Professional Documents
Culture Documents
Mechanical pulping
Open Access. © 2021 Berg et al., published by De Gruyter. This work is licensed under the Creative Commons Attribution 4.0 International
License.
34 | J.-E. Berg et al.: LC refining of CTMP targeting high strength and bulk
tant. They performed laboratory refining trials with CTMP, LC refining trials
of different freeness and fibre length, reinforced by kraft
pulp. Klinga et al. (2008) reported similar results from tri- Pilot
als with CTMP in pilot-scale refiners. Moreover, they found In October 2016, first stage CTMP was taken from Billerud-
that stiff fibres formed stronger bonds if they were pressed Korsnäs’ Rockhammar mill. The sampling point, (posi-
together during drying in a Rapid Köthen sheet former tion 1) is marked with an x symbol in Figure 1a. Sub-
(100 kPa and 93 °C) compared to a standard sheet for- sequently, two pilot trials were performed on that pulp
mer (400 kPa and 23 °C). Elahimehr (2014) showed that at Valmet Technology Centre, Sundsvall in a low con-
bulk correlates to SRE and freeness for different rotational sistency JC00 conical pilot refiner (Valmet, Espoo, Fin-
speeds and filling patterns. He did not find any differ- land). Refining was performed with a filling pattern (type
ence in the relationship between tensile development and JC00RAD2/JC00SAD2) referred to as “standard fillings”
change in bulk in pilot trials where three different rota- and a filling with a fine pattern (type JC00RMM15Z/
tional speeds and a wide range of filling patterns were JC00SMM15Z). In each trial, the pulp was pumped through
used. This is to some extent contradictory to the find- the refiner from one chest to another, as shown in Figure 1b
ings reported by Klinga et al. (2008). However, Elahimehr and the refining gap was adjusted in order to achieve a
(2014) used a standard sheet former. In the present work certain refining energy and thereby a certain refining in-
testing of pulp strength and bulk is performed on Rapid tensity. Pulp samples were taken at six different refining
Köthen sheets, and that is assumed to shed light to these gaps.
contradictory results.
LC refining would make it possible to produce more
Mill
fibrillar fines also called secondary fines (Odabas et al.
In May 2017, a reference mill trial was performed at Rock-
2016) and thereby further increase the network strength
hammar mill. The refining gap in a RF5 conical LC refiner
at maintained bulk (Ljungqvist et al. 2014, Moberg et al.
(Valmet, Espoo, Finland), was adjusted in order to achieve
2014, Hafrén et al. 2014). Also Motamedian et al. (2019)
three different power loads, P (1.5, 1.96 and 2.34 MW)
found that an increased number of fibrillar fines increases
and thereby three different refining intensities. Normally,
the strength of paper. This was explained by the ability
the RF5 mill refiner operates close to 1.5 MW which cor-
of fibrillar fines to reinforce the bonds in the fibre net-
work. responds to 1.0 J/m in specific edge load. The standard
The basic idea in this work is to optimize process con- fillings in the RF5 were of the type RF5RPLF2SDD2/
ditions in LC refining, i. e. to select or ultimately develop RF5SLFSDD2P. All samples for the mill trial were taken
new optimal LC refiner filling patterns, in order to produce within one hour in order to avoid variations with vary-
fibrillar fines, improve fibre surface area and to improve ing fibre treatment on rejects; directly after the LC refiner
the separation of fibres from each other while preserving (position 3 in Figure 1a) and for the zero power load di-
the inherent stiffness as much as possible. Furthermore, rectly before the LC refiner (position 2). The mass reject
the aim is to evaluate if this type of work can be done at ratio was about 10 %. As the refiner functions as a com-
laboratory-scale or if it is necessary to run trials in pilot- or bined second stage and reject refiner it would have been
mill-scale in order to obtain meaningful results. One bene- more correct to evaluate the development of fibre and
fit of laboratory- and pilot-scale trials is that a wide variety pulp properties over the combined refining and screen-
of pulps and filling patterns can be tested at relatively low ing stage, i. e. from position 1 to position 4 (Sandberg
cost compared to mill-scale trials. Another benefit is not et al. 2017). However, this is unworkable due to the long
to jeopardize production losses for the entire mill if a trial time for the process to stabilise after a change in power
should fail. load.
Laboratory
Materials and methods In conjunction with the mill trial, first stage CTMP was
also taken from position 1 (Figure 1a) for two laboratory tri-
First stage CTMP from BillerudKorsnäs’ Rockhammar mill als in a laboratory refiner LR1 (Voith-Sulzer, Heidenheim,
made from Norway spruce (Picea abies) was used in all Germany) at BillerudKorsnäs’ Karlsborg mill. The refining
LC refining trials. Trials were performed at mill-, pilot- and with LR1 was performed with either a conical filling pat-
laboratory-scale. tern (type 3/0.5/30) or a flat filling pattern (type 3/0.84/30).
J.-E. Berg et al.: LC refining of CTMP targeting high strength and bulk | 35
P − P0
SEL = (2)
ω CEL
Ls = ω CEL (3)
SEL
SSL = (4)
IL
Wr + Wst
IL = (5)
2 cos α
Figure 1: Refiner configurations. Sampling positions are marked
with x symbols. a) CTMP mill at BillerudKorsnäs’ Rockhammar mill. where Wr = width of rotor bar (m); Wst = width of stator
Two HC single disc chip refiners in parallel supply pulp to the RF5 LC bar (m); α = bar angle (intersecting angle of opposite bars
refiner. b) JC00 pilot refiner at Valmet Technology Centre, Sundsvall. is 2α)
The pulp is pumped through the refiner from one chest to another. The refining conditions for all trials are summarised in
c) Laboratory refiner LR1 at BillerudKorsnäs’ Karlsborg mill. The
Table 1.
pulp is recirculated through the refiner and a pulp chest. The refiner
symbol indicates a conical refiner, but LR1 may also be configured
as a disc refiner.
Analyses
After hot disintegration (ISO 5263-3), tensile index (ISO
In each trial, the laboratory refiner operated with a fixed 1924-2), z-strength (ISO 15754) and bulk (ISO 5270) were
power load, P. The pulp was recirculated through the re- measured on handsheets (grammage 140 g/m2 ) made with
finer, as shown in Figure 1c, and pulp samples were taken a Rapid Köthen sheet former (Rycobel, Deerlijk, Belgium,
at six different net specific refining energies (0, 40, 80, 120, ISO 5269-2).
160 and 200 kWh/ton). In order to get an indication of fibrillar fines content,
Net specific refining energy, SRE (J/kg) was calculated a method that uses light sources in the UV (peak sen-
by: sitivity wave-length around 0.25 µm) and IR wavelength
spectrum, the crill method was used. The crill value ac-
P − P0 counts for fines of about 0.25 µm in diameter (Lundberg
SRE = (1)
QC et al. 2018) while a typical diameter of fibrillar fines is
0.5 µm (Odabas et al. 2016).
where P0 = no-load power (W); Q = mass flow (kg pulp
Fibre properties of first stage CTMP that were used in
suspension/s); C = pulp consistency (kg fibre/kg pulp sus-
LC refiner trials are shown in Table 2.
pension).
There is no common definition of refining intensity.
Berg et al. (2015) found that specific edge load (Brecht and
Siewert 1966), refining gap (Mohlin 2006) and force on fi- Results and discussion
bres (Kerekes and Senger 2006) were adequate measures
for refining intensity as they all predicted fibre shorten- Different filling patterns were compared in a pilot-scale
ing with approximately equal sufficiency. However, refin- conical JC00 refiner and a laboratory-scale LR1 refiner with
ing gap was not measured with sufficiently high precision regard to tensile index, z-strength and energy efficiency.
in this study and therefore force on fibres could not be cal- A reference trial was also performed in a conical LC refiner
culated properly. RF5 at BillerudKorsnäs’ Rockhammar mill.
36 | J.-E. Berg et al.: LC refining of CTMP targeting high strength and bulk
Figure 2: Tensile index, z-strength and bulk measured on Rapid Köthen sheets. Fillings with different cutting edge length, CEL. Solid lines
(placed at regression lines at bulk 2.3 cm3 /g) indicate mean values of standard deviations for data points.
Figure 3: Tensile index and z-strength measured on Rapid Köthen sheets versus net specific refining energy. Fillings with different cutting
edge length, CEL. Solid lines placed at regression lines, at a strength that corresponds to bulk 2.3 cm3 /g, indicate mean values of standard
deviations for data points. Net SRE was 92 and 91 kWh/ton at bulk 2.3 cm3 /g for fine-patterned and standard fillings respectively, the corre-
sponding specific edge loads were 0.22 and 1.3 J/m.
The refining was also performed with higher energy ef- properties as those shown in Figure 4 are unfortunately
ficiency (+30 %), with regard to both tensile index and z- only available for the pilot trials.
strength. Net SRE was 90 and 74 kWh/ton at bulk 2.1 cm3 /g
for flat and conical filling types respectively as indicated
in Figure 6b. The energy efficiency can be calculated as
Laboratory trials with two different filling 38 (Nm/g)/(MWh/ton) or 780 kPa/MWh/ton for flat fillings
types and 51 (Nm/g)/(MWh/ton) or 680 kPa/MWh/ton for coni-
cal fillings.
Figure 5a shows that tensile index was about 36 Nm/g In summary, the laboratory trials showed that LC re-
at bulk 2.1 cm3 /g for both filling types in LR1 (actually fining in LR1 with flat fillings resulted in higher z-strength
36.2 Nm/g for flat and 35.8 Nm/g for conical fillings). The (+33 kPa) at bulk 2.1 cm3 /g compared to conical fillings.
tensile index at zero power load were 32.8 and 32.0 Nm/g The tensile index was about the same (Figure 6a). Refining
for flat and conical filling types respectively. Figure 5b with a flat filling resulted in opposite differences in energy
shows that z-strength was 345 kPa at bulk 2.1 cm3 /g for efficiency, with regard to tensile index (−25 %) and with re-
the flat type of fillings and 312 kPa for the conical ones. gard to z-strength (+15 %). These finding are somewhat in
The z-strength at zero power load were 275 and 262 kPa for contrast to those by Lumiainen (1997a, 1997b) who indi-
flat and conical filling types respectively. Additional pulp cated that refiners with conical fillings have lower energy
38 | J.-E. Berg et al.: LC refining of CTMP targeting high strength and bulk
Figure 4: Freeness (ISO 5267-2). Average length-weighted fibre length and shives content (PQM, Valmet, Espoo, Finland) and crill value (un-
washed) (PulpEye, Örnsköldsvik, Sweden) versus bulk. Fillings with different cutting edge length, CEL.
Figure 5: Tensile index, z-strength and bulk measured on Rapid Köthen sheets. Conical and flat fillings. Solid lines (placed at regression
lines at bulk 2.1 cm3 /g) indicate mean values of standard deviations for data points.
Figure 6: Tensile index and z-strength measured on Rapid Köthen sheets versus net specific refining energy. Conical and flat fillings. Dash-
dot lines indicate net SRE at z-strength that corresponds to bulk 2.1 cm3 /g.
J.-E. Berg et al.: LC refining of CTMP targeting high strength and bulk | 39
Figure 7: Tensile index, z-strength and bulk measured on Rapid Köthen sheets. RF5 Standard fillings, CEL 120 km/rev.
Figure 8: Tensile index and z-strength measured on Rapid Köthen sheets versus net specific refining energy. RF5 Standard fillings, CEL
120 km/rev. Dash-dot lines indicate net SRE at z-strength that corresponds to bulk 2.1 cm3 /g.
consumption and produce better fibre development than in filling pattern in a laboratory or pilot refiner also could
flat disc refiners due to geometric differences. However, Lu- be detected in larger refiners. Refining in a JC00 pilot re-
miainen performed the trials in larger-scale refiners. finer with fine-patterned fillings (bar width 1.3–1.4 mm) re-
sults in higher tensile index and z-strength at specified
bulk compared to standard fillings (bar width 4 mm). A dif-
Mill trial ference is also seen in an LR1 laboratory refiner where flat
fillings gives higher z-strength compared to conical fill-
Figure 7a–b shows that tensile index was 35.5 Nm/g and ings, both with 3 mm bar width. Pulp properties and refin-
z-strength was 318 kPa, both evaluated at bulk 2.1 cm3 /g. ing characteristics evaluated at specified bulk values are
Tensile index and z-strength versus net SRE are shown in put together in Table 3.
Figure 8a–b. Net SRE was 109 kWh/ton at bulk 2.1 cm3 /g
as indicated in Figure 7b, the corresponding specific edge
load was 1.8 J/m. The tensile index and z-strength before
refining were 30.5 Nm/g and 266 kPa respectively. The en- Conclusions
ergy efficiency can be calculated as 46 (Nm/g)/(MWh/ton)
or 480 kPa/MWh/ton. First stage chemithermomechanical pulp (CTMP) made
from Norway spruce were used in low consistency refining
trials performed at mill-, pilot- and laboratory-scale. Dif-
Summary of all trials ferent filling patterns were compared with regard to tensile
index, z-strength and energy efficiency.
Refining curves from laboratory-, pilot- and mill-scale re- – A fine-patterned filling in a pilot-scale conical refiner
fining follow a common trend as seen in Figure 9a–b. It is gave higher tensile index and z-strength at maintained
therefore plausible that refining effects due to differences bulk than did a standard filling.
40 | J.-E. Berg et al.: LC refining of CTMP targeting high strength and bulk
Figure 9: Tensile index, z-strength and bulk measured on Rapid Köthen sheets. Fillings with different cutting edge length, CEL.
Table 3: Pulp properties and refining characteristics evaluated at specified bulk values.
In: 6th Int. Conf. on New Available Techn. SPCI, Stockholm, Mohlin, U.B. (2006) Refining intensity and gap clearance. In:
Sweden. pp. 367–374. Proceedings, 9th International Refining Conference. Pira,
Kerekes, R.J., Senger, J.J. (2006) Characterizing refining action in Leatherhead, UK.
low-consistency refiners by forces on fibres. J. Pulp Pap. Sci. Motamedian, H.R., Halilovic, A.E., Kulachenko, A. (2019)
32(1):1–8. Mechanisms of strength and stiffness improvement of paper
Klinga, N., Höglund, H., Sandberg, C. (2008) Energy efficient high after PFI refining with a focus on the effect of fines. Cellulose
quality CTMP for paperboard. J. Pulp Pap. Sci. 34(2):98–106. 26(6):4099–4124.
Ljungqvist, C.H., Peng, F., Goldszer, K., Moberg, A. (2014) The Odabas, N., Henniges, U., Potthast, A., Rosenau, T. (2016) Cellulosic
impact of CTMP and PGW fibres and fines on board properties. fines: properties and effects. Prog. Mater. Sci. 83:574–594.
In: Proceedings, Int. Mech. Pulping Conf., Helsinki, Finland. Persson, E., Norgren, S., Engstrand, P., Granfeldt, T., Johansson, M.,
Lumiainen, J.J. (1995) Specific surface load theory. In: Proceedings, Edlund, H. (2019) Spruce HT-CTMP revisited – a high yield,
3rd Int. Refin. Conf., Atlanta, Georgia, USA. energy efficient pulp for future products. In: Proceedings,
Lumiainen, J.J. (1997a) Comparison of the mode of operations Fundamental Mech. Pulping Res. Seminar, Norrköping,
between conical and disc refiners. Pap. Technol. 38(1):53–58. Sweden.
Lumiainen, J.J. (1997b) Post-refining of mechanical pulps. In: Pettersson, G., Höglund, H., Norgren, S., Sjöberg, J., Peng, F.,
Proceedings, 4th Int. Refin. Conf. PIRA, Leatherhead, UK. Hallgren, H., Moberg, A., Ljungqvist, C.H., Bergström, J.,
Lundberg, M., Norgren, M., Edlund, H. (2018) Validation of crill Solberg, D. (2015) Strong and bulky paperboard sheets from
measurements in a high-yield pulp refining process for surface modified CTMP, manufactured at low energy. Nord. Pulp
improved fines material control. Nord. Pulp Pap. Res. J. Pap. Res. J. 30(2):319–325.
33(2):200–209. Rusu, M., Mörseburg, K., Gregersen, Ø., Yamakawa, A., Liukkonen,
Moberg, A., Goldszer, K., Ljungqvist, C.H., Peng, F., Hafrén, S. (2011) Relation between fibre flexibility and cross-sectional
J., Fernando, D., Daniel, G. (2014) Mechanical pulping properties. BioResources 6:641–655.
process impact on fines properties and significance for Sandberg, C., Berg, J.-E., Engstrand, P. (2017) Low consistency
strength-density relationships of board centre layers. In: refining of mechanical pulp – system design. Tappi J.
Proceedings, Int. Mech. Pulping Conf., Helsinki, Finland. 16(7):419–429.