BACK BONDING

( also called as ☐ alive IT bond)

# It's a weak IT bond which is

formed within the molecule . It's an

intramolecular bond .

# It is formed due to unequal

sidewise ( it )
overlapping of atomic

orbitals bonded atom

of
.

# It is also called intramolecular

Lewis acid-base interaction .

C0nditionforEffeBaUBonding
# One the bonded atom must have
of
vacant orbital ,
while other atom

must have done pair .

# One
of the bonded atom must be from
2nd period while other atom is either

from 2nd period or 3rd period .

 r

Effat0fBaucBondi#

① Increases stability molecule

of
.

② Increases Bond order ,

Bond
strength ,

Bond but bond decreases

energy length .

③ Bond Angle Increases or remain constant .

IT bond llaterhloreslap .

-
.

( spit
- WIT)
:
F
up -0 I
Armies
i
-

SP B F
①
:
-

:# foe
-

o
O
'

Ii Due to back
y 210 bonding
vacant
ZPCF ) Boron
.

Bfz molecule becomes

orbital of
more stable .

÷÷÷÷¥÷:÷÷÷÷±i÷÷÷
.

:*

=
F
6
mist
BFF others Ltses
-
- -
.

- B- ,
B- .

Stf
.

Sph Bond Angle remains same

 ④ Affects Acidic strength of compound .

* *

B. Fz 343
'
B Brz BIZ

apt tip apt tip of tip at

ftp.#-
Energy gap between 2
overlapping orbital Mses .

i. chances of overlapping of orbital luges

ie strength of Baek
bonding decreases .

Lewis strength ( tendency

'

to e- &
- -
Acid gain
to become stable) Tss .

strength ( BIZ 131383713437 BFD

'

. - Lewis And >

l
strength of Lewis a -

Acid strength of Baek Bonding

⑤ Hybridization can also change
due to Back Bonding .

EI .
Methyl Thio isocyanate
cuz - Ii =L
I Back bonding not
possibly
f
.

t
vacant vacant '
no no N → Sp
orbital .
orbital
①
N = C =S

H lW° c x
<
(B
si I
=

Silyl Thio isocyanate

Coa
Hz Si
ni -
=c=I
90 ⑧
Vacant
u

f ,
Bane Bonding .
occurs .

d-
orbital
IT IT
⇐ N
Hzsi =c=

⑧
- -

↳ sN= let = z ( spy

-
 Similarly Back
bonding occurs in

silyl isocyanate
.

atN' '

Hassi -
=c=o
°
Y vacant
'

d
-

orbital
-
,

⑥ Affects Basic strength of compound .

A) Explain trimethylamine has

why
pyramidal Shape a trisilylamine has
planar shape .

④
is
Explain why trimethylamine
more basic than toisilylamine .

④
Explain why bond angle in trisilyl -

amine is more than

trimethylamine .
 Lewis Base → e- pair donor .

Strong Lewis Base → donate e- pair easily

Weak lens 's Bases will not able -0 d male e-
summon .

pair easily
-

H④ H④
.

Hf Huo KHz
N
X X N

I \ sing
-

nggbaifnnitin tysio
"B

carbon silly

$
(Trimethylamine) ( Tricity ) amine)
'

NO Back bonding d orbital

'

has vacant
-

# N → SPB .
'

. Back
Bonding
occurs .

Pyramidal Shape
lone is
'

pair
fixed
-
-

# done pair us
delocali Sed
Bond Angle 7110-90
. : N → Spt
$
(S -

N = 3-10=3)
due to stearic

repulsion of
methyl group . Bsi\ Wmd Anne .

.
-
-
two

Trigonalshape .

.
N Sing
planar
Sit
.

spz
↳ Bond Angle more than

trimethylamine .
# due to delocalisah.cn lone pair
of
in trisilylamine ,
its
donating ability
decreases due to which basic

strength decreases .

# In trimethylamine , lone pair is

fixed ,
hence its
donating ability
is Basic
'
is more . .
more

than bristly ) amine .

'
'

8) What is hybridization of B and

' '

O in Boric acid -

one
lepdelocalised
P
if 'M zoned
-

,
soy f
fixed
.

I only is
vaunt 1;
13101133 →

Hybrid
l
Toth
-
'
-

Both Y of
"
o-
- -
n

avid
.

H l
H
B. → Sp2
072-1123 (Spy
0=0 Gp2
 BRIDGE BONDI BENT BONDI
BANANA BOND / 3 Centre -25 bond .

( 3L -
2 E)

Electron deficient compound minimises

its electron
deficient nature either

by back bonding or
by bent bond .

① EI Btb ( Borane )

H Back Bonding ( x)
e- defllimtelpg gp2 Bent Bond ( V)

Ht TH
up
.

vacant up avaunt
#BI
→

K "
H t H
µ
N f "

1. Dimerisannm
.

q .name?7sdmm
:÷÷÷÷÷÷:*¥176::
r

no

&
Hbs bridge Hydrogen3C -
-

2e bony
Hts terminal
( Banana shape,
Hydrogen .
 ZBIB → 132126

( Barany ( Diborane,

3C 25 bind B B
# -
-

Hb -

# 2C -
2E bond B -

Ht

In Diborane
# Eam B is gp3
* 132116 is non planar
2- B & lie
4 -
tf on same plane
while 2- Hb lie above a below
plane

# Bond length y > 2

Hey "" "

# 47 B > r ( Bond Angle, a # Bjj ;3/ " '
H
i.
Hi H
p
# Dipole moment, y €0 ( symmetrical
molemkj
# Diborane is stable than Borane
# 132176 So it act
is still e- deficient .

as Lewis kid .
 ② Bfz Effective Back bonding (V )

Bridge band Cx )

Bxz Less effective Baek

bonding µ)
( X=UlBrlI) bond CX )
Bridge

③ BLAB )z : Tri methyl borane

"
nigh
( C
th
BAB
-
-

. '
.
- '
-
-

i.
III
-

B
III stearic repulsion
gleam off
'

lay
-

-
-

active b) w
-

C
-
-
- -

repulsion Hwy 2
bulky methyl
is
aww guys .

unstable
does not Exitts -

Back bonding Cx)

Bridge bond CX ) due to stearic repulsion

Dimerization ( x)
④ At CUB) , 13¥ AKCUB) ,
↳ B
idgebmd

Miz ,
Ctg, ✓
UB
At t Al

HC
IGE C T be
T

3
c ay
u H

a- bond
t 3
centre
-

II
"

Bc C 413
\
AT
"

exist as
-
-

"
.

'

i
i.
Al
-

size of Al > sire

.

4131
YTB
"

" "
B
of
-
" -
.

-
c .

due to which
H H

✓
Stearic repulsion
2. e-
bond .

centre 2
Ctb
-

3 between

group is
very
legs .
 7

⑤ ( Benin
↳ (Be 11272 ☐→ Benz
( said SIMS
gas ( monomer )
polymer
( dimer,
Hosting
H
B
CTWO Vacant Lp orbital

ypym.gg??
>

→ . -

vacant 2P vacant up
( orbital ) ( orbital )

t.fi? e-bmasp3. r-Hi- -.p,erIf3!'spz' i- .H.-

"

" -
-

-
-

Be
-
-

'
" '
'
'
' " -
-

in
-
.

I,
solid ( polymer)
3. C- 25
bond f
cents and)
H - Be t Be -
H
T
H

t
Bridgend
-
-
-
-
'
Hi .

.
?
.

Be
.

H -

.
Ben
'
' -

H
-
-

Spz Spz
- -
.

d
Bridgeboard
( Dimer )

-
ne

H -
Be -11

Sp (monomer)
⑥ At U3
Ah /U→ 3 period
4
• No Balle

ii. -7
i :

/ Bonding .

µ, + Al =

'
II. • e-
-
:&!
"

Dimerization
by www.nalebmd .

3C -4 e-
bind

"
AÉ "

-4A ,
-
"

( Ah 46 )
/gp3T✓sp3\u
.

a
At → has
coordinate
bond
Valiant d orbital
( Non planar
-
structure
so still it art

as unis avid .

Similar with
case obsessed
ABRI .