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1-17
A C
N A Qualitative aspect :
O T
mis n * determination
of nature
of pendent
-
mm
0
£
formed
D
.
E
*
analysis of even at cathode Kanode .
electrolyte
[ (molten or
ageousj
conducting
factors affecting
non
all men at electrodes
-
*
tank
.
foam
.
molten
1) nature
of electrolyte molten ageous
÷ or .
Nacl .
Nat a-
Nat Ht H2o
ageoees Wace.
, ,
.
A- 0h H2O .
, ,
electrode → metal electrode & it takes part
attacking v9 cell .ly?egAg ,
Cee , ete .
cell em?
inert - electrodes → do not take
part in
Pt graphite
eg .
,
.
.
dilute Mace
of electrolyte
→
iii. conch
aconin Nacl .
iv.
charge density flown during electrolysis efdiltksoy
→
.
impotent points is
always analyse anode been 1st .
iii.
if
electrode is
of metal then
always this particular metal
will
get
oxidised irrespective
of ions present in solution .
2•3V
Agt
•
/ / mg
•
/ = = = , =
Ag
, ,
~
Mr
anode 4- → a. +
deposited at cathode .
⑨
molten Alas -
3-42+3=5
anode .
36 →
'
6mn £
= cathode Aft + 3. e- → Alls)
II mole substance >
in,
gag
92 2 3-2 → 3-
I →
H2 2
02 4
+ 410 .
-
electrolysis of
(2) aq
Mace (Coney .
④ É .p,yo= -1.229
_
Anode
'
[ OH
, .
- _ .
Efe-1cg =
-
1.36 .
slow
onion
of Hao is
kinetically
?n
soar
extra
voltage is
applied but
doing so . a-
instead
gets oxidised .
as€ welt
↑ so
* pH of som .
trees
* comin
of Nau
Nat remains
* loner
of same .
agnace ( dilute
(3)
electrolysis of → 02+44++45
Adde lad 8- 2420 Imd
cathode % -
2m¥
I
.
-
You
result
ph
T④
* as a
.
* .
remains same .
*
V42 = 2
V02 Na →
Aniodeahode
Na-ln
.
electrolysis of ( cathode)
4
using Hg
as
agnace .
Cathode : tie → .
amalgam
sodium .
Anode MP ? date ?
-
de →
electrolysis of
Noce
using l-GFe.is
f)
MM . Anode [ Ag ,
Cl
-
, H2o ] .
.
Agt
Ag Ag Ages ,
-
→ tie
- Mr n
Nati 420 ]
Nat
cathode [ Agt
in
,
~ ~ .
.
I. →→As
a-
Agtcaa ,
-
tie
↓
Anode
Cuts pure metal ]
gets deposited on cathode .
both
NEE .
8-
if the electrodes are
of Metal M ✗ the
electrolyte
solution
oxidised
is also
and
of
seduced
M.
.
then same metal Muriel
get
anode Cee cathode
Ag Ceesay using Ag →
-
*
.
Anode man :
Agis → Agtlaa, tie _
. tie → .
feeders
electroplating
ta this is
* net [ Agt] is
zero
.
[ ait] 6042] pH
* . no
change ,
no
change ,
no
change .
electrodes
electrolysis of
dil Pt
11¥ CIBR] blog
using .
25
anode even Hsoy lag) →
Hzszoset .
fseeoxydisubphuue acid .
O O
$-5 -5
§g→H
' '
Ho
au-g.tn
- -
8
-