Unit 2 Review Key !

Name: ______________________________

Things to consider…

1. Have you looked at old AP tests? – The correct way is to take the test problems and then check your
work. Whatever you get wrong ask Mr. Bear or figure it out. Look for commonalities.

2. Look at the CED documents attached to this review- make sure you are good with each item.

3. Look at the task verbs. Familiarize yourself with them.

As a sidebar- the AP people consider a class period 45 minutes +/- 3 minutes. So we did spend 13 class periods
on this unit.

Vocabulary Words- I am sure quizlets

already exist for AP Chemistry Unit 2 Vocab:
 1. Electronegativity 10. Electron sea 19. Bond length
2. Ionic bond 11. Delocalized electrons 20. Bond Energy
3. Cation 12. Substitutional Alloy 21. Resonance Structure
4. Anion 13. Interstitial Alloy 22. Formal charge
5. Lattice 14. Polar Covalent Bond 23. Molecular Geometry IVSEPR)
6. Lattice energy 15. Nonpolar Covalent Bond 24. Polar vs Nonpolar Molecule
7. Coulomb’s Law 16. Dipole 25. Bond hybridization
8. Metallic Bond 17. Lewis Dot Structure 26. Sigma bond
9. Alloy 18. Bond order 27. Pi bond
bonds
↳
singletdoublet triple
-
higher bond
order
Some Additional Book Problems- It is common for odd #’ed book problems to have answers in the back of
textbooks- these I imagine are no exception.

Pg 404: #’s – 7, 19, 27, 29, 33, 35, 45, 55, 83, 87, 113, 115

Pg 444: #’s – 23, 39, 71

Here’s some extra practice as well.

1. Please draw particle diagrams for the following.

LiBr LiBr dissolved in water Ag (metal) 0 Ag B alloy

① Br O
-
°
-
-

⑤ ' Na ①
①
① to -0 -0
0000
① ① to ①
oooo
00.00
-00--0 to ① 0000 8888
①
① -0

2. Rank the following bonds from most polar to least polar with estimation.
diecast ← most

F-F F-Cl F-Br

p
mid
3. Rank the following bonds from most polar to least polar with estimation.

Cl-Na Cl-Si Cl-B

Lost feast mtid
4. Label the compounds below as ionic, covalent, and metallic.
I C I M I
a. NaOH b. CO c. CoBr d. AuO e. CuBr f. CuAg M

5. Circle the molecules below that have polar bonds but nonpolar molecules.
 Qi page
octahedral
see Prew
linear
.

tetra trigonal

:t÷÷÷÷÷÷÷÷÷÷÷÷÷
.

a. H2O b. F2 c. SF6 d. CO2 e. CF4 f. NF4

pyramidal
bent linear

"n
:÷÷i: in : ÷ .
molecule : polar nonpolar nonpolar nonpolar nonpolar
6. Complete the Lewis structure below. Then complete any resonance structures. Find the formal charge
on all of the C’s and O’s. Lastly, label the arrows and partial charges of each bond that requires it.

qtr! }~
HO Ho

H
°

:
"
O: I +1
,
bonding
ol
=
17 ←
1 11
• C C -
H :c -
C -

H
IN o O -

l l O O

4. 12+42161 )
° H OH

a. What is the hybridization on each C in the original drawing?

both spz
b. Which structure is most likely the correct structure? Why?

left → all o formal charge

c. What are the bond angles associated with the left-most carbon in the original drawing?

spytrig planar = 1200

7. Rank the compounds based on lattice energy. NaCl NaF

strongest
NaBr
weakest I
increases
r

8. Rank the compounds based on lattice energy. MgO MgF2 Mg3N2

+ 2 -
Z +2 -
I t 2 -

3
. -
Coulomb's Law
-
weakest greatest
(for 788)
9. In the image below.
3
a. What is the hybridization of the C in each structure? sp x sp
b. How many sigma and pi bonds exist in each molecule? b ol OT t
20/2 IT
c. Draw and label polarity arrows with +/- charges in the bonds that require it.
d. What is the molecular geometry of HCN? linear
e.
- In the space underneath please draw 1 resonance structure for HCN.

t
g
ex
¥ →

f a

St

Ishii tar radius

10. Will an alloy between Cu and Fe be interstitial or substitutional? _________________-

11. Which molecular geometries are nonpolar when all atoms around the central atom are the same?

-
linear

trig planar
-

- tetrahedral
-

trigonal pyramidal
bi

-
octahedral
-
square planar