Professional Documents
Culture Documents
Physics
Chapter 13 - Nuclei
a) 4 Be9 1 H1 3 Li 6 ..........
4. Write the empirical relation for paschen series lines of hydrogen atom.
1 1 1
Ans: R 2 2 where n 4,5,6,7......
3 n
1. What fraction of tritium will remain after 25 years? Given half life of
tritium as 12.5 years.
Ans: It is given that,
t 25years , T 12.5years
t 25
N 1 T 1 12.5
N0 2 2
2
N 1 1
N0 2 4
N
0.25 , which is the required fraction.
N0
2. Calculate the kinetic energy and potential energy of an electron in the first
orbit of a hydrogen atom. Given e 1.6 1019 C and r 0.53 1010 m .
Ans:
I. Kinetic Energy
ke 2
K.E.
2r
21.74 1019
K.E. 13.59eV
1.6 1019
E mc2
E 16 9 1010 Joules
16 9 1010
E eV
1.6 1019
E 9 1030 eV
Atomic mass of 20
10 Ne , m1 19.99u
Abundance of 20
10 Ne , 1 90.51%
Atomic mass of 21
10 Ne , m 2 20.99u
Atomic mass of 22
10 Ne , m3 21.99u
Abundance of 22
10 Ne , 3 9.22%
1
6. From the relation R R 0 A , where R 0 is a constant and A is the mass
3
where,
R 0 is a constant
01 n 63 Li 42 He 31 H
P
1.6 10 A 1.6 10 A
27 27
3
4 3 4
1
R R 0A 3
3 3
P
1.6 10 A 27
1.6 1027
3.14 1.2 1015
4 4 3
R 03A
3 3
P 2.21 1017 kg m3
5. Distinguish between isotopes and isobars. Give one example for each of
the species.
Ans: The elements which have the same atomic number but different mass
number are called Isotopes.
Thus, nuclides of different elements having the same mass number but different
atomic numbers are called isobars.
t 9 minutes
T1 3 minutes
2
t 9 3
N 1 T1 1 3
1 1
2
N0 2 2 2 8
N0
N
8
N0
N0
8 1 1 7 0.875
N0 8 8
14
7. Obtain the binding energy (in MeV) of a nitrogen nucleus 7 N , given
m 147 N 14.00307u
14
A nucleus of nitrogen 7 N contains 7 protons and 7 neutrons.
Where,
Mass of a proton, m H 1.007825u
m 0.11236 931.5MeV c2
Where,
c is the speed of light
8. Obtain approximately the ratio of the nuclear radii of the gold isotope
197 107
79 Au and the silver isotope 47 Ag .
Ans: Given,
47 Ag R Ag
Nuclear radius of the silver isotope 107
R Au R Au 3
The ratio of the radii of the two nuclei is:
R Ag R Ag
1
R Au 197 3
1.2256
R Ag 107
Therefore, the ratio of the nuclear radii of the gold and silver isotopes is about
1.23 .
56
Ans: The fission of 26 Fe can be given as:
It is given that:
Atomic mass of m 28
13 Al 27.98191u
Q 55.93494 2 27.98191 c 2
Q 0.02888c2 u
NA
Therefore, 1kg of 239
94 Pu contains m atoms
Mass number
Therefore, 4.536 1026 MeV is released if all the atoms in 1kg of pure 239
94 Pu
undergo fission.
11. Calculate the height of the potential barrier for a head-on collision of two
deuterons. (Hint: The height of the potential barrier is given by the
Coulomb repulsion between the two deuterons when they just touch each
other. Assume that they can be taken as hard spheres of radius 2.0fm. )
Ans: If two deuterons collide head-on then, the distance between their centres is:
d Radius of first deuteron Radius of second deuteron
Radius of a deuteron nucleus 2f m 2 1015 m
e2
Potential energy of the two-deuteron system: V
40d
Where,
0 is the Permittivity of free space
1
9 109 Mm 2c 2
40
9 10 1.6 1019
2
V J
4 1015
V eV
4 1015 1.6 1019
V 360keV
Therefore, the height of the potential barrier of the two-deuteron system is
360keV .
1 1 1
R 2 2 , n 3,4,5,.....
2 ni
1 1 1
R 2 2
1 2 3
1 1 1
R
1 4 9
36
1 ........ (1)
5R
For first member of Lyman series
1 1 1
R 2 2
1 ' 1 2
1 1
R 1
1 ' 4
1 ' 4 5R
1 3R 36
5
1 ' 1
27
5
1 ' 6563
27
1 ' 1215.4A
Therefore, the wavelength of first member of Lyman series is 1215.4A .
Mass of reactants m 01 n m 63 Li =
4. State radioactive decay law and hence derive the relation N N0et
where symbols have their usual meanings.
Ans: From the radioactive decay law, the rate of disintegration of a radioactive
substance at an instant is directly proportional to the number of nuclei in the
radioactive substance at that time i.e.
K log e N 0
m
log e N log e N 0 t loge m log e n log e
n
N
log e t
0
N
N
e t
N0
N N0et
Hence derived.
5. Define half life and decay constant of a radioactive element. Write their
S.I. unit. Define expression for half life.
Ans: The time during which half of the atoms of the radioactive substance
disintegrate is called half life of a radioactive substance.
0.6931
T1
2
S.I. unit – second s
Radioactive decay constant is the reciprocal of the time during which the
number of atoms in the radioactive substance reduces to 36.8% of the original
number of atoms in it.
6. Draw a curve between mass number and binding energy per nucleon. Give
two salient features of the curve. Hence define binding energy.
Ans: The total energy required to disintegrate the nucleus into its constituent
particles is called binding energy of the nucleus.
7.
Abundance of 63 Li , 1 7.5%
Abundance of 73 Li , 2 92.5%
m11 m22
The atomic mass of lithium atom, m
1 2
b) Boron has two stable isotopes, 105 B and 115 B . Their respective masses are
10.01294u and 11.00931u , and the atomic mass of boron is 10.811u . Find
the abundances of 105 B and 115 B .
Abundance of 105 B , 1 x%
56 209
8. Obtain the binding energy of the nuclei 26 Fe and 83Bi in units of MeV
from the following data: m 56
26 Fe 55.934939u , m
209
83 Bi 208.980388u
Atomic mass of 56
26 Fe , m1 55.934939u
56
26 Fe nucleus has 26 protons and 56 26 30 neutrons
Where,
Mass of proton, m H 1.007825u
Where,
c is the speed of light
MeV
E b1 0.528461 931.5 2 c2
c
E b1 492.26MeV
492.26
Average binding energy per nucleon 8.79MeV
56
Where,
Where,
c is the speed of light
MeV
E b2 1.760877 931.5 2 c2
c
E b2 1640.26MeV
1640
Clearly, average binding energy per nucleon 7.848MeV
209
9. A given coin has a mass of 3.0g . Calculate the nuclear energy that would
be required to separate all the neutrons and protons from each other. For
simplicity assume that the coin is entirely made of 63
29 Cu atoms (of mass
62.92960 u ).
Ans: It is given that,
Mass of a copper coin, m' 3g
Atomic mass of 63
29 Cu atom, m 62.92960 u
N A m'
The total number of 63
29 Cu atoms in the coin, N
Mass number
Where,
6.023 1023 3
N 2.868 1022 atoms
63
63
29 Cu nucleus has 29 protons and 63 29 34 neutrons
Where,
Mass of proton, m H 1.007825u
m 1.69766958 1022 u
MeV
It is known that, 1u 931.5
c2
MeV
m 1.69766958 1022 931.5
c2
Where,
c is the speed of light
MeV 2
E b 1.69766958 1022 931.5 c
c2
E b 2.5296 1012 J
Clearly, energy required to separate all the neutrons and protons from the given
coin is 2.5296 1012 J .
a) -decay of 226
88 Ra
b) -decay of 242
94 Pu
c) -decay of 32
15 P
d) -decay of 210
83 Bi
f) -decay of 97
43Tc
120
g) Electron capture of 54 Xe
Ans: 120
54 Xe e 120
53 I
11. A radioactive isotope has a half-life of T years. How long will it take the
activity to reduce to
a) 3.125%
Ans: Let the half-life of the radioactive isotope be T years.
Original amount of the radioactive isotope be N 0
N 3.125 1
3.125%
N0 100 32
N
It is known that, et
N0
Where,
is the Decay constant
N 1
1%
N0 100
N
It is known that, et
N0
Where,
is the Decay constant
t is the Time
1
et
100
t ln1 ln100
The decay rate of the specimen obtained from the Mohenjodaro site:
R ' 9decays / min
0.5108
t 4223.5
0.693
5730
Therefore, the approximate age of the Indus-Valley civilisation is 4223.5 years.
60
13. Obtain the amount of 27 Co necessary to provide a radioactive source of
60
8.0 mCi strength. The half-life of 27 Co is 5.3 years.
dN
Ans: The strength of the radioactive source is 8.0mCi
dt
dN
8 103 3.7 1010
dt
dN
29.6 107 decay s
dt
Where,
N is the required number of atoms
T1 5.3 365 24 60 60
2
T1 29.6 108 s
2
1 dN
N
dt
29.6 107
N 7.133 1016 atoms
0.693
29.6 108
For 60
27 Co : Mass of 6.023 1023 (Avogadro's number) atoms 60g
60 7.133 1016
∴Mass of 7.133 1016 atoms 7.106 106 g
6.023 10 23
Half -life of 90
38 Sr , T1 28years
2
T1 28 365 24 60 60
2
T1 8.83 108 s
2
90g of 90
38 Sr atom contains 6.023 1023 (Avogadro's number) atoms.
15. Find the Q-value and the kinetic energy of the emitted α-particle in the
α-decay if m 226
88 Ra 226.02540 u , m 222
86 Rn 222.01750 u ,
m 220
86 Rn 220.01137 u , m 84 Po 216.00189 u of
216
226
a) 88 Ra
m 226
88 Ra 226.02540 u
m 222
86 Rn 222.01750 u
m 42 He 4.002603 u
Q 0.005297uc2
MeV
It is known that, 1u 931.5
c2
Q 0.005297 931.5 4.94MeV
b) 220
86 Rn
It is given that:
Mass of m 220
86 Rn 220.01137 u
Mass of m 216
84 Po 216.00189 u
220 4
Kinetic energy of the α-particle 6.41
220
K.E 6.29MeV
Therefore, Q-value is 641MeV and Kinetic Energy is 6.29MeV .
The change in the Q-value Q of the nuclear masses of the 116 C nucleus is
Q 0.001033c2 u
MeV
It is known that, 1u 931.5
c2
Q 0.001033 931.5 0.962MeV
It is known that, Q E d E e E
17. The nucleus 2310 Ne decays by emission. Write down the decay
equation and determine the maximum kinetic energy of the electrons
emitted. Given that: m 23
10 Ne 22.994466 u , m 11 Na 22.989770 u .
23
Ans: During emission, the number of protons increases by 1 , and one electron
and an antineutrino are emitted from the parent nucleus.
It is given that:
Atomic mass of m 23
11 Na 22.989770 u
Q 22.994466 22.989770 c2
Q 0.004696c2 u
MeV
It is known that, 1u 931.5
c2
Q 0.004696c2 u 931.5
MeV
4.374 MeV
c2
It is given that,
Q 0.00433 c 2 u
MeV
It is known that, 1u 931.5
c2
MeV
Q 0.00433 c2 931.5 4.0334MeV
c2
The negative Q-value of the reaction shows that the reaction is endothermic.
b) 126 C 126 C 20
10 Ne 2 He
4
It is given that,
Atomic mass m 20
10 Ne 19.992439u
Q 0.004958 c 2 u
MeV
It is known that, 1u 931.5
c2
MeV
Q 0.004958 c2 931.5 4.618377MeV
c2
The positive Q-value of the reaction shows that the reaction is exothermic.
19. A 1000MW fission reactor consumes half of its fuel in 5.00y . How much
235
92 U did it contain it initially? Assume that the reactor operates 80% of
the time, that all the energy generated arises from the fission of 235
92 U and
that this nuclide is consumed only by the fission process.
Ans: It is given that,
Half life of the fuel of the fission reactor, t 1 5years
2
235
It is known that in the fission of 1g of 92 U nucleus, the energy released is equal
to 200MeV
20. How long can an electric lamp of 100W be kept glowing by fusion of
2.0kg of deuterium? Take the fusion reaction as
2
1 H 21 H 23 He n 3.27MeV .
6.023 1023
2kg of deuterium contains 2000 6.023 1026 atoms
2
It can be concluded from the given reaction that when two atoms of deuterium
fuse, 3.27MeV energy is released.
Thus, total energy per nucleus released in the fusion reaction:
3.27
E 6.023 1023 MeV
2
3.27
E 6.023 1023 1.6 1019 106
2
E 1.576 1014 J
Power of the electric lamp, P 100W 100 J / s
Hence, the energy consumed by the lamp per second 100J
The total time for which the electric lamp will glow is:
1.576 1014
4.9 104 years
100 60 60 24 365
21. For the (positron) emission from a nucleus, there is another competing
process known as electron capture (electron from an inner orbit, say, the
K - shell, is captured by the nucleus and a neutrino is emitted).
e AZ X ZA1Y . Show that if emission is energetically allowed,
electron capture is necessarily allowed but not vice -versa.
Ans: Let the amount of energy released during the electron capture process be
Q1 . The nuclear reaction can be written as: e AZ X ZA1Y Q1 ...... (1)
Let the amount of energy released during the positron capture process be Q 2 . The
nuclear reaction can be written as: AZ X ZA1Y e Q1 ...... (2)
Q1 m AZ X Zm m m ZA1Y Z 1 m c2
Q2 m N AZ X m N ZA1Y m c2
Also, this means that if emission is energetically allowed, then the electron
capture process is necessarily allowed, but not vice-versa. This is because the Q-
value must be positive for an energetically-allowed nuclear reaction.
Abundance of 25
12 Mg , 2 x %
Abundance of 26
12 Mg , 3 100 x 78.99 % 21.01 x %
21.01 x % 11.71%
25 26
Therefore, the abundance of 12 Mg is 9.3% and that of 12 Mg is 11.71%.
, m 27
13 Al 26.981541 u
Ans: For 41
20 Ca : Separation energy 8.363007MeV
For 27
13 Al : Separation energy 13.059MeV
It is given that,
Mass m 40
20 Ca 39.962591 u
Mass m 20
41
Ca 40.962278 u
Mass m 01 n 1.008665u
It is given that:
Mass m 26
13 Al 25.986895 u
Mass m 27
13 Al 26.981541 u
33
15 P nucleus decay is 10% of the total amount of decay.
33 32
The source has initially 10% of 15 P nucleus and 90% of 15 P nucleus.
32 33
Suppose after t days, the source has 10% of 15 P nucleus and 90% of 15 P nucleus.
Initially:
Number of 33
15 P nucleus N
Number of 32
15 P nucleus 9N
Finally:
Number of 33
15 P nucleus 9N '
Number of 32
15 P nucleus N '
t
N ' 1 T1 2
For 32
15 P nucleus, the number ratio is:
9N 2
t
1 T1 2
N' 9N
2
t
N' 9N 2 14.3 ....... (1)
t
9N ' 1 T1 2
For 33
15 P nucleus, the number ratio is:
N 2
t
1 T1 2
9N' N
2
t
9N' N 2 25.3 ....... (2)
t t
1
On dividing equation (1) by equation (2) : 9 2 25.3 14.3
9
t t
log81 log 2
14.3 25.3
88 Ra 82 Pb 6 C
Ans: Considering a 146 C emission nuclear reaction: 223 209 14
It is known that,
Mass of 223
88 Ra , m1 223.01850u
Mass of 209
82 Pb , m 2 208.98107 u
Q 0.03419c2u
MeV
It is known that, 1u 931.5
c2
It is known that:
Mass of 223
88 Ra , m1 223.01850u
Mass of 219
86 Rn , m 2 219.00948 u
Mass of 42 He , m3 4.00260 u
Q 0.00642c 2 u
MeV
It is known that, 1u 931.5
c2
Q 0.00642c2 931.5
MeV
c2
Q 5.98 MeV
Therefore, the Q-value of the second nuclear reaction is 5.98 MeV . Since the
value is positive, the reaction is energetically allowed.
26. Consider the fission of 238 92 U by fast neutrons. In one fission event, no
neutrons are emitted and the final end products, after the beta decay of
the primary fragments, are 140 99
58 Ce and 44 Ru . Calculate Q for this fission
process. The relevant atomic and particle masses are
92 U 238.05079 u , m 58 Ce 139.90543 u , m 44 Ru 98.90594 u
m 238 140 99
It is given that:
92 U , m1 238.05079 u
Mass of a nucleus 238
Mass of a nucleus 99
44 Ru , m3 98.90594 u
Q m' 238
92 U m 0 n m' 58 Ce m' 44 Ru 10m c
1 140 99
2
Where,
m' Represents the corresponding atomic masses of the nuclei
m' 238
92 U m1 92m
m ' 140
58 Ce m 2 58m
m' 99
44 Ru m 3 44m
m 01 n m 4
Q m1 m 4 m 2 m3 c 2
Q 0.247995c 2 u
MeV
It is known that, 1u 931.5
c2
m 21 H 2.014102 u , m 31 H 3.016049 u
It is given that:
Mass of 21 H , m1 2.014102 u
Mass of 31 H , m 2 3.016049 u
Mass of 42 He , m3 4.002603 u
Mass of 01 n , m 4 1.008665 u
Q 0.018883 c2 u
MeV
It is known that, 1u 931.5
c2
MeV
Q 0.018883 c2 931.5
c2
Q 17.59MeV
Therefore, the energy released is 17.59MeV .
e2
Therefore, the repulsive potential energy between the two nuclei is: V
40 d
Where,
0 Permittivity of free space
1
9 109 Nm2C2
40
V 15
5.76 1014 J
4 10
5.76 1014
V 19
3.6 105 eV 360keV
1.6 10
Therefore, 5.76 1014 J or 360keV kinetic energy (KE) is needed to overcome
the Coulomb repulsion between the two nuclei.
It is given that,
3
K.E. 2 kT
2
5.76 1014
T 23
1.39 109 K
3 1.38 10
Therefore, the gas must be heated to a temperature of 1.39 109 K to initiate the
reaction.
Within the sun, four 11 H nuclei combine and form one 42 He nucleus. In this process
26MeV of energy is released.
Therefore, the energy released from the fusion of 1kg is:
235
b) the fission of 1.0kg of 92 U in a fission reactor.
Amount of 235
92 U , m 1kg 1000g
6 10 200 1000
E2 5.106 1026 MeV
235
Therefore, the energy released is 5.106 1026 MeV .
E1 39.1495 1026
7.67 8
E2 5.106 1026
Therefore, the energy released in the fusion of 1kg of hydrogen is nearly 8 times
the energy released in the fission of 1kg of uranium.
P1 2 104 MW
P1 2 104 106 J / s
235 103
Mass of 78840 10 atoms of
24 235
U 78840 1024
6.023 10 23