CLASS TEST SEQUENTIAL ORDER ORGANIC CHEMISTRY MM-15

1. Bromomethane, Bromoform, Chloromethane, Dibromomethane. - increasing order of boiling points

2. The four isomeric bromobutanes -reactivity towards SN1
3. 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane -reactivity towards SN2 displacement
4. Pentan-1-ol, butan-1-ol, butan-2-ol, ethanol, propan-1-ol, methanol -increasing order of boiling points
5. Pentan-1-ol, n-butane, pentanal, ethoxyethane -increasing order of boiling points
6. Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol, phenol, 4-methylphenol
-increasing order of acid strength
7. Ethanal, Propanal, Propanone, Butanone -increasing reactivity in nucleophilic addition reactions
8. Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
-increasing reactivity in nucleophilic addition reactions
9. CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH (acid strength)
10. C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2 -increasing order of basic strength
11. CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2. -increasing order of basic strength
12. Aniline, p-nitroaniline and p-toluidine -increasing order of basic strength
13. C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3 -decreasing order of basic strength in gas phase
14. CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3 -increasing order of boiling points
15. Ethanal, Propanal, Propanone, Butanone -increasing reactivity in nucleophilic addition reactions.
Differentiate
1. Phenol and benzoic acid
2. Butan-1-ol and 2-methylpropan-2ol
3. CH3CH2NH2 and(CH3)2NH
4. Ethyl amine and diethyl amine
5. Propan-1-ol and propan-2-ol
6. Methyl ethanoate and ethyl ethanoate
7. Aniline and N-ethyl aniline

8.
9. Aniline and benzylamine
10. Ethylamine and Aniline
 CLASS TEST SEQUENTIAL ORDER ORGANIC CHEMISTRY MM-15
1. Bromomethane, Bromoform, Chloromethane, Dibromomethane. - increasing order of boiling points
2. The four isomeric bromobutanes -reactivity towards SN1
3. 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane -reactivity towards SN2 displacement
4. Pentan-1-ol, butan-1-ol, butan-2-ol, ethanol, propan-1-ol, methanol -increasing order of boiling points
5. Pentan-1-ol, n-butane, pentanal, ethoxyethane -increasing order of boiling points
6. Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol, phenol, 4-methylphenol
-increasing order of acid strength
7. Ethanal, Propanal, Propanone, Butanone -increasing reactivity in nucleophilic addition reactions
8. Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
-increasing reactivity in nucleophilic addition reactions
9. CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH (acid strength)
10. C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2 -increasing order of basic strength
11. CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2. -increasing order of basic strength
12. Aniline, p-nitroaniline and p-toluidine -increasing order of basic strength
13. C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3 -decreasing order of basic strength in gas phase
14. CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3 -increasing order of boiling points
15. Ethanal, Propanal, Propanone, Butanone -increasing reactivity in nucleophilic addition reactions.

CLASS TEST SEQUENTIAL ORDER ORGANIC CHEMISTRY MM-15

1. Bromomethane, Bromoform, Chloromethane, Dibromomethane. - increasing order of boiling points
2. The four isomeric bromobutanes -reactivity towards SN1
3. 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane -reactivity towards SN2 displacement
4. Pentan-1-ol, butan-1-ol, butan-2-ol, ethanol, propan-1-ol, methanol -increasing order of boiling points
5. Pentan-1-ol, n-butane, pentanal, ethoxyethane -increasing order of boiling points
6. Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol, phenol, 4-methylphenol
-increasing order of acid strength
7. Ethanal, Propanal, Propanone, Butanone -increasing reactivity in nucleophilic addition reactions
8. Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
-increasing reactivity in nucleophilic addition reactions
9. CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH (acid strength)
10. C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2 -increasing order of basic strength
11. CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2. -increasing order of basic strength
12. Aniline, p-nitroaniline and p-toluidine -increasing order of basic strength
13. C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3 -decreasing order of basic strength in gas phase
14. CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3 -increasing order of boiling points
15. Ethanal, Propanal, Propanone, Butanone -increasing reactivity in nucleophilic addition reactions.
 CLASS TEST SEQUENTIAL ORDER ORGANIC CHEMISTRY MM-10
1. Write the chemical equation involved in the following reactions- 5

a. Rosemnund reduction
b. Hoffman bromamide reaction
c. Wolf kishner reduction
d. carbylamine reaction
e. Swarts reaction
2. Write the mechanism of the following reaction 2
EtOH −H 2 O
nBuBr + KCN nBuCN
❑
3. Write the mechanism of acid dehydration of ethanol to yield ethane 2
4. Arrange Aniline, p-nitroaniline and p-toluidine -increasing order of basic strength 1

CLASS TEST SEQUENTIAL ORDER ORGANIC CHEMISTRY MM-10

1. Write the chemical equation involved in the following reactions- 5

a. Rosemnund reduction
b. Hoffman bromamide reaction
c. Wolf kishner reduction
d. carbylamine reaction
e. Swarts reaction
2. Write the mechanism of the following reaction 2
EtOH −H 2 O
nBuBr + KCN nBuCN
❑
3. Write the mechanism of acid dehydration of ethanol to yield ethane 2
4. Arrange Aniline, p-nitroaniline and p-toluidine -increasing order of basic strength 1

CLASS TEST SEQUENTIAL ORDER ORGANIC CHEMISTRY MM-10

1. Write the chemical equation involved in the following reactions- 5

a. Rosemnund reduction
b. Hoffman bromamide reaction
c. Wolf kishner reduction
d. carbylamine reaction
e. Swarts reaction
2. Write the mechanism of the following reaction 2
EtOH −H 2 O
nBuBr + KCN nBuCN
❑
3. Write the mechanism of acid dehydration of ethanol to yield ethane 2
4. Arrange Aniline, p-nitroaniline and p-toluidine -increasing order of basic strength 1
•
SEQUENTIAL ORDER ORGANIC CHEMISTRY
• Q.1- Bromomethane, Bromoform, Chloromethane, Dibromomethane. - increasing order of boiling
points
• A.1- Chloromethane < Bromomethane < Dibromomethane <Bromoform,
• Q.2- 1-Chloropropane, Isopropyl chloride, 1-Chlorobutane - increasing order of boiling points
• A.2- Isopropyl chloride < 1-Chloropropane < 1-Chlorobutane
• Q.3-The four isomeric bromobutanes -reactivity towards SN1
• A.3- CH3CH2CH2CH2Br < (CH3)2CHCH2Br <CH3CH2CH(Br)CH3 < (CH3)3CBr
• Q.4- C6H5CH2Br, C6H5CH(C6H5)Br, C6H5CH(CH3)Br, C6H5C(CH3)(C6H5)Br -reactivity towards SN1
• A.4- C6H5C(CH3)(C6H5)Br > C6H5CH(C6H5)Br > C6H5CH(CH3)Br > C6H5CH2Br
• Q.5- 2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane -reactivity towards SN2
displacement
• A.5- 1-Bromopentane > 2-Bromopentane > 2-Bromo-2-methylbutane
• Q.6- 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2- Bromo-3-methylbutane
-reactivity towards SN2 displacement
• A.6- 1-Bromo-3-methylbutane > 2-Bromo-3-methylbutane > 2-Bromo-2-methylbutane
• Q.7- 1-Bromobutane, 1-Bromo-2,2-dimethylpropane, 1-Bromo-2-methylbutane,1-Bromo-3-
methylbutane. -reactivity towards SN2 displacement
• A.7- 1-Bromobutane > 1-Bromo-3-methylbutane > 1-Bromo-2-methylbutane > 1-Bromo-2,2-
dimethylpropane, -
• Q.8- Pentan-1-ol, butan-1-ol, butan-2-ol, ethanol, propan-1-ol, methanol -increasing order of boiling
points
• A.8- Methanol, ethanol, propan-1-ol, butan-2-ol, butan-1-ol, pentan-1-ol
• Q.9- Pentan-1-ol, n-butane, pentanal, ethoxyethane -increasing order of boiling points
• A.9- n-Butane, ethoxyethane, pentanal and pentan-1-ol.
• Q.10- Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol, phenol, 4-methylphenol
-increasing order of acid strength
 A.10- Propan-1-ol, 4-methylphenol, phenol, 3-nitrophenol, 3,5-dinitrophenol 2,4, 6-trinitrophenol
 Q.11- CH3CH2CH2CHO, CH3CH2CH2CH2OH, H5C2-O-C2H5, CH3CH2CH2CH2CH3
-increasing order of boiling points
 A.11- CH3CH2CH2CH2CH3 < H5C2-O-C2H5 < CH3CH2CH2CHO < CH3CH2CH2CH2OH
 Q.12- CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3 -increasing order of boiling points
 A.12- CH3CH2CH3 , CH3OCH3, CH3CHO, CH3CH2OH, -
 Q.13- Ethanal, Propanal, Propanone, Butanone -increasing reactivity in nucleophilic addition reactions
 A.13- Butanone , Propanone, Propanal, Ethanal
 Q.14- Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.
-increasing reactivity in nucleophilic addition reactions.
 A.14- Acetophenone, p-Tolualdehyde ,Benzaldehyde, p-Nitrobenzaldehyde,
 Q.15- Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl ketone -reactivity towards HCN
 A.15- Di-tert-butyl ketone < Methyl tert-butyl ketone, < Acetone < Acetaldehyde
 Q.16- CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH
(acid strength)
 A.16- (CH3)2CHCOOH < CH3CH2CH2COOH < CH3CH(Br)CH2COOH < CH3CH2CH(Br)COOH
 Q.17-Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid
(acid strength)
 A.17- 4-Methoxybenzoic acid < Benzoic acid < 4-Nitrobenzoic acid < 3,4-Dinitrobenzoic acid,
 Q.18- C6H5NH2, C2H5NH2, (C2H5)2NH, NH3 - decreasing order of basic strength
 A.18- (C2H5)2NH > C2H5NH2 > NH3 > C6H5NH2
  Q.19- C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 , (C2H5)2NH -increasing order of basic strength
 A.19- C6H5NH2 < NH3 < C6H5CH2NH2 <C2H5NH2 < (C2H5)2NH
 Q.20- C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2 -increasing order of basic strength
 A.20- C6H5NH2 < C2H5NH2 < (C2H5)3N < (C2H5)2NH
 Q.21- CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2. -increasing order of basic strength
 A.21- C6H5NH2 < C6H5CH2NH2< (CH3)3N < CH3NH2 < (CH3)2NH
 Q.22-C2H5NH2, C6H5NHCH3, (C2H5)2NH , C6H5NH2 -decreasing order of the pKb values
 A.22- C6H5NH2 , > C6H5NHCH3, > C2H5NH2, > (C2H5)2NH , -
 Q.23- C6H5NH2, C6H5N(CH3)2, (C2H5)2NH , CH3NH2 -increasing order of basic strength:
 A.23- C6H5NH2, < C6H5N(CH3)2, < CH3NH2, <(C2H5)2NH ,
 Q.24- Aniline, p-nitroaniline and p-toluidine -increasing order of basic strength
 A.24- p-nitroaniline < Aniline < p-toluidine
 Q.25-C6H5NH2, C6H5NHCH3, C6H5CH2NH2. -increasing order of basic strength:
 A.25- C6H5NH2 < C6H5NHCH3 < C6H5CH2NH2
 Q.26- C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3 -decreasing order of basic strength in gas phase:
 A.26- (C2H5)3N > (C2H5)2NH, > C2H5NH2, > NH3
 Q.27- C2H5OH, (CH3)2NH, C2H5NH2 -increasing order of boiling point
 A.27- (CH3)2NH, < C2H5NH2 < C2H5OH
 Q.28-C6H5NH2, (C2H5)2NH, C2H5NH2. -increasing order of solubility in water
 A.28-C6H5NH2, < (C2H5)2NH, < C2H5NH2