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H◦d-ks

sfnrlriomehy A → R for first order gasphase


Assuming
a
a

pure A
is
for 99% conversion of
reaction the size of a PFR

stoichiometry of tse
,

liters In fact, the


calculated G be 32 .

3K For this corrected stoichiometry, find the


reaction is A → .

volume of
reactor
required
.

PFR design → natron :

÷ -11¥
- YA = Kca

a- =

ⁿʰ✓=%%¥a) = ↳
!Ie±a✗a

CAG =

kG¥¥¥
-
ra = Kca =

✗A

÷=!¥÷÷:-:I ,

r¥F=%?¥: →

For A → R Glen :
Ea = ◦
✗a- = 0.99

✗A

VK.ph?---f9II-a---ln( 0
c- ✗ a)

✓=
32lb & ✗A = 0.99
Given :

32kq§0_ In (1-0.99)
'

• . = -

k÷ =
4¥52 = 0.144

For A → 3. R
Ea = = 2

substituting the above in F-qn.IO


,

vi-o.ae =

. )
✗A

=*¥:
0

✗A ✗A

.fi#--J?II-ad*
✗A ✗A

↓% +214¥ *
-

1) ᵈ✗a

✗A
✗A

=3f• - &
/ d✗*
°
0

° '

=
@ lace -

a)
✗ - 2✗ a)
0

= -
3 en@ .
-
1) - 2×0^99

= 13.816 -
1.98 = 11.84

r =
18.94-a ᵗr ,
=

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