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1¥ ELECTROLYTIC CELL

1-17
A C

N A Qualitative aspect :

O T
mis n * determination
of nature
of pendent
-
mm

0
£

formed
D
.

E
*
analysis of even at cathode Kanode .

electrolyte
[ (molten or
ageousj

conducting
factors affecting
non
all men at electrodes
-

*
tank
.

foam
.

molten
1) nature
of electrolyte molten ageous
÷ or .

Nacl .
Nat a-

Nat Ht H2o
ageoees Wace.
, ,
.

A- 0h H2O .

, ,
electrode → metal electrode & it takes part
attacking v9 cell .ly?egAg ,
Cee , ete .

cell em?
inert - electrodes → do not take
part in
Pt graphite
eg .
,
.
.

dilute Mace

of electrolyte

iii. conch
aconin Nacl .

iv.
charge density flown during electrolysis efdiltksoy

.

impotent points is
always analyse anode been 1st .

iii.
if
electrode is
of metal then
always this particular metal
will
get
oxidised irrespective
of ions present in solution .

dii otherwise mentioned electrodes


) unless
always assume
pt .
Question
An aqueous solution containing one mole per litre each of Ae (N°312 ,
AGN 03 Hgz(
,
NO 3)2 ,
Mg (N°31
is being electrolysed by using inert electrodes. The value of standard potentials are
E° Éait / Cee
E°HgÉ Hg E°Mg2+
◦ 80 ✓ ◦ 79 V 0.34 V
-

2•3V

Agt

/ / mg

/ = = = , =

Ag
, ,
~
Mr

With increasing voltage , the sequence of deposition of metals on cathode will be


a) Ag, Hg, Cu, Mg b) Mg, Cu, Hg, Ag c) Ag, Hg, Cu d) Cu, Hg, Ag
molten ( Pt electrodes
☆ 1) electrolysis of Nacl

anode 4- → a. +

Cathode 2 Natt 2 e- → ZNAISJ .

deposited at cathode .


molten Alas -

3-42+3=5
anode .
36 →

'
6mn £
= cathode Aft + 3. e- → Alls)
II mole substance >
in,
gag
92 2 3-2 → 3-

I →
H2 2

02 4

Ñnoµ- + sent +55 → Mm


"

+ 410 .

-
electrolysis of
(2) aq
Mace (Coney .

④ É .p,yo= -1.229
_

Anode
'

[ OH
, .

- _ .

Efe-1cg =
-

1.36 .

slow
onion
of Hao is
kinetically
?n
soar

extra
voltage is
applied but
doing so . a-

instead
gets oxidised .

Anode Kym ÷ 2U-→qt2 Na h


-

* cathode [ Nat , MIT , Hzo ) Nat →

Cathode even 242201-25-742+204=0


fHᵗt2é -3%2 'S)
* .

as€ welt
↑ so
* pH of som .

trees
* comin
of Nau

Nat remains
* loner
of same .
agnace ( dilute
(3)
electrolysis of → 02+44++45
Adde lad 8- 2420 Imd

then (2) yht


-

cathode % -

24201-25 → Hzt 20h ✗

2m¥
I
.
-

You
result
ph
T④
* as a
.

* .
remains same .

*
V42 = 2
V02 Na →
Aniodeahode
Na-ln
.

electrolysis of ( cathode)
4
using Hg
as
agnace .

even Nat Naltlgs


-

Cathode : tie → .

amalgam
sodium .

Anode MP ? date ?
-

de →
electrolysis of
Noce
using l-GFe.is
f)
MM . Anode [ Ag ,
Cl
-

, H2o ] .
.

Agt
Ag Ag Ages ,
-

→ tie

- Mr n

Nati 420 ]
Nat
cathode [ Agt
in
,
~ ~ .
.

I. →→As
a-
Agtcaa ,
-

tie

Anode
Cuts pure metal ]
gets deposited on cathode .

both
NEE .
8-
if the electrodes are
of Metal M ✗ the
electrolyte
solution
oxidised
is also

and
of
seduced
M.

.
then same metal Muriel
get
anode Cee cathode
Ag Ceesay using Ag →
-

*
.

Anode man :
Agis → Agtlaa, tie _

Cathode Wi Agt last Ages>


' -

. tie → .

↳ deposits on Cee cathode


-
-

feeders
electroplating
ta this is

* net [ Agt] is
zero
.

[ ait] 6042] pH
* . no
change ,
no
change ,
no
change .

electrodes
electrolysis of
dil Pt
11¥ CIBR] blog
using .

using low-wage density ( electrolysis of


1) - → water .

anode 2420 → 021-44++45 .

Cathode 1- 425 Hat 204 ?


2h20 →
usinfrhighchaege density -

25
anode even Hsoy lag) →
Hzszoset .

fseeoxydisubphuue acid .

O O

$-5 -5
§g→H
' '
Ho
au-g.tn
- -

8
-

Cathode rpm 8- 2h20 / e) 1- 25 > HI +204 laws . .

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