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Physics
Chapter 12 - Atoms
1. Name the series of hydrogen spectrum lying in ultraviolet and visible region.
Ans: Lyman series lies in ultraviolet region while Balmer series lies in visible
region.
4. The ground state energy of hydrogen atom is 13.6eV . What are the
kinetic and potential energies of the electron in this state?
Ans: We are given,
Ground state energy of hydrogen atom, E 13.6eV
This is the total energy of a hydrogen atom. Kinetic energy is equal to the
negative of the total energy.
Kinetic energy E 13.6 13.6eV
Potential energy is equal to the negative of two times of kinetic energy.
Therefore, Potential energy 2 13.6 27.2eV
232 208
2. How many and - particles are emitted when 90Th changes to 82 Pb
?
Ans: The mentioned reaction is as follows:
232 208 4 o
90Th 82Pb 2He y1e
According to low of conservation of atomic number and mass number
90 82 2x y
2x y 8 ...... (1)
232 208 4x
x 6 ...... (2)
From (1) & (2)
2(6) y 8
12 8 y
y4
232 208
The number of and - particles emitted when 90Th changes to 82 Pb is
found to be 6 and 4 respectively.
Hence, the radii of an electron for n 2 and n 3 orbits are found to be equal to
2.12 1010 m and 4.77 1010 m respectively.
7. In accordance with the Bohr's model, find the quantum number that
characterises the earth's revolution around the sun in an orbit of radius
1.5 1011 m with orbital speed 3 104 m / s (Mass of earth 6.0 1024 kg .)
Ans: We are given:
Radius of the orbit of the Earth around the Sun, r 1.5 1011 m
Orbital speed of the Earth, v 3 104 m / s
Mass of the Earth, m 6.0 1024 kg
According to Bohr's model, angular momentum is quantized and could be given
as:
nh
mvr
2
Where,
h Planck's constant 6.62 1034 Js
n Quantum number
mvr2
n
h
2 6 1024 3 104 1.5 1011
n
6.62 1034
n 25.61 1073 2.6 1074
8. The total energy of an electron in the first excited state of the hydrogen
atom is about 3.4eV .
a) What is the kinetic energy of the electron in this state?
Ans: (a) We are given,
Total energy of the electron, E 3.4eV
Kinetic energy of the electron is equal to the negative of the total energy.
K.E E
K.E 3.4 3.4eV
Hence, the kinetic energy of the electron in the given state is found to be
3.4eV .
c) Which of the answers above would change if the choice of the zero of
potential energy is changed?
Ans: We know that, the potential energy of a system would depend on the
reference point taken. Here, the potential energy of the reference point is taken
to be zero. On changing the reference point, then the value of the potential
energy of the system would also change. Since, we know that total energy is the
sum of kinetic and potential energies, total energy of the system will also
change.
2. Prove that the speed of election in the ground state of hydrogen atom is
equal to the speed of electron in the first excited state of hydrogen like Li
atom.
Ans: We have the following expression,
2Ke2
n
nh
2Ke2
For ground state of hydrogen atom x 1; 1
h
Z 2Ke 2
From hydrogen like atom n ......(1)
nh
Now, for Li atom z 3 n 2
2 2Ke2
n Li
2h
2Ke2
n Li ......(2)
h
Now, from (1) and (2), we have,
n H n Li
Hence, we proved that the speed of election in the ground sate of hydrogen
atom is equal to the speed of electron in the first excited state of hydrogen
like Li atom.
4. Choose the correct alternative from the clues given at the end of each
statement:
a) The size of the atom in Thomson's model is .......... the atomic size in
Rutherford's model. (much greater than/no different from/much less than.)
Ans: The sizes of the atoms taken in Thomson's model and Rutherford's model
have the same order of magnitude.
6.
a) Using the Bohr's model calculate the speed of the electron in a
hydrogen atom in the 1,2, and 3 levels.
Ans: Let v1 be the orbital speed of the electron in a hydrogen atom in the
ground state level, n1 1 . For charge ( e ) of an electron, v1 could be given by
the relation,
e2 e2
v1
h 2 0 h
n1 40
2
Where,
e 1.6 1019 C
0 Permittivity of free space 8.85 1012 N 1C2m2
h Planck’s constant 6.62 1034 Js
Substituting the given values, we get,
v1
1.6 10
19 2
v2
1.6 10
19 2
s
2 2 8.85 1022 6.62 10 34
v2 1.09 106 m / s
v3
1.6 10
19 2
T1
2.18 106 9.1 1031 1.6 1019
2
T2
v2
2 2 6.62 1034 8.85 1012
2 2
T2
1.09 106 9.1 1031 1.6 1019
2
T2 1.22 1015
And, for level n 3 3 , we could write the period as:
2r2
T3
v3
Where,
n 3 h 2 0
2
T3
v3 me2
T3 4.12 1015
7.27 105 9.1 1031 1.6 10
19 2
2r3
T3 4.12 1015 s
v3
Hence, the orbital period in each of these levels are found to be
1.52 1016 s,1.22 1015 s, and 4.12 1015 s respectively.
It is known that the universe is about 156 billion light years wide or 1.5 1027
wide.
Therefore, we can conclude that the radius of the first Bohr orbit is much
greater than the estimated size of the whole universe.
4 02
3 h
2
Where,
v 2 Frequency of radiation at level n 1
Energy ( E ) released as a result of de-excitation:
E E2 E1
hv E2 E1 ......(iii)
Where,
v Frequency of radiation emitted
Putting values from equations (i) and (ii) in equation (iii), we get:
2
For large n , we can write 2n 1 2n and n 1 n
me 4
v 3
......(iv)
h 3
32 n
2
2
0
e2
2
2.81 1015 m
40 m ec
Hence, we found that the numerical value of the taken quantity is much smaller
than the typical size of an atom.
b) You will find that the length obtained in ( a ) is many orders of magnitude
smaller than the atomic dimensions. Further, it involves c. But energies of
atoms are mostly in non-relativistic domain where c is not expected to play
any role. This is what may have suggested Bohr to discard c and look for
'something else' to get the right atomic size. Now, the Planck's constant h
had already made its appearance elsewhere. Bohr's great insight lay in
recognising that h,me , and e will yield the right atomic size. Construct a
quantity with the dimension of length from h,me , and e and confirm that
its numerical value has indeed the correct order of magnitude.
e2
2
2.81 1015 m
40 mec
Hence, we found the value of the quantity taken is of the order of the atomic
size.
12. Obtain the first Bohr's radius and the ground state energy of a muonic
hydrogen atom [i.e., an atom in which a negatively charged muon of
mass about 207me orbits around a proton].
Ans: It is known that,
Mass of a negatively charged muon, m 207me
According to Bohr's model we have,
1
Bohr radius, re
me
And, energy of a ground state electronic hydrogen atom, Ee m .
We have the value of the first Bohr orbit known to be,
re 0.53A 0.53 1010 m
Let r be the radius of muonic hydrogen atom.
At equilibrium, we could write the relation as:
m r m e re
208me r me re
0.53 1010
r 2.56 1013 m
207
Therefore, the value of the first Bohr radius of a muonic hydrogen atom is
2.56 1013 m .
Now, we have,