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Introduction
One of the greatest discoveries in modern science that has unraveled the secrets of matter
is the discovery of the atom. Understanding the nature of the atom has catalyzed
breakthroughs in chemical technology which is a key to human development. Moreover,
unlocking the mysteries of the atom is vital in realizing many of the innovations in the other
allied sciences such as Biology, Physics, Astronomy, Medicine and the like.
An atom is the basic unit of an element that can enter into chemical combination. It is too
small that the human eye can not see but with the use of modern technology like the
electron microscope, this can be made possible.
The atoms of the elements in the Periodic Table are neutral because they have equal
number of protons and neutrons. But somehow, if these atoms start to lose or gain
electrons, they become ions. This process undertaken by atoms is very indispensable in the
formation of compounds and molecules.
Observe three different kinds of leaves, flowers and fruits found in your backyard. Describe
their color, odor and taste and write your observation on the space provided.
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What could explain the difference in the color of the leaves, odor of the flowers and taste of
the fruit of the plant?
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ATOMIC THEORY
At the end of the lesson, you should be able to:
trace the historical development of the atom;
describe the structure of the atom; and
discuss the importance of the different components of the atom.
Everything that we know about the atom today is a collective contribution of the different
scientists who based their hypothesis of the atom to the early ideas of the ancient Greeks.
Democritus
In the 5th century B.C. Democritus believed
that matter consists of very small particles
which he called atomos, a Greek word for
uncuttable or indivisible. He further posited
that these atoms are solid and different
atoms vary in size and shape. The difference
in the size and shape of atoms explains the
differing properties of matter.
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John Dalton
In 1808, an English scientist and school
teacher, John Dalton has formulated a
precise definition of the indivisible
building blocks of matter that we call
atoms. Dalton’s work marked the
beginning of the modern era of
chemistry. The hypotheses about the
nature of matter on which Dalton’s
atomic theory is based can be
summarized as follows:
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A diagram of J.J. Thomson's cathode ray tube. The ray originates at the
cathode and passes through a slit in the anode. The cathode ray is deflected
away from the negatively-charged electric plate, and towards the positively-
charged electric plate. The amount by which the ray was deflected by a
magnetic field helped Thomson determine the mass-to-charge ratio of the
particles.
Ernest Rutherford
Rutherford’s model of the atom is also known as
the nuclear model of the atom. This was
proposed by New Zealand – born physicist
Ernest Rutherford in 1911. The model described
the atom is almost an empty space composed of
tiny, dense, positively charged core called
a nucleus, in which nearly all the mass is
concentrated, around which the light,
negative constituents, called electrons, circulate
at some distance, much like planets revolving
around the Sun.
The following data obtained in his Thin Gold Foil experiment in 1899 were the basis in
describing an atom in his model:
1. Most of the alpha particles travelled straight through the thin gold foil. This indicates
that the atom is almost an empty space.
2. Few of the alpha particles returned back at the same side where they come from.
This indicates that the alpha particles hit a dense part of the atom at the center
known as the nucleus, the part of the atom where the mass is concentrated.
3. Some of the alpha particles were deflected at an angle. The deflection of the alpha
particles is an indication of the positive charge of the nucleus of the atom since alpha
particles are positively charged. This conforms to the “Law of Charges” by Charles
Coulomb which states that “like charges repel and unlike charges attract”
Niels Bohr
Bohr model of the atom is also known as “Planetary
Model of the Atom” and was proposed in 1913 by
Danish physicist Niels Bohr. In his model, he
described an atom as consisted of a positive
nucleus surrounded by electrons that are revolving
around it in circular quantized orbit. The electrons
are held in their orbit by centripetal force.
However, these electrons can jump into a higher
energy levels when they absorbed heat or through
influence of electric current (excited state) and emit
electromagnetic radiation (photon) with
corresponding wavelength when they release the
absorbed heat (ground state).
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Erwin Scrodinger and Werner Heisenberg
The electron cloud model is the current
accepted model of an atom. This was
developed by Erwin Scrodinger and
Werner Heisenberg in 1926. They
described the atom as consisted of a dense
nucleus surrounded by a cloud of fast
spinning electrons at various levels in
orbitals. The electron cloud or orbital is the
region in the atom where one
could get 90% chance of finding the
electrons.
However, the model cannot determine the
exact location and momentum of electrons
at the same time (Heisenberg Uncertainty
Principle). To solve this dilemma,
Schrodinger proposed the following four (4)
sets of quantum numbers:
a. Principal Quantum Number – its symbol is n and has integral values 1, 2, 3 and so
forth. It is related to the average distance of the electron from the nucleus in a
particular orbital.
Example: In the outer electron configuration of Oxygen, 2p4, what is the n value? The
answer is n = 2. Remember that in electron configuration, it follows the symbol nlx.
b. Azimuthal or Angular Quantum number – its symbol is l and its values depend on
the orbital where the electron is located. The l value for s orbital is always 0, for p
orbital, it is always 1, d orbital is always 2 and f orbital is always 3. This quantum
number defines the shape of the sublevel of the atom to which the electron is found.
Example: What is the l value in the above example? The answer is l = 1 because the
electron is in the p sublevel.
c. Magnetic Quantum number – its symbol is ml (read as m sub l). It describes the
probable orientation of orbital in space. Within a subshell, the value of ml depends on
the value of the angular momentum quantum number, l. For a certain value of l,
there are (2l + 1) integral values of ml as follows:
sublevel L value ml = (2l + 1) ml possible values
s 0 1 0
p 1 3 -1, 0, +1
d 2 5 -2, -1, 0, +1, +2
f 3 7 -3, -2, -1, 0, +1, +2, +3
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Example: Give the ml value of the electrons in the outer configuration of the atom
Oxygen – 2p4.
Solution: Since the electrons are in the p sublevels, there are 3 possible values, it
can be -1, 0 or +1.
Note: For ml of specific electron in the orbital, use orbital box diagram to determine
the ml value.
Example: What is the ml value of the last entering electron of Oxygen atom? (This
means electron # 4 in 2p4 configuration)
Solution: Since the electron is in 2p orbital, the third column of the table above tells
that there are 3 orbital present in the sublevel, therefore, in the orbital box diagram,
distribute the 4 electrons in the 2p4 configuration in this manner:
So the answer is ml = -1
d. Spin Quantum Number – describes the angular momentum of electron and has
only two possible values, +1/2 and -1/2. You should remember that both values are
accepted for every electron in the atom. Its symbol is ms (read as m sub s).
Example: What is the ms value of the last entering electron in Oxygen atom with an
outer configuration of 2p4? The answer is either +1/2 or -1/2
Activity 1
ATOMIC STRUCTURE
Atoms are tiny particles of matter (about 10 -10 m in diameter or approximately 1 pm in
diameter). They are the basic unit of matter and the defining structure of an element. Atoms
are composed of the following particles:
a. Protons are positively charged particle of the atom. They are found inside the
nucleus and contributory particles for the mass of the atom. These particles are
discovered by Ernest Rutherford and give atoms their identity.
b. Neutrons are uncharged particles that are found in the nucleus of the atom and
were discovered by James Chadwick. These particles contribute to the mass of the
atom and stabilize the nucleus by effectively moderating the repulsive force among
the protons in it.
Protons and neutrons are collectively called nucleons because they are particles of
the nucleus of the atom. Protons bind with neutron in the nucleus using strong
nuclear force. The nucleus is positively charged and the region in the atom where
the mass is concentrated.
c. Electrons are negatively charged particles which are discovered by J.J. Thomson
and are found outside the nucleus of the atom. These particles are not contributory
to the mass of the atom but are essential participants during chemical reaction
forming various compounds.
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Properties of Sub – atomic Particles
Property Electron Proton Neutron
Symbol e- p+ n
Mass (amu) 0.000549 1.00728 1.00867
Mass (g) 9.1094 x 10 -28 1.6726 x 10 -24 1.6749 x 10 -24
Mass (kg) 9.109 × 10-31 1.673 × 10-27 1.675 × 10-27
Electric Charge -1 +1 0
1 amu = 1.6605 x 10 -24 g
Activity 2
1. Compose a jingle that features an atom, its components and their function.
2. Construct a timeline showing the development of the atom.
ELEMENTARY PARTICLES
Electrons and quarks contain no discernible structure and cannot be reduced or separated
into smaller components. It is therefore reasonable to call these particles elementary
particles. The use of modern high – technology equipment today has helped us understand
better the atom and its fundamental particles. Today, modern view of the atom has proven
that it is comprised of many other elementary particles aside from what we have known
before.
The foundation of this innovation in atomic structure is attributed to the idea of Paul Dirac
who predicted in 1928 that “all particles should have their opposites called the anti –
particles”. The first of this was discovered in 1932 by Carl Anderson, which he called
positron – the anti – particle of electron. When an electron and positron come into contact,
they mutually annihilate each other producing a flood of energy in accordance with
Einstein's famous equation, E = mc2.
Leptons
Leptons are never found in the nucleus of atoms. They are not subject to the Strong
Nuclear Force which keeps the nucleus from flying apart. There are six (6) types of
leptons which include the electron, muon, tau and the neutrino having its three types
known as electron neutrino, muon neutrino and tau neutrino. The electron is
considered the simplest of the leptons. Neutrino on the other hand was postulated in
1934 by Enrico Fermi to explain certain aspect of radioactive decay.
Baryons
The two most common baryons are the proton and neutron. Both are found in the
nuclei of atoms, being kept there by the Strong Nuclear Force that binds them
together. Baryons are made up of even more elementary particles called quarks. A
baryon particle is composed of quark triplet. An example is proton which is
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composed of 2 u (up) quarks and a d (down) quark. Neutron on the other hand is
composed of 2 d quark and a u quark.
Quarks are very unususal because they have fractional electric charges. The are 6
types or flavors of quarks which include the up, down, strangeness, bottom (or
beauty) and top (or truth).
Up u +(2/3) 2–8
Down d -(1/3) 5 – 15
- ddd -(1/3)-(1/3)-(1/3) = -1
0 uds +(2/3)-(1/3)-(1/3) = 0
+ uus +(2/3)+(2/3)-(1/3) = +1
- sss -(1/3)-(1/3)-(1/3) = -1
Mesons
Mesons are particles only discovered when the forces binding nucleons together
were investigated. In a nucleus, the protons and neutrons are not really separate
entities, each with its own distinct identity. They change into each other by rapidly
passing particles called pions () between themselves. Pions are the most common
of the mesons. Mesons are composed of a quark / anti-quark pair. The positive
pion (+) is made from a u quark and and a (d) anti quark. The negative pion (-) is
made from a d quark and a (u) anti quark.
Based on spin of the particle, the elementary particles can be categorized into
Fermions and Bosons. Fermions have spin that have half – integer values like 1/2,
1/3, 3/2 etc. This characteristic spin of Fermion proves that they obey Pauli’s
Exclusion Principle. Leptons and baryons belong to this category. Bosons on the
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other hand, have integer spin (0, 1, 2 etc.) Bosons do not obey the Pauli Exclusion
Principle. The best known Boson is the massless photon, a quantum of light.
Activity 3
Construct a concept map that shows the different categories of elementary particles of the
atom.
The atomic number of an element is the number of protons found in the nucleus of its
atom. Its symbol is Z. For a neutral atom, the number of proton is always equal to the
number of electron in the atom.
Z = p = e-
Example: The atomic number of Oxygen is 8. How many protons and electrons are
there in its atom?
Answer: There are 8 protons in its nucleus and 8 electrons circling around it. The number
of protons equals the number of electrons since the atom is neutral.
Atomic Mass
The atomic mass of an element can be determined by adding the number of protons and
neutrons in the nucleus of its atom. Its symbol is A.
A = p + n or A = Z + n n = A – Z or n = A – p
Example 1: The atomic number of Oxygen is 8 and there are 8 neutron in its nucleus.
What is the atomic mass of Oxygen atom?
Answer: Adding the atomic number and number of neutron, A = 8 + 8 = 16. So atomic
mass is 16. This value coincides with the atomic mass of Oxygen as seen on the periodic
table of elements when rounded off to whole number.
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Example 2. The nuclear symbol for an atom of Tungsten is 74 W , how many protons,
electrons and neutrons are there in the atom?
You should remember that atoms of a given element do not have the same mass. Most
elements have two or more isotopes – atoms that have the same atomic number but
different mass numbers or same number of protons but differ in the number of neutrons.
For example: The three isotopes of Hydrogen are: a.) protium, 11 H , has 1 proton and 0
2 3
neutron; b.) deuterium, 1 H has 1 proton and 1 neutron and c.) tritium, 1 H has 1 proton and 2
neutrons.
Look at the atomic mass of the elements on the periodic table, the value that you see is the
average atomic mass of the element. Example, on the periodic table, the atomic mass of
Carbon is 12.011. This value is the average mass of the naturally occurring mixture of
isotopes of Carbon. How to arrive at the average mass of Carbon?
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Solution: the natural abundances of carbon-12 and carbon-13, the isotopes of Carbon are
98.90 % and 1.10 %, respectively. The atomic mass of carbon – 12 is 12.00000 amu and
carbon – 13 has been determined to be 13.00335 amu. Therefore:
Activity 4
Solve the following problems:
1. Copper, a metal known since ancient times, is used in electrical cables and pennies,
among other things. The atomic masses of its two stable isotopes, 63 29 Cu (69.09 %)
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and 29Cu (30.91 %), are 62.93 amu and 64.9278 amu, respectively. Calculate the
average atomic mass of copper. The relative abundances are given in parentheses.
2. The atomic masses of the two stable isotopes of boron, 105B (19.78 percent) and 115 B
(80.22 percent), are 10.0129 amu and 11.0093 amu, respectively. Calculate the
average atomic mass of boron.
Look and analyzed the nuclear symbols of the following chemical substances:
40 40 40 40 40
16 S 17 Cl 18 Ar 19 K 20 Ca
These substances are classified as isobar. They have the same atomic mass (number of
nucleons) but differ in their atomic number (number of protons).
IONS
Atoms can become ion if it loses or gains an electron. Ions are substances that carry a
charge. The charge is due to the unequal number of electrons and protons in the atom. An
ion that carries a positive charge is called a cation while an anion carries a negative charge.
The positive charge of an atom indicates that it has more proton than electron and negative
charge indicates that the atom has more electrons than protons
Metals are regarded as electron donors, therefore, they tend to become cations. Examples
are Li+ (read as lithium ion), Na + (read as Sodium ion), K +, Be2+, Mg2+, Ca2+ etc. Non-metals
on the other hand are electron acceptors, therefore, they tend to become anions. Examples
include C4- (read as carbide ion), N3- (read as nitride ion), O2- (read as oxide ion) etc.
Example 1: How many protons, electrons and neutrons are present in an atom with a
nuclear symbol 27 3+
13 Al ?
Answer: p = 13, e- = 10, n = 14 Note: Al carries a 3+ charge. This indicates that Al has lose
3 e-. Therefore the difference between its number of protons and electron should be 3.
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Example 2: What is the number of protons, electrons and neutron in an atom with a nuclear
symbol 32 2-
16 P ?
Answer: p = 16, e- = 18, n = 16 Note: S carries 2- charge. This indicates that S has gained 2
electrons. Therefore, the difference between its number of protons and electron should be
2.
Activity 5:
Mg 12 12 12
Cl 17 18 18
Ag 47 108 61
127
I 53 P-
195
Pt 78 Pt
MOLECULES
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Activity 6
Assessment
I. Multiple Choice: Choose the best answer from the given choices. Write the letter of our
choice on the space provided.
_____1. Which of the following shows the CORRECT order of Atomic Theory Timeline?
a. Bohr, Democritus, Thomson, Rutherford, Dalton
b. Rutherford, Bohr, Dalton, Democritus, Thomson
c. Dalton, Thomson, Rutherford, Bohr, Democritus
d. Democritus, Dalton, Thomson, Rutherford, Bohr
____2. Atoms of 16O, 17O, and 18O have the same number of
a. protons, but a different number of electrons
b.protons, but a different number of neutrons
c. electrons, but a different number of protons
d. neutrons, but a different number of protons
____3. A sample of element X contains 90% X-35 atoms, 8.0% X-37 atoms, and 2.0% X-38
atoms. The average
atomic mass will be closest to which value?
a. 35 b. 36 c. 37 d. 38
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____5. The atomic theories of Dalton, Thomson, Rutherford, and Bohr all support which of
the following statements?
a. atoms are mostly composed of empty space
b. electrons orbit the nucleus of an atom at distinct energy
levels
c. all matter is composed of tiny, discrete particles called
atoms
d. atoms are composed of positively and negatively charged
particles.
____7. Teacher Elisha calls on students to characterize protons of an atom. Which of the
following would be an acceptable answer?
a. Protons are involved during chemical reaction forming
various products.
b. The highly reactive electrons are stabilized by the proton
particles.
c. Every atom is identified by the number of protons inside its
nucleus.
d. The mass of the atom is given by the total mass of protons in the nucleus.
____8. A hypothetical element named Pedronium was found to
have 172 protons, 172 electrons and 205 neutrons. What
would be the atomic number of Pedronium?
a. 33 b. 172 c. 205 d. 377
_____12. Which of the responses contain all the statements that are
consistent with the Bohr’s theory of the atom?
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1. An electron can remain in a particular orbit as long as it continually absorbs
radiation of a definite frequency.
2. The lowest energy orbits are those closest to the nucleus.
3. An electron can jump from the K shell (n = 1 major energy
level) to the M shell (n = 3 major energy level) by emitting
radiation of a definite frequency.
a. 1 only b. 2 only c. 3 only d. 2,3
____13. Electrons are either lose or gained by atoms to form ions. What is the driving force
for this mechanism of the atom?
a. Reactivity b. Stability c. Identity d. Volatility
____16. Niels Bohr concluded that atoms are similar with the solar system in its orientation.
Electrons surround the nucleus of the atom and do not fall away from the nucleus. What
possible explanation supports this statement?
a. Electrons are held on their position by their attraction with the nucleus.
b. Electrons are pulled closer to the nucleus by the neutron of the atom.
c. Protons and electrons on the orbit of the atom established strong attractive force.
d. The electrons are being fixed on their position by the different quarks in the nucleus.
____17. Rutherford observed that MOST of the alpha particles went through the thin gold
foil without being deflected. What is indicated by this observation of Rutherford to
atoms?
a. The atom is completely a gaseous object consisted of extremely small particles.
b. The atom is so big and all its small particles are concentrated at the center.
c. The protons, electrons and neutrons are randomly distributed occupying the entire
space of the atom.
d. The volume of an atom is almost an empty space.
____18. The atomic masses of 63 Li and 73 Li are 6.0151 amu and 7.0160 amu, respectively.
If the average atomic mass of Li is 6.941 amu, what are the natural abundances of
these two isotopes?
a. 63 Li = 3.25 %, 73 Li =¿96.75 % c. 63 Li = 7.50 %, 73 Li =¿92.50 %
b. 63 Li = 5.50 %, 73 Li =¿94.50 % d. 63 Li = 9.25 %, 73 Li =¿90.75 %
____20. What sub – atomic particle stabilizes the nucleus of the atom by effectively
moderating the repulsive force among the protons in it?
a. Proton b. electron c, neutron d. positron
References:
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Chang, R. Chemistry.(2010). 5th ed. Mc Graw Hill Book Co.. N.Y.
Masterton and Hurley. (2004). Chemistry: Principles and Reactions. 5 th ed. Thomson
Learning, Inc.
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