestone) 0.017 kg/year 0.020 5
Spray Absorber & Fabric Filter (absorbent) 0.002 kg/year 0.005 5

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Abatement Leonine International Inc
ESP with Carbon Injection 0.004 kg/year 0.018 5
ESP with polishing Wet Scrubber 0.005 kg/year 0.005 5
Fabric Filter with Carbon Injection 0.004 kg/year 0.018 5
Fabric Filter with polishing Wet Scrubber 0.005 kg/year 0.005 5

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Abatement Leonine International Inc
A - Tests are performed by using an EPA reference test method, or when not applicable, a sound
methodology. Tests are reported in enough detail for adequate validation, and, raw data are
provided that can be used to duplicate the emission results presented in the report.

B - Tests are performed by a generally sound methodology, but lacking enough detail for
adequate validation. Data are insufficient to completely duplicate the emission result
presented in the report.

C - Tests are based on an unproven or new methodology, or are lacking a significant amount of
background information.

D - Tests are based on a generally unacceptable method, but the method may provide an order-of
magnitude value for the source.

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
A = Excellent. Emission factor is developed primarily from A- and B-rated source test data taken
from many randomly chosen facilities in the industry population. The source category
population is sufficiently specific to minimize variability.

B = Above average. Emission factor is developed primarily from A- or B-rated test data from a
moderate number of facilities. Although no specific bias is evident, is not clear if the
facilities tested represent a random sample of the industry. As with the A rating, the source
category population is sufficiently specific to minimize variability.

C = Average. Emission factor is developed primarily from A-, B-, and C-rated test data from a
reasonable number of facilities. Although no specific bias is evident, it is not clear if the
facilities tested represent a random sample of the industry. As with the A rating, the source
category population is sufficiently specific to minimize variability.

D = Below average. Emission factor is developed primarily from A-, B- and C-rated test data
from a small number of facilities, and there may be reason to suspect that these facilities do
not represent a random sample of the industry. There also may be evidence of variability
within the source population.

E = Poor. Factor is developed from C- and D-rated test data from a very few number of facilities,
and there may be reason to suspect that the facilities tested do not represent a random sample
of the industry. There also may be evidence of variability within the source category
population.

U = Unrated (Only used in the L&E documents). Emission factor is developed from source tests
which have not been thoroughly evaluated, research papers, modeling data, or other sources
that may lack supporting documentation. The data are not necessarily "poor," but there is not
enough information to rate the factors according to the rating protocol. "U" ratings are
commonly found in L&E documents and FIRE rather than in AP-42.

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
Glossary
7-PAH 7-polynuclear aromatic hydrocarbons
AMS Automatic Measuring Systems
BACT Best Available Control Technology
CAA Clean Air Act
CEM Continuous Emissions Monitoring
CFB Circulating Fluidized Bed
CISWI Commercial & Industrial Solid Waste Incinerators
ESP Electrostatic Precipitator
GACT Generally Available Control Technologies
HAP Hazardous Air Pollutant
LAER Lowest Achievable Emission Rate Standards
LCPD Large Combustion Plant Directive
MACT Maximum Achievable Control Technology
Major Source refer CAA Section 112
NAAQS National Ambient Air Quality Standards
NEMA:AQA (South Africa) National Environmental Management Act: Air Quality Act 8 MWth net based on Lower CV
NHSM Non Hazardous Secondary Materials
NSPS New Source Performance Standard
PEMS Predictive Emissions Monitoring
PM Particulate Matter
POM Polycyclic Organic Matter
PSD Prevention of Significant Deterioration
SRCR Selective Regenerative Catalytic Reduction
tpy ton/year (2,000 lb/year)
WID Waste Incinerator Directive

Legislation
CAA
40 CFR Part 63

Codes
Stationary source emissions. Quality asssurance of
EN 14181 automated measuring system.
GB 13223 Emission standard of air pollutants for thermal power plants
GB 13271 Emission standard of air pollutants for boiler

My Notes - LCPD plant greater than 50 MWth

Prepared by
Leonine International Inc.
Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.
CEMS are not required

Prepared by
Leonine International Inc.
Steam Generation 0 MW

Carbon Dioxide 0.0 µg/year


PM Total 0.0 µg/year
PM Refuse 0.0 µg/year
NOx 0.0 µg/year
Sulphur dioxide SO2 0.0 µg/year
Methane CH₄ 0.0 µg/year
Nitrogen Oxide N₂O 0.0 µg/year
Mercury Hg 0.0 µg/year
Carbon Footprint 0.0 µg/year

Ancilliary Power 45.2 kW

Carbon Dioxide 322.7 ton/year


PM Total 59.4 kg/year
PM Refuse 53.0 ton/year
NOx 465.4 kg/year
Sulphur dioxide SO2 1.3 ton/year
Methane CH₄ 6.7 kg/year
Nitrogen Oxide N₂O 5.0 kg/year
Mercury Hg 6.4 g/year
Carbon Footprint 88.1 ton/year

US figures from eGRID 2005


South Africa figures from Eskom 2009 Year End Report

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Power Plant Leonine International
CO₂ Emission Intensity
Coal Technology kg/MWh gross power
produced lb/MWh
Advanced Ultrasupercritical (USC) Steam Plant 750 1,654
Integrated Gasification Combined Cycle (IGCC) Plant 700 1,544
Advanced USC Plant + 12.5 % Steam Utilization 636 1,402
EPA Standard (Aug 3, 2015) 636 1,402
Advanced USC Plant + 14 % Steam Utilization 636 1,402
IGCC Plant + High Quality Coal 627 1,383
Integrated Gasification Supercritical CO₂ Brayton Cycle Plant 603 1,330
Integrated Gasification Fuel Cell (IGFC) Plant 603 1,330
Advanced USC Plant + 25% Steam Utilization 568 1,252
IGCC Plant + 1,700 °C Combustion Turbine 567 1,250
Integrated Gasification Triple-Cylce Plant 527 1,162
IGFC Plant + Catalytic Gasifier 501 1,105
IGFC Plant + Pressurized Solid Oxide Fuel Cell (SOFC) 498 1,098
Advanced USC Plant + 50 % Steam Utilization 465 1,025
IGFC Plant + Catalytic Gasifier + Pressurized SOFC 430 948

EPRI report 3002006770

Form Revision 60
22 Jan 2019

EPA version 1595.03.05.13


BPVM version 1599.07.71.05

Prepared by
Leonine International Inc.

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