=

KCP ] Taj

P block C̲ i ̲r ̲c̲l ̲e̲

t.AM#-'-zd A+-- 'zdBdldB
It
=
-

£3 %¥-

P block C̲ i ̲r ̲c̲l ̲e̲

@
0.3×10-4
d¥#
-

0 -
I
"

1*01×15
d [ 1-11-13 ]
at
= ?
5- [ {) =

=o.2✗
d4ᵗ %s
]
÷ 3-
-

P block C̲ i ̲r ̲c̲l ̲e̲

 =

£dCN2 ted daˢ

-

=
=

dt

ARE

P block C̲ i ̲r ̲c̲l ̲e̲

Order = I + 2

=
3

P block C̲ i ̲r ̲c̲l ̲e̲

 Unit of k ( rate constant )

A → B

molt 's
-1
Unit Rate
of
"

Rate = k [ A]

R =
Rate = 0Mt
of
Rate
of Rxn

[ Ayn ( unit
"

of conch )

K =
molL-
n
( moi 1)
-

(
' n ' '
Ln
-

)
-

k 5 is
= moi n order
of Rxn

P block C̲ i ̲r ̲c̲l ̲e̲

 's
' _
" " "
Unit K : met L
of
' n -
t
For
-

Gaseous Rxn 8 atm s

Order
Differential Rate law Unit of R

° ' l
[
-

o u = k [ A) moi s

' '
I r = k [ A] Sei

'
l
moé L'
≥ -

2 a = k [ A ] s
' '
r = RCA ] [ B)
≥ °

r = K [ A] [ B)

P block C̲ i ̲r ̲c̲l ̲e̲

NOTE :

= Rate Reaction
constant depends
of only
on
Temperature .

Unit Order
of Rate constant depends upon
the Reaction
of
.

P block C̲ i ̲r ̲c̲l ̲e̲

 Molecularity

Theoretical
Quantity
◦

Applicable Reaction (
for Elementary single step Rain
◦

is
molecularity number
of Reacting species
◦

( atoms
,
ions
,
molecules )
taking part
wi which
an
elementary Reaction must

collide
simultaneously in order to
form Product -

stoichiometric
It
Equal to sum
of coefficient
◦
is

Reactants >
of
.

P block C̲ i ̲r ̲c̲l ̲e̲

◦
can be 1
,
2 and 3

Reaction
molecularity
◦
with 3 and more

are
very
rare because
of
low
probability
of simultaneous collision
of an
species

Example 8

Molecularity
NHYNOZ → Nz 1- 21-120 UÑmo secular

21-11 → 1-12 -1 12 2 Bimolecular

3
2^10 1- Oz → 211102 Tell molecular

P block C̲ i ̲r ̲c̲l ̲e̲

 Reaction can be

↓ ↓

Elementary Complex
Reaction Reaction

◦ one
step Reaction ◦
Multistep Reaction

◦
Reactant → Product
◦
1) Reactant Intermediate

2) Intermediate ᵗ Product

N :
molecularity = order
of
Rxn . Rate of complex Reaction

depends upon slowest step

P blockof Ren .

C̲ i ̲r ̲c̲l ̲e̲
% Slowest
step complex Reaction called
"
of is as
"
RDS Rate
determining step .

P block C̲ i ̲r ̲c̲l ̲e̲

A
At B - P

P block C̲ i ̲r ̲c̲l ̲e̲

ow

P block C̲ i ̲r ̲c̲l ̲e̲

 I-12
≥

a) Rate = R [ Hcroj ] [ [ at ]

1
-

Order Hcrou
with respect to =

2
-

" I =

=
2
" H -1

Overall Order = 5

P block C̲ i ̲r ̲c̲l ̲e̲

 Ran =2
→ Order
of

Rate = KENO ]ʰ [ Hz ] 't

1) 3×10-5 =
R [ 5×10-3 ]ʰ [2-5×10-3] 't
"
2.) 9 ✗ 10-5 =
k [ 15×10-3 ] [2.5×10-3] 't
3) 3.6×10-4 = R [ 15×10-3 ]n [ 10×10-337

P block C̲ i ̲r ̲c̲l ̲e̲

 and
Using
1 2
,

9✗
-
s
= I
3×0

K
3 = 3

lx

and
Using
2 3 ,

3. 6
-
✗ 10-4
= ? )
}
&

a ✗ ios

u = y Y

P block C̲ i ̲r ̲c̲l ̲e̲

?⃝
 C

a) Order
of Ran = 2 =

>c+y

b) 1- :

3×10-5 =
k (5×10-3) (2-5×10-3)

k =
3×10-52
5×10-3 ✗ 2.5×10-3

k =
2.4

c) mate = k [ NO ] ( Hz ]

(8×10-3) (8×10-3)
BE
= 2- 4 ✗
=

P block C̲ i ̲r ̲c̲l ̲e̲

HE

P block C̲ i ̲r ̲c̲l ̲e̲

AMI
'
's
_

Rate
-

: moll

Zero order = moti 's -1

I I
Moll n
Ln
- -

g-

mo1
= 0

P block C̲ i ̲r ̲c̲l ̲e̲

 Integrated. Rate law
nth order Rxn ( n ≠ 1)

A → B

"

Rate = R [ A ]

Rate =
-

dA_ ( Differential Rate law )

at

1ntegrEw :

P block C̲ i ̲r ̲c̲l ̲e̲

 "
-

dCA]_ =
RCA ]
dt

d =
-
kdt

(A)
n

At t

f d
ga ,
=
-
k
/ dt

Ao 0

da =
?

fñndn ( Y)
=
08

grindr ?
=

P block C̲ i ̲r ̲c̲l ̲e̲

 t

Atf d
(A)
n
=
-

O
fdt
Ao

"

( Yy
= -

rat

Ao

,±n( )
' -

n ' -
"
← General
At Ao bet
Expression
-
= -

nth Order Rxn

Cn -1-1)
' -

n ' n

(i
-

At -

Ao = - -
n )kt

P block C̲ i ̲r ̲c̲l ̲e̲

 8 At Ao Rt
a) Zero order =
-
-

1M¥ /Ao-At=k-

b) Second Order :
" '

At -
Ai =
-

( i -
n ) Rt

-
1-
Ao
=
Rt

-
/

P block C̲ i ̲r ̲c̲l ̲e̲

 Zero Order Kinetics

A → Product

rate = k [ A)

↳ rate = k

-
↳ rate = k =
-

( =)
"
↳ Ao At Rt Ao conc at
of A time 1-
=
- =

At conch at time t
of A
=

( At = Ao -

Rt
)
P block C̲ i ̲r ̲c̲l ̲e̲
 Ren : 2A → B ( Zero Orden )
=

rate KCA ]°
g- &¥
= =
-

°
-

1- dA_ R (A) = R
=

2 dt

d_A =
2 R
-

dt

At

/ DA =

-12 kdt

Ao P block C̲ i ̲r ̲c̲l ̲e̲

 At -
A ◦ =
-

2kt

A◦-At=2
Generally Zero order Rxn
PA
: → B

Ao-At=p

P block C̲ i ̲r ̲c̲l ̲e̲

?⃝
 1.) Rate vs [ A]

Rate = k
°
Rate = R (A)
Rate
Rate =
R

Rate is independent of
[ Concentration Reactant
A]
of .

2) [ A ) Vs time •
[ A) ◦

g) ope =
-

k
At = Ao -
Rt
(A)
ma + c
y
=

Slope =
-

P block
time
C̲ i ̲r ̲c̲l ̲e̲
Half life ( tik )

Time taken for 50% completion of the Reaction

Initial Conch Ao

Final Conch ( At ) =

At = Ao -
Rt

Ao Rt
¥
-

P block C̲ i ̲r ̲c̲l ̲e̲

 Module
÷
Rt =

→
A "
/ ME
→
s

t
→
=
Ao_
2k

tyz = A- For Zero Order Ran

2k

( Ao )
ty ,
✗

+42

y= ma

[ A)
P block ◦

C̲ i ̲r ̲c̲l ̲e̲