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  • 11.10.2023 C01

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    robert lawrence
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    1) The activation energy for a certain reaction is 59 kJ/mol as calculated from the given rate constant expression and values. 2) For a first-order parallel reaction with rate constants k1=3 min-1 and k2 at 300K, the temperatures at which reactants A and B will be obtained at the same molar ratio is calculated to be 354K. 3) For a reaction with an activation energy of 30 kJ/mol, the temperature coefficient at 10% conversion is calculated to be 10K. 4) For two parallel reactions with activation energies of 100 kJ/mol and 150 kJ/mol and rate constants of 102 M-1s-1 and 4x

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    1) The activation energy for a certain reaction is 59 kJ/mol as calculated from the given rate constant expression and values. 2) For a first-order parallel reaction with rate constants k1=3 min-1 and k2 at 300K, the temperatures at which reactants A and B will be obtained at the same molar ratio is calculated to be 354K. 3) For a reaction with an activation energy of 30 kJ/mol, the temperature coefficient at 10% conversion is calculated to be 10K. 4) For two parallel reactions with activation energies of 100 kJ/mol and 150 kJ/mol and rate constants of 102 M-1s-1 and 4x

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    © All Rights Reserved
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    6 views8 pages

    11.10.2023 C01

    Uploaded by

    robert lawrence
    1) The activation energy for a certain reaction is 59 kJ/mol as calculated from the given rate constant expression and values. 2) For a first-order parallel reaction with rate constants k1=3 min-1 and k2 at 300K, the temperatures at which reactants A and B will be obtained at the same molar ratio is calculated to be 354K. 3) For a reaction with an activation energy of 30 kJ/mol, the temperature coefficient at 10% conversion is calculated to be 10K. 4) For two parallel reactions with activation energies of 100 kJ/mol and 150 kJ/mol and rate constants of 102 M-1s-1 and 4x

    Copyright:

    © All Rights Reserved
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    of 8

    T

    I
    I
    -
    ↑ 10 -
    2023
    & Of
    -
    ⑭ The wate constant
    of a certain reaction is

    given as ->
    logk
    =

    5 .

    y-12 .
    calculate
    I

    activation
    energy (in call at 127° .

    Ea/R-
    R = A e-

    euk =
    MA-E
    log
    =

    logA-es - 0

    Given
    logk =

    504-
    ↳ -

    So the
    corpain a

    Ea 2 303 x212
    R
    =

    X
    :

    I Fa =2 -
    303 x 212 x
    1 987
    :

    ->
    IEth951
    59 .
    Che most

    -
    ⑫ For this
    first order parallel reaction

    ⑬
    A = 3 min

    .
    i
    ↳
    k2
    at 300K .

    If the activation
    energies for
    the
    formation of B

    and a are 30000 & 38514 Janet


    respectively ,

    calculate the which will


    temp at
    ,
    B I a be

    obtained at same molar ratio .

    k, =
    A ,
    e Ea/RT K2
    =

    Are
    FA2/RB

    I
    4 -
    2

    B =
    - =

    e
    = Tae e [Ea ,
    -Ear)/R5

    em(2) = mu2 + Ear


    RT

    =muz-
    *

    x300

    =>

    en(+) = -

    2 .

    54 -
    At ↑ temp [B]
    =

    [C]

    -> k k2
    =

    *
    /RT -

    Ear/RT
    es A,
    =

    Az e

    (Ea -Eaz)/RT
    I =
    e

    en(E)
    Fu , -Far
    - = - -

    RT

    ene
    - - 2

    g
    -
    .

    I
    I
    -

    ⑬ If Ea
    for a reaction is
    given as 30
    lymol"
    calculate temperature co-efficient at 10 %.

    100

    3
    - =
    =

    283K 4+ +

    10

    7 + 10 =293k E

    be
    = [2-s]
    =)
    -
    ⑭ the reaction ↳
    For
    -> B K =
    102 mal's
    A
    K =

    4x102Lmos-
    a

    corresponding activation
    energies of two
    parallel reactions

    respectively
    are &
    100 rea
    eymolt · Calculate

    net

    of
    activation
    energy A .

    Fa =
    EapK,
    -
    + Faskz

    k, k2
    luk
    +

    Ee

    [em (1 +K2)] = ,
    ⑭ k =
    k

    *
    /RT +
    -
    [en (A , e As Fa3)] =

    Er
    Fa
    ()
    *

    4 ()
    ·

    =
    A, e - Are ?
    -
    A.
    FMRT
    + Ace FE/MT
    -

    Kater
    - -
    Ear

    ->
    -15 smolt
    ⑮ The thermal
    decomposition of acctaldehyde
    in
    follows 2nd order Kinetics .

    If
    25
    % decomposed
    men
    5
    min ,
    calculate
    decorpsed ofter
    10

    A - P
    1 -
    =kE t
    =
    0 a O

    [ASE [A]o
    t =
    t a -
    x e

    -7
    ate = kt

    I
    25
    x = -
    a
    100
    ->
    are = t =
    0 .
    25 a

    a -x =
    a -
    0 .

    259
    ->

    I
    x =
    = 0 ·
    75a .

    a
    K = min-
    a

    t =

    10
    - s
    K = 1 -

    t a (a x) -

    Ta we ana
    = A =

    -
    a -
    x

    -
    I ③
    x 2

    I
    a -

    1 =

    2
    G =

    E. : =

    % decomp I %
    .

    x100 =
    40 %

    O
    Q
    6 For the acid
    hydrolysis of sucrose
    ,
    find
    optical rotation
    of the reaction mixture ,
    when the

    reaction
    % complete (Given 0 32 4
    & Op =-14
    1]
    -

    =
    is
    50
    . -

    k
    I in I in
    =

    [AJo
    I

    =>>
    -Or i

    =>> 00-00 =

    200 - 201
    00
    Of =

    ent
    =
    ⑰ For a second order reaction
    ,
    temp ·

    dependence
    of rate constant is
    given as -

    (T 300k)
    -3
    =

    log / =
    + 11 .

    9
    -
    0
    initial come"
    If 0 008 M calculate
    .

    Ea &
    tix.
    ,

    Ea

    logK =

    log A -

    RT -&

    Fe

    any =
    Ea = 3163 x 2 303
    .
    x 8 314
    -

    562 k5 most

    Putting T =

    300 into eq
    :
    N
    log 1 = - 3
    +
    11 .
    9

    =
    1 :

    36

    -> k =
    22 9
    :

    end
    order +=
    As . -0os .
    (3)
    ↳mols- mol

    5 465
    =
    :

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