Draw Lewis structure .

032
-

① ( → valence e- = 24 (
sleepy

C → central atom cslep 2)

& step ( 3,
3 bond → Gvuknceé

24
O/\o -6 Chinese>

↳ periods
JTvalinue-left.jo:2
Gé_c 18
SKPCD Germinal atom
'
o/\o:
'

.
-
-
.
.

step (5) ✗
slept :
to complete ouet of central atom

convert lone to
one
of pair of oxygen
bond pair
 -
O ( 216 )
se
F G
?
-

C = -
2- 4 = o
÷ o
.

4 4 o o
11 A
=
FC =
- -

8 e-
C F c = G I -
G = -
I
T
-
-

SE j -
yo
. .

'

' -

8
.

e
-
. r
. .

J Os
#

6 I G
F
-
C
-
- =

HN 02
=
-
l
O
r .

" as

ive
② N 050

I
-

O
⑥ NOI ( nitrite ) .
-0

x : ii
18 Valente e- 18 -

4=140
I >

:O
- l
-
ii
GE
- I

②✓ Convert
bond
one
lone pair
DM
'

'
to

④ 03 Course)
⑦

: 0=9 .

⑤ HNOZ ( Nitrous acid )

I
18 valence e- is
H -

I .
-

ii=I .

±
E
A 7
H -

I.
-

nite :
Ge central atom
-

- z .

(
⑥ HN 03 ( Nitric an 'd
,
Valence e- =
24 -
8

:O :
'
④
:O :-O M
tot
l

H o n
'
⇐
H -

into:
(
-
- -

. It
④
-
- -

be

-
x → - x -

' -

⑦ Soy l
sulphate ion)

- -

-0
:O :
-0 I
. .

-12
①
. .

:O -
S -
O :
-

y
-

'
- .

→ Lewis slmunre
of soy
:O :
( octet central atom is
complete)
. .

① of

S is 3rd period element ; hence it

have vacant 3d orbital .

 -0
:
:O :
I 11
+2
: S
l
-

E :O → :
SEE :-O
-0
l
-

-
O
. :O
-0
:
?
J:

-0

t, Ecco)
,

µ
sina.int
formal-
(
minimum
charge
) S -
has Expanded octet
( more than 8 e- in valence Sheil,

so more stable .
 -0
's -0
② Poy ③ cloy
' '

:O: :O:
-

I -13
I +3 i . . . .

Cl
-

O
-
O :
I
-
. -
. .

i
-

ftp.o
.

i
I
-
. . -

i. . .

-
l
l :
? :

? :O :
'

.
: i
:O :
-

-
i Il ① 11
-0
: -
P - :
-

O
-

-
-
a=E
i

I
-

- -

I
:
? : -

'

.
O
.
.

'

-0
-0

④ Xefy ⑤ Xeoz

i. E-
I
o -
- -

-
. r

o=Xe=o
'

if -
Xe -
F :

"

11
~ ,

I
-
-
.

O
-

-
F .

'

. .

↳
8-14173=36 Valen e-
'
- E:
I - .

f
.
. .
.

- .

-
'

-
f - Xe -
f -

-
- I

28
,

24
- -

-
-

I
F :
240
.

- -
d) formal
'
'

what is p
charge of
's
in Lem 's structure
-

of Poy

sunshine
-

Lem's sinruuse → Central atom

ampule octet .

Fey p
-

- ti
'

- I
 RESONANCE :

It's a
phenomenon
in which

2 or more possible structure of

species be drawn
given can .

All possible structure

of given
species are called Resonating
structure or canonical form .

Actual structure / true structure

of
species lie in between all
given
and called
Resonating structure as

Resonance Hybrid '

s - =
-73
"
Eixample :
103 S -

:O : :O ? :O :-O o
l l B - o

1) I B.
0=1-33 :
=L 33 -

C E C
c c t,

%
.
.
' -
o-o.fi?o::o!?o
.
.
-
i

i
.

so
B- 0=1-33
s
.

-0 -0
-

Resonance
CI) CI) ¢ Hybrid .
 structure III III →
Resonating structure /
canonical form .

Bond order CBO ) '

It is total no
of
.

covalent bond possible

between two atom .

B O total bonds between 2 atom

no
of
-
= .

ofalltdesunatingstmdure
total number of Resonating structure .

B- O
=
2 = I
( co) 3
z

Bond order a 1-
B -
O = I -
33
Bond length
(C -
o )

Tn ( 032
-

alt C -
o have Equal bind order .

have bind length

'

.
.
all C-0 Equal .
 Features Resonance
of

i) All particular
Resonating structure
of
species are hypothetical .

ii)
position of all atoms in
Resonating
structure must remain same .

O
PH
es cuz -8 -
H Uz=c
-
H

3- 11 2 H -

-
n

Not R S -

as one H atom

to 0
shifted
.

iii) Resonance Hybrid is more stable

writ its
any of Resonating
Slmetnre .

ii ) In Hybrid delocalized IT electron

,

is present
.
 I

Due to delocalization IT e-
charge
of ,

Hence
density decreases and

stability increases .

ii) released
Energy during resonance

called as Resonance Energy ( R E)

-

RE = P -

E -
p E
-

( Hybrid) ( most stable RS)

Iii) There should not be more than

8 electron Valente Snell

in of
2nd Element 041=1
period -

leg :B / CIN /
-

ii. ⑦
H -
C =0 -
H
"
H
carbon cannot form
more than 4 bind .

wrong lewis structure

 Q) Draw and
Resvnanhrng structure

calculate Bond order and charge

density (S )
-

' - -0
)i soy ii) cloy

O O
iii) NO
,
iii) NO
,

O 's -

il iii)
'

clog Poy