.

CO
2023
its equilibrium constant

↑2 + 342 - 2NB

Sidel it
↑ [units
-Wit)
[more/(r)
2 -

[1 3]
+

(mote/cit)
Generally unit
of ke- (mole/lit)"
where (an I
up - [4p)
=

= at
[r+3]
=

Cath)2-
Cali;
Generally-unit of
·
=
or

(Barton
Relationship between
kp and Ke
- - - - -

aA + bB -
- cc + dD

kp =

epe Py= uRT

P =
cRT
 .. p =

essa lesSee
(2 + d) -
(a +

b)
kp =

K .

[R3)
:

Ste
(r)
2
④ 40 alm
-

reaction
For a
particular ·
kp
=
at
----

ezy'c · calculate Ra (with unit)

--- R =
0 ·
08

40 atm2 Un =
1
↳a hi wolt
p
=

↑p
=

ke(RT)2

6
2
40 =
He .
08 x
500)
=
Ke Yo

-
I (mote/cit 0 .
025
⑨ is applicable
log kp +
2log
RT =

by ke
reactions
for which
of the
following .

⑳ 2502(8) + 02 (8) = 280 (8)

⑥ N2(8) + 3m(8S -
I
I NB (8)
& cusoy -

3520 +2120 # Cusoy . 510 .

log kp +

Log RT =

logke
->)
log up +
log(RT)=logie
-
log [kp (4, 25 log I
=

-]
kp (R3) =

Ke

kp
=

ke (F-

: On =- 2

⑰ An
= 2 -

3 =
-
1 X

⑧ an =
e -
4 = -
2 -

① an 1 3
X
=

2
- = -

option b
 Propertiesof quiliumcost
⑳ M 3
BT
ke =

[A]

I the reaction exewsed

gets
~

=
si

A
i
-
B I Nt =

The
equilibrium constant becomes its own

reaction
reciprocal if is reversed .

② ↑ F 13
↑ p
=

I
A

NA i
m
his n

kp'- A
=
kp

Multiplying a reaction
eq b in'
gives
y ,

the new
equilibrium const oth order
of
-

the

original-
③ A +

B =
c +
D
= Este
E
- F

-
kez =

Es
-
A + B + E + D + k

Me- test e e
④ Effect
- - -
of denp on
Keg
FIRT
-
Arrhenius
eq
R =

Ac
↑
# B
A
Rb

Reg =

I =

errorist
[(Ea)f Ean]/RT
se
-
·

hu
=
/ - 0
Taking
-

en()
he
keg =
-

-
ukeg lots

Exothermic & A <O Endothermic

- -
WwH>0

I I
Stope--Ort

e
E
are
Intere

en v en
CerH
ena stope E

Intercept en
I I
 ⑱
-significance
-g
Exothermic - Inversely
-
related .

Endothermic

tregt Directly
-
-

related .

Differentiating eq *
c . r
. t
-

Keq2

S see -I e
kea , T

- -
-
:

17
;
-
-

--
↳-
WrH

S of
Both .
different
forms
are
eq

KMatter
~H = in
change reaction-ensually which

is
nothing
but
energy [heaty released or absorbed

at constant pressure
= ⑧
-mogeneous eqirium When all the reaction

species are in the same phase-

Phase
-
is part of a
system which has
uniform
composition
&
25 (8) - Pay (8) +
e
(8)
equin
geneous
& BC00245 + to - C3coon (9) -
neit
[s ga

Phase I

Homogeneous equi
Heterogenous" Reaction species are in

different phases
↑ 2 3

⑳ ·acos(S) F Cao(s) + Co2 (9)

Phase- ? B

Heterogeneous eq
⑬ =c -
-
water
phase = 2
⑰ 5 A (8) = B (8) + <
(8) +D(8) ,
Re =:
27
* Calculate
If of 'B' af 3
moles
equ
=
no : .

initial moles
of A taken in the

container /

3A
> B +
c
F
+

a -
3x x e e

B 3 3
a -

be = 2

- = 3
a -
9

39 - 27 =
3

to