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Transition MetalS

→ An element that forms at East One stable ion with a partial y And
d sub Shell
-

(partial ky ta d sub Shell )

* 해 contan s hN d sub Shell of 대기 3010 When formng Et

Variable acid aton States


-

An transition Metal s Show an acid at on State et2


Transition Metal share 2 election s in The its sub Shell ,
re moral of 2 election s

generator tz

successin LE for V IN453 di


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f
fr Noble gas
→ Emotion of +3 or +4

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Catalyst ① Fe in Hate process Fan
3M (97 t 한 T 2NH319)

Catalyst Will he in difference State
from The reactor nts ② VW) oxide in contract process W. (s )

I 2503 (g)
Reactor Minutes arrb 2802 ( g) t 02cg)
on to Me
③ Ni hydrogenaton
Surface of The Catalyst for ra en
in reactions Ni es )

HOMOgenus Catalyst GH5 cm


t
쐐) t (대. ( 9)

he in same State Ma da ㅮ ④
→ Catalyst Will AS MUD oxide with hydrogen particle Miss
variable 에 Numbers → Cardinal with Other Minutes 2H20 (aq) - > 제204 ) t 02cg)

Complex ions

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ans ist of a Central Metal Ton s


Neutral maeculesoranionswhichcontainanon-bond.mg pair of elections
Election form coordinatecovale.int bond s with The Metal ion form

pairs to

Complex ion S

→ Wordin a te number : number of I One pairs bond to that Metal ion

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ng Bia ma Hex
Only pair pair
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pair
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use 2 tone s to form -
use 6 tone s to

wvaentmondtovmwrdinatewvalentb.net
form cordin attwvat.int
cardiac
to The Metal ion bond to Here Metal ion to Here Metal ion

e.g) ethylenediam.int 이
EDTIN.ofligandsshapesofwmpu.org
e.g) H20 and CN
-

( H2N대2대2NH2)

에惑 4 termedral /

Square mana
r
neutron ligandsi.tw
HisandS : C T.CN
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NH3
-
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Br
Magnetic pwpert.es
- Transition Metal s and their Complexes that wntainunpairedeleetonscanexhibitmagne.im
FewmagneticM

Permanent type of
magnetism-sunpaire.cl
alias Parallel election scan to each other in
span of nhether an

external magnetic find is


Present
e.g) Fe , Co , Ni

Para magnetic
→ When transition Metal compass have United election s

The
spinningunpaire.cl

election s created Small magnetic held that an al im
with an Applied magnetic Field

Di
magnetic
→ When transition Metal Complexes have omypaire.cl election s

Spinning of Canal each other Out


→ The
Paint election S

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para magnetic → nia magnetic

Color of transition Metal S * cow less compound


set ,
Ti 내
→ N election in The
d sub Shell ; Impossible
to alsob Energy

Cut 해라 → 10 3d election
Since
,

Space in The

Upper set of Orbitals

→ As isand cause d Orbitals to split into 2 set

Energy in The form of a certain frequency of visible Light Can De a based to

Pro mole an election from The Lower set of Orbitals to nigner set

→ Energy gap comes points to Light in The visible •

regime of The Spectrum


of The substance
Happen
→ Color wi

to an Observer as Me

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d
Split ng of of Orbitals
Greater difference in even between The Lower and Water set of d Orbital s
⇒ Higher frequency ( www.vavelengmoflightabsorbed

→ partial y All at Orbital


LigandS
L1-0 → Act as a Lewis Base and bond
to mental ion

On a is
of -
Axis

viaordinateldativebono.ly
(2) ( 3)
Y
l

ex te
z z

E to
ng and given
ion

axisdirectionsdovb.ms
→ Ligand bond from
cannot

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"
.

sie
-

M제 vs

E
n

bit
in s ta bity
-

Y2세대

split 5 d Orbital s
3 LOW EL
} △E ⇒ A of visible Light

Factorsatfeangtnea.IO r of transition Metal s

Nature of transition element oxideon State of Metal ion

→ Different Nations have diffoe.int election →


Different election Configurations for ions

consulrations Higher Metal



charge on Ion causes
→ Different arrangeme.ms of election s Give Greater split ng of d Orbitals

differentwwrsduetodifferentamountsofrepuls.in
ne to
1호라
between ions 의 (aq)

pad Green 뺎 →
pole Violet


Higher Nuclear charge on mental ion of
same andan on State causes
Greater split ng
of d OrbitalS

Identity of ngands Stereo Chemistry of The Complex


(Shape of The motivation )
Is peetwchemicalsevie.SI

smanerspittingdue.to Strong find ngand


- :

Lower charge density


aspnpairdweak-fie.la
ng Configurationands :
Adopt
as

Act
H causes a Greater
ptaspin.ae
Split between The
Configuration as they cause
d Orbitals
Small or split between
d -
Orbitals

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