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/ Bohr's Atomic

- 1 model .

Neil Bohr was first to use planck's


Quantum theory for his structure of
Atom .

All formula derived in Bohrs atomic

model is applicable only for Hydrogen


atom and
Hydrogen like species Cie single
-

e-
species ) II .

He
'
,
hi -12, Best But , Cst etc
,
.

In Bohrs atomic attractive


model
only
force is considered between nucleus and

electron . ( no
repulsion fora between electron

is
as only one e- present)
-
FEI
POSTULATES OF BOHR 'S ATOMIC MODEL .

l l K p
' '
n d r
,
- .
.

T P n
.

'

- O •
A
\
*
- Nucleus

#
N ,
- • Ctu charge)
\ µ •

C z
L •

µ
:
I May
*

I *

/ &

h=5
/ n
g
/ n=6 *

I r

"
r .

's
"
mini .

( shells / orbits 1

stationary orbit ( Energy States /


Energy levels .
i) Electron revolve around
stationary
nucleus in circular path called
orbits ( shells 1 stationary orbit -

Electron
)
ii revolves in a
particular orbit

without radiating energy .


Hence total
electron in particular orbit
energy of
remains constant .

iii Each orbit is


of certain energy
so its also called
energy States /
energy levels .

iii) As value
of n Tss Energy of shell Tse .

( En )

i) Around nucleus
infinite orbit is present
but e- can revolve
only in those
orbit where its momentum
angular
is an integral multiple of
ahq .
ie
Angular momentum is
quantized .

Angular momentum
of e- Cmvr) = nth
21T

Where na orbit no -
s
n
21,213,4 , 5- -

ha 's
planck constant
= 6.626×10-34 IS

A M e- 1st shell I
of
-
=

( rel ) 2 IT

A M E in 2nd shell I
q
-

C. n=2)
IT

Am
of e- in 5th Shen = 51
25
( N=5 )
I

'

Vi) An electron excited by


gets absorbing
Electromagnetic radiation whose photon
energy is equal to
energy difference
states which
of corresponding in

electron transition occurs .

Exited stale

Emen n
⑦-?¥¥*! Energy of photon /DE)
absorbed .

=
Em -
Em
,

¥
Since
,Enz$E#
n , =
Any low
Energy level / Energy state

nu =
Any High Energy level / Energy state

Eh , =
Energy of state ni

Enz =
Energy of state nr
?⃝
'

iii ) Electron in excited state remains

temporarily and after spending


fraction time it return back
of
to its state ie
ground
original
state C ist Sheil as
only one e-

Bohr's model)
present in .

This is called de excitation E


of
-

when electron makes a transition


from any higher Energy level Cm)
to low level XD photon
energy ,
a

is emitted in form of EMR

whose is equal to energy


energy
difference of corresponding States .

in which transition of e- occurs -

AE = Energy of photon emitted


=
Enz - En , = he
×

Em
DEE
# ( photon energy)
I

iiii ) AU excitation of e- occurs in


but
single step , deexeiatioh
can be
of electron multistep .

"

÷:P
'

pn# E" M ( XD

them Em

#
runny EE


photon
(XD

By law
of Conservation
of Energy ,

Energy absorbed
= Energy Released
Excitation deexuilatim
during during

# Ecn , -5ns )
=

DEnz→nz +
DEnz→n ,

-
The = Ih the
X Xi 72

-1
I,t=IT-
Formulate :

H
En ( Total e- in nth shell)
energy of

rn ( radius nth orbit )


of
Vn ( velocity of E in nth orbit)

Tn ( Time period of e- in nth orbit )

f- n ( frequency of revolution
of e-

in nm orbit,

↳ Applicable for single e- species


(H - atom I
HetM3/Bt . -
-
) .

H Spen
-

-
like es -

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