Sir Zaheer's Academy Total Marks = 40

Time = 60 mintes

A2-Level Chemistry Test

NAME:_____ ____________________________
1

[2]

[1]

and state it's Equations

[2]
3

Br⎯Br = 193
(_______________________________)
4 Al F3 is an ionic compound.
The Born–Haber cycle for the formation of Al F3 is shown.
Al 3+(g) + 3F(g) + 3e–

∆H4

Al 3+(g) + 3F–(g)
∆H3

Al (g) + 3F(g)

∆H2 ∆H5
Al (g) + 1.5F2(g)

∆H1
Al (s) + 1.5F2(g)

∆H6
Al F3(s)

(i) Name the enthalpy changes labelled ∆H4 and ∆H6.

∆H4 = ...................................................................................................................................

∆H6 = ...................................................................................................................................
[2]
(ii) Use the data in the table and data from the Data Booklet to calculate the lattice energy of
Al F3.
enthalpy change
process
/ kJ mol–1
Al (s) → Al (g) +326
Al (g) → Al (g)3+
+5137
F(g) → F (g)–
–328
Al (s) + 1.5F2(g) → Al F3(s) –1504

lattice energy of Al F3 = .............................. kJ mol–1 [2]

(iii) Scandium fluoride, ScF3, is an ionic compound.

Use data from the Data Booklet to suggest how the lattice energy of Al F3 compares with
the lattice energy of ScF3.

Explain your answer.

.............................................................................................................................................

.............................................................................................................................................

....................................................................................................................................... [2]
5 (a) Use the following enthalpies of formation to calculate the enthalpy change for
the reaction:
2NaHCO3(s)  Na2CO3(s)+ CO2(g) + H2O(g)
Hf(kJmol-1): NaHCO3(s) –951, Na2CO3(s) –1131, CO2(g) – 394,
H2O(g) – 242
.............................................................................................................................................

....................................................................................................................................... [2]
(b) Use the following entropies to calculate the entropy change for the same
reaction: NaHCO3(s) 102, Na2CO3(s) 135, CO2(g) 214, H2O(g) 189
(all JK-1mol-1)
.............................................................................................................................................

....................................................................................................................................... [2]
(c) Predict the temperatures for which this reaction will be feasible.

....................................................................................................................................... [2]

6 At 10 °C ice changes to water.

H2O(s) H2O(l) ΔH —O = +6.01 kJ mol–1

a Explain why the entropy change of the system is positive. [2]

b The entropy change for the system is +22.0 J K–1 mol–1. Calculate the gibbs free energy change at 10.0 °C. [4]

c Explain why the process shown in the equation does not occur at –10.0 °C. [2]

d At –10.0 °C, the value of ΔSsystem is –22.0 J K–1 mol–1

Calculate the gibbs free energy change in the process. Include the correct sign. [2]