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https://doi.org/10.1007/s10163-023-01809-2
ORIGINAL ARTICLE
Abstract
The main factors driving the reuse of construction waste in pavement are the rapid decline in the availability of conventional
aggregates, increasing haulage distances, and the scarcity of landfill sites. Municipal Solid Waste Incineration (MSWI) is
a popular solid waste treatment method that can reduce landfill clogging. In an attempt to reduce waste accumulation and
conserve natural resources, this study evaluated the effectiveness and feasibility of using MSWI-BA as a partial replacement
for fine aggregate in Bitumen Concrete Grade II (BC-II), a closely graded wearing course widely used in India. The optimal
asphalt content of asphalt mixes for different MSWI-BA percentages was determined using the Marshall mix design. Tests
to determine the resilient modulus, indirect tensile strength, resistance to moisture-induced damage, and rut resistance using
a dynamic creep test were conducted to study the performance of the asphalt mixes with various MSWI-BA contents. From
the research, it is advisable to replace the fine aggregates with MSWI-BA up to 20% to obtain a physically strong, higher
performing, and economically efficient bituminous concrete layer. The toxicity characteristic leaching procedure test results
indicated that the concentration of heavy metals and the levels of toxicity were significantly reduced after it was mixed with
asphalt mix.
Keywords Asphalt mixtures · Municipal solid waste incineration-bottom ash · Marshall mix design and leaching
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Journal of Material Cycles and Waste Management
dioxide (CO2), water vapor, and hazardous gases, which Table 1 Basic properties of VG 40 Binder
are cleaned by a sophisticated flue gas cleaning system. Test Name References Results
Bottom ash and fly ash are two general categories for the
inorganic ferrous and non-ferrous metal wastes generated Softening point, °C ASTM D 36–14 [17] 51
from waste incineration. Bottom ash is non-combustible Ductility, cm ASTM D 113–17 [18] > 100
and is removed from the incinerator as a slag-like solid Penetration, mm ASTM D5M-20 [19] 42
residue. Depending on the composition of the waste, Specific gravity ASTM D70-21 [20] 1.06
20–25 percent by weight of the incinerated waste is BA. Viscosity at 135 °C, cS ASTM D4402-15 [21] 450
Most of the slag is disposed of in landfills, only a tiny part
is recyclable. The disposal of MSWI-BA bottom ash is
expensive. The search for better, cheaper, and more envi- Table 2 Basic properties of Aggregates
ronmentally friendly ways to recycle garbage has become Test Name References Results
urgent due to concerns about landfills drying up and the
soaring cost of waste disposal. The limited availability Specific gravity ASTM C 127–15 [22] 2.7
and high cost of traditional paving materials have also Water absorption ASTM C 127–15 [22] 0.50%
prompted research into using waste products such as bot- Combined flakiness and IS 2386 (Part 1):1963 [23] 45.66%
elongation index
tom ash as a supplement or partial replacement for natural
Aggregate impact test IS: 2386 Part-4 (1963) [24] 17.71%
paving materials. Bottom ash consists mainly of oxides
Los Angeles abrasion test ASTM C 131 M-20 [25] 27.1%
of Si, Fe, Ca, Al, Na and K, making it compositionally
comparable to traditional road material, and its effect on
road surface properties can be demonstrated to be tech-
nically, economically, and ecologically justifiable [4]. A The aim of this research is therefore to see how well bot-
comprehensive investigation characterized the chemical tom ash can be used as a partial replacement for fine aggre-
waste from MSWIBA, revealing its potential to release gates in bituminous mixtures. Bituminous Concrete Grade
leachable components and influence groundwater, empha- II (BC-II), according to MoRT&H specifications, was used
sizing proper landfill disposal [5]. Incorporating MSWIBA in this study [16].
in bituminous mixes improved stability with increasing ash
concentration, conforming to leaching regulations. How-
ever, the Los Angeles abrasion value of the bottom ash was Materials used
found subpar [6]. Partial replacement of fine aggregates of
bituminous concrete mixes with coal ash and bottom ash The viscosity-graded binder VG-40 was used in this study.
reduced Indirect Tensile Strength (ITS) values impacting Table 1 summarises the basic properties of the binder used.
the Tensile Strength Ratio (TSR) values. The TSR values It was discovered that the Nominal Maximum Aggregates
increased substantially when hydrated lime was added Sizes (NMAS) of coarse aggregates (10 mm NMAS and
[7]. The use of MSWIBA as a partial aggregate substi- 20 mm NMAS), and fine aggregates (stone dust), acquired
tute showcased cost-saving benefits and waste diversion, from a local quarry, met the requirements of the MoRT&H
though with a lower dynamic modulus [8]. Coal slag as (Ministry of Road Transport and Highways) [16]. The basic
filler improved Hot Mix Asphalt (HMA) strength, stiffness, properties of aggregates are tabulated in Table 2.
and flow with optimized bitumen and coal slag ratios [9]. It was observed that MSWI-BA contained some sheet
The use of coal MSWIBA in pavement construction was metal, broken glasses, and ceramic fragments. The MSWI-
found successful, showing that it can perform similarly BA consists of irregularly shaped particles with significant
to natural aggregates when the particle size distribution surface roughness and a porous microstructure, support-
is adjusted appropriately [10–12]. Substituting virgin ing previous density and absorbance results. The MSWI
aggregates with MSWIBA met Superpave requirements BA was subjected to a combined analysis using Scanning
but caused Voids in Mineral Aggregates (VMA) reduction Electron Microscopy (SEM) and X-ray fluorescence (XRF)
and higher bitumen content [13]. Chemical, physical, and techniques to obtain comprehensive insights into the mor-
mechanical analysis of MSWIBA revealed its potential use phological and chemical characteristics of the ash. SEM
as a road base material with the addition of lime treatment analysis revealed that the MSWI BA consisted of agglom-
[14]. MSWI-BA may be dangerous due to high levels of erated and irregularly shaped particles with a rough sur-
water-leachable components. The most typical procedures face texture with open pores. Conversely, the bottom ash
of stabilisation utilising bituminous binders are used to displayed a coarser and irregular morphology with large-
handle such hazardous materials [15]. sized particles. The SEM examination further identified
the predominance of various glassy spheres, spheroids,
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Journal of Material Cycles and Waste Management
Fig. 1 SEM images of MSWI-BA at different magnifications (a) MSWI-BA × 1.0 K; (b) MSWI-BA × 5.0 K; (c) MSWI-BA × 10.0 K; and (d)
MSWI-BA × 20.0 K
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Journal of Material Cycles and Waste Management
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Journal of Material Cycles and Waste Management
failure of the sample. Marshall stability is the maximum cycles are used as a termination condition. The samples must
load at which the specimen fails, whereas the flow value first be preconditioned for at least 2 hours at 40 °C. The con-
is the measure of the deformation of the sample, which is ditioning time should be increased if there is a discrepancy
measured using a flow meter. between skin and core temperatures.
Similarly, the entire process is repeated at different binder
contents, and a series of Marshall stability, flow, Gmm, Gmb, Environmental evalation
percent air voids (Va), and density values were obtained.
Separate graphical plots of each parameter were made The samples of MSW-BA and asphalt mixtures were ana-
against different bitumen contents. In this study, the bitumen lysed for the presence of lead (Pb) using the toxicity char-
content with respect to 4 percent air void was considered the acteristic leaching procedure (TCLP) adopted by both the
optimum, and the other obtained parameters like VMA, sta- Central Environmental Control Board (CPCB) of India
bility, unit weight, and flow values were checked to be under and the U.S. Environmental Protection Agency (EPA). The
the specified limits as per the Ministry of Road Transport extraction of the leachable elements is done using USEPA
and Highways (MoRT&H) Specifications [16]. Test Method 1311, and the testing procedure will be based
on the Toxicity Characteristic Leaching Procedure (TCLP)
Bituminous mix performance tests [42]. TCLP is an analytical method that simulates sanitary
landfill contaminant leaching in waste samples.
The most widely used test methods for determining the This test was performed to simulate the leaching that may
moisture sensitivity of an asphalt mixture are the AASHTO occur if MSWI-BA is used in bituminous mixes. The solid
T-283 indirect tensile test protocols, also known as modified waste samples can be classified as hazardous or non-hazard-
Lottman tests [37]. The indirect tensile test involves load- ous based on the concentrations of the TCLP constituents
ing a cylindrical specimen along its vertical diametral plane and the guidelines set forth by the CPCB, India TCLP regu-
[38]. According to AASHTO T 283, a total of six Marshall latory standard as per Schedule II of Hazardous and Other
samples were prepared at 7 ± 0.5% air voids (by volume Wastes, Rules, 2016 [43].
of mix); out of these, three were tested as unconditioned,
and the other three were tested as conditioned specimens.
The tensile strength ratio (TSR) is the ratio of the average Results and discussion
indirect tensile strength of the conditioned specimens to the
average indirect tensile strength of unconditioned speci- Marshall mix design
mens. It is expressed as a percentage. Conditioning of the
specimen was done by keeping the specimens in a water bath Five Marshall indices (Marshall Stability, Flow, % Air voids
maintained at 60 °C for 24 h and then curing them at 25 °C and Voids in Mineral Aggregates and Marshall Quotient)
for 2 h before commencing the test. The unconditioned test are exhibited in Figs. 4, 5, 6, 7 and 8. Table 6 indicates
was conducted at 25 °C. MoRT&H suggests a minimum of the OBC values for different mixes. It is to be noted that
80% TSR to make the mix resistant to moisture damage [16]. the results illustrated are the average value of the results of
The resilient modulus was calculated as per ASTM D three samples. The binder demand increases with an increase
4123-82 [39]. The test was run using the IPC Global Uni- in the MSWI-BA replacement. The aggregate blend in the
versal Testing Machine. For each replacement percentage,
three Marshall samples were tested. A Haversine loading
waveform, 0.1 s of loading followed by 0.9 s of rest and an
assumed Poisson's ratio of 0.35 were used to complete 100
conditioning cycles. A load equivalent to 10% of the indirect
tensile strength of the mix was applied during the MR test.
The MR test was performed at two different temperatures of
25 °C and 35 °C. This was done to assess how well the blend
performed in terms of stiffness as the temperature increased.
The dynamic creep test was carried out according to
European standards at 40 °C (EN 12697-25) [40]. As per
Indian conditions, a recommended tyre pressure of 560 kPa
was applied in the uniaxial creep test at 40 °C to simulate
stress in an asphalt concrete surface layer [41]. A seating
load of 100 kPa was applied to ensure that the actuator and
sample make firm contact. One thousand eight hundred Fig. 4 Marshall Stability v/s Binder Content
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Journal of Material Cycles and Waste Management
Fig. 5 Marshall Flow v/s Binder Content Fig. 8 Marshall Quotient for different mixes
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Journal of Material Cycles and Waste Management
Modulus of resilience The dynamic creep test for both the control mix and the
bituminous mix whose fine aggregates are replaced has
From Fig. 10, it has been observed that the modified mix been done at 40 °C. From Fig. 11, the increment in stiff-
with 50% MSWI-BA replacement is the stiffest among all ness for the mixes having bottom ash percentages of 20%,
other mixes. The mixes containing BA are stiffer when 30%, 40%, and 50% as fine aggregate replacement is less
Fig. 9 ITS & TSR Values for different mixes Fig. 11 Permanent Actuator deformation for different mixes
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Journal of Material Cycles and Waste Management
Table 7 Metal concentrations (Lead as Pb) of leachates from TCLP further increase in replacement dosages. With the addition of
tests MSWI-BA, the optimum binder requirements of the mixes
Parameter MSWI-BA MSWI-BA with Threshold Limit increased, increasing bitumen costs, while aggregate costs also
Bituminous Mix as per Schedule decreased since BA is free of cost. According to the results,
II of Hazardous blends containing MSWI-BA at lower replacement percent-
and Other Wastes,
Rules, 2016, Mg/L ages are stiffer than the traditional BC-II blend. When com-
pared to the control mix, they often exhibit greater resistance to
Lead as Pb 0.77 0.08 5.0 permanent deformation. The mixes with 50% MSWI-BA as a
(Mg/L)
substitute for fines are found to be the stiffest among all mixes
than the control mix. Due to the decrease in stiffness, the considered. Bituminous mix with 10% MSWI-BA replacement
resistance to permanent deformation increases. It has been as fine aggregate produced the lowest ITS and TSR values of
observed that as BA replacement dosages increase by 20% any mix tested. It has been observed that the indirect tensile
the resistance to permanent deformation decreases. Thus, strength and tensile strength ratio of the mix increase with
Rutting resistance shows a negative correlation with the % of the increase in MSWI-BA replacement. At higher ash con-
MSWI-BA replacement. In CM, 40% and 50% replacement tent (= 50%) ITS value was the highest. With the addition of
mixes, the secondary deformation is linear, which shows MSWI-BA, the affinity of coated aggregates towards bitumen
continuous and ductile failure throughout the 1800 cycles. is increased, thus offering more resistance to moisture damage.
However, in the case of 10%, 20%, and 30% replacement Bituminous mix with 50% BA as fine aggregate replacement
mixes, it shows the slightest deformation; the deformation provided higher resistance to moisture-induced damage due
increases suddenly and then stabilizes, which leads to an to the presence of higher bitumen content, and BA being a
increase in the slope of the deformation curve. This might calcium-rich material, itself acts as an anti-stripping agent.
happen due to the brittle failure of the mix, whereas other All of the mix varieties were found to be capable of resisting
mixes show progressive failure throughout the test cycles. moisture-induced damage as they have a TSR value > 80%.
The cost evaluation provided an economic insight into differ-
Environmental evaluation ent mix varieties. The mix with 30% MSWI-BA replacement
resulted in an economic mix with 0.96% cost reduction com-
Table 7 summarises the heavy metal concentrations (Lead as pared to the control mix.
Pb) of leachates from TCLP tests that were conducted on the The heavy metal concentrations (Lead as Pb) were within
MSWI-BA. The results showed that Lead is present, but the legal limits, according to the TCLP data for the MSWI-BA.
TCLP results of MSWI-BA showed that all Lead concentra- It was also shown that using MSWI-BA instead of natural
tions in leachates were below the CPCB, India TCLP regu- aggregate in bituminous mixes would pose minimal environ-
latory standard as per Schedule II of Hazardous and Other mental problems since the bituminous binder is good at lower-
Wastes Rules, 2016 [43]. As a result, the MSWI-BA used ing metal concentrations in leachates. The test findings of the
in this study could be classified as non-hazardous waste. current study showed that, in terms of both physical qualities
Also, after being mixed with bitumen, the heavy metal con- and environmental safety, the use of MSWI-BA in hot-mix
centration (Lead as Pb) of leachates was undetectable (less asphalt mixes is viable.
than 0.1 mg/L). This means that the trace element and heavy As a result of this work, the researcher recommends replac-
metal concentrations in MSWI-BA could be controlled after ing up to 20% of the fine aggregates with a physically strong,
mixing it with bituminous binder, as the binder is highly better performing, and more economically efficient bituminous
hydrophobic and prevents any pollutant from leaching out. mix to be used as a wearing course.
The test results indicate MSWI-BA would be well encapsu- Acknowledgements The authors would like to acknowledge the Prin-
lated by a bituminous binder and could be used as an aggre- cipal Scientific Advisor (PSA), Government of India and IIT-Delhi for
gate substitute for a bituminous mix. The results obtained funding the project to CSIR-CRRI under Delhi Cluster-“Delhi Research
Implementation and Innovation” (DRIIV), Theme Solid Waste Man-
are in good agreement with those of other researchers [44].
agement, WP-6 Use of construction & demolition wastes, incinerated
residues in road construction scheme.
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Journal of Material Cycles and Waste Management
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