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60 22 Jan 2019
Job Number
Date
Acronym Definition
Definitions Prepared By
Page 2 of 36
701631373.xlsx Leonine International Inc
Job Number
Date
Form Revision 60
22 Jan 2019
Definitions Prepared By
Page 3 of 36
701631373.xlsx Leonine International Inc
Wood - ECBiomass Pellet
Gross calorific value 18.77 MJ/kg
Constituent % mass
Carbon 47.08
Chlorine 0.02
Hydrogen 5.36
Sulphur 0.04
Oxygen 39.12
Nitrogen 0.09
Moisture 7.46
Ash 0.83
Prepared by
Leonine International Inc
Industrial Bake Company Emissions Inventory Job number 0432_x000D_18 Mar 2019
EPA AP-42 - Section 1.6, Sept 2003; IPCC Table 2.2 (2006); NPI Table 33Ver. 3.6, Dec 2011
Fuel details Boiler heating classification Heat In Furnace Configuration 40 CFR Part 63
MMBtu
Wood Industrial 29.0 gross Duth-oven Normal Area Source
Wood - ECBiomass Pellet 8.5 MWth
Operation
Fuel 1,612.1 kg/hour 130.78 USD/hour 1,145,622 USD/year
Steam 8,902 kg/hour 5.52 ton steam/ton fuel 77,982 ton/year
Air 18,185 kg/hour 100.00 % excess air
Feed 12,273 kg/hour 100.00 °C Makeup 7,599 kg/hour 30 °C 7.60 USD/hour 66,569 USD/year
Chemicals 2.28 USD/hour 19,971 USD/year
Operating 8,760 Hours/year 0 hours/day
Emissions for World Wide Woods
Products of
Fuel Air Steam Ash Fly ash Argon Oxygen Nitrogen Water
Boiler Abatement combustion [229°C]
ton/year ton/year ton/year ton/year ton/year ton/year ton/year ton/year ton/year ton/year
SHOD 10000/2400 Multicyclone 14122 159,304 77,981 105.5 13.3 2017.427 18203.2 118,802.9 9,839.1 173,309
Particulate Matter (Multicyclone) VOC
CO2 CO NOx N2O SO2 SO3 TOC Non CH4 Total Carbon
Cond' Filterable Stack SO4
Methane
ton/year ton/year ton/year ton/year ton/year NA ton/year ton/year ton/year NA ton/year ton/year ton/year µg/year ton/year
22,223 8751.2 1.9 45.6 34.2 ND 8,751.2 1.5 2.8 ND 4.4 1.5 2.4 0.0 6,069
24,429
IPCC Fuel Category - Wood: Range - Default followed by Min/Max
CO₂ Global Warming Potential (100 year) N₂O CH₄
ton/year ton CO2e/year kg/year ton/year
27,554 52,147 984.1 7.4
23372 / 32474 50/500 369 / 3690 2.5 / 24.6
Emissions at power plant
Emissions
701631373.xlsx
Prepared by_x000D_Leonine International Inc Page 5 of 36
Acid rain
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc
Averaging period
Criteria Pollutants - Duth-oven furnace configuration - at 7.80
Year 24-hour 8-hour 1-hour 10-min 1-hour Control Method 4.24 Nm³/s
am³/s
Carbon monoxide CO 8751.2 ton/year 50495.1 ppm 277,500,000.0 0.0 ### ### µg/s 65,448.1 mg/Nm³
Lead Pb 5.5 kg/year 0.0 ppm 173.5 0.0 173.5 173.5 µg/s 0.0 mg/Nm³
Nitrogen dioxide NO2 8749.8 ton/year 50486.6 ppm 277,453,024.0 0.0 ### ### µg/s 65,437.0 mg/Nm³
Nitrogen oxide NO ND NA ND NA -277,777.8 0.0 -277,777.8 -277,777.8 µg/s -65.5 mg/Nm³
Nitrous oxide N2O 1.5 ton/year 8.5 ppm 46,978.8 0.0 46,978.8 46,978.8 µg/s 11.1 mg/Nm³
NOx based on NO2 8751.2 ton/year 50495.1 ppm 277,500,000.0 0.0 ### ### µg/s 65,448.1 mg/Nm³
Ozone 0.0 µg/year 0.0 ppm 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
PM2.5 34.6 ton/year 199.9 ppm 1,098,582.0 0.0 1,098,582.0 1,098,582.0 µg/s 578,201.0 Multicyclone 259.1 136.4 mg/Nm³
PM5 39.2 ton/year 226.2 ppm 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
PM10 41.0 ton/year 236.7 ppm 1,300,952.4 0.0 1,300,952.4 1,300,952.4 µg/s 975,714.3 Multicyclone 306.8 230.1 mg/Nm³
PM condensable 1.9 ton/year 11.2 ppm 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
PM filterable 45.6 ton/year 263.0 ppm 1,445,502.6 0.0 1,445,502.6 1,445,502.6 µg/s 1,084,126.9 Multicyclone 340.9 255.7 mg/Nm³
PM total 47.5 ton/year 274.2 ppm 1,506,936.5 0.0 1,506,936.5 1,506,936.5 µg/s 355.4 0.0 mg/Nm³
Sulphur dioxide SO2 2.8 ton/year 16.4 ppm 90,343.9 0.0 90,343.9 90,343.9 µg/s 21.3 mg/Nm³
Sulphur trioxide SO3 ND NA ND NA 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
Sulphate particulate ND NA ND NA 1.0 0.0 1.0 1.0 µg/s 0.0 mg/Nm³
SOX as SO2 2.8 ton/year 16.4 ppm 90,343.9 0.0 90,343.9 90,343.9 µg/s 21.3 mg/Nm³
Uncontrolled values Bold results are the values required for reporting in the South African regulations Uncontrolled Controlled
Results Results
Rolling
EPA Limits Valid Year
3-month
24-hour 8-hour 3 hourly 1-hour 10-min Notes
Carbon monoxide CO 76 FR 54294 - 31 Aug 2011 9 35 ppm Not to be exceeded more than once per year
Lead Pb 73 FR 66964 - 12 Nov 2008 0.15 µg/m³ 0.15 µg/m³, averaging period= rolling 3-month, not to be exceeded.
Nitrogen dioxide NO2 77 FR 20218 - 3 Apr 2012 100 ppb 98th percentile of 1-hour daily maximum concentrations, averaged over 3 years
Ozone 80 FR 65292 - 26 Oct 2015 0.070 ppm Annual fourth-highest daily maximum 8-hour concentration, averaged over 3 years
PM2.5 78 FR 3086 - 15 Jan 2013 35 µg/m³ 98th percentile, averaged over 3 years
PM2.5 78 FR 3086 - 15 Jan 2013 12 µg/m³ Annual mean, averaged over 3 years
PM10 78 FR 3086 - 15 Jan 2013 150 µg/m³ Not to be exceeded more than once per year on average over 3 years
Sulphur dioxide SO₂ 75 FR 35520 - 22 Jun 2010 75 ppb 99th percentile of 1-hour daily maximum concentrations, averaged over 3 years
Primary - provide public health protection, including protecting the health of "sensitive" populations such as asthmatics, children, and the elderly.
Lead Pb 73 FR 66964 - 12 Nov 2008 0.15 µg/m³ 0.15 µg/m³, averaging period= rolling 3-month, not to be exceeded.
Nitrogen dioxide NO2 53 ppb Annual Mean
Ozone 0.070 ppm Annual fourth-highest daily maximum 8-hour concentration, averaged over 3 years
80 FR 65292 - 26 Oct 2015
PM2.5 78 FR 3086 - 15 Jan 2013 35 µg/m³ 98th percentile, averaged over 3 years
PM2.5 78 FR 3086 - 15 Jan 2013 15 µg/m³ Annual mean, averaged over 3 years
PM10 78 FR 3086 - 15 Jan 2013 150 µg/m³ Not to be exceeded more than once per year on average over 3 years
Sulphur dioxide SO₂
77 FR 20218 - 3 Apr 2012 0.5 ppm Not to be exceeded more than once per year
(Secondary)
Secondary - provide public welfare protection, including protection against decreased visibility and damage to animals, crops, vegetation, and buildings.
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc.
EPA version 1595.03.05.13
BPVM version 1599.07.71.05
Prepared by
Leonine International Inc.
to be exceeded.
to be exceeded.
Prepared by
Leonine International Inc.
Polychlorinated dibenzo-p-dioxins
Polychlorinated dibenzo-p-furans
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc
Greenhouse EPA Limit
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc.
Actual
Prepared by
Leonine International Inc.
Hazardous air pollutants
Prepared by
Leonine International Inc.
Phenol 5.8 kg/year 0.0 ppm
Phosphorous 3.1 kg/year 0.0 ppm
POM ND NA ND NA
Propionaldehyde 7.0 kg/year 0.0 ppm
Selenium 319.1 g/year 0.0 ppm
Styrene 216.5 kg/year 1.2 ppm
2,3,7,8-Tetrachlorodibenzo-p-
980.1 µg/year 0.0 ppm
dioxin
Tetrachloroethylene ND NA ND NA also known as Perchloroethylene
Toluene 104.8 kg/year 0.6 ppm
1,1,2-Trichloroethane 3.5 kg/year 0.0 ppm
2,4,6-Trichlorophenol 2.5 g/year 0.0 ppm
Vinyl chloride 2.1 kg/year 0.0 ppm
Xylenes ND NA ND NA
m-Xylene ND NA ND NA
o-Xylene 2.8 kg/year 0.0 ppm
p-Xylene ND NA ND NA
TOTAL
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc.
40 CFR Part 63
[ton/year]
0.1042855
0.0004021
0.5025790
0.0009926
0.0027640
0.5277072
0.0000000
0.0001382
0.0000000
0.0005151
0.0000000
0.0056536
0.0992592
0.0000000
0.0041465
0.0047749
0.0026383
0.0008167
0.0000000
0.0002234
0.0000000
0.0000226
0.0000000
0.0038951
0.0000000
0.0000000
0.0000000
0.0000000
0.5528365
0.0000000
0.0000024
0.0000000
0.0000000
0.0060307
0.2010310
0.0004398
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0121870
0.0041465
0.0000138
0.0000064
Prepared by
Leonine International Inc.
0.0064077
0.0033924
0.0000000
0.0076646
0.0003518
0.2387254
0.0010805
0.0000000
0.1155927
0.0038951
0.0000028
0.0022612
0.0000000
0.0000000
0.0031410
0.0000000
2.4200234 Area Source
Prepared by
Leonine International Inc.
Trace elements
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc.
Various organic compounds
Prepared by
Leonine International Inc.
Hexane ND NA ND NA
Isobutyraldehyde 1.4 kg/year 0.0 ppm
Isophorone ND NA ND NA
Methyl bromide ND NA ND NA
3-Methylchloranthrene ND NA ND NA
Methyl chloride ND NA ND NA
Methyl ethyl ketone ND NA ND NA
Methyl hydrazine ND NA ND NA
Methyl methacrylate ND NA ND NA
2-Methylnaphthalene 18.2 g/year 0.0 ppm
Methyl tert butyl ether ND NA ND NA
Methylene chloride ND NA ND NA
Monochlorobiphenyl 25.1 mg/year 0.0 ppm
2-Nitrophenol 27.4 g/year 0.0 ppm
4-Nitrophenol 12.5 g/year 0.0 ppm
Pentachlorobiphenyl 136.8 mg/year 0.0 ppm
Pentachlorophenol 5.8 g/year 0.0 ppm
Pentane ND NA ND NA
Perylene 59.3 mg/year 0.0 ppm
Phenol 5.8 kg/year 0.0 ppm
Polycyclic Organic Matter (POM) ND NA ND NA
Propanal 364.7 g/year 0.0 ppm
Propane ND NA ND NA
Propionaldehyde 7.0 kg/year 0.0 ppm
RSH, RSR and RSSR ND NA ND NA
Styrene 216.5 kg/year 1.2 ppm
Tetrachlorbiphenyl 284.9 mg/year 0.0 ppm
Tetrachloroethene 4.3 kg/year 0.0 ppm
Tetrachloroethylene ND NA ND NA
o-Tolualdehyde 820.5 g/year 0.0 ppm
p-Tolualdehyde 1.3 kg/year 0.0 ppm
Toluene 104.8 kg/year 0.6 ppm
Trichlorobiphenyl 296.3 mg/year 0.0 ppm
1,1,1-Trichloroethane 3.5 kg/year 0.0 ppm
Trichloroethene 3.4 kg/year 0.0 ppm
Trichlorofluoromethane 4.7 kg/year 0.0 ppm
2,4,6-Trichlorophenol 2.5 g/year 0.0 ppm
Xylenes ND NA ND NA
m-Xylene ND NA ND NA
o-Xylene 2.8 kg/year 0.0 ppm
p-Xylene ND NA ND NA
Vinyl acetate ND NA ND NA
Vinyl chloride 2.1 kg/year 0.0 ppm
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc.
EPA version 1595.03.05.13
BPVM version 1599.07.71.05
Prepared by
Leonine International Inc.
Polynuclear aromatic hydrocarbons
Biphenyl ND NA ND NA
Acenaphthene 103.7 g/year 0.0 ppm
Acenaphthylene 569.8 g/year 0.0 ppm
Anthracene 341.9 g/year 0.0 ppm
Benzo(a)anthracene 7.4 g/year 0.0 ppm
Benzo(a)pyrene 296.3 mg/year 0.0 ppm
Benzo(b)fluoranthene 11.4 g/year 0.0 ppm
Benzo(b,j,k)fluoranthene ND NA ND NA
Benzo(b,k)fluoranthene ND NA ND NA
Benzo(j,k)fluoranthene 11.4 g/year 0.0 ppm
Benzo(k)fluoranthene 4.1 g/year 0.0 ppm
Benzo(g,h,i)perylene 10.6 g/year 0.0 ppm
Chrysene 4.3 g/year 0.0 ppm
Fluorathene 182.3 g/year 0.0 ppm
Fluorene 387.5 g/year 0.0 ppm
Indeno(1,2,3-cd)pyrene 9.9 g/year 0.0 ppm
Naphthalene 11.1 kg/year 0.1 ppm
Phenanthrene 797.7 g/year 0.0 ppm
Pyrene 421.7 g/year 0.0 ppm
5-Methyl chrysene ND NA ND NA
Total PAH 13.9 kg/year 0.0 kg/year
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc.
Industrial Bake Company World Wide Woods
Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Flue gas temperature NA 229.3 °C NA NA
Hot gas stack flow NA 7.8 am³/s
Hydrochloric acid HCl 7647-01-0 2,165 kg/year 0.000 2,165.305 ND 10,000.000 87,591,240
Hydrogen fluoride HF 7664-39-3 ND kg/year 0.000 0.000 ND 10,000.0
Hydrogen sulfide H2S 7783-06-4 ND kg/year 0.000 0.000 10000
Nitrogen dioxide NO2 10102-44-0 8,749,759 kg/year 460.4 0.000 460.373 8,750,219.288
Nitrogen oxide NO 10102-43-9 ND kg/year 0.000 0.000
Nitrous oxide N2O 10024-97-2 1,482 kg/year 5.039 0.000 5.0 1,486.6 369.0 984.1 3,690 2,700.000
NOx based on NO2 10102-44-0 8,751,240 kg/year 465.4 0.000 465 8,751,706 21,041 21,467.000
Sulphur dioxide SO2 7446-09-5 2,849 kg/year 1,282 0.000 1,282 4,131 2,401 20,000.000
Sulphur trioxide SO3 - ND kg/year 32.1 0.000 32.052 32.052
SOx as SO2 7446-09-5 2,849 kg/year 1,314 0.000 1,314 4,163
PM2.5 - Uncontrolled N/A - M10 34,645 kg/year 0.0 29,258.8 38,694 300.000
PM5 - Uncontrolled - 39,203 kg/year 0.0 0.0
PM10 - Uncontrolled N/A - M09 41,027 kg/year 0.0 44,922.0 45,754 500.000
PM Condensable - Uncontrolled - 1,937 kg/year 0.0 2,680.5
PM Filterable - Uncontrolled - 45,585 kg/year 0.0 52,252.4 20,000 87,591,240
PM Total - Uncontrolled - 47,523 kg/year 59.4 0.000 204.4 55,137.3 20,000.000
Carbon monoxide CO 603-08-0 8,751,240 kg/year 0.0 8,935.1 57,617 20,000.000 1,732,913
Lead Pb NA - 08 5.470 kg/year 0.000 5.470 3.149 10,000.000
Nitrogen dioxide NO2 10102-44-0 8,749,759 kg/year 460.4 0.000 460 8,750,219
Nitrogen oxide NO 10102-43-9 ND kg/year 0 0
Nitrous oxide N2O 10024-97-2 1,482 kg/year 5.039 0.000 5.0 1,486.6 2700
NOx based on NO 10102-43-9 0.000 465.4 0.000 465.4 465.4 14000
NOx based on NO2 10102-44-0 8,751,240 kg/year 1,602 0.000 1,602 8,752,842 21,467.000
Ozone - 0.000 kg/year 0.000 0.000 21,041 21467
PM2.5 - Controlled Multicyclone N/A - M10 18,234 kg/year 0 18,234 300
PM10 - Controlled Multicyclone N/A - M09 30,770 kg/year 0 30,770 500
PM Total - Controlled Multicyclone - 34,189 kg/year 204.4 0.000 204 34,393
Sulphur dioxide SO2 7446-09-5 2,849 kg/year 1,282 0.000 1,282 4,131 2,401 20,000.000
Sulphur trioxide SO3 - ND kg/year 32.1 0.000 32.052 32.052
Sulphate particulate - ND kg/year 0.000 0.000
SOX as SO2 7446-09-5 2,849 kg/year 1,314 0.000 1,314 4,163
701631373.xlsx Prepared By
Page 22 of 36
Complete Leonine International
Industrial Bake Company World Wide Woods
Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Greenhouse [kg/year]
701631373.xlsx Prepared By
Page 23 of 36
Complete Leonine International
Industrial Bake Company World Wide Woods
Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Dibenzofuran 0.203 g/year 0.000 0.203
1,4-Dichlorobenzene ND g/year 0.000 0.000
2,4-Dinitrophenol 20.5 g/year 0.000 20.513
2,4-Dinitrotoluene 121-14-2 ND g/year 0.000 0.000 10000
Ethyl benzene 100-41-4 3,533 g/year 0 3,533 10000
Ethyl chloride ND g/year 0.000 0.000
Ethylene dibromide ND g/year 0.000 0.000
Ethylene dichloride ND g/year 0.000 0.000
Ethylidene dichloride ND g/year 0.000 0.000
Formaldehyde 50-00-0 501,439 g/year 0 501,439 10000
Hexane 100-54-3 ND g/year 0.000 0.000 10000
Hydrochloric acid 7647-01-0 2,165,305 g/year 0 2,165,305 ND 10,000.000
Hydrogen fluoride 7664-39-3 ND g/year 0.000 0.000 ND 10,000
Isophorone ND g/year 0.000 0.000
Lead NA - 08 5,470 g/year 0.0 5,470.2 3,149 10,000.000
Manganese NA - 09 182,341 g/year 0 182,341 ND 10,000
Mercury NA - 10 398.9 g/year 0 399 36.4 5.000 ###
Methyl bromide ND g/year 0.000 0.000
Methyl chloride ND g/year 0.000 0.000
Methyl ethyl ketone 78-93-3 ND g/year 0.000 0.000 10000
Methyl hydrazine ND g/year 0.000 0.000
Methyl methacrylate 80-62-6 ND g/year 0.000 0.000 10000
Methyl tert butyl ether 1634-04-4 ND g/year 0.000 0.000 10000
Methylene chloride ND g/year 0.000 0.000
Naphthalene 91-20-3 11,054 g/year 0 11,054 10000
Nickel NA - 11 3,761 g/year 0 3,761 487.2 10,000.000
4-Nitrophenol 12.5 g/year 0.000 12.536
Pentachlorophenol (PCP) 87-86-5 5.812 g/year 0.000 5.812 500
Phenol 108-95-2 5,812 g/year 0 5,812 10000
Phosphorous 7723-14-0 3,077 g/year 0 3,077
Polycyclic Organic Matter (POM) ND g/year 0.0 0.0
Propionaldehyde 123-38-6 6,952 g/year 0 6,952 10000
Selenium NA - 12 319.1 g/year 0 319 ND 10,000.000
Styrene 100-42-5 216,530 g/year 0 216,530 10000
2,3,7,8-Tetrachlorodibenzo-p-dioxin 1746-01-6 0.001 g/year 0.000 0.001 0
Tetrachloroethylene 127-18-4 ND g/year 0.000 0.000 10000
Toluene 108-88-3 104,846 g/year 0 104,846 10000
1,1,2-Trichloroethane 79-00-5 3,533 g/year 0 3,533
2,4,6-Trichlorophenol 88-06-2 2.507 g/year 0.000 2.507
Vinyl chloride 75-01-4 2,051 g/year 0 2,051 10000
Xylenes 1330-20-7 ND g/year 0.0 0.0 10000
m-Xylene 108-38-3 ND g/year 0.000 0.000
o-Xylene 95-47-6 2,849 g/year 0 2,849
p-Xylene 106-42-3 ND g/year 0.000 0.000
701631373.xlsx Prepared By
Page 24 of 36
Complete Leonine International
Industrial Bake Company World Wide Woods
Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Manganese NA - 09 182,341 g/year 0 182,341 10,000
Mercury NA - 10 398.9 g/year 0.000 398.872 36.4 5.0
Molybdenum 239.3 g/year 0.000 239.323 5.000
Nickel NA - 11 3,761 g/year 0.0 3,760.8 10000
Phosphorous 7723-14-0 3,077 g/year 0.000 3,077.012
Potassium - 4,444,574 g/year 0.000 4,444,573.623
Selenium NA - 12 319.1 g/year 0 319 ND 10,000.000
Silver NA - 13 193,738 g/year 0.000 193,737.821 10000
Sodium - 41,027 g/year 0.000 41,026.828
Strontium - 1,140 g/year 0.000 1,139.634
Tin 7440-31-5 2,621 g/year 0.000 2,621.158 3000
Vanadium 7440-62-2 111.7 g/year 0.000 111.684 10000
Yttrium 34.2 g/year 0.000 34.189
Zinc NA - 14 47,865 g/year 0.0 47,864.6 0.000 10,000.000
701631373.xlsx Prepared By
Page 25 of 36
Complete Leonine International
Industrial Bake Company World Wide Woods
Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Ethylene dibromide ND g/year 0.000 0.000
Formaldehyde 50-00-0 501,439 g/year 0 501,439 10000
Heptchlorobiphenyl 0.008 g/year 0.000 0.008
Hexachlorobiphenyl 0.063 g/year 0.000 0.063
Hexanal 797.7 g/year 0 798
Hexane 110-54-3 ND g/year 0.000 0.000 10000
Isobutyraldehyde 78-84-2 1,368 g/year 0 1,368 10000
Isophorone ND g/year 0.000 0.000
Methyl bromide ND g/year 0.000 0.000
3-Methylchloranthrene ND g/year 0.000 0.000
Methyl chloride ND g/year 0.000 0.000
Methyl ethyl ketone 78-93-3 ND g/year 0.000 0.000 10000
Methyl hydrazine ND g/year 0.000 0.000
Methyl methacrylate 80-62-6 ND g/year 0.000 0.000 10000
2-Methylnaphthalene 18.2 g/year 0.0 18.2
Methyl tert butyl ether 1634-04-4 ND g/year 0.000 0.000 10000
Methylene chloride ND g/year 0.000 0.000
Monochlorobiphenyl 0.025 g/year 0.000 0.025
2-Nitrophenol 27.4 g/year 0.0 27.4
4-Nitrophenol 12.5 g/year 0.0 12.5
Pentachlorobiphenyl 0.137 g/year 0.000 0.137
Pentachlorophenol (PCP) 87-86-5 5.812 g/year 0.0 5.8 500
Pentane ND g/year 0.000 0.000
Perylene 0.059 g/year 0.000 0.059 50
Phenol 108-95-2 5,812 g/year 0 5,812 10000
POM ND g/year 0.000 0.000
Propanal 364.7 g/year 0 365
Propane ND g/year 0.000 0.000
Propionaldehyde 123-83-6 6,952 g/year 0 6,952 10000
RSH, RSR and RSSR ND g/year 0.000 0.000
Styrene 100-42-5 216,530 g/year 0 216,530 10000
Tetrachlorbiphenyl 0.285 g/year 0.000 0.285
Tetrachloroethene 4,331 g/year 0 4,331
Tetrachloroethylene 127-18-4 ND g/year 0.000 0.000 10000
o-Tolualdehyde 820.5 g/year 0 821
p-Tolualdehyde 1,254 g/year 0 1,254
Toluene 108-88-3 104,846 g/year 0 104,846 10000
Trichlorobiphenyl 0.296 g/year 0.000 0.296
1,1,1-Trichloroethane 71-55-6 3,533 g/year 0 3,533
Trichloroethene 3,419 g/year 0 3,419
Trichlorofluoromethane 4,672 g/year 0 4,672
2,4,6-Trichlorophenol 88-06-2 2.507 g/year 0.0 2.5
Xylenes 1330-20-7 ND g/year 0.000 0.000 10000
m-Xylene 108-38-3 ND g/year 0.000 0.000
o-Xylene 95-47-6 2,849 g/year 0 2,849
p-Xylene 106-42-3 ND g/year 0.000 0.000
Vinyl acetate 108-05-4 ND g/year 0.000 0.000 10000
Vinyl chloride 75-01-4 2,051 g/year 0 2,051 10000
701631373.xlsx Prepared By
Page 26 of 36
Complete Leonine International
Industrial Bake Company World Wide Woods
Steam Canadian
CAS Total Emissions Ancilliary Total Emissions Total Global IPCC EMEP /
Emission ID Number at Boiler Power at Utility
Generation at
at Utility Emissions
Min
Default
Max NPI
CORONAIR
Threshold CFR
Utility kg/year
Benzo(b,k)fluoranthene ND g/year 0.000 0.000
Benzo(j,k)fluoranthene 11.4 g/year 0.0 11.4
Benzo(k)fluoranthene 207-08-9 4.103 g/year 0.0 4.1 50
Benzo(g,h,i)perylene 10.6 g/year 0.0 10.6 50
Chrysene 218-01-9 4.331 g/year 0.0 4.3 50
Fluorathene 206-44-0 182.3 g/year 0 182 50
Fluorene 86-73-7 387.5 g/year 0 387 5
Indeno(1,2,3-cd)pyrene 193-39-5 9.915 g/year 0.0 9.9
Naphthalene 91-20-3 11,054 g/year 0 11,054 10000
Phenanthrene 85-01-8 797.7 g/year 0 798 50
Pyrene 129-00-0 421.7 g/year 0 422 50
5-Methyl chrysene ND g/year 0.000 0.000
Total 13,919 g/year 0 13,919 25,137
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Complete Leonine International
Canadian
National Pollution Inventory - Table 34 Threshold
kg/year
Oxides of Nitrogen
Sulphur Dioxide
Mercury (Hg)
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Abatement Leonine International Inc
ESP with Carbon Injection 0.004 kg/year 0.018 5
ESP with polishing Wet Scrubber 0.005 kg/year 0.005 5
Fabric Filter with Carbon Injection 0.004 kg/year 0.018 5
Fabric Filter with polishing Wet Scrubber 0.005 kg/year 0.005 5
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Abatement Leonine International Inc
A - Tests are performed by using an EPA reference test method, or when not applicable, a sound
methodology. Tests are reported in enough detail for adequate validation, and, raw data are
provided that can be used to duplicate the emission results presented in the report.
B - Tests are performed by a generally sound methodology, but lacking enough detail for
adequate validation. Data are insufficient to completely duplicate the emission result
presented in the report.
C - Tests are based on an unproven or new methodology, or are lacking a significant amount of
background information.
D - Tests are based on a generally unacceptable method, but the method may provide an order-of
magnitude value for the source.
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A = Excellent. Emission factor is developed primarily from A- and B-rated source test data taken
from many randomly chosen facilities in the industry population. The source category
population is sufficiently specific to minimize variability.
B = Above average. Emission factor is developed primarily from A- or B-rated test data from a
moderate number of facilities. Although no specific bias is evident, is not clear if the
facilities tested represent a random sample of the industry. As with the A rating, the source
category population is sufficiently specific to minimize variability.
C = Average. Emission factor is developed primarily from A-, B-, and C-rated test data from a
reasonable number of facilities. Although no specific bias is evident, it is not clear if the
facilities tested represent a random sample of the industry. As with the A rating, the source
category population is sufficiently specific to minimize variability.
D = Below average. Emission factor is developed primarily from A-, B- and C-rated test data
from a small number of facilities, and there may be reason to suspect that these facilities do
not represent a random sample of the industry. There also may be evidence of variability
within the source population.
E = Poor. Factor is developed from C- and D-rated test data from a very few number of facilities,
and there may be reason to suspect that the facilities tested do not represent a random sample
of the industry. There also may be evidence of variability within the source category
population.
U = Unrated (Only used in the L&E documents). Emission factor is developed from source tests
which have not been thoroughly evaluated, research papers, modeling data, or other sources
that may lack supporting documentation. The data are not necessarily "poor," but there is not
enough information to rate the factors according to the rating protocol. "U" ratings are
commonly found in L&E documents and FIRE rather than in AP-42.
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Glossary
7-PAH 7-polynuclear aromatic hydrocarbons
AMS Automatic Measuring Systems
BACT Best Available Control Technology
CAA Clean Air Act
CEM Continuous Emissions Monitoring
CFB Circulating Fluidized Bed
CISWI Commercial & Industrial Solid Waste Incinerators
ESP Electrostatic Precipitator
GACT Generally Available Control Technologies
HAP Hazardous Air Pollutant
LAER Lowest Achievable Emission Rate Standards
LCPD Large Combustion Plant Directive
MACT Maximum Achievable Control Technology
Major Source refer CAA Section 112
NAAQS National Ambient Air Quality Standards
NEMA:AQA (South Africa) National Environmental Management Act: Air Quality Act 8 MWth net based on Lower CV
NHSM Non Hazardous Secondary Materials
NSPS New Source Performance Standard
PEMS Predictive Emissions Monitoring
PM Particulate Matter
POM Polycyclic Organic Matter
PSD Prevention of Significant Deterioration
SRCR Selective Regenerative Catalytic Reduction
tpy ton/year (2,000 lb/year)
WID Waste Incinerator Directive
Legislation
CAA
40 CFR Part 63
Codes
Stationary source emissions. Quality asssurance of
EN 14181 automated measuring system.
GB 13223 Emission standard of air pollutants for thermal power plants
GB 13271 Emission standard of air pollutants for boiler
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Form Revision 60
22 Jan 2019
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Leonine International Inc.
CEMS are not required
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Leonine International Inc.
Steam Generation 0 MW
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Power Plant Leonine International
CO₂ Emission Intensity
Coal Technology kg/MWh gross power
produced lb/MWh
Advanced Ultrasupercritical (USC) Steam Plant 750 1,654
Integrated Gasification Combined Cycle (IGCC) Plant 700 1,544
Advanced USC Plant + 12.5 % Steam Utilization 636 1,402
EPA Standard (Aug 3, 2015) 636 1,402
Advanced USC Plant + 14 % Steam Utilization 636 1,402
IGCC Plant + High Quality Coal 627 1,383
Integrated Gasification Supercritical CO₂ Brayton Cycle Plant 603 1,330
Integrated Gasification Fuel Cell (IGFC) Plant 603 1,330
Advanced USC Plant + 25% Steam Utilization 568 1,252
IGCC Plant + 1,700 °C Combustion Turbine 567 1,250
Integrated Gasification Triple-Cylce Plant 527 1,162
IGFC Plant + Catalytic Gasifier 501 1,105
IGFC Plant + Pressurized Solid Oxide Fuel Cell (SOFC) 498 1,098
Advanced USC Plant + 50 % Steam Utilization 465 1,025
IGFC Plant + Catalytic Gasifier + Pressurized SOFC 430 948
Form Revision 60
22 Jan 2019
Prepared by
Leonine International Inc.