tarea 5 : metodos Integrales

José Arturo Ferrera Abogado

Ramzi Nash Sangri

A B a

C /a 502 > C. la + 502

Orden e v = cte

K = 2. z ✗ 10-5 1 90min 60s =

5400s

s Infra

T =
320°C =
593.15K

rrvz =
1- DCA = krz CÁ
a
dt
-

=
_
DCA =
Kita CA krz -
a
= Ka
de
CA E

f C. Ao
DCA
CA
=

kafdt o

CA

IRCA cao
=
KAE

In C. 1- + IRCAO =
Kat

IRCA =
In CAO -

KAE
 base de calculo
Proponemos CAO en
=
una

Im CA =
In ( lle ) -

2.2 ✗ 10-5 1 5400s

Inc A = -
O .
1188

° " ⊕
¿
-

c. A = =
0.887M

CA ( 5400s ) =
0.887M

5400s

✗ A
=
CAO -

CAE .
100

CAO

5400s

✗ A 1M 0.887M
= -
100
.

1M

-15400s
z =
11.3% % Clase
descompuesto
✓

A B C D 1=1

>
CAS He
Hos
(g)
C.
Haig) COCGI
c. O + +
g)
- -

T =
504°C =
777 .
15 K
rrvz =
1- DCA = krz CÁ
a
dt
-

=
_
DCA =
KRRXACA krz -
a
= Ka
de
CA E

f
C. Ao
DCA
CA
=

kafdt o

CA

IRCA cao
=
KAE

In C. 1- + Inc -10 =
KAE

INCA =
Inc -10 -

KAE

ELAIPTmmlt-3.GL 908 0.5368 1

777 488 0.6921

1587 629 0.8211

3150 Y> 9 1 .
025

XIE

① letra otra
408
mmg = 0.5368

>
toommtg
 Balance de concentraciones

CAO O O O CAO

CAO -
E

E. 1- = CA -

CAO EB = CB -

CBO EA = EB = Ec = ED

-
1 1

CA -
CAO = -

EA C. B. -

CBO =
EB

C. A- = -
EATCAO CB =
EB + CBO

CA = CAO -

EA CB =
# + E CB = E

ZOO

CAO -

EA =
o

EAOO =
CAO

( calculo iletrados
② CTOO = P = 1.225 ahh =
0.0192 mol
RT 0.082 atrae C > 77.15*1 <

mal# < TE = Pt

RT

C. Too =
3C -10

CAO =
0.0192M = G. 9×10-3M
3
 390º
=
a ,- 0.0084M

0.0084 M
=
ZE + CAO

>

0.0084M =
ZET 6. y ✗ / Ó µ

(0.0084-6.4×10-3)
"

E. =
M = 1×10-3
°

É Calculo iterativo )
E

③
=
CT -

CAO (
Z

④ CA =
CAO -

É ( calculo iterativos

3900
C. A = C. Ao -

>
=
6.4×70-3 _
1×10-3 =
5.4 × > Ó te

IRCA =
In CAO -
KAE

ka = Ksrz

Kat INCA En CAO

porque
+ =
a =/

Kat =
In CAO -

INCA Inc -10 =

-5.051

390s
In CA = -

5.229

⑤ Ka =
In CAO -
In CA

C-

ka =
(-5.051 + 5.224) = 4.4359 ✗ IÓ
"
l

390s A

Usando Excel se saco una ka =

knz
promedio
✗
Krtzlfmomeahof =
9.43×10-4 1

A
.

✗
 Calculos Iterativos
5

INCA Inc KAE

Ctf
= -10 C- C. 1-
1-3
-

Im CAI = En CAO Kat

Es
-

In CAO In
El
¥0
-
=

Ka

=
En (6.9×10-3) -
In G. 4×10-3
3

-
Y
4 43×10
÷
.

§
C- =
2479.94 A

✗
✓

A B C D B

z , 3 2 ,

:
:

:
①
T = 300°C = 573.75K

Catral
Ellas
PTCMMHGI PT

✓ = dé
3 878.50 1- 156

CAO = 0.02169 mol

4 906.05 1.192 L

1dm >
=/<

5 932.02 1.226
 ① latas 1. otra
878.50mHz 156
=

760
mmHg

Balance de concentraciones
catalizador

| |
" " " " " ° ° ° " " " " " "" " " °

◦ , .am .

≥. < ☐ ◦ se < a a. ◦ + , amenaza

Para E :

EA = CA -
CAO Ea = Cc -
Cao < D= C. D- CDO

z 3 2

C. A -

CAO = -

ZEA Cc -

Cao = 3. EC CD -

CDO =
ZED

CÉ
q

CA =
CAO -

ZEA CC = 3sec CD =
Cfo + ZED

Para £00

a ☐

CAO -
ZEA = °
3 E. A ZEA

EA CAO
≤
=

CAO = ZEA

EA =
EA CAO
2-
CAO =

EA = CA -

C =
≈
✓
PV = m RT

P = CRT →
P = ( 0.02169M ) 0.0822ohm (573.15k ) = 1- 019 atr
molk
 ② ③ ④

ECLPtH-ICTCFE-MC-g-MJI.SC
'

0.02459 2.9×10-3 0.01589

② CT = P = 1. 156 ata = 0.02459M

RT ( 0.0822 atra knock ) ( 573.15kt

CT =
CAO + E

③ < = CT -

CAO

3h
>

E
=
0.02459M -

0.02169M
=
2. 9 ✗ SÓ te

⑨ C. 1- =
CAO -

ZE

34
CA =
0.02169M
-
zlz.az/o-3M)-- 0.01589M

✗1- = CAO -
CA

CAO
a)
34
ZA =
0.02169M -
0.07589M .
100 =
26.74%11
0.02169M

"
4
ZA =
0.02169M -
0.01435M 100 = 33.84%
.

y
0.02169M

54
ZA =
0.02169M -

0.02289M 100 = 90.57%

µ
.

0.02169M
 aún
"
↳

apf catalogador heterogéneo

afecta porque
es u n

rrrz = 1 DCA = kr ≥

-
a dt

i.
B o
=

Orden
r = o
global = o

i. ✗
=p
= o

strz = 1 DCA = Krrz

-
a de

=
_
DCA =
Kita

de ka
g

CA E

f. CAO
DCA =

krxafdt O

- -
-

-
CA -

CAO
=
Ka -
E -
o
-

CA + Cao =
KAE

Ka = CAO -
CA

→
f. A- =
CAO -
KAE E

Orden ( )
r
=
e
global =
e
Tipos
i. ✗ = 1
B
= o
,

strz = 1 DCA = Krz C. A

-
a de

=
_
DCA =
krxa CA

de

fe
"

g ca -
DCA
CA
=
Ka o
alt
 CA

IRCA cao
=
KAE

In C. 1- + Inc -10 =
Kat

→
IRCA =
In CAO -

KAE Ka =
Inc-10 -
INCA

C-

Orden
va
=
a
global =
a

i. L =

B
=
z °
,

strz = 1 DCA = Krz CA

-
a de

=
_
DCA =
krxa CÁ
de

CA E

f
CAO
DCA
dC -12
=

kafodt
CA

1 = Kat

CA ato

1 1 =
Kat
_

CA CAO

e- -
1-
/ =
/ Kat Ka = c. A CAO
+ →

CA CAO €

Para ordeno :

⑤ Ka = CAO -
CA

"
Kal =
0.02169M
-

0.01589M = 1.93×70-31
3h A
 ⑤ ⑥ ⑦

ka -
_ (MK ) Kei ( V2 ) ka -111mL)

óf
ECLCAcut-O.c o/
go.otzf.86.sn
5 89:
3

: : - -: - -. . -
Para ordenar :

⑥ Ka =
In CAO -
INCA

> "
Ka
=
In ( 0.02169Mt -

In (0.0/589) = 0.10372 /

32 A

Para orden z :

e- -
1-

③ Ka = C. A CAO

"
ka = 1 l
-

O - 01589M 0.02169M = 5.6095 1

32 Mt

Clhtyamdo calculadora
cientifica
≥
R
para sacar

z
y
Orden O
"
O 0.02169

3 0.01589 PÍ =
0.9958

Y 0.01435

3- 0.01289
 Clthgamdo calculadora
cientifica
≥
R
para sacar

Orden l
:
z
y
3 In / 0.015891 PÍ =
0.9998
✗
9 In ( 0.01435)

5 In ( 0.01289 )

Clthgamdo calculadora
cientifica
≥
R
para sacar

Orden z
:
z
y
3 1 ÷ 10.015891 PÍ =
0.9978

9 1 ÷ (0.0/435)

5 1 ÷ ( 0.01289 )

b)

i. Por lo tanto la reaccion es de ordene (

Tipo e) porque
la

PÍ es
la mas cercana a '

Kal promedio =
0.10369 1

Krz -

a = Ka

las
KNX =
ta = O . 10369 1/1 = 0.0 518 1

a 2 h
✗

"

strz = 1 d CA = Krz CA d = 1
B
= o

-
a d. C- A = e

M = A =
1
( conectadas de Kord Es una reaccion

mía Hk h se elemental
e ata

otra = 1 d CA = 0.0518 1 C A

z DE A
✗

Expresión uretra de la rrx

 -
Ea
RT
krz =
Ae Ea = Attrx

sttrx =
np
AH
-

f p
-

nr
HAY )r
=
3 lo ) + zlo) -

2C 171.5 KJ mal )
/

AHLY =
-343 KJ = -

343000£

mol mol

c) Ea =
-343000 J

'
mol

La
- : reaccion es exotérmica
porque
AHÍ es
negativo

A =
Kira = ° - 05/8 (1/1)
Ea
-34300051mmol
-

RT
ezfs
-

8. 314µmol K ( 573.15K)

el =

A = 2.84×10-33 1

Ir C. A =
Ir CAO -

Kat

C- →
CA CAO
(≤ f
=

Ir CAO =
In C. Ao -

Ka C-

Kat =
En CAO In
( CAF)
-
 c-
En CAO -
In
(c )
¿g
=

(
ka

(≤)
C- =
In ( 0.02169M ) -

Im 0.02169M

0.10369 1

A
d) 6.68h
≤
€ =

Si c. 1- = 0.02169 -1=0.8 = O -2
y YI

CT
(g)
O CAO -1 CI CAO = 0.8C CT )

C- CAO + ETCI =
0.820.02169M )

=
O .
0173M

CA = CAO -
ZE

3h
C. A =
0.0173M -
212-9×10-3 ) =
0 . 0115M

44
213.67×10-3 )
>
C. A =
0.0173M -
=
9.96 ✗ IÓ M

54
10-3 )
>
C. A =
0.0173M -
2L 4. Y ✗
=
8.5 ✗ só te

ZA = CAO -
CA .
100

CAO

el
> &
ZA
=
0.0173M -
0.0115M 100 = 33.53%
✗
.

0.0173M
 e)
"
"
ZA
=
0.0173M -
9.96×10-74 100 =
42-43 %
.

0.0173M

el
34
ZA
=
0.0173M -
8.5×10-74 .
100
=
50.88%11
0.0173M

T = 320°C =
593 15K
.

-
E. a

RT
Krx = A e

Ea =
-343000 J

mal

A = 2.84×10-33 1

2
-

343000µmol
Knrz = 2.84×10-33 1 Ó 8.314J 593.15K

La molk

Krz = 4.57×10-3 1

Krz -

a
=
Ka

Ka = 4.57×10-3 1 .

z = 9.14×10-3 1-
a h

Ka =
INCAO -
INCA C- = IRCAO -

INCA
→

C-
Ka
 >& > &
z A =
26 .
>y % →
C. A =
0.01589 M

44 4h
ZA =
33.84 % → C A =
0.01435M CAO = 0.02169M

5h 54
ZA =
90 .
57 % →
C A =
0.01289 M

↓
£ = In ( 0.02169M ) -

IRCOOI 589M ) = 34.04h

✗
9. 14×10-3 1-
A

£ = In ( 0.02169M ) -

In (0.01435M ) = 45.20h
y
9. 14×10-3 1-
A

£ = In ( 0.02169M ) -

In ( O -01289M ) = 56 94k
✗
.

9. 14×10-3 1-

%
A

al ser una reaccion exotérmica libera

energía , por
lo cual

al aumentar la temperatura la reaccion se vuelve menos

espontánea esto provoca

la reacción se
produzca en
y que

muchos mas Loros .

A B C D
"
z As H>
cgs
>
317a
cgst z Ases )
T =
300°C

t = 5 horas
srntz = 1 d. CA =
0.0 5/8 1 ( 0.01289M$
-

a dt A

"

RRNX =
G. 68 ✗ ró te

h
 DCA dc.rs alce DCD
La ¡ al
rrrz =
_
= =
1- =

DE DE c DE de

rrrz =
- L DCA =
1- dcrs =
1- alce = 1- DCD

2 DE 1 DE 3 DE 2 DE

"
6.68 IÓ
La NA
uh
=
-
✗

gs
VA =
-2 6.68 ✗ IÓ
"
1
=
-1.34×10-31 velocidad de
2 h
× desaparición

rB= o
✗
No teme
porque es un
catalizador
"
6.68 IÓ
1-3 uh
va = ✗

rra = 3 6.68 ✗ só
"
1
=
2.00×75
"
M velocidad
a h de
✗ aparecían
"

1- 6.68 IÓ
Mz
ND = ✗

r D= a 6.68 ✗ só
"
1
=
1.34×10-3 M velocidad
te
ha de
aparecían
 =
✓

✓ 5dm
>
52 1 atmí Torr
Hg
= =
76o = 1mm

>
/< = 1dm

① 802.1 Tdr latma = 1.055 otra

760 TOY
 ①
Pictor) Ptlalñal te
propone
C- ( s ) una

o 76o e
temperatura inicial
5 802.1 1.055
de : 25°C =
298.15 K

10 835 / 1.099 -10 0.45

y
=
.

20 883 1. 162 B-
=
0.45
y

50 959.8 1.263 Io = 0-10

y

100 1012-2 1.332

A + B + I →
zc + D

Balance de concentraciones

CAO CIO

÷:*
CAOTCBO CEO
O +
C B. O O

C-

O O CIO ZCAO CAO 3C -10 + CIO

Ea = EB = EC -_ ED

Para C- :

E. 1- = CA -

CAO Ec = CC -
CCO ED = CD -

CDO

-
1 z 1

O
°
q
CA =
CAO -

EA « = C # + ZEC C. D= Cfo -1 ED
Para Zoo

CAO -

E = o Para C

CAO = E E. = CAO

d. E. = ZCAO

PV =p RT
→ P = m RT C =
se F- CRT

v ✓

② C = P = / atra = 0.0409M =
CTO

RT 0.082 < atrn ( 298.15k ) ( Iterativo)

smolk

CAO
YAO
Ao CAO = CTO
g.
= -

>

C. TO

CAO =
( 0.45 ) ( 0.0409M ) =
0.0184M =
CBO

CIO =
( 0.10 ) ( 0.0409M ) =
4.09×10-71

CT =
CAO -1 CBO + CIO + En

E. =
CT -

CAO -

CBO -
CIO

e¡Í O 1 0.0409 0.0184

④

>
5 1.055 0.0431 2. ZIX / Ó 0.0162

>
10 1.099 0.0499 4.0 / XIÓ 0.0142

>
20 1 . / 62 0.0475 6.6 / ✗ IÓ 0.0118

50 2263 0.0517 0.0108 7.6×10-3

100 1.332 0.0545 0.0136 4.8×10-3
 Ctá
>
③
=
[ 0.0431M
-

0.0184M -

0.0184M -

4.09 ✗ / Ó M

E. =
2.21 ✗ ió
>
M ( Eláratuof

⑨ CA = C. Ao -
E

5s
>
C A =
0.018414
-

2.21 XIÓ M =
0.0162M

rrrx =
1- DCA = knz CÁCBB
-
a dt

concentraciones
Como las de CA
y
CB s on
iguales
entonces
a
cualquier tempo :

rrsrz = 1 dc A = Krx C -1×+3

-
1 DE

Orden ( )
→
=
e
global =
1
Tipos
i. ✗ = 1
B
= o
,

strz = 1 d C. A = Krrz C. A
-
a de

=
_
DCA =
Krxa CA

de

Kaf}
CA

f DCA de
-

CAO CA
 C. A

IRCA cao
=
KAE

In C. 1- + IRCAO =
Kat

→
IRCA =
In CAO -

KAE Ka =
Inc-10 -
INCA

C-

Orden
r
=
a
global =
a

i. ✗ =

B
=
z °
,

strz = 1 DCA = Krz C. A

-
a de

=
_
DCA =
Krxa CÁ
de

CA E

f
CAO
DCA
dc -12
=

kaf o
dt

CA

1 = Kat

CA ato

1 1 =
Kat
_

CA CAO

e- -
1-
/ =
/ Kat Ka = c. A CAO
+ →

CA CAO €
 Orden
1=3
global =3

i. ✗ =
3
B
=
o
,

>

strz = 1 DCA = Krz CA

-
a de

>
=
_
DCA =
krxa CA

de
CA E

CAO
f DCA
dC -13
=

kafodt
-
CA
-3+1
-

-
CA =
Kat

-
-

3+1 _
CAO

-
-

-
1 1 =
Kate
-

-
ZCÁ ZCAÓ

Kat = 1
_ 1-
ZCÁ ZCAÓ

1-
a.at
-

1 =
/ < "€ -
s ka = C -102
+

1-02
≥

CA < 2€

⑤ Ka =
In CAO -
INCA

"
ka
=
Info .
- 184m ) -

Im lo -0162M ) =
0.0255L
5s A
 5O ⑥ ⑦

Ka=( Vs ) ká CNN.sfka-lihi.es )

go.o-i.gg/
orden orden
CACM )
carotenos
s 1 ≥

0.0162 0.0255 1. 4761 85.67

10 .

0.0118 0.0222 1.5199 105.70

-1000.0*341.5399202-24
e- -
1-

⑥ Ka = C. A CAO

5s

Ka = 1 1
_

0.0162M O -0184M = 1.4761 /

5s M -

1- -
1-

⑦ Ka = CA
'
C -102

2€

"
Ka = 1
-
1 1
≥
≥

0.0184Mt
≥
( 0.0162M ) ( = 85.6T M -
s

215s)

Usando el metodo
Grafica Gul
≥
en R :

Order I : O .
9754

Orden a : 0.9999

Orden 3 :
0.9815
 ≥
i.
srrz =
1- DI = krz CA CA =
CB

-
I DE

' '

rrrz =
1 d CA = Krx CA CB

-
i alt a)
Es reaccion
'

a = ✗ . . una

✗ +
B
=
a Condena ) la =
B
elemental

tocando la ka promedio con Excel :

Krz -

a = Ka

Krz . 1 =
Ka → Ka =
KNX

=
krz (promedio ) =
1.5370 1

M -
s

µ Unidades de
¥ !
= = kvx

.rs , µ ,

a)
=
otra =
1- d. C. A = 1.5376 1 CÁ
-

l de m s -

cineteca de la
CA CB
Expresión rrx
-

×
-

C. 1-
=
3. CAO + CI

=
SC 0.0184M ) + (4.09×10-4) =
0.0593M

00
»

A- =
CT R T

atroz 5kt
0.0593M¥ (298
=
0.082 ✗ .
/

mal #
 ↳
=
PÍ= 1.4498 otra

C- -
s C. A =
CAO
2

1 =
/ Kat ( Na )
+

CAO CAO
2

Katya) =
Z /
_

CAO CAO

C- 1
f-
= a _

CA - CA -

Ka

b)
c-
(E)
= a ,
_

0.0184M 0.0184M = 35.34s

✗
1. 5376 1

M .
A

P = 1. rata

C. e- = P = 1. Zahir =
0.0991M

RT 0.082 Catre ( 298.15kt

molt

E. =
CT -

CAO -

CBO -
CIO

>
E =
0.0491M -

0.0184M -

0.0184M -
4.09 ✗ 1Ó te

>
E =
8.21 ✗ > Ó M
 C. 1- =
CAO -
E

CA =
0.0184M
-

8.21 ✗ 753M =
0.0 1019M

1 1
-

ka = CA CAO

C-

1 1 1 /
_

C- = C A CAO = 0.01029M 0.0184M

Ka 1.5376 1

M -
s

al =

C- =
28.98
segundos
28.48s < 8.48s
=
CA 0.01019M =
CB

V =
52

C =
R M = C. ✓ = 0.01019mmol .

5¢
w ←

28.48s
M
=
0.0509 mol

d) A+ B s za + D

MA =
MB

MA =
0.0509 mol
×

MB
=
0.0509mmol
y

>
CIO =
9-09 ✗ / Ó µ

MI = 4.09 × > Ósea ( 52 ) =

O 0204 mal
y
.
 CC =
ZE

CC =
z (8.21×70-314) =
0 . 0169M

me =
( 0.0164nF 52 =
0.0821 moler

C. D= E

nos = ( 8.21×15%9-52 =
0.0410 moly

e) { a
= -

10 KJ = -

10000 T

mol mol

-
Ea

krz= A e RT

A =
Krz = 1.53761M -
s

Ea 1000051mmol
ezfs
- -

C RT 8.3 / Y Jtmolk ( 298.15K )

A =
0.0272
/

M -

T =
12C 25°C ) = 300°C =
573.15K

Kurtz =
0.0272 /
_
-

10000µmol
M -
s C 8.314£ ( 573.15K )

molk

Kntzz =
0.2218 /

µ •
A
 Ka = krz

1 =
1 Ka -
z
+

CA CAO

l = /
+
0.2218 / ( 28.48s )
C. A 0.0184M Mis

1 =
60 6697 1 CA =
0.0165M =
Cps
.

C. A M

CA =
C. Ps mA
-

-
MB
,

C =
M m = C -
V

MA = ( 0.0165m ) ( 52 ) = 0.0825mmol
✗

MB =
0.0825mmol
✗

MI = 4.09 ✗ sósee ( 52 ) =
O 0204mmol
y
.

C. 1- = CAO -

"
"°

E =
CAO -

CA E =
0.0184M -
0.0165M

28-48
¿
? 1. q ✗ /Ó
>
M

CC =
ZE

>
CC =
z ( 1-9×10-3M f =
3.8 ✗ só M

Me =
( 3.8×10-74952 =
0.019mmol
µ

C. D= E

( 1.9×10-749-52 mol
>
nos = =
9.5×15
×
Los moles en los reactivos aumentan en
los productos disminuyen
y
.

Como la reaccion exotérmica desprende calor

es
y
a
mayor

temperatura la kv × se hace más

pequeña , por
lo cual a

mayor temperatura se hace menos

espontanea .