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SnS2
d. Al2S3
1. What is the [Co+2] and [Cl-] when 6. Which of the following has a
0.35 mol of COCl2 is dissolved in solubility of less than 0.10 M?
enough water to make 100mL of a. SrS
solution? b. SrCl2
a. [Co+2] = 3.5 M and [Cl-] = 3.5 c. SrSO4
M d. Sr(OH)2
b. [Co+2] = 3.5 M and [Cl-] = 7 M
c. [Co+2] = 0.35M & [Cl-] = 0.35M 7. Which of the following is the least
d. [Co+2] = 0.35 M & [Cl-] = 0.7 M soluble in water at 25° C?
e. a. CaSO4
2. When 250Ml of 0.36M Sr(OH)2 are b. BaSO4
added to 750mL of water, the c. CuSO4
resulting ion concentrations are d. MgSO4
a. [Sr+2] = 0.12M & [OH-] =
0.12M 8. Which of the following will be most
b. [Sr+2] = 0.12M & [OH-] = soluble in water at 25° C?
0.24M a. AgI
c. [Sr+2] = 0.09M & [OH-] = b. PbS
0.09M c. MgSO4
d. [Sr+2] = 0.09M & [OH-] = d. Ba(OH)2
0.18M
9. The least soluble salt in water is
3. In 1.5M (NH4)2SO4, the ion a. BaS
concentrations are b. AlCl3
a. [NH4+] = 1.5M & [SO4-2] = 1.5M c. CaSO3
b. [NH4+] = 1.5M & [SO4-2] = 3M d. ZnSO4
c. [NH4+] = 3M & [SO4-2] = 1.5M
d. [NH4+] = 3M & [SO4-2] = 3M 10. Which of the following compounds
will form a saturated solution with
4. If the solubility of Pb(OH)2 is the greatest concentration of Ag+?
0.155g/L, then the concentration of a. AgI
each ion in a saturated solution of b. AgBr
a Pb(OH)2 is c. AgIO3
a. [Pb+2] = 0.155 g/L & [OH-] = d. AgBrO3
0.155 g/L
b. [Pb+2] = 0.052 g/L & [OH-] = 11. Which of the following is most
0.103 g/L soluble?
c. [Pb+2] = 6.43x10-4 M & [OH-] = a. Na2S
1.29x10-3 M b. CaSO4
d. [Pb+2] = 6.43x10-4 M & [OH-] = c. PbCO3
6.43x10-4 M d. Zn(OH)2
d. 𝑀𝑔 ( ) +𝑆 ( ) + 𝑆𝑟 ( ) +
2𝑂𝐻 ( ) → 𝑀𝑔(𝑂𝐻) ( )
+
𝑆 ( ) + 𝑆𝑟 ( ) 39. A solution contains CO3-2 and OH-.
Separation of these two anions by
35. The complete ionic equation for the selective precipitation is
reaction between MgCl2(aq) and accomplished by first adding
AgNO3(aq) is Sr(NO3)2 solution, then filtering and
a. 𝐴𝑔 ( ) + 𝐶𝑙 ( ) → 𝐴𝑔𝐶𝑙( ) finally adding to the filtrate a
b. 2𝐴𝑔𝑁𝑂 + 𝑀𝑔𝐶𝑙 → solution of
( ) ( )
a. HNO3
2𝐴𝑔𝐶𝑙( ) + 𝑀𝑔(𝑁𝑂 ) ( ) b. RbNO3
c. 2𝐴𝑔 ( )
+ 𝑀𝑔 ( )
+ 2𝑁𝑂 ( )
+ c. NH4NO3
2𝐶𝑙 ( ) → 𝑀𝑔𝐶𝑙 ( )
+ 2𝐴𝑔 ( )
+ d. Zn(NO3)2
2𝑁𝑂 ( )
d. 2𝐴𝑔 ( )
+ 𝑀𝑔 ( )
+ 2𝑁𝑂 ( )
+ 40. A reagent that may be used to
2𝐶𝑙 ( ) → 𝐴𝑔𝐶𝑙( ) + 𝑀𝑔 ( )
+ separate CI- from S-2 by
2𝑁𝑂 ( )
precipitation is
a. KNO3 added but not when Zn2+(aq) is
b. AgNO3 added:
c. Pb(NO3)2 a. S2−
d. Al(NO3)3 b. Cl−
c. SO42−
41. Which of the following ions could d. CO32−
be added to an aqueous mixture
containing Pb2+ and Ba2+ to 47. Which of the following anions could
separate the ions by precipitating be used to separate Pb2+ from
one of them? Ba2+ by precipitation?
a. I– a. Cl−
b. NO3- b. OH–
c. PO43− c. NO3−
d. SO42− d. CO32−
53. A student could precipitate silver 58. Consider the following equilibrium:
chloride from a saturated solution 𝐴𝑔𝐶𝑙( ) ⇌ 𝐴𝑔( ) + 𝐶𝑙( )
of silver chloride by adding When Br-(aq) is added to a saturated
a. Water solution of AgCl,
b. sodium iodide a. more AgCl dissolves and its
c. sodium nitrate solubility product increases.
d. sodium chloride. b. more AgCl precipitates and its
solubility product decreases.
54. Consider the following equilibrium c. more AgCl dissolves and its
system: solubility product remains
𝑃𝑏𝐼 ( ) + ℎ𝑒𝑎𝑡 ⇌ 𝑃𝑏( ) + 2𝐼( ) constant.
Which of the following changes d. more AgCl precipitates and its
would result in more PbI2 solubility product remains
dissolving? constant.
a. adding more PbI2
b. increasing the pressure 59. Magnesium carbonate would be
c. adding some Pb(NO3)2 most soluble in a solution of
d. increasing the temperature a. MgCl2
b. NaNO3
55. In which of the following would c. Na2CO3
solid AgCl be most soluble? d. Mg(NO3)2
a. 1 M HCl
b. 1 M MgCl2 60. Consider the following solubility
c. 1 M AgNO3 equilibrium:
d. 1M NH4NO3 𝑀𝑔𝐶𝑂 ( ) ⇌ 𝑀𝑔( ) + 𝐶𝑂 ( )
The addition of which of the
56. Consider the following equilibrium:
following substances would
𝐶𝑎𝐶𝑂 ( ) ⇌ 𝐶𝑎( ) + 𝐶𝑂 ( ) decrease the solubility of MgCO3?
Which of the following reagents, a. H2O
when added to the equilibrium b. NaCl
system, would cause more CaCO3 c. NaOH
to dissolve? d. Na2CO3
a. KNO3(s)
b. CaCO3(s) 61. The greatest mass of solid SnS will
c. H2C2O4(s) dissolve in 1.0 L of
d. Na2CO3(s) a. H2O
57. Consider the following equilibrium: b. 0.10 M MgS
c. 0.10 M (NH4)2S 66. The solubility of PbI2 will increase
d. 0.10 M Sn (NO3)2 with the addition of
a. PbI2
62. Consider the following equilibrium: b. heat.
𝑀𝑔𝐶𝑂 ( ) ⇌ 𝑀𝑔( ) + 𝐶𝑂 ( ) c. water
A saturated solution of MgCO3 is in d. Pb(NO3)2
contact with undissolved solute.
More MgCO3(s) can be dissolved 67. Consider the following equilibrium:
by adding solid 𝑆𝑟𝐹 ( ) ⇌ 𝑆𝑟( ) + 2𝐹( )
a. oxalic acid. 68. The equilibrium will shift left upon
b. sodium carbonate. the addition of
c. magnesium chloride. a. H2O(l)
d. Magnesium carbonate. b. SrF2(s)
e. c. SrCl2(s)
63. When solid AgBr is added to a d. NaNO3(s)
saturated solution of AgBr, the
reaction can be described as: 69. Consider the solubility equilibrium:
rate of rate of 𝐶𝑎𝐶𝑂 ( ) ⇌ 𝑀𝑔( ) + 𝐶𝑂 ( )
dissolving crystallization An additional piece of solid CaCO3
a. increase increase is added to the equilibrium above.
b. increase decrease The rate of dissolving and rate of
c. decrease increases
crystallization have
d. increases no change
rate of rate of
dissolving crystallization
64. Which of the following describes
a. increase increase
the changes in ion concentration b. increase not changed
when 1g of solid ZnS is added to a c. not changed increased
saturated solution of ZnS? d. not changed
[Zn+2] [S-2]
a. increase decreases 70. Silver chloride, AgCl, would be
b. decreases decrease least soluble in
c. increases increases a. 1.0 M HCl
d. remains constant b. 1.0 M NaNO3
c. 1.0 M ZnCl2
65. Consider the following graph for a
d. 1.0 M AgNO3
saturated Ag2CO3 solution: What
e.
change occurred at time t1?
71. Consider the following solubility
equilibrium:
𝑃𝑏𝐶𝑙 ( ) ⇌ 𝑃𝑏( ) + 2𝐶𝑙( )
A student adds NaCl(s) to a
saturated solution of PbCl2. When
equilibrium is reestablished how
have the concentrations changed
from the original equilibrium?
a. Water was added.
a. [Pb+2] and [Cl-] both increased
b. AgNO3 (s) was added.
b. [Pb+2] and [Cl-] both decreased
c. Na2CO3 (s) was added.
c. [Pb+2] decreased and [Cl-]
d. The temperature was
increased
increased.
d. [Pb+2] increased and [Cl-]
decreased
72. Consider the following solubility 75. A solution containing a single
equilibrium: unknown cation is added to three
test tubes. The following anions
𝐵𝑎𝑆𝑂 ( )
⇌ 𝐵𝑎( ) + 𝑆𝑂 ( )
were added and observations were
Which of the following will result in recorded:
an increase of [Ba2+]? test anion observation
a. adding water tube added
1 SO4-2 ppt
b. adding BaS(s)
2 S-2 ppt
c. adding BaSO3(s)
3 OH- ppt
d. adding Na2SO3(s)es
The solution contains:
a. Sr2+
73. During a lab on qualitative analysis,
b. Ag+ or Pb2+
an unknown solution containing
c. Ca2+ or Ba2+
one cation was analyzed and the
d. K+, NH4+ or H+
following data were collected:
0.2 M anions
76. A student wishes to identify an
added to the
observation unknown cation in a solution. A
unknown
solution precipitate does not form with the
S-2 no ppt addition of SO42− , but does form
SO4-2 ppt with the addition of S2− . Which of
OH- ppt the following is the unknown
CO2-3 ppt cation?
Which one of the following cations a. Ag+
is found in the unknown solution? b. Mg2+
a. Mg2+ c. Ca2+
b. Ca2+ d. Cu2+
c. Sr2+
d. Ba2+ 77. A solution containing an unknown
cation was added to three solutions
74. A nitrate solution containing an and the following observations
unknown cation is added to each of were recorded:
the following three test tubes. Solution observation
A precipitate forms in one test tube. NaI no ppt
only. Na2SO4 ppt
NaOH no ppt
The unknown cation is:
a. Pb2+
b. Sr2+
c.
Ca2+
d. Ag+
a Ksp?
d. 𝐾𝑠𝑝 = 4[𝐶𝑟𝑂 ]
1. B 35. D 69. C
2. D 36. A 70. C
3. C 37. B 71. B
4. C 38. D 72. B
5. A 39. D 73. C
6. C 40. D 74. B
7. B 41. A 75. D
8. C 42. A 76. B
9. C 43. B 77. B
10. D 44. A 78. B
11. A 45. B 79. B
12. D 46. C 80. C
13. D 47. A 81. D
14. D 48. D 82. D
15. C 49. D 83. B
16. B 50. A 84. A
17. B 51. B 85. A
18. C 52. C 86. C
19. D 53. D 87. B
20. A 54. D 88. B
21. D 55. D 89. D
22. B 56. C 90. A
23. A 57. A 91. C
24. B 58. C 92. B
25. A 59. B 93. B
26. B 60. D 94. B
27. A 61. A 95. A
28. A 62. A 96. A
29. B 63. A 97. B
30. B 64. D 98. A
31. D 65. B 99. C
32. D 66. B 100. A
33. B 67. C
34. D 68. A