t.

me/neetpreparationadda247
* D-BLOCK

lost centers
** in a subshell

43
*
to 412

# 3d series -> P4

ud series->P5

5 sais=) P6

(-1)dongo-2
*

I ↳ valence shell
penultimate shell

t.me/neetpreparationadda247
 *
(n-1)d-10ns
General Electronic 0 -2
8 -

Configuration
d-orbital
elements:-incompetely
Transition filled ovidationstate.
&

either in GS or in

"
c Ar] 3d as 95

cut Ar]3d"us" onidation state

t.me/neetpreparationadda247
 Not transition element
912
Mg
In ad

psuedo Tinsition element

zu Ar] 3d' use as

Zutz Ar] 3d uso OS

t.me/neetpreparationadda247
D-BLOCK

3d series Sa 30

4 period -
zu
39 48

5 period no series- Y Cd

57 72 88
~a period 50 series - La I
My Hg
89
=* period od series - As, By an"2
Lauthanads- 2: 58 71PSG3
to
FBLOCK
90 to 103
Actinoids ->2= p=G

t.me/neetpreparationadda247
So Ti VG Mn Fe Co Ni L zu 3d
3
3d 305 3d5 3d 3d7 3dt 3d 3d
3d 3d

us us us 41 use 4s" is use us' us

uc
4 To No No TC Ru Rh Pd
2010
Agd10 Co
4

58058582
Ta Re Pt An 5d
La
Hy
W Os Ir
Hg
509 5dO 5 d'O

6868 6

t.me/neetpreparationadda247
 Zu

Properties:
-

Coh
-

-
--

do not
↳
High
Tensile We
Mg
I
-> mallabable
-
I
Ductile
-
-
My
crystal
e
↳ Lustere
I

↳
High
Thermal and
-
conductivity
electrical
↳ Less volatile
-
-

t.me/neetpreparationadda247
#MP and BP 8-

e- => metallic
More is bonding
of
More no value

ef
Surfaced
96 912

Gr
max no.
of zu Min BP/MP

unfaced
S

e Cd
Mo
W
Max BP/MP ug

t.me/neetpreparationadda247
 96
4t sudden
drof
*

MP/BU

t.me/neetpreparationadda247
#
Enthalpy of
atomisation ->
energy required to break

inter
convert
metal I
lattice
atom
gaseous
3d series Vanadium MAX

X X X-

X X X- x(g)
X X X-Anatomisation
t.me/neetpreparationadda247
# Atomic Size
Ti)v> G> Mm FecoNiGluLIn
3d series
>
- Sc)
Ze screwing
Zoff> scuning
affect effery effel
effect
2 Factors -
*

3d < 4d5d
i) size x 1

<eff contraction
Lanthroid

ii) size ↳
a
effect
screening
Poor
screening
orbitals
t.me/neetpreparationadda247 of $o
a
 267
Conisation
#
Energy
>V<G[Mn Fe) (o)Nicu(
↳
an Se < Ti in

Series

912
intron
In
confignitionfully file
is abide

Highestt STABLE
IEa G > Mm

IE2 a Cu r] 3d' us" Get Mnt

3d5 3d54s"
Cut AAr] 3d" us" LE
High
t.me/neetpreparationadda247
# Ouidation
State
OS
variable
↳ All d-block element show

Sc and In
except Man OS = + 8

↓ ↓ Os Ru
+3 + 2

3d series
Se Ti V Ge Ma Fe Co Ni an in

+2 2 2 +2 + 1
th
+

2 +2
+

3 +2
+

+3 +3 3
+ 3
+

+2
+3 3
+ 3
+

+4 4 + 4 4
+
+

+ 4 + 4 +4
+ +y
+ 5 5
6
+

+ 6
+ 6
+
7

t.me/neetpreparationadda247
# Halides
and Oxides

Halide
* -
--

Ti v Ge Mn Fe Co Ni a zu
Su

TiXa VX2 GX1 MmX2 Fexz CoXa NiXz(uX inNe

X
TiXs UXs GXs MuFs FeXs COFs Waxe
NO
Halide TiXy MuFy
UXy Gy ·

VU5X
VF5 GES
GF6
ME
MnF7
X
I allowed Steric hindrance
·; small
of size
--
-

t.me/neetpreparationadda247
MnF7 exist.
*
does,not Mn does not
go
to +10s

Stuvi hindrance with

Fluorine
F -F
Why? -
F
Mn
/
⑰7
F -

XF
F

MnOzF exists
forms
Mn +5 OS
·of abilityofonygen
*

multiple bod

Why?
to
form
I
-7
with
onygen
Mn
·*
Yo

#
t.me/neetpreparationadda247
 cuza exist exapt (urI2

and
Cut
compound
unstable
eg.
in medium
undergoes
-
↑

disproportionalioin
2ctlag-> cit(aq)
+
(uls)
HEX
charge
stable
size
-

unstable
-
⑳

I due
high
to
In medium,
aqueous hydration enugy
cute cut
more stable then
is

t.me/neetpreparationadda247
Oxide
3d series

V De Mn Fe Co Ni a zu
Se Ti
MO FCO COO Nio GO
TiO VO GO TO
Sea0z
VaUs G20s MnzO3 FezOs C020s C20
TizUs
TiOL VeOy GOz MnOz FezOy
↳ mixed ovide
V205 MusOy FeO.
+2
Fez03
+3

GO3 Mn207

t.me/neetpreparationadda247
#MagneteiProperty
Diamagnetic Paramagnetic Ferromagnet
-> o
unpaid
eatest
unfaind
e-
one

Attraction by magnetic my stron

-
->
repelled by magnetic- alleaction
-

fold
-

feld

t.me/neetpreparationadda247
 of comfound:
it Icongres
#colors -

kMnOy Coloured
unfainde 6
+
*

of

at
unford-
&

No

&11 11
-

charge bausfu color

d-d transition ab

t.me/neetpreparationadda247
#Catalylin Property: Reason
-

· variable
they
↳ show os.
-

Process8 -V205
Contact
R Block
-
process.
Habe's - Fe

-NilPtPd
Hydrogenation:
Fetz Fet

t.me/neetpreparationadda247
 *
H, C, B, N
# Intestial
compounds:
-

YAAD
-

① -
-

* VOIDS

⑪I h
MPX
High
->

hard
very
->

·:: 1..I
⑪ - -
x
->

->
chemically
Have metallic
inet *

~
-
conductively
-

t.me/neetpreparationadda247
# ALLOY FORMATION
↳ Mixture 2 or more metals
of
↳ size metals should be almost
To
form alloy, of same.
BRASS - G+ zu
YAAD

:- Ge + Sn
BRONZE

Gun metal: -
Cut Su + In

human Silves: - G+ In+ Ni

t.me/neetpreparationadda247
 Electrode Potential electronic
A configuration
-

MCERT
↳ reduction
potential

Eine
AG =
= nF Ear
Nitz

Spontaneous 1440=> Eve >O ↓ high

-

Run
Mogi ve
-

Ni
Elected
1470 Fall 20
spontaneous
-

Now =>
Potential
↑

Rxn Nahi
Moge
t.me/neetpreparationadda247
 2
Mn
+
*
Mn Emnt/Mn= -
ve

[Ar]3d5
STABLE

* Zuth -> In
Eatlan-- ve
[Ar]3d
STABLE

t.me/neetpreparationadda247
 Sets Sath
->
Esc/st=- ve
*

Ar] 3d'us
STABLE

*Int -> Inth Eznt3/zi= A ve

[Ar] 3d9 [Ar] 3d

STABLE

t.me/neetpreparationadda247
 6
Ondising Agent
+

# Dichromate
Potassium K2G2Oy
Chromite soda
PREPERATION ore +
Washing
FeGzOn Mar203

1) FeGOut NacCOz +Oz

->
NazGOn + FezO3 + CO2

yellow
So
a) NazGOy + [H+] ->
Na,Gy07
Sodium
Dichromate

t.me/neetpreparationadda247
3) NazGz07 Kah -
K2G207 t Mach

Potassium
Dichromate Orange
2
-

*
GOy G20y-
*

chromate Dichromate
O- ⑧ 0

GOy2- GOy- I
0 G
11
0 -
11
4 0

for o E io]
-

-
-Gig
=
=
-

2
1 - -
-

+ 6
-
cr-0- Go I
-

t.me/neetpreparationadda247
 *
I
2 H
GOR
-

GOy -
-

yellow Of
orange
KO7=> strong
odising agent
acidi
in
-

media
-

+6 I
Ht Ct3
K2G207 I ->

t.me/neetpreparationadda247
 -

I I2
-
20
HeS -> S

⑫
Su - Su
Fe- Fr
CLOy2- -> CO2
+ 3 +Y

t.me/neetpreparationadda247
 Test
chloride
#
Chromyl
metal chloride com.
+

U2SO4+Y2GaUI

d
* GO2Uz chloride
chromyl
-
-
-

Red
vapour

t.me/neetpreparationadda247
# Potassium
Pumanganate (Mon) ordingent
Preparation
--
-
Mn0z=> Pyrolusite ore

Ma02 I YOU + or
-
kaMnOnw
Manganate Jon
(Mont
+I
6
+

Ht
+
4
Disproport
2
MaOy Mas
-

MaOy -> I + 428

Permangarate
Purple

t.me/neetpreparationadda247
 Prepare
Commercial
Fused with YOU 2 -

MnO2 -> MnOy

+
with
oxidise

Air or UNO3 Manganate

electrolytic
-

2-
MeOy -
MO
oudali
Permanganat
--

t.me/neetpreparationadda247
Lab
-
-

+2
Mn I SaO2--> MuO+ SOr

Permanganate
-

t.me/neetpreparationadda247
 Manganate 2
-
Permanganate
MnOy MaOn-
+6 0 1
change
- +

i S
I

unfared Yo Transfer
Mu
Mu
o- ·* -

i
-
o
e
3d" 3 do

Paramagnetic
-

Diamagneti
GREEN PURPLE

t.me/neetpreparationadda247
 KMnOy in medium
Acidic NOA 8 -

⑧
-

5 +1 ⑰ don't He in
ng We use
= -

MeOn -> Mu
+Y acidic
medie
+3 2 -

CaOu ->
CO2 + 2
Mu
HCL+ KNOy ->
⑫
Fe -> Fe +(2
= 0
I-> 22
⑰ ⑧
S -> S
⑭ 2-
0
6+

sOb -
SOy
2 -

t.me/neetpreparationadda247
 medium
KMnDy Neutral
in

+7
vary slight alkaline

+4
Mu
KMaOy ->

CaDy" -> CO2

gar ->
5
+

I
->

103 Redox
-
-
n.xny,=42xy
-
↑

↳ Tration

t.me/neetpreparationadda247
NOTWA 8 -

-
-

Basic -Oz => Basic

Lower OS =>

NCERT
Intumediate OS=>
Amphoter V2O5=> Amphoteric -

Os -> Acidic GO=> Basic

Higher
+ 6 +6

HaGon
G20z=>Amphotic
GOz +428-
GO Audi
+7 +7

Mu207 +420 ->

HMnOy MuxU7=> Auchi

Acidit

t.me/neetpreparationadda247
 D- BLOCK

FINISH

t.me/neetpreparationadda247